7月纯MDI市场报告

正一、市场行情简述本月行情:本月纯MDI市场弱势向下,月初开盘,万华公布结算及挂牌,但下游对于万华挂牌结算反馈平平,按需采购,采购意向一般,持货商心态不稳,积极出货,随后,淡季需求明显萎缩,需求利空依旧延续,贸易商减仓避险,让利走货,中旬,夏季高温来临,受到限电等影响,下游生产积极性不高,且场内利好难寻,商谈重心小幅下挫,临近月末,随着万华公布本月挂牌与结算,与上月持稳,超过市场预期,下游反馈平平,成交重心持续低     

7月TDI市场报告

正一、市场行情简述本月行情:7月,国内TDI市场报盘行情上行。月初,受7月高挂牌影响,持货商坚挺报价,然市场需求寡淡,持货商存出货压力,报盘相对平稳。月中,受巴斯夫高结算消息支撑,持货商挺市意向明显,报盘向上引导市场,然传统淡季,下游抵触情绪明显,场内货源充足,挺市不易,多数交投僵持。月末,TDI工厂8月挂牌结算出台,高结算超出预期,工厂挺市心态明显,持货商心态消极,报盘调涨,场内低价货源逐渐消失,然下游抵触高价,多有价无市,实质性交投寥寥。下游需求跟进不足,预计TDI市     

一种氢溴酸普拉格雷醋酸化合物及其制法

正本发明涉及一种氢溴酸普拉格雷醋酸化合物的合成方法。以普拉格雷为中间体,将普拉格雷和水混合搅拌,得悬浊液,然后与氢溴酸和醋酸反应,加入有机溶剂,析出固体,干燥,即得,或者,以氢溴酸普拉格雷为中间体,将氢溴酸普拉格雷和水混合搅拌,得悬浊液,然后和醋酸反应,加入有机溶剂,析出固体,干燥,即得。本发明采用水作为溶剂,更加环保,节能,而且本发明步骤简单,得到的产物纯度高,生产成本低,可工业化生产。公开号:CN103450219A     

张云龙篆隶作品赏析

晚清以来碑学大兴,大篆名家辈出,吴昌硕结体长方,左低右高,取斜势,陶博吾书自石鼓,自得天成,放逸随意,破石鼓文之匀雅,变而奇崛峭拔。大篆取向多样,吸引着学人为之研究,近人罗振玉、丁辅之、董作宾诸人均在此处取得了可贵的成就,张云龙先生所书的大篆有独到之处,《石鼓文》之外,兼擅《散氏盘》、《毛公鼎》、琅邪刻石等,于秦砖汉瓦自有天机处,别开新境。大篆是以形为上,云龙先生取钟鼎之浑圆,玉筋之婉通,或取诏版之方折,不拘泥于原形勾画。其大篆的线条自成一相,方圆错落有致,章法布白高妙,静中有动,动中有静,字距参差有致,行距疏宕有韵,别具生机。     

优化结构有序建设积极促进橡胶工业全面协调和可持续发展

改革开放以来,我国橡胶工业的发展速度是前所未有的,其间有许多成功的经验,特别是入世后,在上世纪末全行业整体亏损的不利情况下,大家认识一致,认真对待,风雨同舟,趋利避害,经受住了考验,不仅行业经济全面复苏,而且取得新的发展。当前,全行业面对的是新一轮的竞争,而且更为激烈     

硫酸氢钠催化合成乙酸乙酯的工艺研究

以硫酸氢钠为催化剂,乙酸与乙醇为原料合成了乙酸乙酯,讨论了酸醇物质的量比、催化剂用量、反应时间、带水剂等因素对酯化率的影响,确定了最佳工艺条件为:以0.2mol乙醇为基准,酸醇物质的量比为1.5∶1,催化剂用量为1.5g,反应时间为2h,带水剂环己烷为10mL,乙酸乙酯的酯化率为85.2%.该催化剂具有催化效果好,使用量少,酯化率高,能够重复使用,环境污染小,腐蚀性小,价格低廉易得等特点,是一种很有发展前景的催化剂.     

SINOSTEEL LUOYANG INSTITUTE OF REFRACTORIES RESEARCH CO.,LTD.

<正>Sinosteel Luoyang Institute of Refractories Research Co.,Ltd.(LIRR)is a science and technology enterprise affiliated to Sinosteel Corporation,China.LIRR,established in 1963,is the only large integrated research institute and the center of technology,science,information and services in refractories industry.Its business scope covers refractory products,testing equipment,processing tools,project design,consultation and turnkey,domestic and foreign trade,products quality inspection,information service,etc.     

6月AA市场报告

<正>一、市场行情简述本月行情:本月AA市场窄幅整理,月初,海力公布挂牌,受到上游原料纯苯强势走势影响,上调500元/吨,对外执行11,500元/吨,贸易商心态得到提振,纷纷上调报盘,刺激下游接货,但端午节后归市下游惯性观望,交投有限,中旬时期,随着下游进入传统行业淡季,需求明显萎缩,贸易商报盘坚挺,但实则成交重心暗降,随着明稳暗降操作,场内低价货源陆续增多,下游采购谨慎,临近月末,上游原料纯苯挂牌上调300元/吨,强势震荡影响市场操作积极性,海力又公布了6月结算价格,对外执行11,500元/吨,提振持货商心态,但实盘成交寥寥,下游需求跟进滞缓。上游原料:     

半隐于郊 艺术之调

柳林小径深处,一扇木门掩映的白色建筑,即是王功新林天苗夫妇在宋庄的别墅。从大门进来,前方是白色的月亮门,像一道影壁墙,遮蔽外人的视线,经过一片水竹摇曳的甬道,才入院子。院内,三层小楼房顶上两层主体分别向两侧挑空,蜿蜒的池塘从花园延伸至室内,隔着一面大大的落地玻璃墙,恍惚间分不清哪里是室内,哪里是室外。更不可思议的是,池塘中间竟然是空的,下面就是那个巨大的工作室,鱼儿游过,涟漪荡漾开来,总担心这水会不会溢出……     

硫磺供需现状与市场分析（上）

硫磺别名硫、胶体硫、硫黄块,外观为淡黄色脆性结晶或粉末,有特殊臭味.分子量为32.06,蒸汽压是0.13 kPa,闪点为207℃,熔点为119℃,沸点为444.6℃,比重、熔点及其在二硫化碳中的溶解度均因晶体不同而异,工业硫磺呈黄色或淡黄色,有块状、粉状、粒状或片状等.块状硫磺为淡黄色块状结晶体,粉末为淡黄色粉末,能溶于二硫化碳、四氯化碳和苯,不溶于水.     

连续聚酯装置增容

叙述该装置增容的各项措施。在充分利用原有厂房、设备的基础上 ,经过物料衡算 ,调整部分设备和部件解决物流瓶颈 ;更换终聚釜气相出口挡板 ,由圆形换成扇形 ,并尽量缩短与出口的距离以防止真空系统堵塞。浆料总量比保持在 1.74,酯化温度提高 2～ 3℃ ,压力增加 5～ 8kPa,停留时间不变或略有缩小 ;预缩聚Ⅱ的液位加大到 45 % ,升高温度 ,余压降低到1.3kPa ,搅拌转速调为 8.9r/min ;终缩聚液位增加到 49% ,并适当提高搅拌速度等。当熔体日产量由 32 5t提到 35 3t时 ,切片质量指标没有明显变化 ,一等品率在 99%以上。     

工业大麻秆的显微构造和纤维形态研究

大麻秆芯是大麻的废弃物,一种优质的木质纤维原料。为了更好地开发和利用这种原料,论文主要对大麻秆的显微构造和纤维形态进行了研究,结果表明大麻秆的显微构造类似于阔叶材的散孔材。大麻秆皮部的纤维平均长度为22.7 mm,平均壁腔比为0.40,平均长宽比为705.38,83.5%纤维的长度为11～30 mm,72%的细胞长宽比为310～900,72%的壁腔比为0.11～0.50;是一种长度大、壁腔比小、长宽比大的优质纤维原料。而木质部的纤维平均长度为0.65 mm,平均壁腔比为0.32,平均长宽比为29.53,92%纤维的长度为0.41～0.90 mm,91.5%纤维的长宽比为11～50,66%纤维的壁腔比为0.11～0.40;是一种长度中等,长宽比大,壁腔比小的优质原料,可用于造纸和人造板制造的工业原料。     

CFRP层板的疲劳损伤研究方法

介绍了CFRP层板疲劳损伤研究方面的主要模型。剩余强度来度量疲劳损伤破坏准则清楚明了，但实验工作量大、费用高，并且一个试件只能得到一个数据；剩余刚度可在疲劳试验过程中连续测量而不影响材料的性能，但破坏准则较难确定，弹性模量对损伤不很敏感；用电阻的变化来反映碳纤维层板结构的疲劳损伤操作简单易行，具有较高的工程实用价值。     

Adhesion of RFL-coated aramid fibres to elastomers: The role of elastomer–latex compatibility

The performance of fibre-reinforced composites is strongly dependent on the nature and the strength of the fibre–matrix interface. Good interfacial bonding is required to ensure load transfer from matrix to reinforcing fibres. For rubber-reinforced composites, resorcinol formaldehyde latex (RFL) is known as a fibre surface coating which is able to provide good adhesion between rubber and fibres. In the present study, aramid fibres are investigated, because of their significantly higher modulus and strength, compared to other commercial fibres. Their adhesion after being coated with RFL, in compounds based on natural rubber (NR) and in NR blended with a small amount of styrene butadiene rubber (SBR) is investigated. It is shown that though having very similar tensile properties, the latter compound has much better adhesion to RFL which is also less sensitive to RFL ageing, compared to the pure NR compound. It is argued that an interphase region is formed between RFL and the elastomer, which is stronger for the compound containing SBR due to its enhanced compatibility with the latex part of the RFL.     

Approximate solutions for the ignition of a solid as a function of the Biot number

The ignition of a finite planar 1‐dimensional solid is addressed for constant applied radiant heat flux. An ignition temperature criterion is used, with constant properties, and linearized reradiation. An approximate integral analysis leads to analytic formulas to predict the ignition time in terms of Biot (Bi) number and heat flux. The accuracy of the integral solution is found to be good compared to the exact infinite series solution for the conduction equation. The integral model is then used to assess the accuracy of common ideal thick and thin formulas for ignition. There is a domain of heat flux and Bi where the ideal formulas are not accurate. An example is given where the integral model is accurately applied to ignition data to illustrate the range where the ideal formula is not accurate.     

粗糙集与模糊推理相集成的过程建模方法及其应用

针对复杂化工过程机理建模困难的问题,采用适应性较广的模糊方法经验建模,鉴于模糊法对于高维、强相关的样本数据很难导出规则,本文提出先用粗糙集方法消除冗余性,约简系统,获取最小规则集,在此基础上构建结构合理、参数可适当初始化的模糊-神经网络,并采用LM算法训练,收敛速率快,模型预测性能良好.将此法用于PTA装置溶剂脱水塔精馏过程的经验建模,效果令人满意,性能优于现代统计方法和前馈神经网络.     

木质素对糖蜜酒精废液的脱色效果

用活性炭脱除糖蜜酒精废液色素是行之有效的方法,但由于其成本过高制约了该方法在实际中的应用。作者提出用造纸黑液提取的木质素替代活性炭脱除糖蜜酒精废液色素的新治理方法,可以使脱色率达95％,COD去除率达82％。这种方法处理效率高,成本低,且工业化应用的可能性大。     

工程机械轮胎罐式胶囊硫化新工艺

介绍工程机械轮胎罐式胶囊硫化新工艺。罐式胶囊硫化新工艺模具上加装胶囊进出水塔台,利用塔台加过渡盘作胶囊进出水循环通道;模具与罐体采用过渡盘连接,无快装接头点,操作简便;加装罐式胶囊定型压力控制装置;钢圈与模具的分型面直径加大。罐式胶囊硫化新工艺硫化时间短,生产效率高,能耗降低。     

含氧燃料--二甲醚合成技术发展现状分析(二)

基于优良的燃烧和动力特性及友好的环境特性,二甲醚作为柴油和LPG的代用品,在国内外均呈现蓬勃发展的态势。两步法气相甲醇脱水流程长,但工艺成熟;一步法合成气直接合成技术新颖,但尚处于发展阶段。满足燃料生产大宗化、低成本的需要,二甲醚的出路在于采用先进工艺,建设(超)大型化生产装置,同时也需要积极的配套政策支持。     

Universal sequential outlier hypothesis testing

Universal outlier hypothesis testing is studied in a sequential setting. Multiple observation sequences are collected, a small subset of which are outliers. A sequence is considered an outlier if the observations in that sequence are generated by an “outlier” distribution, distinct from a common “typical” distribution governing the majority of the sequences. Apart from being distinct, the outlier and typical distributions can be arbitrarily close. The goal is to design a universal test to best discern all the outlier sequences. A universal test with the flavor of the repeated significance test is proposed and its asymptotic performance, as the error probability goes to zero, is characterized under various universal settings. The proposed test is shown to be universally consistent. For the model with at most one outlier, conditioned on the outlier being present, the test is shown to be asymptotically optimal universally when the typical distribution is known and as the number of sequences goes to infinity when neither the outlier nor the typical distribution is known. With multiple identical outliers, the test is shown to be asymptotically optimal universally when the number of outliers is the largest possible and with the typical distribution being known, and its asymptotic performance with neither the outlier nor the typical distribution being known is also characterized. Extensions of the findings to models with multiple distinct outliers are also discussed. In all cases, it is shown that the asymptotic performance guarantees for the proposed test when neither the outlier nor the typical distribution is known converge to those when the typical distribution is known as the number of sequences goes to infinity.