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针对柠檬酸生产废水二级生化出水色度高、难生化降解的特点,采用催化臭氧化-曝气生物滤池组合工艺对其进行深度处理。结果表明,该组合工艺可实现废水脱色和降解有机物的目的。当催化臭氧化接触氧化时间为30 min,臭氧投加量为22.5 mg/L;BAF气水比为3∶1,水力停留时间为3 h时,出水COD降至60 mg/L以下,色度维持在10~15倍,处理出水达到《城市污水再生利用工业用水水质》(GB/T 19923—2005)的标准。 相似文献
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为了获得最佳的臭氧催化氧化工艺参数,采用1 t/h臭氧催化氧化装置利用单因素及正交试验法研究了臭氧通气量、臭氧浓度及催化剂投加量对COD去除效果的影响规律,确定了工艺条件的影响主次顺序及最佳工艺参数。最后在最佳工艺参数下进行连续试验80 h,进一步考察了最佳工艺参数下COD的去除效果。结果表明:3种工艺条件(即臭氧浓度、臭氧通气量、催化剂投加量)对COD去除率均有很大影响。通过单因素试验发现,随着臭氧通气量、臭氧、催化剂投加量增加,在同等条件下COD去除率越大,但相应的处理成本会增加,最终选择臭氧通气量为1.5 m3/h≤臭氧通气量≤2.5 m3/h,臭氧浓度为150 mg/L≤臭氧浓度≤250 mg/L,催化剂投加量选择为20 kg/t≤催化剂投加量≤30 kg/t。通过正交试验发现,3种臭氧氧化条件对COD去除率影响的主次顺序为臭氧浓度通气量催化剂投加量,验证了上述单因素试验结果,得到最佳工艺参数为:臭氧通气量2.0 m3/h,臭氧浓度250 mg/L,催化剂投加量30 kg/t。最后采用1 t/h臭氧氧化装置,在最佳工艺参数下对脱酚蒸氨后废水进行连续臭氧氧化试验80 h,COD去除率稳定在43.5%左右,反应后可生化性(B/C)稳定至0.4以上,减轻了后续生化处理的负荷及难度。证明臭氧氧化工艺实际应用效果良好。 相似文献
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《工业水处理》2018,(11)
采用中试装置,考察了NiO/Al_2O_3催化臭氧技术深度处理城市污水厂出水的可行性。结果表明,NiO/Al_2O_3催化剂加大了臭氧在水中的溶解度,并促进羟基自由基的产生,相同条件下,NiO/Al_2O_3催化臭氧化工艺对COD、DOC、NH_4~+-N、NO_3~--N的去除率分别为50.4%、49.3%、57.6%、35.1%,比单独臭氧工艺分别提高了25.7%、27.5%、46.8%、31.2%。在催化剂投加质量浓度10 g/L,臭氧投加量53.3 mg/min,水力停留时间30 min下,出水COD满足《地表水环境质量标准》(GB 3838—2002)Ⅴ类标准。NiO/Al_2O_3催化剂稳定性良好。 相似文献
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臭氧-活性炭工艺深度处理煤制气废水试验研究 总被引:4,自引:2,他引:4
以煤制气废水为研究对象,考察臭氧接触时间和臭氧通量对色度和UV254去除效果的影响,研究了臭氧-活性炭工艺在煤制气废水深度处理中的应用效果及影响因素。结果表明,与臭氧直接氧化相比,臭氧催化氧化对色度和UV254的去除效果显著提高,最佳臭氧接触时间为2 h,最佳臭氧通量为5 L/min,在此试验条件下连续运行该工艺深度处理煤化工废水,进水SS浓度和pH值对处理效果有较大影响,CODCr和色度去除率分别为89.95%和86.50%,出水CODCr的质量浓度小于30 mg/L,色度为30度,远优于GB 8978—1996《污水综合排放标准》中一级标准的要求,达到废水回用相关标准的要求。 相似文献
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The applicability of a sequential process of ozonation and ozone/hydrogen peroxide process for the removal of soluble organic compounds from a pre-coagulated municipal sewage was examined. 6–25% of initial T-CODCr was removed at the early stage of ozonation before the ratio of consumed ozone to removed T-CODCr dramatically increased. Until dissolved ozone was detected, 0.3 mgO3/mgTOC0 (Initial TOC) of ozone was consumed. When an ozone/hydrogen peroxide process was applied, additional CODCr was removed. And we elucidated that two following findings are important for the better performance of ozone/hydrogen peroxide process; those are to remove readily reactive organic compounds with ozone before the application of ozone/hydrogen peroxide process and to avoid the excess addition of hydrogen peroxide. Based on these two findings, we proposed a sequential process of ozonation and multi-stage ozone/hydrogen peroxide process and the appropriate addition of hydrogen peroxide. T-CODCr, TOC and ATU-BOD5 were reduced to less than 7 mg/L, 6 mgC/L and 5 mg/L, respectively after total treatment time of 79 min. Furthermore, we discussed the transformation of organic compounds and the removal of organic compounds. The removal amount of CODCr and UV254 had good linear relationship until the removal amounts of CODCr and UV254 were 30 mg/L and 0.11 cm?1, respectively. Therefore UV254 would be useful for an indicator for CODCr removal at the beginning of the treatment. The accumulation of carboxylic acids (formic acid, acetic acid and oxalic acid) was observed. The ratio of carbon concentration of carboxylic acids to TOC remaining was getting higher and reached around 0.5 finally. Removal of TOC was observed with the accumulation of carboxylic acids. When unknown organic compounds (organic compounds except for carboxylic acids) were oxidized, 70% was apparently removed as carbon dioxide and 30% was accumulated as carboxylic acids. A portion of biodegradable organic compounds to whole organic compounds was enhanced as shown by the increase ratio of BOD/CODCr. 相似文献
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The possibility of improving the biodegradability of drilling wastewater using ozone was investigated following coagulation pretreatment. The biodegradability of wastewater was improved significantly following the start of ozonation, and the molecular weight of organic compounds decreased continuously with the progress of oxidation. It is interesting that minimum biochemical oxygen demand, total organic carbon (BOD/TOC) ratio (0.4 g/g) was observed when wastewater was treated with ozone continuously for 15 min. The combination of ozonation for 5 min (ozone consumption ratio of 2.6 g ozone/g TOC) followed by biological degradation produced a total TOC removal rate of 54.3%, which was comparable to direct ozonation for 30 min under the same conditions (TOC removal rate of 54.9%; ozone consumption ratio of 8.7 g ozone/g TOC). It is clear that biological treatment following short-term ozonation was very efficient in TOC removal. A process of successive coagulation-precipitation, ozone oxidation, and biodegradation seemed to be a good option for drilling wastewater treatment. 相似文献
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臭氧催化氧化与曝气生物滤池的联合工艺可用于炼油厂含盐污水的深度处理。惠州炼化分公司采用BAF-O3组合工艺对含盐二级生化出水进行深度处理改造。运行结果表明,在进水COD浓度平均值97.9mg/L,臭氧催化氧化池和臭氧接触氧化塔的臭氧投加量分别为80~90 mg/L、30~20 mg/L的条件下,装置总出水COD浓度均值为43.5 mg/L,满足污水COD≤50 mg/L的限值要求,COD总去除率达到55.57%。BAF单元前置后,其COD去除率提高,COD去除量由2.71 mg/L提高至9.5 mg/L,经分析主要系生物絮凝作用;由于活性炭罐和BAF单元对悬浮物的有效过滤,有利于保护后续的臭氧催化氧化单元。 相似文献
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The post-treatment of composting leachate via an ozonation process in laboratory scale was studied in batch mode. According to the experiments, the COD removal was 47% after 30 min of ozonation via 0.4 g/h ozone (equivalent to 2.8 mg O3/mg COD removed) at pH 9. In this circumstance, the removal of color and turbidity was also 86% and 89%, respectively. Increasing the ozone mass flow rate higher than 0.4 g/h had no considerable effect on the process variables. However, increasing the reaction time had a significant effect on both the removal of color and on COD of the leachate. Experimental data indicated that complete removal of color and 51% removal of COD were achieved after about 40 min of ozonation via 0.4 g/h ozone (equivalent to 3.3 mg O3/mg COD removed). The ozone consumption rate increased as the reaction progressed and reached 4.1 mg O3/mg COD removed after 60 min. 相似文献
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该文研究了臭氧技术应用于剩余污泥处理过程中臭氧利用率及污泥的可生化性随时间的变化,组建了臭氧氧化与序批式好氧活性污泥法结合的联合工艺。将臭氧单元处理过的污泥全部回流至曝气池与污水进行合并处理,考察了不同臭氧投加量下联合工艺中剩余污泥的产量和污水处理效果。结果表明,当处理污泥浓度为4 000 mg/L,污泥体积为3 L,臭氧进气浓度为6.5 mg/L,气量为6 L/min时,前20 min的臭氧利用率几乎为100%,随后利用率逐渐降低;污泥的可生化性先降低,而后逐渐升高,在30 min时达到最大,其后又开始下降;当臭氧投加量为0.078 kg O3/kg MLSS时,联合工艺的污泥增长率几乎为0,同时出水水质相对对照组没有明显变化。 相似文献