A dual‐cell‐gap transflective liquid‐crystal display with identical response time in transmissive and reflective regions

Abstract— A dual‐cell‐gap transflective liquid‐crystal display (TR‐LCD) with identical response time in both the transmissive and reflective regions is demonstrated. In the transmissive region, strong anchoring energy is used to decrease the response time, while in the reflective region, weak anchoring energy is used to increase the response time. And overdrive voltage technology is adopted to make the response time identical in both the transmissive and reflective regions. The device structure and operating principle of the TR‐LCD was analyzed, the anchoring energy in the transmissive and reflective regions was designed, and the response time and electro‐optic characteristics of the TR‐LCD was calculated. The simulated dual‐cell‐gap TR‐LCD demonstrated good performances.     

Stability of liquid‐crystal layers based on the analysis of the adsorption on the alignment‐layer surface

Abstract— The adsorption strength of liquid‐crystal molecules on the alignment‐layer (polymer) surface was judged measuring temperature dependence of birefringence of an absorbed liquid‐crystal layer above the nematic—isotropic transition temperature. The relationship between the surface‐order parameter and the adsorption strength of liquid‐crystal molecules on the non‐rubbed polymer surface was also discussed.     

Polarization‐independent and electrically tunable liquid‐crystal Fresnel lenses based on photoalignment in dye‐doped liquid crystals

Abstract— This work demonstrates polarization‐independent and electrically tunable liquid‐crystal (LC) Fresnel lenses based on photoalignment in dye‐doped liquid crystals (DDLCs). The LC alignments in the adjacent odd and even zones of the LC Fresnel lens are orthogonally hybrid alignments. Those are generated by surface treatment of homeotropic and homogeneous alignment layers, and the dye‐adsorption layer onto the UV‐cured surface‐relief Fresnel zone plate. The maximum focusing efficiency (～34.14%) of the fabricated LC Fresnel lens by applying a suitable AC voltage is close to the maximal theoretical focusing efficiency of a binary phase LC Fresnel lens (～40.5%). Additionally, the focusing efficiency is polarization‐independent and electrically tunable.     

Optical rewritable liquid‐crystal‐alignment technology

Abstract— A new optical rewritable (ORW) liquid‐crystal‐alignment technology has been developed to create a display and to demonstrate its maturity and potential. ORW displays have no electrodes and use polarizers as substrates. The display requires no photolithography on plastic. Its simple construction secures durability and low cost for mass production. The on‐screen information is optically changed in a writing unit that consists of an LCD mask and an exposure source that is based on LEDs, low power, and low cost in comparison with Hg lamps or lasers. A high contrast image can be easily written, viewed, and rewritten through a polarizer, while the multi‐stable gray‐level image requires zero power to maintain the image. Reconfigurable LC alignment using ORW technology best suits plastic‐card displays as well as for LC photonics and various one‐mask processes of patterned LC‐alignment applications.     

Luminescent dichroic‐dye‐doped cholesteric liquid‐crystal displays

Abstract— LCDs based on a luminescent dichroic‐dye‐doped non‐absorbing cholesteric LC with positive dielectric anisotropy is proposed. In the initial state, the orientation of the dye molecules provides effective light absorption and irradiation. By applying an electric field to the cell, the absorption and thus the luminescence is absent. A two‐color luminescence could be achieved by sandwiching two cells: the upper cell consists of a cholesteric LC with two dyes (sensitizer and emitter) and is used with an applied voltage (active cell); the lower cell consists of a cholesteric LC doped with one dye and works without applying a voltage (passive cell). The performance characteristics of luminescent dye‐doped cholesteric‐LCDs were investigated.     

The emission characteristics of liquid‐crystal lasers

Abstract— Liquid‐crystal lasers exhibit narrow linewidth, large coherence area, and low threshold laser emission. Moreover, the wavelength of the laser line can be readily tuned using a variety of different external stimuli, including electric fields. These combined features make them particularly attractive as compact tunable laser light sources. Recent experimental results with regards to the emission characteristics of chiral nematic photonic band‐edge lasers are discussed. This type of liquid‐crystal laser consists of a self‐organizing one‐dimensional photonic band structure and a gain medium in the form of a laser dye. Some of the generic features that are observed for these lasers are discussed, including the typical emission linewidth of the laser line, the change in emission energy of the laser for high excitation energies and high pump repetition rates, and the dependence of the excitation threshold and slope efficiency on the cell thickness. In addition, how the performance changes when either the molecular structure of the chiral nematic host or the gain medium is varied is considered. To conclude, results are presented on the laser emission for a wide‐temperature‐range blue phase I band‐edge laser which consists of a self‐organizing three‐dimensional photonic band structure.     

Properties of azo‐dye alignment layer on plastic substrates

Abstract— The alignment properties of the azo‐dye photo‐alignment material SD‐1/SDA‐2 on plastic substrates are investigated. Important liquid‐crystal cell parameters, such as azimuthal and polar anchoring energy, pretilt angle, voltage holding ratio, and the corresponding electro‐optical properties are presented. Excellent alignment with high anchoring energy can be achieved with a polarized UV dose less than 1.0 J/cm². A reflective six‐digit flexible passive‐matrix‐driven TN‐LCD for smart‐card applications showing excellent electro‐optical properties is demonstrated.     

Nano‐structured liquid‐crystal alignment layers (Invited Paper)

Abstract— The alignment of liquid crystal by nano‐structured surfaces is investigated. It is shown that reliable pretilt angles of any value between 0° and 90° can be produced with these surfaces. The physics and properties of such alignment layers are studied using a variety of techniques. The anchoring energy and temperature stability of the alignment are also measured. Dependence on various processing conditions is also characterized. It is shown that these nano‐structured alignment layers are useful for the production of high pretilt angles needed for a variety of applications.     

Ferroelectric nanoparticle/liquid‐crystal colloids for display applications

Abstract— A non‐synthetic approach to modify liquid crystals (LCs) by dispersing low concentrations of ferroelectric nanoparticles is reported. These dilute colloids are stable and appear similar to a pure LC. However, by changing the concentration and the type of ferroelectric particles, the physical properties of the LC materials can be tailored, including the nematic isotropic transition temperature (T_NI), the dielectric constants, the birefringence (Δn), elastic constants, and the threshold voltage. Specifically, doping low concentrations of BaTiO₃ nanoparticles (～1%) into a LC MLC‐6609 increases T_NI up to ～40°C. This giant shift of T_NI has never been previously reported and indicates strong interactions between the LC and ferroelectric nanoparticles on a molecular level. The doped LC also demonstrates significant enhancement in birefringence (by 10–30%), dielectric anisotropy (by ～50%), and the elastic constant K₃₃ (by ～20%). Ferroparticles act as molecular additives and modify the intrinsic properties of LC materials without time consuming and expensive chemical synthesis. The new LC materials are very attractive and suitable for use in displays, switchable lenses, beam steering, as well as other light‐controlling devices.     

Tailored liquid‐crystal switching on ferroelectric polymer films

Abstract— The development of voltage‐controlled visible‐wavelength progression in displays and optical data storage devices using ferroelectric polymers and liquid crystals is described. Ferroelectric polymers are materials that have a ready distribution of dipoles which can be oriented by manipulating material composition and external fields. Utilizing the charge polarization distribution, their performance as an alignment layer for inducing liquid‐crystal alignment is presented. The switching response of the devices was tailored by changing the material composition through copolymers and nanoclay doping.     

Synthesis and application of an alkylated pyrazole‐based azo dye for electrofluidic display

Electrofluidic display (EFD) is one of the most promising reflective displays for its full color and video speed. Colored EFD oil, normally formulated by soluble organic dyes in non‐polar solvent, dominates the color, electro‐optical behavior, and reliability performances for EFD devices. In this paper, a novel yellow electrofluidic dye with excellent solubility in non‐polar EFD solvent was achieved based on the introduction of long alkyl chain into pyrazole azo dye. The resulting EFD device fabricated by the dye showed excellent application properties, such as fast switching speed (17.8 ms), high aperture ratio (68.5%), low threshold voltage (24v), good light stability (240 h under accelerated conditions), and low backflow phenomenon.     

Aggregate‐induced emission in light‐emitting liquid crystal display technology

Nowadays, liquid crystal displays (LCDs) with light‐emission are considered as energy‐efficient devices and are promising alternatives to conventional LCDs. To realize such possibility, strong fluorescent materials with a dichroic properties are required. Aggregate‐induced emission (AIE) is an unusual photophysical phenomenon shown by some luminogenic materials that will be highly emissive in their aggregate state. In this work, we studied the AIE effect of a luminescent liquid crystalline molecule TPE‐PPE in our LC system as a luminophore dopant. The result showed the excellent AIE effect that higher concentration of luminogen in the nematic LC host induced stronger luminescent intensity. Through exposure of a photoisomeriable alignment material sulfonic‐dye‐1, the photopatterning of a light‐emitting LC device was achieved with the use of the TPE‐PPE/nematic LC mixture.     

Ultra‐fast‐switching flexoelectric liquid‐crystal display with high contrast

Abstract— The flexoelectro‐optic effect provides a fast‐switching mechanism (0.01–0.1 msec), suitable for use in field‐sequential‐color full‐motion‐video displays. An in‐plane electric field is applied to a short‐pitch chiral nematic liquid crystal aligned in the uniform standing helix (or Grandjean) texture. The switching mechanism is experimentally demonstrated in a single‐pixel test cell, and the display performance is investigated as a function of device parameters. A contrast ratio of 2000:1 is predicted.     

Technologies toward flexible liquid‐crystal displays

Abstract— Several leading technologies for flexible liquid‐crystal displays have been developed recently at ERSO. The roll‐to‐roll compatible techniques, polymer‐added liquid crystal, have been applied on a film‐like substrate. A flexible black‐and‐white cholesteric liquid‐crystal display was also implemented by photo‐induced phase separation. Color filters placed on a plastic substrate by a low‐temperature manufacturing process was successfully fabricated. A novel design of a wide‐viewing‐angle color plastic LCD was also proposed.     

Controling color of liquid‐crystal displays

Abstract— Two newly derived characterization models for a liquid‐crystal (LC) display have been tested for five LC‐based displays. Data measured from a series of test colors indicated that all LC‐based displays showed similar characteristics, including an S‐shaped tone curve and poor channel chromaticity constancy. Because they include a hyperbolic function in their definition, the models do not have analytical inverses, and so iterative mathematical techniques are applied. It was shown that a new characterization model based on a hyperbolic function fits the tone curve very accurately with only four coefficients per channel for any type of LCD. In addition, it was also shown that the first derivative of the function provides a means of accurate correction of the chromaticity variation.     

Comparison of organic and inorganic alignment layers for low‐power liquid‐crystal devices using low‐frequency applied‐voltage waveforms

Abstract— Bistable displays are known to have low‐power consumption, but they usually lack the ability to display full‐color video‐rate images. Operating active‐matrix liquid‐crystal displays (AMLCDs) with an ultra‐wide refresh‐rate range, down to ～1 Hz, can lower the power consumption to that of bistable devices and offer video rates as well. A SiO^x‐layer‐based liquid‐crystal (LC) alignment technique is studied here to overcome the ion problems typically encountered with low‐refresh‐rate devices. The effect of ions on the voltage‐holding ratio (VHR) and residual DC voltage (RDC) with SiO^x‐based LC alignment is compared with those for polyimide‐based LC alignment. It is found that only SiO^x alignment provides high VHR and small RDC, with good stability over time. Therefore, it is shown that SiO^x alignment is an excellent candidate for low‐power AMLCDs operated with an ultra‐wide refresh‐rate range.     

Cell‐parameter measurement system for a liquid‐crystal cell by using a telecentric lens

Abstract— A two‐dimensional cell‐parameter measurement for determining the pretilt angle in addition to both the cell thickness and twist angle of liquid‐crystal (LC) cells is proposed. Because the measurement images of an LC cell is perfectly focused by using a telecentric lens, the 2‐D cell‐parameter distribution can be determined by measuring the Stokes parameters of the LC cell at several different wavelengths by changing the oblique angle of the incident light on the LC cell.     

Energy‐efficient liquid‐crystal displays (e2‐LCDs) using a photonic‐crystal backlight system

Abstract— Cholesteric liquid crystals automatically form one‐dimensional photonic crystals. For a photonic crystal in which light‐emitting moieties are embedded, unique properties such as microcavity effects and simultaneous light emission and light reflection can be expected. Three primary‐color photonic‐crystal films were prepared based on cholesteric liquid crystal in which fluorescent dye is incorporated. Microcavity effects, i.e., emission enhancement and spectrum narrowing, were observed. Two types of demonstration liquid‐crystal displays (LCDs) were fabricated using the prepared photonic‐crystal films in a backlight system. One is an area‐color LCD in which a single photonic‐crystal layer is used for each color pixel and the other is a full‐color TFT‐LCD in which three stacked photonic‐crystal layers are used as light‐conversion layers. The area‐color LCD was excited by using 365‐nm UV light, and the full‐color TFT‐LCD was excited by using 470‐nm blue LED light. Because of the photonic crystal's unique features that allow it to work as light‐emitting and light‐reflecting layers simultaneously, both LCDs demonstrate clear readable images even under strong ambient light, such as direct‐sunlight conditions, under which conventional displays including LCDs and OLED displays cannot demonstrate clear images. In particular, an area‐color LCD, which eliminated color filters, gives clear images under bright ambient light conditions even without backlight illumination. This fact suggests that a backlight system using novel photonic‐crystal layers will be suitable for energy‐efficient LCDs (e²‐LCDs), especially for displays designed for outdoor usage.     

New properties and applications of rewritable azo‐dye photoalignment

Abstract— The rewritable azo‐dye photoalignment (ORW) of liquid crystals (LCs) for application in optical rewritable electronic paper has been investigated. It was observed that a periodic change in the azimuthal aligning direction with polarized UV light (365 nm) brings about homeotropic alignment, while utilization of visible light (450 nm) does not affect the LC tilt angle. The wavelength dependence of the ORW photoalignment result and the behavior of the photoinduced anisotropy was explored. The dark amplification of film anisotropy after exposure was observed, which is believed to be the relaxation process related to hydrogen bonding in azo‐dye film. New material, CD1, for azo‐dye rotation photoalignement that possesses a high azimuthal anchoring energy (about 2 × 10^?4 J/m²) was found.     

Liquid‐crystal photoaligning by azo dyes (Invited Paper)

Abstract— Liquid‐crystal (LC) photoalignment using azo dyes is described. It will be shown that this photoaligning method can provide a highly uniform alignment with a controllable pretilt angle and strong anchoring energy of the LC cell, as well as a high thermal and UV stability. The application of LC photoalignment to the fabrication of various types of liquid‐crystal displays, such as VAN‐LCDs, FLCDs, TN‐LCDs, and microdisplays, on glass and plastic substrates is also discussed. Azo‐dye photoaligned super‐thin polarizers and phase retarders are considered as new optical elements in LCD production, in particular for transflective displays.