Optimization of early flexural strength of pavement concrete with silica fume and fly ash by the Taguchi method

In this study, an attempt has been made to optimize the early flexural strength of concrete pavement (CP) by using the Taguchi Method. The experiments were designed using an orthogonal array technique in L₁₆ array with four factors, namely, the water/cementitious ratio of 0.30, 0.35, 0.40 and 0.45, four different types of gradations with maximum aggregate size of 32?mm, fly ash (FA) 0%, 5%, 10%, 15% and silica fume (SF) 0%, 10%, 20% and 30% by weight of cement. The response data were analyzed using an analysis of variance (ANOVA) technique by the Taguchi method. According to the ANOVA table, water/cementitious ratio and SF content play significant roles for early flexural strength of CP. Moreover, the optimum conditions were found to be 0.35 water/cementitious ratio, gradation with minimum content of fine aggregates, 5% FA content and 0% SF content at 7 days curing. Maximum flexural strength of 5.31?MPa was achieved at the optimum conditions.     

Sulfate resistance of plugging grouts

Conclusions 1. Plugging clay-cement grouts made from ordinary portland cement are sufficiently stable under the action of extremely aggressive sulfate media, and their use for compacting karstic soil bases can be recommended.2. The sulfate resistance of all grouts increases significantly as a result of addition to them of Na₂SO₄ · 10 H₂O in the amount of 2% with respect to the binder mass.Scientific-Research Institute of Bases and Underground Structures. Translated from Osnovaniya, Fundamenty i Mekhanika Gruntov, No. 5, pp. 21–24, September–October, 1986.     

Distribution and habitat selection of wintering birds in urban environments

Habitat selection of wintering land-birds was studied in 31 human settlements in Finland. A total of 26 wintering bird species representing 5155 individuals were observed. Between-year variation (CV_B%) and short-term fluctuation within one winter (CV_W%) in species richness (CV_B=10% CV_W=15%) were low, as were total numbers of birds (CV_B=22% CV_W=24%) and populations of the most common bird species (CV_B=20–40% CV_W=15–47%). The most abundant bird species (e.g., Passer domesticus, Parus major and Pica pica) occurred in most of the study sites. The total densities of omnivorous birds, sedentary birds and bird species that commonly use feeding tables were higher in a heavily urbanized areas than in moderately or less urbanized areas. According to the Canonical Correspondence Analysis, three corvid species populations, P. domesticus and Columba livia domestica were positively related to human population density. Corvus corone cornix and P. domesticus populations correlated positively with the proportion of the built-up areas in the study plots. The omnivorous diet of these species was a possible reason for their success in urban environments. Dendrocopus major, Parus montanus, Parus cristatus, Parus ater and Certhia familiaris were negatively related to the urbanization axis. These species live mainly in coniferous forest habitats and are probably unable to use deciduous-dominated urban parks in winter time. To attract these species, coniferous trees and shrubs should also be used in park management and planning in northern latitudes. Many species, like Pic. pica, Carduelis chloris and Parus caeruleus, were located at an intermediate place on an urban–forest gradient axis. We suppose that these species are the most probable candidates for colonizing or increasing their abundances in European towns and cities in near the future. All of these species use feeding tables, which help them to adapt to urban environments.     

Effects of salinity on synthesis of DNA, acidic polysaccharide, and growth in the blue-green alga, Gomphosphaeria aponina

A blue-green alga, Gomphosphaeria aponina, was grown in artificial sea water at salinities 20–36%. Fair to good growth was obtained at all salinities, and growth constants (K_e) were obtained. A parabolic relationship was obtained for the growth salinity relationship, e.g. (S−S_max)² = −2p(K_e−K′_e), where S and S_max is the given salinity and the maximum salinity, respectively, for which growth constants K_e and K_e^′ were obtained; p is a constant. The rate of DNA synthesis increased linearly with growth constant above K_e = 0.95 day⁻¹. Linear correlation coefficients were obtained for rate of polysaccharide synthesis and the rate of DNA synthesis, as well as for the rate of DNA synthesis and the rate of synthesis of aponin. The latter is material isolated from G. aponina and has cytolytic activity toward the Florida red tide organism, Gymnodinium breve, an unarmoured dinoflagellate.     

The growth inhibition of planktonic algae due to surfactants used in washing agents

A survey of inhibitory effects of nonionic and anionic surfactants, including a soap, used in washing agents, on the growth on three species of freshwater phytoplankton, Selenastrum capricornutum, Nitzschia fonticola and Microcystis aeruginosa was conducted. Based on the specific growth rate, μu estimated from a short period (2 or 3 days) cultivation of test algae, the growth inhibition was determined using EC₅₀ values where μu in the culture medium with surfactant decreased 50% of that without surfactant.The EC₅₀ values of nonionic and anionic surfactants tested here for S. capricornutum ranged from 2 to 50 mg l⁻¹ and from 10 to 100 mg l⁻¹, respectively. The tolerances of three species of algae tested with three surfactants, LAS, AE (EO:9) and soap, were different and the inhibitory effects were species specific. EC₅₀ values of LAS, AE (EO:9) and soap for S. capricornutum were 50–100, 4–8 and 10–50 mg l⁻¹, respectively. Those for N. fonticola were 20–50, 5–10 and 20–50 mg l⁻¹, and those for M. aeruginosa were 10–20, 10–50 and 10–20 mg l⁻¹, respectively.     

A Taguchi approach for investigation of some physical properties of concrete produced from mineral admixtures

Durability of concrete structures is often liked to the presence (or not) of deleterious chemical species in the environment. Sulfate or acid-bearing environment originating, for instance, from industrial wastes is one of the severe conditions for durability of the concrete. In this paper, laboratory tests were performed to assess the damage caused by chemical attack on high strength concrete mixtures prepared with silica fume (SF) and blast furnace slag (BFS). The “Taguchi method” has been used to determine the optimum conditions required to obtain the physical properties that will yield to the most durable concrete mixtures. Concrete specimens were cured up to 14 days in lime-saturated water at 23±2 °C. After this period, the concrete specimens were immersed in various aggressive solutions until the experimental days. Test variables selected in this investigation were mineral admixture, water-to-binder ratio, curing regime and curing time. Results of the analysis have shown that the most durable mixtures to be the one prepared with 10% SF and 5% BFS. The water–binder (W/B) ratio of this mixture was 0.30 and it was cured in limewater for 120-day period.     

Thermal conductivity and compressive strength of concrete incorporation with mineral admixtures

In this study, the effect of silica fume (SF), class C fly ash (FA), blast furnace slag (BFS), SF+FA, SF+BFS, and FA+BFS on the thermal conductivity (TC) and compressive strength of concrete were investigated. Density decreased with the replacement of mineral admixtures at all levels of replacements. The maximum TC of 1.233 W/mK was observed with the samples containing plain cement. It decreased with the increase of SF, FA, BFS, SF+FA, SF+BFS, and FA+BFS. The maximum reduction was, 23%, observed at 30% FA. Compressive strength decreased with 3-day curing period for all mineral admixtures and at all levels of replacements. However, with increasing of curing period reductions decreased and for 7.5% SF, 15% SF, 15% BFS, 7.5% SF+7.5% FA, 7.5% SF+7.5% BFS replacement levels compressive strength increased at 28 days, 7- and 28-days, 120 days, 28- and 120 days, 28 days curing periods, respectively. Maximum compressive strength was observed at 15% BFS replacement at curing period of 120 days.     

Growth kinetics of the filamentous microorganism Sphaerotilus natans in a model system of a food industry wastewater

Bulking by Sphaerotilus natans has been attributed to several factors such as low dissolved oxygen in the aeration basin, wastes with high C:N ratios and phosphorus limitation; however, the occurrence of bulking has been reported in fruit, vegetable, meat and poultry wastewaters in which the ratio C:N is variable.Growth of S. natans was analyzed in a model system of a food industry wastewater (potato processing waste) that was characterized by HPLC determining that citric acid was the most important identified component. The effect of several carbon sources on S. natans growth was also studied; different C:N ratios were tested in a continuous culture system (chemostat). This strain grew in a mineral medium with citric acid as a sole carbon source, in spite of the contradictory results found in literature. Chemostat studies showed that the medium was carbon-limited when C:N ratios <19 mgCOD (mgN-NH₃)⁻¹. Monod kinetic growth coefficients, determined for this strain in chemostat were: maximum specific growth rate, μ_max=0.301 h⁻¹; Monod constant, K_S=4.6 mgCOD l⁻¹; true biomass growth yield, Y^T_X/S=0.490 mgVSS (mgCOD)⁻¹; endogenous decay rate, k_d=0.011 h⁻¹ and maintenance coefficient, m_S=0.022 mgCOD (mgVSS)⁻¹ h⁻¹. The obtained parameters were compared with literature data and the effect of glucose and citric acid as carbon sources was discussed; these parameters are useful in modeling the growth of S. natans in potato processing wastewaters (or in other effluents under carbon-limiting conditions) especially when citrate is the main component and can be used to control filamentous bulking by metabolic or kinetic selection.     

Temperature and oxygen-nitrogen gas ratios affect fish survival in air-supersaturated water

Juvenile steelhead trout and juvenile chinook, coho and sockeye salmon were tested at different temperatures (8°, 9°, 10°, 12°, 15°, 18° and 20°C) at the same concentration of air-supersaturated water. Supersaturated water concentrations in different tests were 115, 116, 117, 118 and 120% saturation. Increased temperatures caused a significant (P< 0.005) increase in steelhead mortality, a significant increase (P < 0.025) in chinook deaths, but no significant effect on coho or sockeye mortality. Regression model data for steelhead indicate that a 10°C increase in temperature will decrease the time to 50% death by a factor of 2.7, e.g. from 190h at 8°C to 70h at 18°C, when tested at the same total dissolved gas pressure. Effects of different oxygen-nitrogen gas ratios on fish mortality at the same total dissolved gas pressure in supersaturated water were demonstrated with juvenile steelhead trout. Mortality was rapid (time to 50% death in 1–6 h) at 140, 135 and 130% saturation, with fish dying more rapidly as the ratio of oxygen-nitrogen decreased (decrease in O₂, increase in N₂) Mortality patterns were similar at 125%; time to 50% death occurred in 5–20 h, with more rapid deaths occurring as oxygen (O₂/N₂ ratio) was decreased.     

An evaluation of the potential toxicity of treated bleached kraft mill effluent to striped bass (Morone saxatilis walbaum) larvae exposed through metamorphosis to the juvenile stage

Twenty-day-old striped bass (Morone saxatilis) larvae were exposed to a range of treated bleached kraft mill effluent (BKME) concentrations from 0 to 20% effluent by volume (v/v) under continuous flow test conditins. The experimental test concentrations in the 2–20% BKME test aquaria had a BOD₅ which ranged from < 1 to 5 mg l⁻¹, TSS 12–17 mg l⁻¹, and true color 35–416 mg l⁻¹. Bleached kraft mill effluent did not kill larvae exposed to it for 20 days through metamorphosis to the juvenile stage. The BKME did not alter growth in length, weight or condition factor in larvae over the 20-day exposure period as determined by multiple regression analysis. A linear regression analysis on the dry weight data at Day 20 only, however, indicated a trend of decreasing weight with increasing BKME concentration. Effluent-exposed larvae also developed normally during the 20-day study. All individuals examined completed the transformation from postlarvae to juveniles by the age of 40 days.     

Deterioration and Recovery of Metakaolin Blended Concrete Subjected to High Temperature

The deterioration and spalling frequency of metakaolin (MK) blended concrete subjected to high temperature is analyzed and compared with the equivalent silica fume (SF), fly ash (FA) and pure OPC concretes. Normal and high strength concrete mixes incorporating 0–20% MK were prepared and exposed to a series of high temperatures till 800°C. The residual compressive strength, porosity and pore size distribution were determined. It was found that after an increase in compressive strength at 200°C, the MK concrete suffered a more severe loss of compressive strength and permeability-related durability than the corresponding SF, FA, and pure OPC concretes at higher temperatures. Explosive spalling was observed in both normal and high strength MK concretes, and the frequency increased with higher MK contents. It is concluded that the dense micro-structure and low porosity are the main reasons of the poor performance of MK concrete at high temperature. The effect of post-fire curing on the strength and durability recovery of fire-damaged concrete was also investigated. The test results indicated that the post-fire curing, results in substantial strength and durability recovery, and its extent depends upon the types of concrete, exposure temperature, method, and duration of re-curing.     

Fatigue design of welded very thin-walled SHS-to-plate joints under in-plane bending

The existing fatigue design S–N curve for SHS-to-plate T-joints under in-plane bending is given in the Canadian Standard, CAN/CSA-S16.1-M89, in terms of the classification method. That S–N curve is however based on the class of longitudinally loaded plates with welded non-load carrying attachments, which are different from the SHS-to-plate T-joints. The increased use of welded thin-walled (t<4 mm) tubular joints in the road transport and agricultural industry for applications such as lighting poles, traffic sign supports, truck trailers, swing ploughs, haymakers and linkage graders, means that there is a need to develop fatigue design curves for tubular joints where the tube wall thickness is less than 4 mm. This paper aims to determine fatigue design curves for SHS-to-plate T-joints where the thin-walled tubes have a thickness of less than 4 mm. Tube-to-plate T-joints, made up by welding a square hollow section tube to a plate, are tested under fatigue loading. Constant stress-amplitude cyclic loading is applied to these connections as in-plane bending load. Stress concentration factors (SCFs) have been determined from strain distributions obtained using strain gauge measurements. Analysis of the fatigue test data using least squares method is carried out to determine the design curves of the tube-to-plate T-joints under in-plane bending, for both the classification method and the hot spot stress method. A class of 44 is recommended for the classification method. An S_r._hs–N curve is proposed, with a recommended SCF of 2.0 for the hot spot stress method.     

Lake restoration by dilution: Moses lake, Washington

Dilution water, low in macronutrients, was added to Moses Lake on three occasions in 1977 and once in 1978 during the spring-summer period. The addition resulted in reducing the annual average inflow concentration of phosphorus from about 130–140 μg l⁻¹ to 100 μg l⁻¹. The water exchange rate in Parker Horn, which is 8% of the lake volume, increased from about 1% day⁻¹ normally to 7 and 11% day⁻¹ for the May–September period in 1977 and 1978, respectively. Lake water was displaced at a predictable rate in the whole lake as well as the areas proximal to the input, as verified by specific conductance.Improvements in lake quality, compared to values from 1969–70, were rather good with greater reductions in algal biomass occurring than might have been expected to result from the less impressive reductions in total P content. Chlorophyll a decreased by about 60–80% and total P decreased by about 50–60%, depending on the area of the lake. However, Chl a averaged only 15 μg l⁻¹ during May–September 1978, while total P was rather high at 70–80 μg l⁻¹. The fraction of the phytoplankton composed by blue-green algae decreased from 96% in 1970 to 68% in 1977–78. The cause for the effect on biomass and species composition is unknown, but may be related to dilution of blue-green excretory products.A dilution water input of about 6 m³ s⁻¹ continuously during April–September would require 20% less total water and should provide adequate control of eutrophication in at least 30% of the lake volume proximal to the input and Parker Horn. That would provide an exchange rate of 5% day⁻¹ for Parker Horn and should achieve lake water residuals by midsummer of 50%. Two additional inputs to the lake are also proposed as two more phases in the restoration project.     

An appraisal of the effect of biological treatment on the environmental quality of high-yield mechanical pulping effluents

Before biological treatment, the effluents from one CTMP (chemi-thermomechanical pulping) and three TMP (thermomechanical pulping) mills were acutely lethal to fathead minnows (Pimephales promelas) and the water flea Ceriodaphnia with 48-h LC₅₀ values of 2.2 to > 50%. The effluents also caused chronic effects at concentrations of 0.01–5.3%. After biological treatment, effluents from the three TMP mills were not acutely lethal to either test species. Biotreated effluents from the CTMP mill were also not acutely lethal to minnows but were lethal to Ceriodaphnia (48-h LC₅₀: 54–80%). The chronic effects of biotreated effluents occurred at concentrations of 47 to > 100% for fathead minnows and at 5–37% for Ceriodaphnia. Biological treatment also reduced the levels of BOD (>80%), COD (>60%) and wood extractives (>99%).     

Seismic fragility assessment of effectiveness of viscous dampers in R/C buildings under scenario earthquakes

Fragility curves are used to represent the probabilities that the structural damages, under various level of seismic excitation, exceed specified damage states by means of earthquake intensity–damage relations. In this study, the fragility curves have been developed for comparative seismic evaluation of several retrofitting measures by incorporation of fluid viscous (VS) dampers applied to a representative high-rise reinforced concrete (R/C) office building located in Istanbul. In the retrofitting strategies considered, similar type of VS dampers was used and designed to provide the structure with three different effective damping ratios of 10%, 15%, and 20%. In the fragility analysis, a set of 240 artificially generated earthquake ground motions compatible with the design spectrum selected to represent the variability in ground motion was employed to study nonlinear dynamic responses of the structures before and after retrofit. Four damage states: slight, moderate, major, and collapse were defined to express the condition of damage. The fragility curves in this study are represented by lognormal distribution functions with two parameters and developed as a function of peak ground acceleration (PGA), spectral acceleration (S_a), spectral displacement (S_d). Comparison of the fragility curves indicated that the VS dampers were very effective in attenuating seismic structural response under various earthquake ground motions. It was also found that a two-fold reduction in the probability of exceeding damage states might be achieved by introducing passive VS damper systems.     

Testing the potential of aquatic plants to treat abattoir effluent

The potential of 3 genera of emergent aquatic plant species (Typha spp, Phragmites and Scirpus) to ameliorate effluent from a poultry abattoir was evaluated in an experimental trench system. Three plastic-lined trenches containing Typha (two species), Phragmites and Scirpus plants in a gravel substrate were constructed near the abattoir. Effluent was allowed to percolate, with retention times of 2.7–3.6 days, through the trenches. The quality of the inflowing and outflowing effluent was compared by a regular sampling program for suspended solids, conductivity, turbidity, pH, dissolved oxygen, Na, K, Cl, N and P concentrations. The importance of water loss by evapotranspiration was investigated.Comparing the inflow to outflow, each trench system successfully reduced the suspended solids (83–89%), turbidity (58–67%), total nitrogen (14–56%) and total phosphorus (37–61%) concentration of the effluent while maintaining an acceptable pH and in the case of the Phragmites and Scirpus systems oxygenating the anaerobic inflow. Conductivity increased in the Typha and Phragmites trenches. If a correction is made for water lost by evapotranspiration, the three experimental trench systems reduced the nitrogen (42–75%), phosphorus (68–79%), sodium (7–34%), potassium (9–56%) content of the effluent. The chloride content of the effluent in the Phragmites system was increased by 15% but was reduced by 31 and 53% in the Typha and Scirpus systems respectively. The results from this initial experiment give an indication of the relative abilities of the three plant systems to treat the wastewater from the abattoir. Of the three, that containing the Scirpus was superior.     

Flow-induced vibration of two circular cylinders in tandem arrangement. Part 2: Suppression of vibrations

This paper presents an experimental investigation on suppression of cross-flow vibrations of two circular cylinders in tandem arrangement, conducted at the fluid mechanics laboratory of Kitami Institute of Technology, Japan. To suppress the vibrations of the cylinders, tripping wires were deployed, attached symmetrically about the leading stagnation lines of the cylinders. Five spacing ratios were examined, i.e., L/D=0.1, 0.3, 0.8, 2.0 and 3.2 (L is the gap spacing between the two cylinders; D is the diameter of cylinder), which are representative for five Regimes I (0.1≤L/D<0.2), II (0.2≤L/D<0.6), III (0.6≤L/D<2), IV (2≤L/D<2.7) and V (L/D≥2.7), respectively, as classified in Part 1 [Kim et al., 2009. Flow-induced vibrations of two circular cylinders in tandem arrangement (part 1: characteristics of vibration). Journal of Wind Engineering and Industrial Aerodynamics, submitted together for publication]. Tripping wire position θ measured from the leading stagnation lines of the cylinders was changed from 20° to 60° to determine the optimum range of θ for suppressing structural vibrations. The shear layers separated from the two cylinders were investigated based on flow visualization. The main findings are: (i) the flow-induced vibration on the two cylinders depends strongly on θ, (ii) at θ=20–30° the vibrations on both cylinders are almost completely suppressed for all regimes except V, and (iii) for θ≥40° the vibration amplitudes of both cylinders are considerably larger than those of the plain cylinders, particularly at θ=40°, where the vibration of the upstream cylinder becomes divergent.     

Growth responses of selected freshwater algae to trace elements and scrubber ash slurry generated by coal-fired power plants

In laboratory studies, the freshwater algae Ankistrodesmus falcatus, Scenedesmus obliquus, Selenastrum capricornutum, and Microcoleus vaginatus were exposed to potential pollutants from coal-fired power plants, and their growth responses were evaluated. Using a modification of the EPA Algal Assay Procedure Bottle Test, algae were incubated in media containing As(V) as Na₂HAsO₄ · 7H₂O, Cd(II) as CdSO₄, Hg(II) as HgSO₄, Se(VI) as Na₂SeO₄, in solution, and scrubber ash slurry generated at a western U.S. coal-fired power plant complex. First significant inhibition levels as well as algistatic-algicidal levels are reported. The median effective concentration (EC50) values for the potential pollutants ranged from 0.048–30.761 mg l⁻¹ (0.00064–0.41058 M) As(V), 0.005–0.019 mg l⁻¹ (0.00004–0.00017 M) Cd(II), 0.033–0.253 mg l⁻¹ (0.00016–0.00126 M) Hg(II), 0.033–8.511 mg l⁻¹ (0.00042–0.10779 M) Se(VI), and 3.048–15.417% scrubber ash slurry extract (SASE).     

On the idea of ex ante and ex post normalization of biproportional methods

Biproportional methods project a matrix A to give it the column and row sums of another matrix; the result is R A S, where R and S are diagonal matrices. As R and S are not identified, one must normalize them, even after computing, that is, ex post. This article starts from the idea developed in de Mesnard (2002) – any normalization amounts to put constraints on Lagrange multipliers, even when it is based on an economic reasoning, – to show that it is impossible to analytically derive the normalized solution at optimum. Convergence must be proved when normalization is applied at each step on the path to equilibrium. To summarize, normalization is impossible ex ante, what removes the possibility of having a certain control on it. It is also indicated that negativity is not a problem.Received: October 2002/Accepted: June 2003     

The feasibility of using disused water treatment filter beds for rearing carp (Cyprinus Carpio L.) in the U.K.

The feasibility of rearing carp (Cyprinus carpio) at a disused water treatment works in East London (U.K.) was investigated. The 10 ha of filter beds represented an atypical site for carp culture; in order to assess whether in-house aquaculture would enable a Water Authority to gain advantage in cost, availability and disease-free status of stock, a series of trials was undertaken. These enabled comparison of the weight of carp produced in relation to: extensive cultivation, artificial feeding, a range of stock densities and a range of ages and sizes. The filter beds were unsuitable for natural spawning, early fry production and the rearing of first year fish (0⁺ age group). However, growing-on of subsequent stages (i.e. 0⁺ − 1⁺ or 1⁺ − 2⁺) gave good survival (60–80%) and growth rates. Fish stocked at 20 g in April/May reached 200–400 g by September and 1 kg plus, 1 yr later. Production levels of 300–350 kg ha⁻¹ yr⁻¹ without artificial foods (i.e. extensive cultivation) and up to 2.2 tonnes ha⁻¹ yr⁻¹ with supplementary feeding were comparable with mainland European fish farms. These high values reflect the eutrophic nature of this site and successful exploitation of the available secondary production. It was possible to harvest 15,000–20,000 carp yr⁻¹ for restocking. Carp rearing integrated with existing operations and activities on site (e.g. pipe and equipment stores) and represents a novel, alternative use of a semi-redundant site. Cost benefit assessment showed that fish production was economically viable returning nominal profit margins of between £1.10 and £2.06 kg⁻¹ of carp harvested. The resultant cost/benefit ratios per kilogram harvested were 1:1.9 for extensive production (without feeding) and 1:1.34–1.43 when intensive cultivation employing artificial foods was used.