跨导为220mS/mm的AlGaN/GaN HEMT

介绍了 Al Ga N/ Ga N HEMT器件的研制及室温下器件特性的测试。漏源欧姆接触采用 Ti/ Al/ Pt/ Au,肖特基结金属为 Pt/ Au。器件栅长为 1 μm,获得最大跨导 2 2 0 m S/ mm,最大的漏源饱和电流密度 0 .72 A/ mm。由 S参数测量推出器件的截止频率和最高振荡频率分别为 1 2 GHz和 2 4GHz。     

AlGaN/GaN HEMT器件的研制

介绍了AlGaN/GaN HEMT器件的研制及室温下器件特性的测试.漏源欧姆接触采用Ti/Al/Pt/Au,肖特基结金属为Pt/Au.器件栅长为1μm,获得的最大跨导为120mS/mm,最大的漏源饱和电流密度为0.95A/mm.     

跨导为220mS／mm的AIGaN／GaN HEMT

介绍了AIGaN／GaN HEMT器件的研制及室温下器件特性的测试。漏源欧姆接触采用Ti／Al／Pt／Au．肖特基结金属为Pt／Au。器件栅长为1μm，获得最大跨导220mS／mm，最大的漏源饱和电流密度0．72A／ram。由S参数测量推出器件的截止频率和最高振荡频率分别为12GHz和24GHz。     

1.0μm栅长GaAs基MHEMT器件及SPDT开关MMIC

利用MBE外延材料和接触式光学光刻方式,成功制备出1.0μm栅长GaAs基MHEMT器件,分别蒸发Pt/Ti/Pt/Au和Ti/Pt/Au作为栅电极金属.获得了优越的DC和RF性能,Pt/Ti/Pt/Au和Ti/Pt/Au MHEMT器件的gm为502(503)mS/mm,JDss为382(530)mA/mm,VT为0.1(-0.5)V,fT和fmax分别为13.4(14.8),17.0(17.5)GHz.利用单片集成增强/耗尽型GaAs基MHEMT器件制备出九阶环型振荡器,直流电压为1.2V时,振荡频率达到777.6MHz,门延迟时间为71.4ps.利用Ti/Pt/Au MHEMT器件设计并制备出了DC-100Hz单刀双掷(SPDT)关MMIC,其插入损耗、隔离度、输入输出回波损耗分别优于2.93,23.34和20dB.     

1.0μm栅长GaAs基MHEMT器件及SPDT开关MMIC

利用MBE外延材料和接触式光学光刻方式,成功制备出1.0μm栅长GaAs基MHEMT器件,分别蒸发Pt/Ti/Pt/Au和Ti/Pt/Au作为栅电极金属.获得了优越的DC和RF性能,Pt/Ti/Pt/Au和Ti/Pt/Au MHEMT器件的gm为502(503)mS/mm,JDss为382(530)mA/mm,VT为0.1(-0.5)V,fT和fmax分别为13.4(14.8),17.0(17.5)GHz.利用单片集成增强/耗尽型GaAs基MHEMT器件制备出九阶环型振荡器,直流电压为1.2V时,振荡频率达到777.6MHz,门延迟时间为71.4ps.利用Ti/Pt/Au MHEMT器件设计并制备出了DC-100Hz单刀双掷(SPDT)关MMIC,其插入损耗、隔离度、输入输出回波损耗分别优于2.93,23.34和20dB.     

fT为102 GHz的蓝宝石衬底AlGaN/GaN高电子迁移率晶体管

研究了一款高性能的AlGaN/GaN高电子迁移率晶体管器件(HEMT),器件基于在蓝宝石衬底上外延生长的AlGaN/GaN异质结构HEMT材料,器件栅长为86 nm,源漏间距为0.8μm。电子束光刻实现T型栅和源漏,保证了器件小的栅长和高的对准精度。制备的器件显示了良好的直流特性和射频特性,在栅偏压为0 V时漏电流密度为995 mA/mm,在栅源电压Vgs为-4.5 V时,最大峰值跨导为225 mS/mm;器件的电流增益截止频率fT和最大振荡频率fmax分别为102和147 GHz。高fT值一方面得益于小栅长,另一方面由于小源漏间距减小了源漏沟道电阻。     

高跨导AlGaN/GaN HEMT器件

报道了生长在蓝宝石衬底上的AlGaN/GaNHEMT器件的制造工艺以及在室温下器件的性能.器件的栅长为1 0 μm ,源漏间距为4 0 μm .器件的最大电流密度达到1 0 0 0mA/mm ,最大跨导高达1 98mS/mm ,转移特性曲线表现出增益带宽较宽的特点.同时由所测得的S参数推出栅长为1 0 μm器件的截止频率(fT)和最高振荡频率(fmax)分别为1 8 7GHz和1 9 1GHz.     

增强型InGaP／AlGaAs／InGaAs PHEMT栅退火工艺

针对InGaP/AlGaAs/lnGaAs PHEMT器件,进行了Ti/Pt/Au和Pt/Ti/Pt/Au两种栅金属结构的退火实验,通过实验研究比较,得到了更适用于增强型器件的退火工艺,利用Ti/Pt/Au结构,在320℃退火40min,使器件阈值电压正向移动大约200mV,从而成功制作了高成品率的稳定一致的增强型器件,保证了增强型器件阈值电压在零以上.     

增强型InGaP/AlGaAs/InGaAs PHEMT栅退火工艺

针对InGaP/AlGaAs/lnGaAs PHEMT器件,进行了Ti/Pt/Au和Pt/Ti/Pt/Au两种栅金属结构的退火实验,通过实验研究比较,得到了更适用于增强型器件的退火工艺,利用Ti/Pt/Au结构,在320℃退火40min,使器件阈值电压正向移动大约200mV,从而成功制作了高成品率的稳定一致的增强型器件,保证了增强型器件阈值电压在零以上.     

新型双异质结双平面掺杂功率PHEMT

设计并制作了双异质结双平面掺杂的Al0 .2 4 Ga0 .76 As/ In0 .2 2 Ga0 .78As/ Al0 .2 4 Ga0 .76 As功率PHEMT器件,采用双选择腐蚀栅槽结构,有效提高了PHEMT器件的输出电流和击穿电压.对于1μm栅长的器件,最大输出电流为5 0 0 m A/ mm ,跨导为2 75 m S/ m m,阈值电压为- 1 .4 V,最大栅漏反向击穿电压达到了33V .研究结果表明,在栅源间距一定时,栅漏间距对于器件的输出电流、跨导和击穿电压有很大关系,是设计功率PHEMT的关键之一.     

P型GaAs欧姆接触的制作

在以Be作为离子源离子注入形成的P型GaAs衬底上分别使用Ti/Pt/Au和Cr/Pt/Au多层金属作为欧姆接触金属,并对比合金前后的差别。结果表明,使用Ti/Pt/Au作为欧姆接触金属效果更好,合金对于降低欧姆接触电阻率效果明显,合金后Ti/Pt/Au的接触电阻率可达到3.08×10-5Ω.cm2。     

单片集成GaAs增强／耗尽型赝配高电子迁移率晶体管

介绍了单片集成GaAs增强／耗尽型赝配高电子迁移率晶体管（PHEMT）工艺。借助栅金属的热处理过程,形成了热稳定性良好的Pt／Ti／Pt／Au栅。AFM照片结果表明Pt金属膜表面非常平整,2nm厚度膜的粗糙度RMS仅为0．172nm。通过实验,我们还得出第一层Pt金属膜的厚度和退火后的下沉深度比大概为1：2。制作的增强型／耗尽型PHEMT的闽值电压（定义于1mA／mm）、最大跨导、最大饱和漏电流密度、电流增益截止频率分别是＋0．185／-1．22V、381．2／317．5mS／mm、275／480mA／mm、38／34GHz。增强型器件在4英寸圆片上的阈值电压标准差为19mV。     

Monolithic microwave amplifiers formed by ion implantation into LEC gallium arsenide substrates

A fabrication procedure for broad-band monolithic power GaAs integrated circuits has been demonstrated which includes formation of via holes through the 100-µm-thick GaAs substrate. A selective implant of²⁹Si ions into the GaAs substrate is used to dope the FET channel region to 1.2 × 10¹⁷cm^-3. The ohmic contacts are AuGe/Ni/Pt and the gates are Ti/Pt/Au. A 1.5-µm-thick circuit pattern is achieved using metal rejection assited by chlorobenzene treatment of AZ1350J photoresist. Using undoped Czochralski wafers of GaAs pulled from a pyrolytic boron nitride crucible, integrated amplifiers have been produced which deliver 28 ± 0.7 dBm from 5.7 to 11 GHz. These chips are 2 mm × 4.75 mm × 0.1 mm thick.     

Low resistance, thermally stable Au/Pt/Ti/WSiN ohmic contacts on n+-InGaAs/n-GaAs layer systems

The electrical properties of the ohmic contact systems Au/Pt/Ti/WSiN and Au/Pt/Ti to n⁺-InGaAs/GaAs layers grown by metalorganic vapor phase epitaxy were investigated and compared to each other. The thermal stability properties of these contact systems were characterized by accelerated stress tests at elevated temperatures and by complementary thin film x-ray diffraction analysis to evaluate the microstructural properties of degraded and nondegraded structures. The goal of these efforts was to develop stable, homogeneous emitter contacts for power heterojunction bipolar transistors. It was found that for both contact systems the best (specific) contact resistance R_c (ρ _c) is about 0.05 Ωmm (2 × 10⁻⁷ Ωcm²) in the as-deposited state. Au/Pt/Ti/WSiN contacts show no degradation after aging at 400°C for more than 20 h. This is in contrast to standard Au/Pt/Ti contacts which significantly degrade even after short time annealing at 400°C. The good long-time stability of the Au/Pt/Ti/WSiN system is related to the advantageous properties of the reactively sputtered WSiN barrier layer.     

Improved Hydrogen Production of Au–Pt–CdS Hetero‐Nanostructures by Efficient Plasmon‐Induced Multipathway Electron Transfer

The design of new functional materials with excellent hydrogen production activity under visible‐light irradiation has critical significance for solving the energy crisis. A well‐controlled synthesis strategy is developed to prepare an Au–Pt–CdS hetero‐nanostructure, in which each component of Au, Pt, and CdS has direct contact with the other two materials; Pt is on the tips and a CdS layer along the sides of an Au nanotriangle (NT), which exhibits excellent photocatalytic activity for hydrogen production under light irradiation (λ > 420 nm). The sequential growth and surfactant‐dependent deposition produce the three‐component Au–Pt–CdS hybrids with the Au NT acting as core while Pt and CdS serve as a co‐shell. Due to the presence of the Au NT cores, the Au–Pt–CdS nanostructures possess highly enhanced light‐harvesting and strong local‐electric‐field enhancement. Moreover, the intimate and multi‐interface contact generates multiple electron‐transfer pathways (Au to CdS, CdS to Pt and Au to Pt) which guide photoexcited electrons to the co‐catalyst Pt for an efficient hydrogen reduction reaction. By evaluating the hydrogen production rate when aqueous Na₂SO₃–Na₂S solution is used as sacrificial agent, the Au–Pt–CdS hybrid exhibits excellent photocatalytic activity that is about 2.5 and 1.4 times larger than those of CdS/Pt and Au@CdS/Pt, respectively.     

Novel resonant tunneling transistor with high transconductance atroom temperature

A resonant tunneling transistor (RTT) utilizing a novel heterodimensional Schottky gate technology is described. The gate is formed by electroplating Pt/Au onto the side of an AlGaAs/GaAs double barrier structure. The gate voltage modulates the drain current by modulating the area of the quasi-two dimensional electron accumulation layer which forms above the source barrier under drain-source bias. Room temperature transistor characteristics included a peak current of 225 mA/mm and peak transconductance of 218 mS/mm. The ultrafine fabrication process is also discussed     

负载Au或Pt的TiO2纳米管薄膜的光电性能研究

为了比较两种贵金属(Au和Pt)在改善TiO₂纳米 管(TNT)阵列薄膜光电性能时的不同 贡献,实验采用后期掺杂法和前期掺杂法分别制备了Au或Pt纳米粒子修饰的TNT阵列薄膜, 分别命名为TNT-Au和TNT-Pt、Au/TNT和Pt/TNT。通过测试样品的P-V特性曲线和光催化降解 行为,发现无论采用哪种方法,贵金属掺杂的TNT阵列薄膜的光电性能都得到了改善。相对 于纯TNT阵列薄膜,TNT-Pt薄膜的光电转换效率最高,约是35倍;TN T-Au薄膜的光催化活性 最高,约是2倍。而且还发现,对于光电转换效率,TNT-Pt薄膜约是TNT-Au薄膜的10倍,Pt /TNT薄膜约是Au/TNT薄膜的2.9倍;对于光催化降解率,TNT-Au薄膜 约是TNT-Pt薄膜的1.5倍 ,Au/TNT薄膜约是Pt/TNT薄膜的1.2倍。因此可以总结,Pt纳米粒子 比Au纳米粒子更有利于 提高TNT阵列薄膜的光电转换效率,而Au纳米粒子比Pt纳米粒子更有利于改善TNT阵列薄膜的 光催化活性。