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2-噁唑烷酮合成的工艺研究 总被引:1,自引:0,他引:1
本文研究了2-唑烷酮的合成,产品收率为58.2%,纯度为86.4%。对原料配比、溶剂用量、反应温度及反应时间等影响因素进行了探讨,确定了较佳的反应条件。 相似文献
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介绍2-噁唑烷酮的应用及几种不同的合成方法,并加以简单比较。同时介绍2-噁唑烷酮五类衍生物的应用及先进的合成方法。 相似文献
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噁唑烷酮改性环氧树脂的性能 总被引:1,自引:0,他引:1
采用4,4-二苯基甲烷二异氰酸酯(MDI)对双酚A环氧树脂和脂肪族环氧树脂进行噁唑烷酮化共改性,研究了MDI及作为活性稀释剂的脂肪族环氧用量对改性产物黏度及树脂固化物力学性能、耐热性的影响。结果表明,低改性比和稀释剂可以有效降低唑烷酮改性环氧树脂黏度,当改性比为4∶1时,树脂固化物拉伸强度、弯曲强度达到75.4 MPa和158.2 MPa,分别比环氧树脂固化物提高了64%和57%,断裂延伸率和冲击强度有较大提高,具有高强高韧的特点。稀释剂含量对Tg影响较小,各改性树脂Tg在108~118℃之间,与纯环氧树脂的耐热性相当。 相似文献
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手性噁唑硼烷酮能够催化不对称1,3偶极加成反应并取得很好的效果。手性噁唑硼烷酮以廉价易得的手性氨基酸为原料合成的一系列氮磺酰化氯基酸配体与硼烷原位制备而成.本文主要对手性噁唑硼烷酮的合成,及其不对称诱导机理进行了探讨。 相似文献
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负载型杂多酸催化剂催化合成油酸正丁酯 总被引:5,自引:0,他引:5
制备了以混合氧化物为载体的杂多酸盐催化剂HPA/TiO2MoO3,以油酸和正丁醇为原料,催化合成了油酸正丁酯。确定了该反应的优化条件:醇酸物质的量比2∶1,催化剂用量为反应物总质量的1%,反应时间60min,反应温度130℃以上,在此条件下,油酸正丁酯的酯化率可达98%。 相似文献
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Dendrigraft polystyrene was prepared using poly(p-chloromethyl styrene) as the multicentre initiator by atom transfer radical polymerization (ATRP). The resulting polymer was characterized with light scattering, intrinsic viscosity, thermal analysis and atomic force microscopy (AFM) imaging. The AFM image showed there were two kinds of different structural dendrigraft polystyrenes in the product, ie the ‘coupling’ dendrigraft polystyrene and ‘free’ dendrigraft polystyrene. The ‘coupling’ structure might result from the coupling reaction of growing radical chain ends. The second virial coefficient A2 and intrinsic viscosity of the dendrigraft polystyrene were smaller than those of the relative linear and twelve-arm star polystyrene, and the thermal analysis showed that the initial decomposition temperature was a little higher than that of linear polystyrene. © 1999 Society of Chemical Industry 相似文献
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Yong Gao Hua-Ming Li Feng-Shou Liu Xia-Yu Wang Zhi-Gang Shen 《Journal of Polymer Research》2007,14(4):291-296
Benzoylated syndiotactic polystyrene, a functional polymer bearing benzophenone(BP) moiety, has been synthesized in a heterogeneous
process by using carbon disulfide as the dispersing medium, and benzoyl chloride and anhydrous aluminum chloride as benzoylating
agent and catalyst, respectively. The benzoylation reaction can be well controlled and the resultant polymer was characterized
by FTIR and NMR spectroscopy. The incorporation of benzoyl groups into syndiotactic polystyrene was found to have a profound
effect on the thermal properties of these new materials. The melting point and the degree of crystallinity decreased by the
presence of benzoyl groups, while the glass transition temperature increased. 相似文献
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用一种新的方法合成了3-((E)-2-丁烯酰基)-1,3-(口恶)唑烷-2-酮,先用(E)-2-丁烯酸与二氯亚砜反应合成(E)-2-丁烯酰氯,再由(E)-2-丁烯酸与(E)-2-丁烯酰氯反应合成(E)-2-丁烯酸酐,最后把(E)-2-丁烯酸酐加入到三乙胺,无水LiCl,1,3-(口恶)唑烷-2-酮的无水四氢呋喃溶液中,在室温下反应5h,正己烷重结晶得3-((E)-2-丁烯酰基)-1,3-(口恶)唑烷-2-酮,产率80%.并确定了反应的最佳条件反应温度为25℃,反应时间为5h,催化剂无水LiCl与1,3-(口恶)唑烷-2-酮的摩尔比为1:1. 相似文献
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本文论述了二(2-苯并咪唑亚甲基)胺及配合物的合成方法,并对配合物进行了元素分析,为研究SOD提供了基础和数据。 相似文献
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以4-羟基-3-硝基香豆素为起始原料,经过开环、脱羧,得到2-硝基-2,-羟基苯乙酮,再和甲氧胺盐酸盐反应生成中间体1-(2-羟基苯基)-2-硝基-乙酮-O-甲基肟。最后通过碱性条件下关环得到苯并呋喃-2,3-二酮3-(O-甲基-肟)2-肟。目标化合物及中间体结构经1H-NMR确证。反应总收率70.4%,产品纯度99.2%。该工艺原料廉价,操作简单,收率较高,具有较好的工业化应用前景。 相似文献
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This work examined how the molecular weight of atactic polystyrene (aPS) affects the thermal properties and crystal structure of syndiotactic polystyrene (sPS)/aPS blends using differential scanning calorimetry, polarized light microscopy and wide angle X-ray diffraction (WAXD) technique. For comparative purposes, the structure and properties of the parent sPS was also investigated. The experimental results indicated that these blends showed single glass transition temperatures (Tgs), implying the miscibility of these blends in the amorphous state regardless of the aPS molecular weight. The non-isothermal and isothermal melt crystallization of sPS were hindered with the incorporation of aPSs. Moreover, aPS with a lower molecular weight caused a further decrease in the crystallization rate of sPS. Complex melting behavior was observed for parent sPS and its blends as well. The melting temperatures of these blends were lower than those of the parent sPS, and they decreased as the molecular weight of aPS decreased. Compared with the results of the WAXD study, the observed complex melting behavior resulted from the mixed polymorphs (i.e. the α and β forms) along with the melting-recrystallization-remelting of the β form crystals during the heating scans. The degree of melting-recrystallization-remelting phenomenon for each specimen was dependent primarily on how fast the sPS crystals were formed instead of the incorporation of aPSs. Furthermore, the existence of aPS in the blends, especially the lower molecular weight aPS, apparently reduced the possibility of forming the less stable α form in the sPS crystals. 相似文献