Synthesis, crystal structure and X-ray powder diffraction data of the phosphor matrix 4SrO·7Al2O3

The white phosphor matrix 4SrO·7Al₂O₃ has been synthesized by firing the appropriate mixture of SrCO₃, Al(OH)₃ and H₃BO₃ in the molar ratios 1:3.5:0.135 at 1300°C for 4–7 h. The crystal structure of 4SrO·7Al₂O₃ has been determined as a orthorhombic Pmma space group with a=24.7451(2)Å, b=8.4735(6)Å, c=4.8808(1)Å, V=1023.41(3)ų, Z=2, and D=3.66 g cm^–3 by the Rietveld analysis. The refinement figures of merit are R_p=8.26, R_wp=11.60, R_bragg=4.44 and s=2.61 for 844 reflections with 2<119.94°. And the corresponding X-ray powder diffraction data are presented for search/match analysis.     

An energy approach to crack closure

Crack closure is analyzed using an energy approach whereby it is shown that crack closure does not completely shield the input mechanical energy to the crack tip at a load below the crack opening load P _op if the compliance below P _op is non-zero. An equivalent shielding stress intensity range is defined by the energy release rate against crack closure. From this energy standpoint, the true effective stress intensity range should be defined as K _eff=K _max–K _op, where is the shielding factor. The conventional definition (K _eff=K _max–K _op) is equivalent to the new definition only when the compliance below P _op is zero such that =1, i.e., for a fully closed crack. The corrected K _eff is found to be effective in correlating fatigue crack growth rates (FCGRs) generated in 8090-T8771 aluminum-lithium alloy with and without crack closure. In contrast, the conventional K _eff fails to reconcile the FCGR data within an acceptable scatter band.The Canadian Government's right to retain a non-exclusive, royalty-free licence in and to any copyright is acknowledged.     

Toughening of titanium alloys by twinning and martensite transformation

Two kinds of titanium alloys, titanium alloy (Ti-10V-2Fe-3Al) and titanium alloy (Ti-5Al-2.5Sn) were used to investigate the toughening mechanisms with new approaches. The results show that Ti-5Al-2.5Sn alloy possesses good combination of strength and ductility as well as satisfied low-cycle fatigue life both at 293 K and 77 K. As for Ti-10V-2Fe-3Al alloy, the microstructure with metastable phase shows lower strength and ductility but higher threshold stress intensity factor (K _th) than solution treated and aged microstructure composed of and phases. The microstructures also show that twinning occurs in deformation of Ti-5Al-2.5Sn alloy at 77 K. Twinning seems to be helpful for improving the low-cycle fatigue life to a great extent at cryogenic temperature. It's also found that owing to stress-assisted martensite transformation in metastable Ti-10V-2Fe-3Al alloy, the fatigue crack propagation path shows a very tortuous way, which decrease the effective stress intensity factor (K _eff) at crack tip, and increase threshold stress intensity factor (K _th).     

The significance of RPG load for fatigue crack propagation and the development of a compliance measuring system

In can be postulated that fatigue crack does not grow if no damage occurs in the vicinity of the crack tip. Damage may occur beyond the Re-tensile Plastic zone's Generated load (RPG load) in the vicinity of a crack tip under loading process. We propose an effective stress intensity factor range ( K _RP) corresponding to the period in which the re-tensile plastic zone appears, in place of K _eff proposed by Elber [1], for a fatigue crack propagation parameter.We then consider the small change of compliance for a cracked body under cyclic loading, for the purpose of measuring RPG load as well as crack opening load and crack closing load. Moreover a subtraction circuit which can measure the small change of compliance during fatigue test is developed and an automatic controlled system which can control the adequate values of resistance in the circuit and the output voltage range from strain amplifiers for minimizing relative noise level is also developed. Then fatigue crack propagation tests of CT specimens were carried out with various stress ratios of constant amplitude loadings. Moreover K _th tests with the conditions of constant stress ratio and constant maximum load with increasing stepwise minimum load were also carried out. It becomes clear that the logarithmic curve of K _RP—crack propagation rate appears to be linear in a wide range from the region of very slow growth rate to the region of stable growth rate. On the other hand, threshold phenomenon appears only circumstantially due to the particular loading pattern on K _eff based on the crack opening load and K _eff ^cl based on the crack closing load. Moreover K _RP gives the quantitative effect of stress ratio on fatigue crack propagation rate.     

Slow crack growth analysis of brittle materials with finite thickness subjected to constant stress-rate flexural loading

A two-dimensional, numerical analysis of slow crack growth (SCG) was performed for brittle materials with finite thickness subjected to constant stress-rate (dynamic fatigue) loading in flexure. The numerical solution showed that the conventional, simple, one-dimensional analytical solution can be used with a maximum error of about 5% in determining the SCG parameters of a brittle material with the conditions of a normalized thickness (a ratio of specimen thickness to initial crack size) T>3.3 and of a SCG parameter n10. The change in crack shape from semicircular to elliptical configurations was significant particularly at both low stress rate and low T, attributed to predominant difference in stress intensity factor along the crack front. The numerical solution of SCG parameters was supported within the experimental range by the data obtained from constant stress-rate flexural testing for soda-lime glass microslides at ambient temperature.     

The unzipping model of fatigue crack growth and its application to a two-phase steel

The unzipping analysis, based on the alternate shear deformation process of two intersecting shear planes at a crack tip, is extended to study fatigue crack growth in a two-phase martensitic-ferritic steel. The unzipping crack increment a _uz is directly related to K and J in the case of small scale yielding. It is preferrable to use a _uz is directly related to K and J in the case of small scale yielding. It is preferable to use a _uz as a physical parameter to correlate with the growth rates of micro-cracks and fatigue cracks in a multi-phase material. In the case of micro-cracks, K is often not applicable because of extensive plastic deformation; and in the case of multi-phase material, neither K nor J is applicable because of material inhomogeneity. The effective K, K _eff, is defined in terms of a _uz. The relations between the endurance limit of a two-phase steel and crack nucleus size, ferrite layer thickness, the constraint by the strong martensite on crack tip deformation in the ferrite domain, and K _th's of the martensite and ferrite are analyzed.

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Résumé Une analyse de rupture progressive et continue des liaisons, basée sur un processus de déformation de cisaillement alterné de deux plants de cisaillement s'intersectant à l'extrémité d'une fissure, a été étendue à l'analyse de la propagation des fissures de fatigue dans un acier martensito-ferritique à deux phases. L'accroissement de la fissure a est directement en relation avec K et J dans le cas de déformation plastique de faible étendue. II est préférable d'utiliser a comme paramètre physique en corrélation avec les vitesses de croissance de microfissures et des fissures de fatigue dans un matériau à phases multiples. Dans le cas de microfissures, K n'est souvent pas applicable en raison de la déformation plastique importante. Dans le cas de matériau multiphase ni K ni J ne sont applicables en raison de l'inhomogénéité du matériau. La valeur effective K _eff est définie en terme de a. Les relations entre la limite d'endurance d'un acier à deux phases et la taille du nodule de fissuration, l'épaisseur de la couche de ferrite, la contrainte qu'exerce une zone martensitique dure sur le domaine ferritique, sur la déformation à l'extrémité de la fissure en domaine ferritique, et les valeurs de K de la martensite et de la ferrite sont analysées.

     

Effect of crack shape,inclination angle,and friction coefficient in crack surface contact problems

In rolling/sliding contact fatigue, it is known that the crack propagates at a characteristic angle =15–30 deg to the surface. To analyze the mechanism, however, the body force method has been widely used assuming 3D crack models for =45–90. In this study, therefore, the unknown body force densities are newly approximated by using fundamental density functions and polynomials. Then, a semi-elliptical crack model is analyzed for =15–90 under compressive residual stresses and Hertzian contact loads. The stress intensity factors K _II, K _III are calculated with varying the crack shape b/a, inclination crack angle , and crack face friction coefficient . The calculations show that the present method is useful for the analysis for =15–30 deg with high accuracy. It is seen that the K _II-values when b/a0 are larger than the ones when b/a=1 by 0–24% for both under compressive residual stress and Hertzian contact load. Regarding the maximum K _II values under Hertzian contact load, the results of =15 deg are smaller than the ones of =45 deg by 23–34%. Regarding the amplitude of (K _{II max}–K _{II min}), the results of =15 deg are smaller than the ones of =45 deg by 4–24%. With increasing the value of friction coefficient for crack faces the value of K _II decreases significantly. When the crack is short and the inclination angle is small, the value of friction coefficient f for Hertzian contact load largely affect the K _II value.     

Temperature effects on the properties of Ge thin films

The effects of substrate temperature (T_s) on the properties of vacuum evaporated p-type Ge thin films have been investigated for 25s<400°C. Increase in the substrate temperature improves the crystallinity and increases the grain size resulting a gradual change from amorphous to polycrystalline structure which was attained above a substrate temperature of 225°C. Low resistive (1×10^–2 ohm-cm) and high mobility (280 cm²/V·s) films were obtained at T_s=400°C. It has been observed that the conduction mechanism in polycrystalline films was dominated successively by hopping, tunneling and thermionic emission as the sample temperature was increased from 40 to 400 K. In amorphous samples, conduction was described in terms of different hopping mechanisms.     

Dielectric and Magnetic Properties of Pb(Fe1 /2Nb1 /2)O3–Pb(Fe2 /3W1 /3)O3Solid Solutions

Pb(Fe_1/2Nb_1/2)O₃–Pb(Fe_2/3W_1/3)O₃solid solutions were characterized by dielectric measurements at low frequencies and in the microwave range and magnetic measurements at high frequencies. The observed microwave dispersion was tentatively attributed to the domain mechanism of polarization. The obtained results suggest that the solid solutions studied are potential microwave-absorbing materials.     

Zr surface diffusion in tetragonal yttria stabilized zirconia

The value for surface diffusivity of Zr tetragonal ZrO₂–3mol% Y₂O₃ has been calculated from measurements of surface area reduction and pore growth in powder compacts during sintering. The surface diffusivity thereby obtained can be described by D =5.52×10⁵ exp[–531(kJ mol^-1)/RT] m²/s, which is in reasonable agreement with values calculated by prior researchers from direct TEM observation of neck growth between touching particles.     

Calculated evaluations of the threshold characteristics for ferritic-pearlitic steels

On the basis of modern physical concepts of the process of formation of the prefailure zone and rules of the change in microcleavage resistance during deformation within the limits of the deformation theory of plasticity relationships of the threshold criteria of fracture to the standard mechanical properties _t, _0.2, and _K were obtained analytically. It was shown that the resistance to crack advance in ferritic-pearlitic steels is determined by the strain hardening exponent. A method of analytical determination of the constant relating the two basic threshold characteristics K_th and _th was developed.Translated from Problemy Prochnosti, No. 4, pp. 50–56, April, 1992.     

Thermodynamic properties of antiferromagnetic superconductors containing nonmagnetic,magnetic, and spin-orbit impurities

Effects of all types of impurities (nonmagnetic, magnetic, and spin-orbit) on an antiferromagnetic superconductor (AFSC) have been investigated by studying the transition temperatureT _c and the specific heat jump. We have assumed a one-dimensional electron band. The impurity scattering is treated within the self-consistent Born approximation. We find that: (a) the molecular fieldH _Q and the magnetic impurities depress superconductivity of AFSC and their pair-breaking effect is additive; (b) the effect of spin-orbit impurities is the same as that of nonmagnetic impurities—these enhance superconductivity by screening the molecular field; and (c) in the extreme dirty limit, the AFSC is described in terms of an effective pair-breaking parameter given by 1/_eff=1/₂+H _Q ² where 1/=1/₁+2/3_so(1/₁, 1/₂, and 1/_so, respectively, are the scattering rates from nonmagnetic, magnetic and spin-orbit impurities).     

Synthesis of SrCu1 /3Nb2 /3O3 from Strontium Cuprates and Niobates

The formation of the perovskite phase SrCu_1/3Nb_2/3O₃ in solid-state reactions between different strontium cuprates and niobates is studied. The effect of the starting reagents on the rate of SrCu_1/3Nb_2/3O₃ formation is analyzed. The reactions with the participation of SrCuO₂ are shown to proceed at a faster rate than those involving Sr₂CuO₃. The presence of excess SrO leads to the formation of by-products. Large strontium excesses inhibit the reaction.     

Modeling of crack bridging in a unidirectional metal matrix composite

The effective fatigue crack driving force and crack opening profiles were determined analytically for fatigue tested unidirectional composite specimens exhibiting fiber bridging. The crack closure pressure due to bridging was modeled using two approaches; the fiber pressure model and the shear lag model. For both closure models, the Bueckner weight function method and the finite element method were used to calculate crack opening displacements and the crack driving force. The predicted near crack tip opening profile agreed well with the experimentally measured profiles for single edge notch SCS-6/Ti-15-3 metal matrix composite specimens. The numerically determined effective crack driving force, K _eff, was calculated using both models to correlate the measured crack growth rate in the composite. The calculated K _eff from both models accounted for the crack bridging by showing a good agreement between the measured fatigue crack growth rates of the bridged composite and that of unreinforced, unbridged titanium matrix alloy specimens.     

Liquidus Relations in the Na2WO4–LiPO3–WO3System

The liquidus relations in the Na₂WO₄–LiPO₃–WO₃system (diagonal section of the quaternary mutual system Li,Na||PO₃,WO₄,WO₃) were studied by thermal analysis at WO₃contents of 60 mol %. The results demonstrate that, in the composition region studied, the liquidus surface comprises the primary-crystallization fields of Na₂WO₄, LiPO₃, and the congruently melting compounds Na₂WO₄· WO₃, 3LiPO₃· WO₃, Na₂WO₄· NaPO₃, and 2Li₂WO₄· LiPO₃. The low-melting compositions revealed in the system studied are of interest for the preparation of Li _x Na _y WO₃bronzes.     

Fatigue crack growth behaviour of tungsten carbide-cobalt hardmetals

Fatigue crack propagation studies have been carried out on a range of WC-Co hardmetals of varying cobalt content and grain size using a constant-stress intensity factor double torsion test specimen geometry. Results have confirmed the marked influence of mean stress (throughK _max), which is interpreted in terms of static modes of fracture occurring in conjunction with a true fatigue process, the existence of which can be rationalized through the absence of any frequency effect. Dramatic increases in fatigue crack growth rate are found asK _max approaches that value of stress intensity factor ( 0.9K_IC) for which static crack growth under monotonic load (or static fatigue) occurs in these materials. Lower crack growth rates, however, produce fractographic features indistinguishable from those resulting from fast fracture. These observations, and the important effect of increasing mean free path of the cobalt binder in reducing fatigue crack growth rate, can reasonably be explained through a consideration of the mechanism of fatigue crack advance through ligament rupture of the cobalt binder at the tip of a propagating crack.     

Application of Raman in phase equilibrium studies: the structures of substitutional solid solutions of KNO3 by RbNO3

Raman spectroscopy was employed to investigate the KNO₃-RbNO₃ system. Raman studies indicated that Rb⁺ may substitute K⁺ up to 67 mol% in the solid solutions of the KNO₃ II structure (denoted as K_1–x Rb_xNO₃ (KII)) and up to 80 mol% in the solid solutions of the KNO₃ III structure (denoted as K_1+x Rb_xNO₃ (KIII)). The substitutional crystals retained the transitions of I to III to II of KNO₃ on cooling and the metastable property of KNO₃ III at room temperature. It was found that rubidium nitrate had a considerable tendency to have the structure of potassium nitrate. This accounts for the fact that larger rubidium ions can replace many more smaller potassium ions in the nitrate than vice versa. When the concentration of rubidium ions was more than 67 mol%, the substituted crystals underwent the mixed structural phase transition of the KNO₃ III structure to the RbNO₃ IV structure, and K_1–x Rb_xNO₃ (KIII) seemed to consist of disordered R3m microstructure.     

Liquid phase sintering of RE2O3: YSZ ceramics Part I Grain growth and expelling of the grain boundary glass phase

Experiments on silicate liquid phase sintering of YSZ ceramics with addition of 0.5 mol% of rare earth ions have been done in order to study the effect of these ions on the kinetics of grain growth and the expulsion of glass through the grain boundaries. Kinetics follow a third power law in the following order YPr>YPrEr>YY>YEr. The expelled glass does not spread over the ceramic grains and its mass is inversely related to grain size. Glass phase separation inside the grain boundaries is found to be a necessary condition for glass expulsion.     

Microstructure and mechanical properties of rapidly quenched L20 and L20+L12 alloys in Ni-Al-Fe and Ni-Al-Co systems

Ductile L2₀-type wires and+L1₂-type duplex wires with high strengths and large elongation in the Ni-Al-Fe and Ni-Al-Co ternary systems have been manufactured directly from the liquid state by an in-rotating-water spinning method. The wire diameter was in the range 80 to 180m and the average grain size was 2 to 4m for the wires and 0.2 to 1.0m for the+ wires. _y, _f and _p of the wires were found to be about 360 to 760 MPa, 560 to 960 MPa, and 0.2 to 5.5%, respectively, for the Ni-Al-Fe system, those of the+ wires were about 395 to 660 MPa, 670 to 1285 MPa, and 3.5 to 17%, respectively, for the Ni-Al-Fe system, and about 260 to 365 MPa, 600 to 870 MPa, and 4.0 to 7.0%, respectively, for the Ni-Al-Co system. Cold-drawing caused a significant increase in _y and _f and the values attained were about 1850 and 2500 MPa, respectively, for Ni-20Al-30Fe and Ni-25Al-30Co wires drawn to about 90% reduction in area. The high strengths, large elongation and good cold-workability of the melt-quenched and+ compound wires have been inferred to be due to the structural change into a low-degree ordered state containing a high density of phase boundaries, suppression of grain-boundary segregation and refinement of grain size.