Fuel‐Free Synthetic Micro‐/Nanomachines

Inspired by the swimming of natural microorganisms, synthetic micro‐/nanomachines, which convert energy into movement, are able to mimic the function of these amazing natural systems and help humanity by completing environmental and biological tasks. While offering autonomous propulsion, conventional micro‐/nanomachines usually rely on the decomposition of external chemical fuels (e.g., H₂O₂), which greatly hinders their applications in biologically relevant media. Recent developments have resulted in various micro‐/nanomotors that can be powered by biocompatible fuels. Fuel‐free synthetic micro‐/nanomotors, which can move without external chemical fuels, represent another attractive solution for practical applications owing to their biocompatibility and sustainability. Here, recent developments on fuel‐free micro‐/nanomotors (powered by various external stimuli such as light, magnetic, electric, or ultrasonic fields) are summarized, ranging from fabrication to propulsion mechanisms. The applications of these fuel‐free micro‐/nanomotors are also discussed, including nanopatterning, targeted drug/gene delivery, cell manipulation, and precision nanosurgery. With continuous innovation, future autonomous, intelligent and multifunctional fuel‐free micro‐/nanomachines are expected to have a profound impact upon diverse biomedical applications, providing unlimited opportunities beyond one's imagination.     

Recent Progress on Man‐Made Inorganic Nanomachines

The successful development of nanoscale machinery, which can operate with high controllability, high precision, long lifetimes, and tunable driving powers, is pivotal for the realization of future intelligent nanorobots, nanofactories, and advanced biomedical devices. However, the development of nanomachines remains one of the most difficult research areas, largely due to the grand challenges in fabrication of devices with complex components and actuation with desired efficiency, precision, lifetime, and/or environmental friendliness. In this work, the cutting‐edge efforts toward fabricating and actuating various types of nanomachines and their applications are reviewed, with a special focus on nanomotors made from inorganic nanoscale building blocks, which are introduced according to the employed actuation mechanism. The unique characteristics and obstacles for each type of nanomachine are discussed, and perspectives and challenges of this exciting field are presented.     

Dream Nanomachines

Locomotion on the nanoscale through a fluid environment is one of the grand challenges confronting nanoscience today. The vision is to synthesize, probe, understand, and utilize a new class of motors made from nanoscale building blocks that derive on‐board or off‐board power from in‐situ chemical reactions. The generated mechanical work allows these motors to move through a fluid phase while simultaneously or sequentially performing a task or series of tasks. Such tiny machines, individually or assembled into designed architectures, might someday transport medicine in the human body, conduct operations in cells, move cargo around microfluidic chips, manage light beams, agitate liquids close to electrode surfaces, and search for and destroy toxic organic molecules in polluted water streams. Are these just “nanomachine dreams”, or “dream nanomachines”? Some very recent exciting developments suggest that a world of amazing chemically powered nanomachines will be the way the story unfolds in the not‐too‐distant future!     

Programming Motions of DNA Origami Nanomachines

DNA nanotechnology enables the precise fabrication of DNA‐based machines with nanoscale dimensions. A wide range of DNA nanomachines are designed, which can be activated by specific inputs to perform various movement and functions. The excellent rigidity and unprecedented addressability of DNA origami have made it an excellent platform for manipulating and investigating the motion behaviors of DNA machines at single‐molecule level. In this Concept, power supply, machine actuation, and motion behavior of DNA machines on origami platforms are summarized and classified. The strategies utilized for programming motion behavior of DNA machines on DNA origami are also discussed with representative examples. The challenges and outlook for future development of manipulating DNA nanomachines at the single molecule level are presented and discussed.     

Moving‐least‐squares‐particle hydrodynamics—I. Consistency and stability

The Smooth‐Particle‐Hydrodynamics (SPH) method is derived in a novel manner by means of a Galerkin approximation applied to the Lagrangian equations of continuum mechanics as in the finite‐element method. This derivation is modified to replace the SPH interpolant with the Moving‐Least‐Squares (MLS) interpolant of Lancaster and Saulkaskas, and define a new particle volume which ensures thermodynamic compatibility. A variable‐rank modification of the MLS interpolants which retains their desirable summation properties is introduced to remove the singularities that occur when divergent flow reduces the number of neighbours of a particle to less than the minimum required. A surprise benefit of the Galerkin SPH derivation is a theoretical justification of a common ad hoc technique for variable‐h SPH. The new MLSPH method is conservative if an anti‐symmetric quadrature rule for the stiffness matrix elements can be supplied. In this paper, a simple one‐point collocation rule is used to retain similarity with SPH, leading to a non‐conservative method. Several examples document how MLSPH renders dramatic improvements due to the linear consistency of its gradients on three canonical difficulties of the SPH method: spurious boundary effects, erroneous rates of strain and rotation and tension instability. Two of these examples are non‐linear Lagrangian patch tests with analytic solutions with which MLSPH agrees almost exactly. The examples also show that MLSPH is not absolutely stable if the problems are run to very long times. A linear stability analysis explains both why it is more stable than SPH and not yet absolutely stable and an argument is made that for realistic dynamic problems MLSPH is stable enough. The notion of coherent particles, for which the numerical stability is identical to the physical stability, is introduced. The new method is easily retrofitted into a generic SPH code and some observations on performance are made. Copyright © 1999 John Wiley & Sons, Ltd.     

EUV‐Lithographie für zukünftige IC‐Chips. EUV‐Lithography for Future IC‐Technology

In the past the overwhelming success of the semiconductor industry was based on the realisation of ever smaller structures on chips in ever shorter periods. This allowed to increase the computational speed of the processors and the amount of data that can be stored in a memory chip. This reduction of the critical dimension was mastered within optical lithography by transition to smaller wavelengths. Those lithography technologies that are currently in the development or test phase, based on 193 nm or as well 157 nm laser sources, will not achieve dimensions around 50 nm. A fundamental change of technology is thus emerging. The currently favored basis for dimensions of 50 nm and below is EUV lithography, based on an optical technology with an exposure wavelength of 13,4 nm. This substantial reduction of the wavelength also implies a radical change of the methodology used up to now.     

Fuel Cells: Structure‐Morphology‐Property Relationships of Non‐Perfluorinated Proton‐Conducting Membranes (Adv. Mater. 42/2010)

A fundamental understanding of structure‐morphology‐property relationships of proton exchange membranes (PEMs) is crucial in order to improve the cost, performance, and durability of PEM fuel cells (PEMFCs). In this context, there has been an explosion over the past five years in the volume of research carried out in the area of non‐perfluorinated, proton‐conducting polymer membranes, with a particular emphasis on exploiting phase behavior associated with block and graft copolymers. This progress report highlights a selection of interesting studies in the area that have appeared since 2005, which illustrate the effects of factors such as acid and water contents and morphology upon proton conduction. It concludes with an outlook on future directions.     

Nanomachines Based on Carbon Nanotubes Walls Motion: Operation Modes and Controlling Forces

Abstract

Possible types of nanomachines based on threadlike relative motion of nanotube walls are considered. The theory for dynamics of such a motion is developed. Types of motion, controlling forces, and operation modes for these nanomachines are analyzed.     

Vakuum‐Drehdurchführungen mit Magnetflüssigkeitsdichtungen. Magnetic‐liquid‐sealed vacuum rotary feedthrough

Most vacuum manufacturing processes require some type of motion to take place within the chamber. A magnetic liquid sealed feedthrough is a device that transmits rotary motion into a vacuum chamber with minimal torque requirements and minimal contamination level. The are widely employed in high and ultra‐high vacuum conditions, such as: semiconductor fabrication industry, coating equipment, high power X‐ray generators, robotics applications and the others. In the paper is given principle of operation of a magnetic liquid seal and various standard and special designs of vacuum rotary feedthroughs, sealed with magnetic liquid are described.