共查询到19条相似文献,搜索用时 234 毫秒
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离子液体催化脱除重整芳烃中微量烯烃 总被引:1,自引:0,他引:1
以室温离子液体作为催化剂,考察了间歇反应中离子液体用量和反应时间等因素对脱除芳烃中微量烯烃的影响,并通过连续反应考察了离子液体的寿命.结果表明,在室温,离子液体用量5%,反应10 min的条件下,[bmim]Br-AlCl2离子液体具有优良的催化性能,芳烃中微量烯烃脱除率达到98%以上.离子液体脱除烯烃催化反应机理是烷基化反应. 相似文献
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综述了离子液体在Heck反应、氧化反应、加氢还原反应、傅-克反应和醇的卤代反应中的应用。氯铝酸离子液体催化的合成丁基苯的傅-克反应中,室温下反应3m in即可反应完全,而在离子液体中进行的烯烃加氢反应只需反应6h。离子液体也能加快氧化反应的反应速度。 相似文献
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室温离子液体及其研究进展 总被引:1,自引:0,他引:1
室温离子液体是在室温或室温附近呈液态、具有离子特性的一种液体.因具有较低的熔点,良好的导电性和可以忽略的蒸汽压等优点,引起了科学界和工业界的广泛瞩目.近年来,随着研究的深入,室温离子液体已在化学分离、催化、电化学等方面发挥着重要作用,特别是室温离子液体作为高效绿色溶剂的应用方面越来越被关注.本文对室温离子液体的种类、特性及研究进展方面进行了综述. 相似文献
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在溴化N,N-二烷基咪唑型室温离子液体反应介质中,尝试了甲苯、多聚甲醛和氯化氢气体的氯甲基化反应。以[C5mim]Br为催化剂,考察了反应温度、反应时间和离子液体用量对反应转化率的影响,获得的较佳反应条件为:反应温度65℃,反应时间10h,离子液体催化剂用量为甲苯物质的量的4%,在此条件下甲苯的转化率为82.6%,单氯甲基化选择性为100%。随着溴化N,N-二烷基咪唑型室温离子液体烷基链的增长,甲苯转化率有所提高;以溴化N-十二烷基-3-甲基咪唑离子液体为催化剂时,甲苯转化率可达90%,单氯甲基化选择性为100%。反应结束后产物与离子液体自动分层,便于分离。离子液体催化剂重复使用6次,甲苯转化率保持恒定。 相似文献
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离子液体在有机反应中的应用 总被引:1,自引:0,他引:1
室温离子液体,由含氮的有机阳离子和无机阴离子组成,由于离子液体是很多化合物的溶剂,也能够溶解作为催化剂的过渡金属络合物,其阴离子还是潜在的配位体,故它们能起催化剂的功能,本文着重讨论这方面的发展状况。 相似文献
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Room temperature ionic liquids are salts that are liquids at ambient temperature. They are excellent solvents for a broad
range of polar organic compounds and they show partial miscibility with aromatic hydrocarbons. Typical room temperature ionic
liquids have a stable liquid range of over 300 K and have a very low vapor pressure at room temperature. Ionic liquids that
are not hydrolyzed show a wide range of solubility in water. These unique properties have suggested that they might be useful
as environmentally benign solvents that could replace volatile organic compounds (VOC). By varying the length and branching
of the alkane chains of the cationic core and the anionic precursor, the solvent properties of ionic liquids should be able
to be tailored to meet the requirements of specific applications to create an almost infinitely set of “designer solvents”.
A review of recent applications of ionic liquids is presented along with some results of measurements of liquid-liquid equilibria
and partition coefficients with alcohols. The results are compared with predictions based on quantum mechanic calculations. 相似文献
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室温离子液体的制备及物化性能研究 总被引:8,自引:2,他引:8
合成了[bm im]B r和[bm im]BF4室温离子液体,考察了其在不同溶剂中的溶解性能及导电性能,同时对离子液体在不同溶剂中的紫外吸收进行了测定。结果表明,离子液体在水、乙醇、乙酸、丙酮中可以较好的溶解,而在乙醚、苯、正己烷中不溶解;离子液体的电导率随浓度的增大和温度的升高而增大,在不同的溶剂中的电导率K不同,而且相差很大,其顺序为K(水作溶剂)>K(乙醇作溶剂)>K(乙酸作溶剂)。溶剂的极性对离子液体的紫外吸收影响较大,最大吸收波长的顺序为:λm ax(水为溶剂)<λm ax(乙醇为溶剂)<λm ax(乙酸为溶剂)。 相似文献
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Ionic liquids as electrolytes 总被引:5,自引:0,他引:5
Salts having a low melting point are liquid at room temperature, or even below, and form a new class of liquids usually called room temperature ionic liquids (RTIL). Information about RTILs can be found in the literature with such key words as: room temperature molten salt, low-temperature molten salt, ambient-temperature molten salt, liquid organic salt or simply ionic liquid. Their physicochemical properties are the same as high temperature ionic liquids, but the practical aspects of their maintenance or handling are different enough to merit a distinction. The class of ionic liquids, based on tetraalkylammonium cation and chloroaluminate anion, has been extensively studied since late 1970s of the XX century, following the works of Osteryoung. Systematic research on the application of chloroaluminate ionic liquids as solvents was performed in 1980s. However, ionic liquids based on aluminium halides are moisture sensitive. During the last decade an increasing number of new ionic liquids have been prepared and used as solvents. The general aim of this paper was to review the physical and chemical properties of RTILs from the point of view of their possible application as electrolytes in electrochemical processes and devices. The following points are discussed: melting and freezing, conductivity, viscosity, temperature dependence of conductivity, transport and transference numbers, electrochemical stability, possible application in aluminium electroplating, lithium batteries and in electrochemical capacitors. 相似文献
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Ionic liquids in separations 总被引:5,自引:0,他引:5
Ionic liquids are liquids composed completely of ions. In the past two decades, ionic liquids have been widely used as "green solvents" replacing traditional organic solvents for organic synthesis and catalysis. In addition, ionic liquids are playing an increasingly important role in separation science. In this Account, the application of ionic liquids in all areas of separation science including extractions, gas chromatography, and supported liquid membrane processes are highlighted. 相似文献
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Sang-Mok Lee Woo-Jin Chang Ah-Rom Choi Yoon-Mo Koo 《Korean Journal of Chemical Engineering》2005,22(5):687-690
Ionic liquids are compounds that composed only of ions and are liquid at room temperature. Thus, it is normally named room
temperature ionic liquid (RTIL). In this study, the application of RTILs to the extractive fermentation of biomaterials was
investigated as a substitute of organic solvents. The relative toxicity of the RTILs on the growth ofE. coli was tested. The inhibition of cell growth in the presence of various ionic liquids was measured using solid and liquid culture,
and EC50 of each RTILs was calculated. The number of viable and total cells was measured by the number of colonies and optical density,
respectively. Effective concentrations of toxicity (EC50) in these tested systems were similar with conventional solvents, such as acetone, acetonitrile, and ethanol. The viability
ofE. coli was affected by the polarity and ionic properties of ionic liquids. The resistance of the microorganisms against ionic liquids
was different with the cations and anions composing ionic liquids. No general influence of the anionic compound of the ionic
liquids was found on toxicity comparing with distinctive influence of cationic moiety. 相似文献
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硅胶固定化离子液体的合成与催化醚化性能 总被引:2,自引:0,他引:2
室温离子液体是近年来开发并逐渐应用于有机反应中的绿色溶剂和新型催化剂。将离子液体固定于固相载体上可大大减少离子液体在使用过程中的流失。以硅胶为载体,KH-560为偶联剂合成了烷基硅烷化环氧硅胶,再与N-甲基咪唑在浓硫酸作用下制备硅胶固定化离子液体。探讨了在H 促进下的离子液体对醚化反应的催化性能。实验表明,当仅用浓硫酸催化合成正丁醚时,其产率为34%,当体系中仅加入0.5g离子液体和少量浓盐酸时产率则提高至42%,合成固定化离子液体易回收,可重复利用,当重复使用5次后,正丁醚的产率仍可达37.5%。 相似文献
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绿色溶剂——离子液体及其应用 总被引:9,自引:0,他引:9
离子液体作为“绿色的、可设计性”溶剂越来越受到关注。本文介绍了离子液体种类、特性和制备,综述了离子液体在分离过程、电化学、化学反应及材料领域中的应用,展望了离子液体的应用前景。 相似文献