共查询到20条相似文献,搜索用时 78 毫秒
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采用相转化法,以聚醚砜(PES)、合成辣素、聚乙二醇400(PEG400)、吐温80和N,N-二甲基乙酰胺(DMAc)为原料制备聚醚砜/羧甲基壳聚糖共混超滤膜,并对影响超滤膜结构和性能的各个因素进行了研究。结果表明,在辣素含量为0.5%、反应温度为70℃条件下制备的PES/辣素共混超滤膜性能最优,其纯水通量为87.35 L/m2·h,对牛血清白蛋白截留率为90.71%。改性超滤膜的表面接触角下降为90.7°,阻力增大系数减小为1.09,亲水性能和耐污染性能提高不大,但对大肠杆菌有显著的抑菌作用。 相似文献
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针对聚醚砜(PES)高分子膜材料的分子结构特点进行分子设计,合成了一系列既具有聚醚砜结构单元又有聚乙二醇(PEG)亲水链段的两亲性聚合物PES-co-PEG,与PES共混用相转化法制备超滤膜,对PES-co-PEG进行了表征,考察了反应条件对聚合产物的影响,测试了PES-co-PEG膜的性能。结果表明,使用相对分子质量为2 000的PEG、以环丁砜做溶剂、在230℃下聚合8 h以上反应效果为佳;共混改性的超滤膜纯水通量由99.5 L/(m2.h)最高上升到277.7 L/(m2.h),截留率与纯PES膜相比差别很小,均保持在90%以上;经过纯水清洗后的共混膜的通量基本恢复到原来水平。共混改性成功改善了PES超滤膜的亲水性和抗污染性能。 相似文献
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通过对聚醚砜(PES)超滤膜的水通量,尿素去除率和肌肝去除率的测定,研究了铸膜液中聚醚砜质量分数,凝固浴质量分数,大分子添加剂PVP的含量,小分子添加剂PEG的含量对聚醚砜超滤膜的影响。 相似文献
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采用相转化法,以聚醚砜(PES)、壳聚糖、聚乙二醇400(PEG400)、吐温80和LiCl/N,N-二甲基乙酰胺(DMAo)混合溶剂为原料制备聚醚砜/壳聚糖共混耐污染超滤膜。并对影响超滤膜结构和性能的各个因素进行了研究。结果表明.在壳聚糖质量分数为0.3%、反应温度为80℃条件下制备的聚醚砜/壳聚糖共混耐污染超滤膜性能最优。在25℃、0.1MPa操作条件下,膜的纯水通量为745.22(L/m2·h),牛血清白蛋白截留率为91.79%。改性后的超滤膜表面接触角为74.6°,阻力增大系数为0.54,通量衰减速度小于未改性超滤膜,亲水性能和耐污染性能得到很大提高。 相似文献
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采用静电喷雾法制备了聚醚砜(PES)多孔微球,通过加入亲水性聚合物聚乙烯醇(PEG)和聚乙二醇(PVA)来调控PES多孔微球的孔隙率,利用扫描电子显微镜和热失重法分析仪表征了PES多孔微球的形貌和孔隙率。结果表明,加入亲水性聚合物PEG和PVA均能显著提高PES多孔微球的孔隙率,且随着其添加量的增多,孔隙率呈先增大后减小的趋势;PVA对PES多孔微球孔隙率的调控效果优于PEG,当PVA添加量为3%(质量分数,下同)时,PES多孔微球孔隙率达到最高值91.35%。 相似文献
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乙烯酮(双乙烯酮)是十分重要的化工中间体,其下游产品较多。江苏某化工厂开发生产乙烯酮(双乙烯酮)下游产品三十多个,年生产规模三万多吨,是国内以乙烯酮(双乙烯酮)为中间体生产精细化学品的综合骨干企业。针对乙烯酮(双乙烯酮)下游产品废水特点,该厂结合企业实际,开展了产品优化,结构调整,清洁生产,资源循环利用,节水降耗等工作,从源头削减了污染物的生产。同时投资二千多万元新建预处理装置三套,6000m3/d废水生化处理装置一套,使全厂乙烯酮(双乙烯酮)下游产品的废水得到了有效的治理。 相似文献
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D. G. Gordeev L. F. Gudarenko M. V. Zhernokletov V. G. Kudel’kin M. A. Mochalov 《Combustion, Explosion, and Shock Waves》2008,44(2):177-189
A semi-empirical equation of state for metals is described. Its capabilities are demonstrated by the example of the equation
of state for aluminum. New experimental data are presented on the location of the isentrope of aluminum for unloading from
the state at p = 229.71 GPa on the shock adiabat to an aerogel (SiO2) of density 0.08 g/cm3.
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Translated from Fizika Goreniya i Vzryva, Vol. 44, No. 2, pp. 61–75, March–April, 2008. 相似文献
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Jorge Marcelo Romero Soledad Bustillo Hugo Enrique Ramirez Maisuls Nelly Lidia Jorge Manuel Eduardo Gómez Vara Eduardo Alberto Castro Alicia H. Jubert 《International journal of molecular sciences》2007,8(7):688-694
A thermochemical rather simple experimental technique is applied to determine the enthalpy of formation of Diperoxide of ciclohexanone. The study is complemented with suitable theoretical calculations at the semiempirical and ab initio levels. A particular satisfactory agreement between both ways is found for the ab initio calculation at the 6–311G basis This set level. Some possible extensions of the present procedure are pointed out. 相似文献
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The objective of the study was to explore the effect of the degree of deacetylation (DD) of the chitosan used on the degradation rate and rate constant during ultrasonic degradation. Chitin was extracted from red shrimp process waste. Four different DD chitosans were prepared from chitin by alkali deacetylation. Those chitosans were degraded by ultrasonic radiation to different molecular weights. Changes of the molecular weight were determined by light scattering, and data of molecular weight changes were used to calculate the degradation rate and rate constant. The results were as follows: The molecular weight of chitosans decreased with an increasing ultrasonication time. The curves of the molecular weight versus the ultrasonication time were broken at 1‐h treatment. The degradation rate and rate constant of sonolysis decreased with an increasing ultrasonication time. This may be because the chances of being attacked by the cavitation energy increased with an increasing molecular weight species and may be because smaller molecular weight species have shorter relaxation times and, thus, can alleviate the sonication stress easier. However, the degradation rate and rate constant of sonolysis increased with an increasing DD of the chitosan used. This may be because the flexibilitier molecules of higher DD chitosans are more susceptible to the shear force of elongation flow generated by the cavitation field or due to the bond energy difference of acetamido and β‐1,4‐glucoside linkage or hydrogen bonds. Breakage of the β‐1,4‐glucoside linkage will result in lower molecular weight and an increasing reaction rate and rate constant. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 3526–3531, 2003 相似文献