Tuning the alignment of liquid crystals by means of nano‐structured surfaces (Invited Paper)

Abstract— The solid‐surface/liquid‐crystal interactions, defining the field‐free alignment of the liquid crystal in conventional liquid‐crystal displays, are playing a vital role in their optical appearance and performance. Nano‐scale changes in the solid‐surface structure induced by light have been recently shown to affect the anchoring strength and the easy‐axis direction. Fine tuning of the anchoring strength is also demonstrated by nano‐structuring of the Langmuir‐Blodgett monolayer employed as liquid‐crystal alignment layers promoting homeotropic orientation. On the basis of nano‐engineering of the surface alignment properties, two novel alignment concepts have been introduced: electrically commanded surfaces (ECS) and high‐performance alignment layers (HiPAL). Nano‐structured polymers related to these concepts have been designed, synthesized, and used as materials for alignment layers in LCDs. ECS materials belong to the category of active alignment materials designed to mediate switching of the liquid crystal, whereas the HiPAL materials make possible the control of the molecular tilt angle in a broad range, from 0° to 90°, and they seem to enable the control of the anchoring strength as well. The nano‐structured alignment materials are strong candidates for implementation in a new generation of advanced liquid‐crystal displays and devices.     

Properties of azo‐dye alignment layer on plastic substrates

Abstract— The alignment properties of the azo‐dye photo‐alignment material SD‐1/SDA‐2 on plastic substrates are investigated. Important liquid‐crystal cell parameters, such as azimuthal and polar anchoring energy, pretilt angle, voltage holding ratio, and the corresponding electro‐optical properties are presented. Excellent alignment with high anchoring energy can be achieved with a polarized UV dose less than 1.0 J/cm². A reflective six‐digit flexible passive‐matrix‐driven TN‐LCD for smart‐card applications showing excellent electro‐optical properties is demonstrated.     

Simulation and fabrication of a fast fringe‐field switching liquid crystal with enhanced surface anchoring enabled by controlled polymer topology

We demonstrate a fringe‐field switching nematic liquid crystal with electro‐optical behavior modulated by both bulk and surface polymer stabilization. The polymer is formed by ultraviolet irradiation‐induced phase separation of various amounts of a reactive monomer in the planar‐aligned nematic liquid crystal. Simulation is carried out to verify the effect of anchoring energy. Experimental evidence validates the effect of monomer concentration on transmittance–voltage and response times curves of fringe‐field switching cells. The polymer‐stabilized alignment with a higher polymer concentration escalates the interaction between the liquid crystal and the polymer structure and increases the surface anchoring energy. The polymer stabilization also improves the dynamic response times of liquid crystal. The enabling polymer‐stabilized alignment technique has excellent electro‐optical properties such as a very good dark state, high optical contrast, and fast rise and decay times that may lead to development of a wide range of applications.     

Photoalignment and photo‐patterning of planar and homeotropic liquid‐crystal‐display configurations

Abstract— Optical alignment and micro‐patterning of the alignment of liquid‐crystal displays (LCDs) by linear photopolymerization (LPP) technology renders high‐quality multi‐domain twisted‐nematic (TN) and supertwisted‐nematic (STN) displays with broad fields of view over wide temperature ranges feasible. The prerequisites are the generation of photo‐induced high‐resolution azimuthal alignment patterns with defined bias‐tilt angles 0° ≤ θ ≤ 90°. For the first time, LPP‐aligned single‐ and dual‐domain vertically aligned nematic LCDs (VAN‐LCDs) are presented. Dual‐domain VAN‐LCDs are shown to exhibit broad fields of view which are further broadened by combining the displays with LPP‐aligned optical compensators made of liquid‐crystal polymers.     

Photo‐aligned photonic ferroelectric liquid crystal fibers

Preliminary studies of photonic crystal fibers (PCFs) partially infiltrated with photo‐aligned ferroelectric liquid crystals (FLCs) under the influence of external electric field are reported. The proper alignment of the FLC molecules is achieved by generating a photo‐aligning layer on the inner side of the PCF microcavities. The sulfonic azo dye, which is used as an alignment layer, offers a variable anchoring energy depending on the irradiation energy, and thus, a good control on the FLC alignment inside microchannels is possible. Moreover, a state of polarization of the light being guided inside the PCF infiltrated selectively with FLC changes under the influence of external electric field.     

Azo‐dye aligning layers for liquid‐crystal cells

Abstract— The photo‐induced alignment of liquid crystal onto a photochemical stable azo‐dye film was studied for liquid‐crystal display (LCD) applications. The photo‐aligning of azo dye takes place due to the pure reorientation of the molecular absorption oscillators perpendicular to the UV‐light polarization. The order parameters S = ?0.4 (80% of the maximum absolute value S_m = ?0.5) was measured at a wavelength of 372 nm from the polarized absorption spectra. The temperature‐stable pretilt angle of 5.3° was obtained by a two‐step exposure of azo‐dye film using normally incident polarized light followed by oblique non‐polarized light. The azimuthal anchoring energy of the photo‐aligned substrate was A_? > 10^?4 J/m², which is of the same magnitude as the anchoring of the rubbed PI layer. The VHR value of the photo‐aligned LC cell was also found to be very high (98–99%) at room temperature and more than 95% at T=80°C. The thermal stability of the photo‐aligned azo‐dye layers is sufficiently high, while UV stability has to be improved, _e.g., by polymerization. The new LCD aligning technology based on photochemical stable azo‐dye layers is envisaged.     

Electrically suppressed helix ferroelectric liquid crystals for modern displays

In this article, we disclose electrically suppressed helix ferroelectric liquid crystal (ESHFLC) that is characterized by high optical quality and fast response time at the cost of extremely small driving voltage. These unique features of the ESHFLCs are highly sensitive to the anchoring energy that should be smaller and comparable to the elastic energy of the ferroelectric liquid crystal helix. The photo alignment, which offers good control on the anchoring energy by means of the irradiation energy, is critically important to lock the optimum parameters of the ESHFLC display cell. An example of field sequential color display with the frame frequency of 240 Hz at the driving voltage of 2 V has been demonstrated.     

Invited Paper: New technology for HTPS‐LCD panels for projection systems

Abstract— A new technology has been developed for high‐temperature‐polysilicon (HTPS) TFT liquid‐crystal panels employed in projection systems. It consists of vertically aligned nematic (VAN) liquid‐crystal, inorganic alignment layers, and a new driving technique. Full‐HD (1080p) resolution was realized in a 0.7‐in.‐diagonal device with high contrast and low power consumption.     

Alignment control technology of liquid crystal molecules

Liquid crystal displays are now indispensable in everyday life. The display characteristics considerably depend on the configuration of liquid crystal (LC) molecules and interactions between the LC molecules and an alignment film surface. In this paper, we introduce various methods to control parameters that dominate the LC alignment. These parameters include order parameters, the pretilt angle, the director direction, and surface anchoring strength. We also introduce their evaluation methods. In particular, recent alignment film‐free technology is explained in detail. In addition, details of how these parameters are related to the display characteristics, particularly wide viewing angles and fast response characteristics, are described primarily with reference to recent technologies.     

A single‐cell‐gap transflective liquid‐crystal display using different pretilt angles in transmissive and reflective regions

Abstract— A single‐cel l‐gap transflective liquid‐crystal display with two types of liquid‐crystal alignment based on an in‐plane‐switching structure is proposed. The transmissive region is almost homeotropically aligned with the rubbed surfaces at parallel directions while the reflective region has a homeotropic liquid‐crystal alignment. For every driving voltage for a positive‐dielectric‐anisotropy nematic liquid crystal, the effective cell‐retardation value in the transmissive region becomes larger than that in the reflective region because of optical compensation film which is generated by low‐pretilt‐angle liquid crystal in the transmissive region. Under the optimization of the liquid‐crystal cell and alignment used in the transmissive and reflective areas, the transmissive and reflective parts have similar gamma curves. An identical response time in both the transmissive and reflective regions and a desirable viewing angle for personal portable displays can also be obtained.     

Alignment materials with controllable anchoring energy

New polymers with photo‐controllable anchoring energy and tunable pretilt angle within 90°–0° range for nematic liquid crystals alignment were developed. The functional properties of polymers are provided by the effect of photoinduced planar alignment and the presence of side hydrocarbon chains in macromolecules that create a homeotropic alignment effect. Applying photosensitive alignment layers based on polymers with side benzaldehyde and hydrocarbon groups, fabrication of optical devices with refractive index gradient, uniform cell gap, and low operation voltage is possible. The developed materials are suitable for simple fabrication of tunable liquid crystal lenses.     

Polymer‐stabilized pretilt angle on the surface of nanoparticle‐induced vertical‐alignment surface for multi‐domain vertical‐alignment liquid‐crystal display

Abstract— By introducing polyhedral oligomeric silsesquioxane (POSS) nanoparticles along with a controlled amount of UV‐curable reactive mesogen (RM) into a liquid‐crystalline (LC) medium, a multi‐domain vertical‐alignment LC device was successfully demonstrated. The device, possessing a vertically aligned LC director in four different azimuthal directions, exhibited a fast response time and wide‐viewing‐angle characteristics, in the absence of conventional polymer‐type vertical‐alignment layers. Electro‐optic characteristics of the fabricated device, before and after UV curing of the cell, were studied. The surface morphology of the substrate surfaces were analyzed by using field‐emission scanning electron microscopy (FESEM). The experimental results show that the technology will possibly be applicable to cost‐effective vertical‐alignment liquid‐crystal devices and is suitable for green‐technology liquid‐crystal displays.     

Deformed nanostructure of photo‐induced biaxial cholesteric films and their application in VA‐mode LCDs

Abstract— Novel biaxial retardation films made from photo‐induced deformed cholesteric liquid‐crystal (LC) nanostructures using reactive mesogen mixtures (RMMs) for a viewing‐angle compensation of vertically aligned liquid‐crystal displays (VA‐LCDs) was developed. The deformed cholesteric LC nanostructure has been observed by X‐ray‐diffraction (XRD) measurement. The birefringence of the film was described well by our optical model based on a form birefringence theory. The VA‐LCDs with photo‐induced biaxial cholesteric films have excellent viewing‐angle properties.     

Use of quantum rods for display applications

We examined the use of quantum rods (QRs) in two configurations for display applications, including the backlight and emissive color pixels for liquid crystal and organic light‐emitting diode displays, respectively. For the backlight, we used an electrospun nanofiber sheet embedded with QRs, and found the nanofiber‐aligned sheet showed polarized emission with a very high outcoupling efficiency. We then fabricated emissive color pixels with QRs using an inkjet printer, and evaluated their optical properties. The color gamut area size was 82% of the BT2020 standard and the overlap with it was 69%.     

Electro‐optical characteristics of ion‐beam‐aligned FFS‐LCDs on diamond‐like‐carbon thin film

Abstract— A fringe‐field‐switching (FFS) mode cell having LC alignment has been developed by using a non‐rubbing method, a ion‐beam‐alignment method on a‐C:H thin film, to analyze the electro‐optical characteristics of this cell. The suitable inorganic thin film for FFS‐LCDs and the alignment capabilities of nematic liquid crystal (NLC) have been studied. An excellent voltage‐transmittance (V‐T) and response‐time curve for the ion‐beam‐aligned FFS‐LCDs were observed using oblique ion‐beam exposure on DLC thin films.     

Ferroelectric liquid crystals: Excellent tool for modern displays and photonics

The ferroelectric liquid crystals, because of their fast electro‐optical response, are one of the most important classes of liquid crystals. Here, in this review, we have summarized the different electro‐optical modes for ferroelectric liquid crystals. Clark–Lagerwall effect (surface stabilized ferroelectric liquid crystal), deformed helix ferroelectric (DHF) effect, electrically suppressed helix (ESH) mode, DHF orientational Kerr effect, and ESH diffraction modes have been discussed. All of the crucial features, that is, optics, electro‐optics, dynamics, and their dependence on material parameters, operational regime, and applications, have been reviewed.     

A self‐aligned multi‐domain liquid‐crystal display on polymer gratings in a vertically aligned configuration

Abstract— We report on a new method of fabricating a vertically aligned multi‐domain liquid‐crystal display (LCD) using surface‐relief gratings. A linear array of surface‐relief gratings was produced by using a photosensitive polymer material coated on glass substrates by the illumination of the UV light through a photomask. The LCD cell was assembled with two substrates with polymer gratings in such way that the grating vectors were orthogonal to each other. In this LCD configuration, the nematic molecules were reoriented by distortions of an external electric field at the grating surfaces to make four different domains. The LC cell with self‐aligned four domains shows excellent extinction in the off‐state and wide‐viewing characteristics in the on‐state.     

Flexible ferroelectric liquid‐crystal devices containing fine polymer fibers

A new flexible ferroelectric liquid‐crystal‐display device with gray‐scale capability has been created by using submicrometer‐diameter polymer fibers. The polymer fibers, which are formed by photopolymerization of aligned monomer molecules in liquid crystal, align the ferroelectric liquid crystal and mechanically support two flexible thin plastic substrates. The composite film made of liquid crystal and polymer with a thickness of 2 μm was formed between the plastic substrates by using a fabrication method consisting of coating, lamination, and ultraviolet irradiation processes without the conventional gap‐forming and injection processes. The fabricated flexible device revealed gray‐scale capability due to the change in spatial distribution of micrometer‐sized binary‐switching liquid‐crystal domains. From the polarizing microscope observation, it was found that the switching domains are generated and expanded from the areas with poor polymer density. The experimental results indicated that the polymer fibers spatially modulate the threshold voltage for molecular switching. Our device exhibits great potential for flexible large‐sized light‐weight motion‐image displays.     

Contrast improvements for scrolling‐color LCoS

Abstract— A scrolling‐color LCoS (liquid‐crystal‐on‐silicon) display must exhibit both fast speed and high contrast. These requirements drive design choices for the liquid crystal and optics of the image kernel. The input director was aligned to the incoming polarization and a compensated 45TN0 effect was choosen. Contrast demands place tight requirements on interfacial reflections. A wire‐grid PBS can achieve high contrast and can simplify the system construction. With attention to the above, we report a sequential contrast of 800:1 at the viewing screen. With a 90TN0 effect, the contrast can be increased even further, but with some penalty in light efficiency. With this effect, sequential contrast of 2000:1 was measured.     

Defect‐free deformed‐helix ferroelectric liquid‐crystal mode in a vertically aligned configuration (Invited Paper)

Abstract— A novel deformed‐helix ferroelectric liquid‐crystal (DHFLC) mode in a vertically aligned (VA) configuration is described. In this configuration, several unique features of display performance such as uniform alignment, fast response, and analog gray‐scale capability are obtained. Particularly, this VA‐DHFLC mode allows for the defect‐free uniform alignment of both the FLC molecules and the smectic layers over a large area without employing additional processes such as rubbing or electric‐field treatment that are generally required for planar FLC modes. Based on the VA‐DHFLC mode, a transflective display having a single‐gap geometry with in‐plane electrodes on two substrates in the transmissive regions and on one substrate in the reflective regions is described.