Chemically reactive solute transfer in a boundary layer slip flow along a stretching cylinder

This paper presents the distribution of a solute undergoing a first order chemical reaction in an axisymmetric laminar boundary layer flow along a stretching cylinder. Velocity slip condition at the boundary is used instead of no-slip condition. Similarity transformations are used to convert the partial differential equations corresponding to momentum and concentration into highly nonlinear ordinary differential equations. Numerical solutions of these equations are obtained by the shooting method. The velocity decreases with increasing slip parameter. The skin friction as well as the mass transfer rate at the surface is larger for a cylinder than for a flat plate.     

SLIP EFFECT ON DIFFUSION OF CHEMICALLY REACTIVE SPECIES IN BOUNDARY LAYER FLOW OVER A VERTICAL STRETCHING SHEET WITH SUCTION OR BLOWING

In the present investigation, we study the effects of slip boundary condition on the diffusion of chemically reactive species in steady boundary layer flow of viscous incompressible fluid over a vertical stretching sheet with suction or blowing. The first-order chemical reaction is considered and wall concentration varies linearly along the sheet. The self-similar equations are obtained using similarity transformations and are solved numerically using shooting method. Our study reveals that due to the increase of diffusion parameter and blowing, the velocity increases, and it decreases with suction, Schmidt number, and reaction rate parameter. Importantly, for increase of slip parameter, the boundary layer thickness increases. In contrast, the concentration at a point increases only for increasing slip and blowing, while it decreases for increase of all other parameters.     

UNSTEADY MHD BOUNDARY LAYER FLOW WITH DIFFUSION AND FIRST-ORDER CHEMICAL REACTION OVER A PERMEABLE STRETCHING SHEET WITH SUCTION OR BLOWING

In this study, unsteady MHD boundary layer flow with diffusion of chemically reactive species undergoing first-order chemical reaction over a permeable stretching sheet with suction or blowing and also with power-law variation in wall concentration is investigated. Using similarity transformation, the governing partial differential equations are converted into nonlinear self-similar ordinary differential equations. The transformed equations are then solved by the finite difference method using the quasi-linearization technique. Due to the increase in the unsteadiness parameter, the velocity initially decreases, but after a certain point it increases. A similar effect is also observed in case of concentration distribution. The increase in magnetic parameter causes a decrease in velocity and an increase in concentration. For increasing strength of applied suction both momentum and concentration boundary layer thicknesses decrease. On the other hand, applied blowing has reverse effects. Moreover, the mass transfer from the sheet is enhanced with increasing values of Schmidt number, reaction rate parameter, and also power-law exponent (related to wall concentration distribution). For high negative values of the power-law exponent, mass absorption at the sheet occurs. Moreover, due to increase of unsteadiness, this mass absorption is prevented.     

DIFFUSION OF CHEMICALLY REACTIVE SPECIES IN BOUNDARY LAYER FLOW OVER A POROUS PLATE IN POROUS MEDIUM

Analysis was made to study the effect of diffusion of chemically reactive species in boundary layer flow of an incompressible fluid over a porous flat plate in porous medium. The first-order chemical reaction was considered and the reaction rate of the reactive species was taken in such a manner that it varied inversely along the plate. Self-similar equations were obtained using similarity transformations and were then solved by the shooting technique using the fourth-order Runge-Kutta method. This analysis revealed that at a fixed point, with increase of the permeability of the porous medium the velocity increases, but the concentration decreases. The suction reduces the thicknesses of momentum and concentration boundary layers but due to blowing the thicknesses become larger. With increase of both the Schmidt number and the reaction rate parameter, the reactive concentration profiles decrease. For a destructive chemical reaction, the concentration profiles exhibit negative value when the Schmidt number is large. It is very significant to note that in some constructive chemical reaction cases the mass absorption at the plate occurs for small Schmidt number.     

Stagnation slip flow and heat transfer on a moving plate

A two-dimensional or axisymmetric stagnation flow impinges on a plate moving in its own plane. The no slip condition on the solid boundary is replaced by the partial slip condition. The Navier-Stokes and energy equations admit exact similarity solutions. The resulting nonlinear differential equations are solved asymptotically and numerically. The flow depends heavily on the velocity slip factor λ. We find drag decreases as 1/λ and heat transfer increases with λ, the Prandtl number, and decreased thermal slip.     

Effects of radiation and heat source/sink on unsteady MHD boundary layer flow and heat transfer over a shrinking sheet with suction/injection

In this paper, an investigation is made to study the effects of radiation and heat source/sink on the unsteady boundary layer flow and heat transfer past a shrinking sheet with suction/injection. The flow is permeated by an externally applied magnetic field normal to the plane of flow. The self-similar equations corresponding to the velocity and temperature fields are obtained, and then solved numerically by finite difference method using quasilinearization technique. The study reveals that the momentum boundary layer thickness increases with increasing unsteadiness and decreases with magnetic field. The thermal boundary layer thickness decreases with Prandtl number, radiation parameter and heat sink parameter, but it increases with heat source parameter. Moreover, increasing unsteadiness, magnetic field strength, radiation and heat sink strength boost the heat transfer.     

反渗透过程的浓度极化及其传质系数测定

The relationship between osmotic pressure difference across the membrane and mass transfer coefficient is developed in this paper. On the basis of this relationship, a method for measuring mass transfer coefficient by using experimental data on reverse osmosis is established. Pitzer's equations are used to calculate osmotic pressure differences in order to assure accuracy of results. Under the conditions of constant operating pressure and bulk flow, mass transfer coefficient is scarcely affected by membrane structure, but decreases slightly with increasing feed concentration. The solute concentration in the polarization layer is calculated by using the measured values of mass transfer coefficient. Polarization layer concentration increases with augmentation in bulk concentration. However, their difference increases with increasing bulk concentration until a maximum difference is reached, and then decreases. Mass transfer coefficient increases with higher velocity of bulk flow. If mass transfer coefficient is so large that the ratio(PwΔπσ/k)becomes very small, polarization could be neglected.     

UNSTEADY FLUID AND HEAT FLOW INDUCED BY A STRETCHING SHEET WITH MASS TRANSFER AND CHEMICAL REACTION

The effect of chemical reaction on the flow, heat, and mass transfer within a viscous fluid on an unsteady stretching sheet is examined. The stretching rate, temperature and concentration of the sheet, and the chemical reaction rate are assumed to vary with time. The time-dependent boundary layer equations governing the flow are reduced through a convenient similarity transformation to a set of ordinary differential equations, which are numerically solved by applying the fourth-order Runge-Kutta-Fehlberg scheme with the shooting technique. Results for the velocity, temperature, and concentration distributions as well as the wall temperature and concentration gradients are presented graphically for various values of the unsteadiness parameter A, Prandtl number Pr, Schmidt number Sc, and chemical reaction parameter γ.     

Effects of higher order chemical reaction on micropolar fluid flow on a power law permeable stretched sheet with variable concentration in a porous medium

An analysis has been carried out to obtain the effects of higher order chemical reaction on flow and mass transfer characteristics of micropolar fluids past a nonlinear permeable stretching sheet immersed in a porous medium with variable concentration of the reactant. The local similarity solutions for the flow, microrotation and mass transfer are obtained numerically and are illustrated graphically for various material parameters. Comparisons carried out with results from previously published work present excellent agreement. The results show that rate of mass transfer from the sheet to the surrounding fluid decreases significantly with the increase of nonlinear stretching parameter and increases with the increase of concentration parameter. The mass transfer of the reactive species strongly depends on the reaction rate parameter as well as order of the chemical reaction. It is stronger for the first‐order reaction than that for the higher order reaction. The rate of surface mass transfer decreases with the increase of the Darcy parameter. The results also show that the effect of these parameters on the micropolar fluids are less compared to the Newtonian fluids.     

边界层方程求解传热传质复合自然对流的偏差分析

引　言动量、能量及质量的边界层方程是Naveir Stokes完整方程的简化形式 ,自上世纪初提出以来 ,应用极广 .传热传质复合自然对流是自然界和工业过程中常见的现象 ,由于存在热与物质扩散两种浮力相对大小及方向的差异以及Prandtl数和Schmit数的影响 ,使该问题颇为复杂 .Bottema     

MHD flow and heat transfer of a micropolar fluid over a nonlinear stretching surface with variable surface heat flux and heat generation

An analysis has been carried out to study magnetohydrodynamic boundary layer flow and heat transfer of an electrically conducting micropolar fluid over a nonlinear stretching surface with variable wall heat flux in the presence of heat generation/absorption and a non‐uniform transverse magnetic field. The governing system of partial differential equations is first transformed into a system of ordinary differential equations using similarity transformation. The transformed equations are solved numerically. Results for the dimensionless velocity, micro‐rotation, and temperature profiles are displayed graphically delineating the effects of various parameters characterising the flow. The results show that the velocity profile decreases as the magnetic parameter and the velocity exponent increase, while it increases as the material parameter increases. The results show also that the temperature profile increases as the magnetic parameter, the velocity exponent, and the heat generation parameter increase. Furthermore, the temperature profile decreases as the material parameter, the heat absorption parameter, and the Prandtl number increase.     

MASS TRANSFER OVER AN EXPONENTIALLY STRETCHING POROUS SHEET EMBEDDED IN A STRATIFIED MEDIUM

The boundary layer flow and mass transfer towards an exponentially stretching porous sheet embedded in a stratified medium is presented in this analysis. A first-order constructive/destructive chemical reaction is also considered. Similarity transformations were used to convert the partial differential equations corresponding to the momentum and concentration into highly nonlinear ordinary differential equations. Numerical solutions of these equations were obtained by the shooting method. Mass absorption at the surface was found in the case of a stratified medium, and it increased with an increase of stratification parameter. Due to increasing reaction rate parameter the concentration decreased. It is important to note that concentration overshoot was observed in the case of a stratified medium.     

Boundary layer flow past a stretching/shrinking surface beneath an external uniform shear flow with a convective surface boundary condition in a nanofluid

The problem of a steady boundary layer shear flow over a stretching/shrinking sheet in a nanofluid is studied numerically. The governing partial differential equations are transformed into ordinary differential equations using a similarity transformation, before being solved numerically by a Runge-Kutta-Fehlberg method with shooting technique. Two types of nanofluids, namely, Cu-water and Ag-water are used. The effects of nanoparticle volume fraction, the type of nanoparticles, the convective parameter, and the thermal conductivity on the heat transfer characteristics are discussed. It is found that the heat transfer rate at the surface increases with increasing nanoparticle volume fraction while it decreases with the convective parameter. Moreover, the heat transfer rate at the surface of Cu-water nanofluid is higher than that at the surface of Ag-water nanofluid even though the thermal conductivity of Ag is higher than that of Cu.     

Mechanisms of mass transfer of dissolved gas from a gas-evolving electrode and their effect on mass transfer coefficient and concentration overpotential

Dissolved gases in the boundary layer of gas-evolving electrodes, in constrast to all other substances generated or consumed at electrodes, undergo two superimposed mass transfer mechanisms. Their interaction results in an increase of the effective mass transfer coefficient of disolved gas. A correction factor to the coefficient calculated from available mass transfer equations is proposed. The effect on the concentration overpotential is discussed.     

Unsteady mass transfer around spheroidal drops in potential flow

Unsteady mass transfer in the continuous phase around spheroidal drops in potential flow and at high Peclet numbers has been theoretically studied. Analytical solutions for the concentration profile, the molar flux, the concentration boundary layer thickness, and the time to reach steady state are presented. The solution to the problem was obtained by the useful equations derived by Favelukis and Mudunuri for axisymmetric drops of revolution, with the only requirements being the shape of the drop and the tangential velocity at the surface of the drop. The solution suggests that, as the eccentricity increases, the total quantity of material transferred to or from the drop decreases (for prolate spheroids) and increases (for oblate spheroids). It was also determined that when the dimensionless time is greater than 2, then steady state is in practice obtained, with prolate drops attain steady-state conditions faster than oblate drops.     

Combined effects of internal heat generation and higher order chemical reaction on the non‐darcian forced convective flow of a viscous incompressible fluid with variable viscosity and thermal conductivity over a stretching surface embedded in a porous medium

In this paper, we study the combined effects of internal heat generation and higher order chemical reaction on a steady two‐dimensional non‐Darcian forced convective flow of a viscous incompressible fluid with variable dynamic viscosity and thermal conductivity in a fluid saturated porous medium passing over a linear stretching sheet. Using similarity transformations, the governing nonlinear‐coupled partial differential equations are made dimensionless and solved numerically for similarity solutions using very robust computer algebra software Maple 8. The non‐dimensional velocity, temperature and concentration distributions are presented graphically for various pertinent parameters such as relative temperature difference parameter, Darcy number, porosity parameter, reaction rate parameter and the order of the chemical reaction. The variations of Prandtl number and Schmidt number within the boundary layer are also displayed graphically when the fluid dynamic viscosity and thermal conductivity are temperature dependent. From the present numerical computations it is found that Prandtl number as well as Schmidt number must be taken as variables within the flow domain when the fluid's dynamic viscosity and thermal conductivity are variable. In the presence of internal heat generation, dynamic viscosity and thermal conductivity of the fluid are found to be higher than when it is absent. Increasing Darcy number reduces dynamic viscosity as well as thermal conductivity whereas increasing pore size reduces the Schmidt number and increases the Prandtl number within the boundary layer. For higher order reaction the rate of increase in mass transfer function is less compared to the rate of increase for the lower order reaction. © 2011 Canadian Society for Chemical Engineering     

Mass‐transfer enhancement by a reversible chemical reaction across the interface of a bubble rising under Stokes flow

Mass transfer around a bubble rising in a liquid under Stokes regime is investigated when a reversible chemical reaction, , is taken into account. Four dimensionless parameters control the interfacial transfer rate: the Péclet and Damköhler numbers, the ratio of the diffusion coefficient of both species, and the reaction equilibrium constant. The mass‐transfer equations are solved numerically with a finite element technique. A boundary layer approach is also proposed and solved with a coupled technique of finite difference and Chebyshev‐spectral method. The equilibrium constant and the ratio of diffusion coefficients have a strong influence on the coupling between the chemical reaction and mass transfer leading to an increase of the Sherwood number. The interaction between the chemical reaction and advection is clearly established by the simulations. Conditions corresponding to Péclet number larger than the Damköhler number reduces the effect of the chemical reaction. © 2014 American Institute of Chemical Engineers AIChE J, 60: 3376–3388, 2014     

Fundamentals of membrane transport

A review is presented to give a generalized membrane transport theory based on the principles of nonequilibrium thermodynamics. This theory is then used to develop specific flux equations for gas separation, pervaporation, osmosis, reverse osmosis, nanofiltration, ultrafiltration, microfiltration, dialysis, and electrodialysis. All membrane processes suffer from boundary layer mass transfer resistances caused by concentration polarization. The convective motions parallel and perpendicular to the membrane surface are distinguishable, and the former becomes more relevant than the latter in the boundary layer mass transfer. The modified P??clet number is introduced and its importance is discussed in characterizing the boundary layer mass transfers of various membrane processes. Many different transport mechanisms through membrane itself are reviewed including the solution-diffusion model, pore model, permeation through composite membranes, and transport through inorganic membranes. Finally, the differences between membrane mass transfer and other mass transfer are delineated, including a discussion of negative mass transfer coefficient.     

Thermal Diffusion and MHD Effects on Combined Free‐Forced Convection and Mass Transfer of a Viscous Fluid Flow Through a Porous Medium with Heat Generation

The problem of thermal diffusion and magnetic field effects on combined free‐forced convection and mass transfer flow past a vertical porous flat plate, in the presence of heat generation is studied numerically. The governing momentum, energy and concentration equations are converted into a system of nonlinear ordinary differential equations by means of similarity transformations. The resulting system of coupled nonlinear ordinary differential equations is solved numerically by using the Shooting method. Numerical results are presented for velocity, temperature and concentration profiles within the boundary layer for different parameters of the problem including suction parameter, heat generation parameter, Soret number, Dufour number, magnetic parameter, etc. In addition, the effects of the pertinent parameters on the skin friction and the rates of heat and mass transfer are discussed numerically and illustrated graphically.     

On MHD heat and mass transfer over a moving vertical plate with a convective surface boundary condition

In this paper, the magnetohydrodynamics (MHD) boundary layer flow with heat and mass transfer over a moving vertical plate in the presence of magnetic field and a convective heat exchange at the surface with the surrounding has been studied. The similarity solution is used to transform the system of partial differential equations, describing the problem under consideration, into a boundary value problem of coupled ordinary differential equations, and an efficient numerical technique is implemented to solve the reduced system. The results are presented graphically and the conclusion is drawn that the flow field and other quantities of physical interest are significantly influenced by these parameters.