Nb-Ti微合金钢碳氮化物的析出热力学模型及分析

以规则溶液亚点阵模型为基础,针对Fe-Nb-Ti-C-N系统,进行了热力学平衡计算。计算结果表明,高温阶段的析出相为TiN,微细的TiN强烈地抑制奥氏体晶粒长大;低温阶段的析出相以碳化物(NbTi)C为主,NbC和TiC是抑制奥氏体再结晶及再结晶后晶粒长大的主要因素。析出相形成元素Ti的增加引起其形核化学驱动力增大,并加快析出的动力学过程。     

控轧控冷时Nb-V微合金钢中碳氮化物的析出行为

研究了Ｎｂ（ＣＮ）,Ｖ（ＣＮ）在控轧控冷不同阶段的析出行为,探讨了各阶段析出物在钢中的作用。结果表明,轧后冷却制度对碳氮化物的析出有较大影响。     

Nb-Ti微合金钢中第二相析出的热力学计算

分析了Nb-Ti微合金钢在液相、凝固过程、奥氏体以及铁素体相中氮化物、碳化物和碳氮化物等第二相析出的热力学条件,计算了钛和铌的碳化物和氮化物在不同温度下的溶度积,由此得出微合金钢在不同相阶段的析出规律。计算结果表明,在该微合金钢中,氮化物、碳化物和碳氮化物不可能在液相中析出;TiC0.03N0.97和TiN在凝固过程中具备析出的热力学条件;在奥氏体相中,随着温度的降低,氮化物、碳化物及碳氮化物的析出顺序为:NbC0.75N0.25、NbC、TiC、NbN。     

Nb-Ti微合金钢热变形后组织演变及第二相粒子析出行为

利用GLEEBLE-2000对试验钢进行热模拟试验,并结合显微硬度测试,研究了一种Nb-Ti微合金钢热变形奥氏体的变形后冷却相变行为.利用JEM-2000FX电镜对碳膜萃取复型法获取的第二相析出物进行分析,从而对热变形后冷却相变中的第二相析出行为进行了研究,探讨了不同冷却速度对第二相析出的影响,结果表明,有大量弥散分布的细小粒子析出,析出相主要以Nb-Ti碳氮化物复合相形式存在,一般呈方形、椭圆形、圆形以及不规则形状,并且随着冷却速度的增加,第二相析出增多且变得细小.     

含Nb-Ti微合金汽车用钢高温变形组织及力学性能的研究

研究了含Nb-Ti微合金汽车用钢高温变形时的软化行为和晶粒析出,对析出物的尺寸和分布进行了电镜分析。通过单道次和双道次压下模拟实验,分析了试验钢在不同温度和不同变形条件下的流动应力及显微组织。这些研究为制定最佳控轧工艺,得到细化奥氏体晶粒,获得良好的组织、性能打下了理论基础。     

Nb-Ti微合金钢中的奥氏体晶粒长大行为研究

Nb、Ti是管线钢中常用的合金元素。主要通过热处理和喷碳处理等手段研究了合金元素Nb、Ti的含量及加热制度对再加热奥氏体晶粒长大的影响。试验结果表明:试验钢在再加热过程中,奥氏体晶粒尺寸随加热温度升高而增大;在常规含铌钢中,为获得较小的加热态奥氏体晶粒,钛的质量分数应控制在一定范围内(0.010%~0.015%),钛含量过高或过低都对晶粒细化有不利影响。此外,在钛含量相同的情况下,高铌钢奥氏体晶粒长大明显,高铌钢的最佳钛含量范围也与常规含铌钢的最佳钛含量不同。     

微合金管线钢的碳氮化物高温溶解与析出

结合无缝管线钢的生产实践,根据固溶度积公式和理想化学配比计算出各种微合金的全固溶温度.在连铸过程中,Nb、Ti、Al的析出将降低连铸坯的高温热塑性;在穿孔和连轧过程中,固溶的Ti、Nb、Al的碳氮化物将有效地阻止形变奥氏体再结晶,并诱导析出(Ti,Nb)(C,N);在定径终轧期间及终轧结束后,随着钢中N含量的增加,V的沉淀强化作用增强.     

Nb-Ti微合金钢力学性能的预报模型

根据Nb Ti高强度低合金钢 (0 0 8%～ 0 11%C ,0 0 1%～ 0 0 4 %Nb ,0 0 1%～ 0 2 3%Ti)板材实际生产数据 ,采用多元逐步线性回归 ,得出钢板屈服强度σs(MPa)和抗拉强度σb(MPa)的数学模型 :σs=2 94 0 1Wc+74 7 89WNb+10 2 1 0 9WTi- 0 17Tc+5 95 99;σb=135 6 73WNb+136 1 39WTi- 0 0 1b - 1 6 9h +44 2 4 3(Wc,WNb,WTi为成分质量分数 / % ;Tc 为卷取温度 ;b为成品板宽 ;h为成品板厚 )。同时建立了BP神经网络预报模型 ,两种模型均具有较好的预报精度 ,神经网络预测值与实测值之间的相对误差小于± 10 %。     

碳氮化物析出模型在Nb微合金船板钢连铸工艺中的应用

针对含铌微合金钢(D36船板钢,%:0.12～0.16C、0.25～0.45Si、1.25～1.45Mn、≤0.020P、≤0.010S、0.015～0.040Als、0.015～0.025Nb、≤0.009 0N)连铸过程裂纹敏感性大的问题,建立了Nb(C,N)和A1N在奥氏体中的析出模型,以分析板坯在850～1150℃矫直时Nb(C,N)和AlN析出对铸坯热塑性的影响。结果表明,含铌微合金钢中碳氮化物的析出方式主要是晶界和位错线形核,在950℃时Nb(C,N)的综合析出速度和AlN在晶界上的析出速度最大。因此,含铌微合金钢的矫直温度应大于950℃。     

Two-Sublattice Thermodynamic Model on Carbonitride Precipitation in Microalloyed Steels Bearing Nb-V-Ti

Based on the two sublattice model of the regular solution,one being metal atom sublattice and another being interstitial atom sublattice,a thermodynamic model for the precipitates of niobium carbonitride,vanadium carbonitride and titanium carbonitride was established to study the starting-temperature of precipitates and the austenite compositions at given temperature in a low carbon steel.The calculation results show that starting-temperature of the precipitation of niobium carbonitride,vanadium carbonitride and titanium carbonitride are 1100℃,920℃ and 1340℃,respectively,the mole fraction of carbonitride precipitates is 8.65×10-4 in the 0.053C-0.0028N-1.28Mn-0.008S-0.031Al-0.046Nb-0.008Ti0.029V-Fe steel.When the N content is from 0.0028% to 0.0056%,the starting-temperature of the precipitation of the titanium carbonitride changes from 1340℃ to 1430℃.And the C content is from 0.053% to 0.07%,the startingtemperature of the precipitation of the titanium carbonitride hardly changes,but the atomic fraction of niobium in the carbonitride obviously increases.     

Effects of Rare Earth on Behavior of Precipitation and Properties in Microalloyed Steels

The influence of rare earths on the behavior of precipitation of 14MnNb,X60 and 10Mn V steels was studied by STEM, XRD, ICP and thermal simulation method. The main carbonitride precipitates are Nb(C, N), (Nb, Ti) (C, N) and V(C, N). In austenite RE delays the beginning of precipitation, and decreases the rate of precipitation. In ferrite RE promotes precipitation and increases the amount of equilibrium carbonitride precipitation. RE can make precipitates fine,globular and dispersed in the microalloyed steels. With the increase of the amount of RE in steel, the amount of precipitation increases. The promotion effect is weakened with excessive RE. RE has only little influence on the strength of microalloyed steel, but it can improve impact toughness effectively.     

Influence of cooling rates on the precipitation behavior and microstructure of Nb-Ti microalloyed steel

Influence of different cooling rates on the microstructure and the precipitation behavior of Nb-Ti microalloyed steel was investigated by CSLM,OM,SEM and EDS. The results show that the precipitation process of carbonitrides can be in-situ observed by CSLM,and with the increase of the cooling rate,the distribution of precipitates changes from along the austenitic grain boundaries to within the grains. With the increase of the cooling rate,the proeutectoid ferritic film becomes smaller and smaller and then disappears,and the original austenitic grains become finer and finer. In order to obtain non-film like proeutectoid ferrites or non-chain like precipitates along the austenitic grain boundaries and finer austenitic grains,the cooling rate should be at least 5℃/s.     

Determination of Optimal Recrystallization Annealing Temperature of Nb-Ti Microalloyed High Strength IF Steel

The Nb-Ti microalloyed high strength IF steel sheet was used to study the effect of annealing temperature on the microstructures,mechanical properties and textures.The experimental results show that experimental steel is incomplete recrystallization at 750℃ annealing,but complete recrystallization from 780℃ to 870℃ under experimental conditions.When the annealing temperature was increased,the yield strength and tensile strength would gradually reduce,the plastic strain ratio and yield point elongation would gradually increase.The yield strength,tensile strength,elongation,the plastic strain ratio and the strain hardening exponent were approximate 300MPa,410MPa,36.5%,1.7 and 0.22 respectively under annealing temperature 810℃ to 840℃.When the annealing temperature was increased,the α-textures and γ-textures were gradually weakened,and the α-textures have a trend to {111} texture.Therefore,the suggestion of the optimal recrystallization annealing temperature is about 810℃ to 840℃ in industrial production.     

低碳微合金钢中Nb、Ti碳氮化物的回溶行为研究

利用透射电镜和X射线衍射技术研究了一种低碳微合金钢中Nb、Ti碳氮化物的回溶行为.研究结果表明,随着加热温度的升高,保温时间的延长,第二相粒子发生回溶,第二相粒子的数量减少,尺寸也逐渐变细小.同时,粒子形貌由主要呈近球形逐渐变为主要呈方形.加热过程中,Nb和Ti的碳氮化物均会发生溶解,Nb的回溶速度要比Ti快.     

V含量对V-Mo-N微合金钢贝氏体区析出行为的影响

通过热模拟和透射电镜(TEM)等研究方法对三种不同V含量的V-Mo-N微合金钢在贝氏体铁素体基体中析出粒子分布、形貌和尺寸进行了观察和分析。结果表明:在V-Mo-N微合金钢中,当Mo的添加量较低时,析出粒子为V(C,N),Mo元素全部固溶于基体中起到固溶强化作用,并不会形成Mo的碳氮化物析出。随着V含量的提高,组织中的贝氏体板条逐渐变细并向粒状贝氏体转变。V含量在0.05%~0.16%时,试验钢析出量随V含量增加而增加,同时,钢的硬度也增加。     

Niobium Carbide Precipitation in Microalloyed Steel

The precipitation of niobium carbo‐nitrides in the austenite phase, interphase and ferrite phase of microalloyed steel was assessed by a critical literature review and a round table discussion. This work analyses the contribution of niobium carbide precipitates formed in ferrite in the precipitation hardening of commercially hot rolled strip. Thermodynamics and kinetics of niobium carbo‐nitride precipitation as well as the effect of deformation and temperature on the precipitation kinetics are discussed in various examples to determine the amount of niobium in solid solution that will be available for precipitation hardening after thermomechanical rolling in the austenite phase and successive phase transformation.