半固态等温热处理对ZA12合金组织和性能的影响

将初生相为枝晶形态的常规ＺＡ１２合金铸锭重新加热到半固态进行等温热处理，可获得具有良好触变性的非枝晶组织合金。文中对半固态热处理工艺参数与显微组织之间的关系进行了研究，并对铸态和经过半固态热处理的两种材料的半固态形性能以及成形制品的力学行为进行了试验对比。结果表明，经适当工艺热处理后，ＺＡ１２合金可以实现半固态成形，不仅成形抗力低，液相偏析少，且提高了制品的力学性能。     

半固态等温热处理对铸态AZ80镁合金组织的影响

研究了等温热处理温度和保温时间对铸态AZ80镁合金半固态组织演变的影响.研究结果表明:在热处理过程中,随保温时间的延长,初生α相演变过程是,首先由大部分粗大的树枝晶二次枝晶臂合并成为大块状,而后大块状晶粒在晶粒内部及晶界处液相和固液界面的曲率共同作用下熔化分离为小块状,继续保温则圆整化;保温时间相同,等温处理的温度越高,枝晶演变过程越快,保温温度越高或保温时间越长,球状晶粒也容易趋于长大.AZ80镁合金半固态成形所需的最佳工艺条件为加热温度570℃左右,保温时间30min.     

等温热处理对过共晶铝硅合金半固态组织的影响

过共晶Al-17%Si-4.5%Cu-0.5%Mg合金通过0.6%Na 1.2%P-Cu变质处理获得初晶硅细小的微观组织。在固液两相区进行等温热处理，结合金相分析研究了组织的演化规律：等温热处理的初期，共晶硅经历了熔断、粒状化和粗化的过程；随着加热温度的提高和保温时间的延长，共晶体不断熔化成液相；液相体积分数逐渐增加，使液相薄膜包围着α相；α相由不规则形状向球状转化；α相的粗化和合并几乎同时进行，最终获得非常理想的半固态组织。     

变质剂对ZA27合金半固态等温热处理组织的影响

研究了变质剂Ti、B－Ti及Zr对ZA27合金铸态组织和半固态等温热处理组织的影响。结果表明：Zr的变质效果最好,下来依次是B－Ti,Ti经半固态等温热处理后都可获得触变成形所需的半固态非枝晶组织、但变质组织越细,越易获得良好的非枝晶组织,变质效果越差,需要热处理的时间越长或温度越高。     

等温热处理工艺对AZ91D镁合金半固态组织演变和成形性的影响

研究了等温热处理温度和保温时间等工艺参数对AZ91D镁合金半固态组织演变和成形性的影响。结果表明 ,半固态等温热处理可以将普通金属型铸造的AZ91D镁合金锭中的枝晶组织转变为球形晶粒组织 ,其演变过程为 :在升温过程中晶界处部分γ相先发生溶解 ,随着温度的升高 ,剩余的γ相开始熔化 ,继而δ相也发生熔化 ,并在等温处理中逐渐演变为球状 ;保温温度越高 ,半固态重熔和δ相演变过程越快 ,保温温度过高或保温时间过长 ,试样易发生变形 ,同时 ,球状晶粒也容易趋于长大。AZ91D镁合金半固态成形所需的最佳工艺条件为加热温度 5 70℃左右 ,保温时间 2 5～ 35min ;或加热温度 5 80℃左右 ,保温时间 15～ 2 0min。     

半固态等温处理对Cu-Ca合金组织的影响

通过对比Cu-Ca合金铸态组织,研究了半固态等温处理主要工艺参数对半固态Cu-Ca合金组织的影响,得出了其半固态组织的演变规律。结果表明,在半固态等温处理工艺参数中,影响组织的主要参数为等温温度和保温时间。在一定选择范围内,随着等温温度的升高和保温时间的延长,组织将发生由树枝晶组织到非枝晶组织的一系列转变。研究发现,保温温度为957～967℃,等温时间为45～60min时,合金的球化效果最好,圆整度最高。     

等温热处理对Mg-6Zn-3Cu合金半固态组织演变的影响北大核心CSCD

通过半固态等温热处理,研究了重熔温度和保温时间对铸造ZC63镁合金半固态组织演变的影响。结果表明:半固态等温热处理能够将ZC63合金中的枝晶组织转变为球状组织,并可获得更加细小、分布均匀的球状颗粒;重熔温度和保温时间对非枝晶组织演变有着重要的影响,提高保温温度或延长保温时间,可加快原始铸锭重熔进程及组织形态的优化,保温温度过高或保温时间过长,试样会发生严重变形,同时球状颗粒易于粗化和长大;非枝晶组织演变是在熔化和结晶的动态变化中完成,主要的演变机制是在等温热处理过程中晶界处的共晶组织向基体溶解,原始组织的粗化、分离、球化以及球状颗粒的合并与长大。ZC63合金半固态触变成形最适合的等温热处理工艺是600℃×30 min。     

AZ91D镁合金在半固态等温热处理中的组织演变

研究了未变质处理和变质处理的AZ91D镁合金在半固态等温热处理过程中的组织演变,并对其组织演变机理进行了探讨。结果表明：AZ91D镁合金在液－固相区570℃等温处理时,未变质处理的δ相由粗大的树枝晶演变为大块状,随后δ相发生熔化分离,并在半固态等温过程中演变为球状,产生相最小尺寸可达50－80μm;变质处理的初生δ相由等轴晶演变为小块状,随后进一步熔化分离为更细小的斑块,接着逐渐演变为球状组织,初生相最小尺寸可达20－60μm。等温处理时间过长时,两种组织都会发生合并长大。     

等温温度和时间对ZL104铝合金半固态等温热处理组织的影响

研究了半同态等温热处理制备非枝晶组织ZL104铝合金的可行性以及保温温度和时间对合金半固态等温热处理组织的影响.结果表明,通过合适的半固态等温热处理工艺制备非枝品球状组织ZL104铝合金是可能的.在580℃保温下随着保温时间从30 min延长到120 min或在120 min保温下随着从570 oC保温提高到580℃,合金半固态组织巾未熔初生相颗粒的尺寸减小,其球状化趋势逐渐变得更明显.在本文条件下,ZL104合金最佳的半固态等温热处理工艺为580℃×120 min,通过该工艺合金可以获得液相含量为49%和未熔固相颗粒尺寸为115μm的非枝品球状组织,能够满足后续半固态成形的需要.     

Al-Ti-B对AM60B合金半固态等温淬火组织的影响

研究了变质剂Al-Ti-B对AM60B镁合金铸态组织和半固态等温淬火组织的影响.结果表明:变质处理后的镁合金在等温淬火过程中组织演变更快;等温淬火过程中加热温度偏低,不利于晶粒均匀圆整;温度偏高,再结晶速度快,晶粒易变形和粗大.     

等温热处理对AZ91D+Ce镁合金半固态组织的影响

研究了等温热处理对AZ91D+Ce镁合金半固态组织的影响,获得了较理想的球状或类球状晶粒组织。结果表明,在等温热处理的过程中,加入稀土Ce会阻碍原子向固相粒子聚集和结合,抑制固相颗粒的长大,形成细小圆整的半固态组织。随等温热处理温度的升高,原子活动能力增强,熔化速度加快,液相量增加,固相颗粒尺寸先减小后增大。在等温初始阶段,熔化对初生固相颗粒尺寸起决定作用,使得颗粒尺寸减小。但是,随等温时间的进一步增加,由于合并粗化和Ostwald熟化的作用,固相颗粒开始长大。     

Microstructural evolution of equal channel angular pressed AZ91D magnesium alloy during semi-solid isothermal heat treatment

The microstructural evolution of AZ91D magnesium alloy processed by equal channel angular pressing during isothermal heat treatment at 570℃ was investigated. The results indicated that the equal channel angular pressing followed by semi-solid isothermal heat treatment was an effective method to prepare semisolid nondendritic slurry of AZ91D magnesium alloy. During this process, its microstructure change underwent four stages, the initial coarsening stage, the structure separation stage, the spheroidization stage and the final coarsening stage. The microstructural spheroidization effect was the best after being heated for 15 min for the alloy pressed for four passes, and the grain size was the smallest. With the further increase of heating time, the grain size and shape factor increased. When the heating time was kept constant, the grain size and shape factor decreased with the increase of pressing passes.     

等温温度对轧制SIMA法制备7075合金半固态显微组织的影响

分别采用以同步轧制和异步轧制为预变形方式的应变熔化激活法(SIMA)制备7075铝合金半固态坯料,研究了辊径比和等温保温温度对预变形板材热处理过程中组织演变的影响。结果表明:随等温温度的升高,初生固相晶粒内生成大量液相,固相晶间冷却后出现大量共晶相。在相同的热处理条件下,异步轧制预变形工艺能够比同步轧制预变形工艺获得更多液相,且半固态进程更迅速;获得半固态坯料的优化工艺条件为异步轧制作预变形、等温温度选择610 ℃。     

等温热处理对消失模铸造AZ91D镁合金组织与性能的影响

对AZ91D镁合金消失模铸件进行了近半固态等温热处理,通过光学显微镜、扫描电镜以及金属拉伸试验对其组织和力学性能进行了研究.结果表明,AZ91D镁合金消失模铸件经过530 ℃×60 min近半固态等温热处理后,合金显微组织中β-Mg17 Al12相基本熔入基体,枝晶状的铸态组织在等温处理过程中变得均匀圆整,由此产生的固溶强化作用使材料的力学性能大大提高,抗拉强度达到213.17 MPa,屈服强度达到115.63 MPa,伸长率达到4.11%,等温热处理后的断口呈现明显的韧性断裂特征.     

Effects of Sm addition on microstructural evolution of Mg-6Zn-0.4Zr alloy during semi-solid isothermal heat treatment

The application of segmental semi-solid thixoforming of magnesium alloys is confined due to the dimensional distinction existing in solid particles of the alloy billet from edge to center zones. In the present study, the effects of Sm addition on the microstructural evolution of Mg-6Zn-0.4Zr and Mg-6Zn-4Sm-0.4Zr alloys by semi-solid isothermal heat treatment were investigated, to obtain optimum semi-solid microstructures for the subsequently thixoforming. The results indicate that the grains of the Sm-bearing alloy are evidently refined and gradually evolve from dendritic to globular and elliptic particles. In addition, the distinctly dimensional effect of the Mg-6Zn-0.4Zr alloy is eliminated with 4% Sm addition; the particle sizes in all zones from center to the edge of the billet are almost identical. With the increment of isothermal heat treatment temperature, the dendritic microstructures completely disappear, and meanwhile, the irregular and globular particles gradually form. The size, morphology and the distribution of solid particles mainly depend on the formation and permeation of the liquid phase in the process of isothermal heat treatment. As the isothermal temperature increases from 570 °C to 610 °C, the average size and shape factor of solid particles of both the alloys with and without Sm addition gradually decrease while the liquid fraction gradually increases.     

Effects of holding temperature and time on semi-solid isothermal heat-treated microstructure of ZA84 magnesium alloy

The feasibility of fabricating ZA84 magnesium alloy with non-dendritic microstructure by a semi-solid isothermal heat treatment process and the effects of holding temperature and time on the semi-solid isothermal heat-treated microstructure of the alloy were investigated. The results indicate that it is possible to produce ZA84 alloy with non-dendritic microstructure by suitable semi-solid isothermal heat treatment. After being treated at 560-575℃ for 120min, ZA84 magnesium alloy can obtain a non-dendritic microstructure with 14.2%-25.6% liquid fraction and an average size of 56-65μm of the unmelted primary solid particles. With the increasing holding time from 30 to 120min or holding temperature from 560 to 575℃, the average size of unmelted primary solid particles decreases and globular tendency becomes more obvious. Under the experimental condition, the microstructural evolution of ZA84 alloy during semi-solid isothermal treatment is mainly composed of three stages of initial coarsening. structulseparation and spheroidization. The subsequent coarsening of spheroidal grains is not observed.     

热处理温度对半固态挤压锡青铜组织性能的影响

以半固态挤压ZCuSn10P1锡青铜为研究对象,采用光学显微镜、扫描电镜、显微硬度仪、布氏硬度计、拉伸试验机研究了热处理温度对半固态挤压锡青铜微观组织和力学性能的影响规律。结果表明:热处理对半固态挤压锡青铜强度、硬度和组织影响较大。当热处理温度由250℃升高至650℃时,锡青铜抗拉强度先增加后降低,延伸率增加;布氏硬度先增加后降低;固相和固液界面显微硬度增加,液相显微硬度降低;固相平均晶粒尺寸增加,但热处理温度650℃时组织已不是球状而变成蔷薇状。随温度增加,固相中Sn和P元素增加,元素偏析减弱。综合性能较佳的热处理工艺为350℃保温120 min,此时锡青铜抗拉强度为402 MPa,延伸率为4.5%,布氏硬度为1360 MPa,与热处理前相比分别提高了3.88%,60.71%,6.25%。     

Microstructure evolution of semi-solid Mg-14Al-0.5Mn alloys during isothermal heat treatment

A new Mg-14Al-0.5Mn alloy that exhibits a wide solidification range and sufficient fluidity for semi-solid forming was designed.And the microstructure evolution of semi-solid Mg-14Al-0.5Mn alloy during isothermal heat treatment was investigated. The mechanism of the microstructure evolution and the processing conditions for isothermal heat treatment were also discussed.The results show that the microstructures of cast alloys consist ofα-Mg,β-Mg17Al12 and a small amount of Al-Mn compounds.After holding at 520℃ for 3 min,the phases ofβ-Mg17Al12 and eutectic mixtures in the Mg-14Al-0.5Mn alloy melt and the microstructures ofα-Mg change from developed dendrites to irregular solid particles.With increasing the isothermal time,the amount of liquid increases,and the solid particles grow large and become spherical.When the holding time lasts for 20 min or even longer,the solid and liquid phases achieve a state of dynamic equilibrium.     

等温处理对挤压态AZ80A镁合金半固态组织的影响

采用应变诱发熔化激活法(SIMA)工艺制备了AZ80A镁合金半固态坯料,研究了保温温度和保温时间对半固态组织的影响。结果表明:随着保温温度的升高和保温时间的增加,AZ80A镁合金的平均晶粒尺寸与液相率都呈上升趋势,形状因子呈先增大后减小的趋势。半固态组织由α-Mg晶粒、Al、Zn元素富集形成的晶界处液相和晶内“小液池”组成,其组织演变分为初始晶粒合并长大,晶粒球化、彼此分离,最终合并粗化3个阶段。采用该种方法制备AZ80A镁合金半固态坯料时合适的保温温度为550 ℃、保温时间为45 min,此时半固态组织的平均晶粒尺寸、形状因子和液相率分别为89 μm、0.795和26.7%。