低阶煤热解提质技术发展现状及趋势研究

本文围绕褐煤资源综合开发利用的问题进行了探讨;对褐煤煤质的特殊性进行了分析;对国内外褐煤提质加工技术进行了分类,简要说明了各类工艺的工作原理和技术特点;重点分析了国内外褐煤干燥热解技术的研究进展和工业应用情况,对工业化示范装置出现的问题进行了评价和总结;分析了制约褐煤发展的主要因素,并指出了未来产业发展的方向和重点.     

碱洗塔洗塔系统的优化

介绍了氯乙烯合成工段碱洗塔洗塔工艺流程,并针对存在的问题对其进行了优化升级,使碱洗塔自控洗塔、配碱,提高了系统的自动化控制水平,节约了水资源,也降低了废水处理系统的负荷,最大限度地提高了碱液的利用率,提高了工作效率,增加了经济效益,     

焦炉生产操作改进

介绍了焦炉生产中的改进措施,通过改进装煤方式,减少了装煤冒烟;配制新型填料,增强了炉体维护;改进了1M管的冲洗方式;改进炉顶水箱槽的高度;降低上升管底座的高度,杜绝连接处冒烟;改进装煤孔底座。通过采取这些改进措施,大大降低了生产成本,改善了职工的操作环境,降低了职工的劳动强度,提高了职工的工作效率,有效地保障了生产的平稳顺行。     

2010年度工作会议

<正>2010年1月16日—17日,公司召开了2010年度工作会议。会议认真回顾总结了2009年的主要工作,分析了当前的形势和机遇,部署了2010年的工作任务。会上,公司董事长蒋明作了重要讲话,总经理毛绍融作了行政工作报告,党委副书记陈百河作了党委工作报告,副总     

关于丁二烯生产技术及使用新途径的研究探讨

文中详细介绍了几中丁二烯的生产工艺并进行了比较，总结出了它们的特点。对各地区丁二烯的生产能力以及消费状况进行了分析，并探究了丁二烯的新用途。     

淀粉的化学改性研究

简要介绍了淀粉的结构及其化学改性的原理和方法;综述了国内外淀粉化学改性的研究工作;详细介绍了非离子淀粉、阴离子淀粉、阳离子淀粉以及两性淀粉的合成方法.淀粉通过化学改性改善了水溶性、大大降低了水不溶物的含量、增加了黏度的稳定性、从而扩大了淀粉的应用领域,使得改性淀粉广泛应用于食品、纺织、造纸、油田和医药等众多领域.     

带式过滤机在多品种氢氧化铝生产中的应用

介绍了带式真空过滤机的工作原理及其在多品种氢氧化铝生产方面的应用情况,并对带式真空过滤机使用过程中存在的问题进行了改造。改造之后,提高了洗涤过滤效率,降低了滤饼水分,降低了能耗,提高了产量,确保了产品质量,取得了较好的经济效益。     

庄信万丰发布《铂金2009年年鉴》

据庄信万丰公司最近出版的《PLATINUM 2009》报道,2008年,全球铂金市场出现了11.7t的短缺,铂金的供应量下降了9.5%,达到了185.7t。汽车尾气净化催化剂行业对铂金的需求下降了8.2%,达到了118.3t。除去回收料,全球首饰行业对铂金原材料的需求下降了6.2%,达到了42.5t。     

分析GPS在油田井位测量上的应用

我国科学技术的不断发展,推动了我国GPS技术的不断进步,在我国多个领域获得了应用,实现了我国国民经济的快速、高效的增长。GPS在我国油田井位测量中的应用,大大提高了工作人员的工作效率,且保证了油田井位测量结果的准确性。本文先是对GPS全球定位系统进行了概述,又详细阐述了GPS技术在井位测量中的建立,后分析介绍了GPS全球定位系统的其它应用。     

对羟基苯甲醛合成技术研究及应用进展(待续)

叙述了对羟基苯甲醛的合成方法,对比了各种方法的优缺点,着重介绍了Reimer-Tiemann法和对甲酚催化氧化法;简述了对羟基苯甲醛参与的主要反应,讨论了羟基和醛基参加的反应.     

A Review of Contemporary Views of Theories of Adhesion

The once distinct and independent theories of adhesion have been losing their isolation and converging. Ideas of the effects of surface roughness, once dismissed as irrelevant except in the case of textiles, have been revised; albeit on a smaller scale as details of surfaces have been revealed by sophisticated techniques. Electrostatic interactions across an interface have been more deeply explored and their significance recognised and expounded. Diffusion of groupings and chain segments within a polymer have been related to the possibilities of interaction with a variety of surfaces. Perhaps most important, theories of adsorption have been extended in depth. The precise nature of the molecular interactions have been recognised and quantified. In doing this the contribution of diffusion and elastoplastic phenomena have been integrated. These developments are collated and analysed to present the present understanding of the concepts.     

A Review of Contemporary Views of Theories of Adhesion

The once distinct and independent theories of adhesion have been losing their isolation and converging. Ideas of the effects of surface roughness, once dismissed as irrelevant except in the case of textiles, have been revised; albeit on a smaller scale as details of surfaces have been revealed by sophisticated techniques. Electrostatic interactions across an interface have been more deeply explored and their significance recognised and expounded. Diffusion of groupings and chain segments within a polymer have been related to the possibilities of interaction with a variety of surfaces. Perhaps most important, theories of adsorption have been extended in depth. The precise nature of the molecular interactions have been recognised and quantified. In doing this the contribution of diffusion and elastoplastic phenomena have been integrated. These developments are collated and analysed to present the present understanding of the concepts.     

Study of the kinetics of processes during electrochemical deposition of zirconia from nonaqueous electrolytes

The processes of electrochemical deposition of zirconia from nonaqueous electrolytes on different substrates have been investigated. Cyclic voltammetry and linear sweep voltammetry have been used to investigate the oxygen and hydrogen reduction processes preceding/accompanying the discharge of the zirconium complex being identified. On the basis of simultaneous XPS and SEM analyses, the potential region of zirconia layer formation has been defined. The kinetic parameters of successive and parallel reduction processes have been determined. The factors hindering the formation of thick zirconia layers have been discussed.     

The Application of Biocatalysis in the Preparation and Resolution of Morita-Baylis-Hillman Adducts and Their Derivatives

The Morita-Baylis-Hillman (MBH) reaction affords highly functionalised allylic alcohols containing a new stereogenic centre. These MBH adducts are very versatile and have been transformed into a large range of products, some of which have medicinal potential. Several examples of asymmetric syntheses of MBH adducts have been reported, although a generally applicable method remains to be developed. Biocatalytic approaches for the synthesis and enzymatic kinetic resolution of MBH adducts have been reported, and are discussed in detail in this review. Enzymes able to catalyse the asymmetric MBH reaction have been identified, but selectivity and efficiency have generally been low. Lipases, esterases and nitrile-converting enzymes have all been successfully applied in the resolution of MBH adducts, with excellent selectivity being realised in most cases.     

A function of external doping: Characteristics of inorganic nanostructure based diode

The present study has been related to synthesis and characterization of ZnO films growth by chemical spray pyrolysis technique. Variation in the characteristics of ZnO film has been evaluated as a function of Cobalt content. The influence of cobalt content on structural, morphological, optical and electrical features have been observed by XRD, SEM, AFM, UV–vis spectroscopy and I-V measurement, respectively. Structural measurements of the samples indicate that all samples have polycrystalline nature with (002) preferential orientation. SEM and AFM images have indicated that films have smooth and uniform morphology. Changes in the surface morphology of the samples have been explained by taking Cobalt incorporation into consideration. Optical studies reveal that the band gap values of the samples exhibit decreasing tendency with Cobalt content. Performance of ZnO films in Schottky diode application has been conducted by evaporation Au contact on ZnO:Co films. From I-V curves of the devices, it has been observed that all devices exhibit good rectifying properties. Also, some diode parameters such as ideality factor, barrier height have been calculated by considering thermionic emission theory (TE) and have been found in the range of 1.89–1.57 and 0.57–0.62 eV, respectively. Additionally, these results and series resistance values of the diodes have been checked and calculated by using Cheung's function. Results showed that all diode parameters highly depended on cobalt concentration. All results have been discussed in detail depending on cobalt incorporation.     

微乳液特性及在纳米材料制备中的应用

本文主要介绍了W／O相微乳液的组成、内部结构等特性,并简要分析了其制粉原理及影响因素。并对其在纳米材料制备领域中的应用进行了评述,对其今后的研究方向作了简要推测。     

Investigation of multiphase polymeric systems of PVC

Graft copolymers of chlororubber-20-g-(ethylacrylate-co-acrylonitrile (2:1)) and chlororubber-20-g-(styrene-co-vinyl acetate-co-acrylonitrile [1:1:1]) have been synthesized by solution precipitation polymerization technique. The graft copolymers have been characterized by elemental analysis, IR spectroscopy, and viscometry. The graft copolymers have been melt blended with PVC. The mechanical properties, such as flexural, tensile strength, and impact strength, of the blends have been studied to evaluate the relative performance of various graft copolymer blends of PVC as impact modified systems. Mechanical properties of the blends have been discussed in terms of morphology of impact fractured samples.     

Study of modal parameters and vibration signatures of notched concrete prisms

In the present study, vibration tests have been carried out on notched concrete prisms. The tests have been conducted to study modal parameters and vibration signatures in order to enhance the knowledge of monitoring concrete structures. Notch (artificially introduced crack) of constant widths and varying depths has been introduced in the concrete prisms at different locations. The specimens have been subjected to impact excitations by dropping a specific weight from a fixed height and at a particular location. The natural frequencies of notched and intact prisms have been experimentally measured. The frequency response functions (FRF) as obtained from multichannel pulse analyzer have been synthesized to evaluate the fundamental mode shape of vibration of the prisms by a curve fitting method. These curves have been further post-processed to obtain the modal curvature values. Pattern Recognition Scheme is applied to synthesize vibration signatures for the evaluation of the curvature differential values. The curvature differential values corresponding to different sensor locations in both intact and notched specimens have been obtained. Experimental results with different depth of flaws suggest that natural frequency alone cannot be a reliable parameter for the detection of damage in concrete beams with shallow depth of flaws. The modal curvature values have been found to be a reasonably good indicator of the location of the damage. The curvature differential values show the extent of damage but found to be dependent on the sensor location from the position of notch.     

纯净磷酸盐工艺中三聚氰胺与湿法磷酸反应条件的研究

采用二次正交组合实验设计研究了三聚氰胺反应媒循环法由湿不磷酸生产纯净磷酸二氢析工艺中三聚氰胺与湿法磷磷酸浓度、搅拌速度、反应温度、反应时间、三聚氰胺用量诸因素的一交、二次及交互作用对磷收率、硫和氟净化的影响。找出了相应的数学模型,为复杂反应体系提供了定量描述,根据其数学模型求得磷收率、硫和氟净化率最佳的处理条件。     

Structural,mechanical, and gas barrier properties of poly(ethylene terephthalate) nanohybrid using nanotalc

Amorphous poly(ethylene terephthalate) (PET)/nanotalc nanohybrids have been prepared through solution casting route. The fine dispersion of nanotalc clay in the polymer matrix has been examined through transmission electron microscopy (TEM). The intercalation and interaction of nanoclay have further been confirmed using X-ray diffraction, ultraviolet, and Fourier transform infrared techniques. The thermal stability has been tested via thermogravimetric analysis and nanohybrids have been found thermally stable. The glass-transition temperature has been further confirmed through DTA and differential scanning calorimetry analysis which has been increased in the presence of nanotalc arising from greater interaction. The nanohybrids have been tested for their mechanical performances and have been found to have improved mechanical responses for nanotalc-filled nanohybrids. The modulus has been increased whereas toughness has been compromised meagerly. The modulus values have been theoretically predicted using various micromechanical models. The microhardness of the nanohybrids has been examined through Vicker hardness test. The theoretical prediction of the hardness values has been done using different micromechanical models. The structural development upon uniaxial stretching of the samples has been studied using small-angle X-ray scattering and wide-angle ray diffraction. The stretched samples have found to have short-range ordering as well as increased blob size and better coherency in the presence of nanotalc. The aspect ratio has been increased upon stretching. The inclusion of nanotalc has induced high barrier for gas permeation as compared to pure PET. The oxygen transmission rate has been found to decrease up to 64% for 8 wt % of filler concentration. The prediction of the permeability data has been done using different models considering different aspect ratios. The permeability values have been predicted very closely and nanohybrids have been found suitable for practical applications such as packaging. © 2020 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 137, 48607.