An evaluation exercise of a wind pressure distribution model

The wind pressure distribution (WPD) around a building is an important parameter for multi-zone airflow simulation. The input is usually in the form of pressure coefficients (C_p). The values of C_p are traditionally derived based on wind tunnel studies. However, since it is not possible to always conduct wind tunnel tests to obtain the C_p values, alternative approaches have been suggested. One approach involves the use of statistical regression analysis of data obtained from wind tunnel studies. In this paper, C_p values of a shophouse building under investigation are generated using wind tunnel, a WPD model, which is based on the regression analysis of wind tunnel data as well as based on wall averaged values from published data. Using the C_p values obtained from the wind tunnel as the reference, the accuracy of the C_p values generated by the WPD model and the wall averaged values are analysed and discussed. The effects of such accuracy on the computed air flow rates and age of air for the building using a multi-zone network airflow model are also considered.     

Vertical profiles of aerosol absorption coefficient from micro-Aethalometer data and Mie calculation over Milan

Vertical profiles of aerosol number-size distribution and black carbon (BC) concentration were measured between ground-level and 500 m AGL over Milan. A tethered balloon was fitted with an instrumentation package consisting of the newly-developed micro-Aethalometer (microAeth® Model AE51, Magee Scientific, USA), an optical particle counter, and a portable meteorological station. At the same time, PM_2.5 samples were collected both at ground-level and at a high altitude sampling site, enabling particle chemical composition to be determined. Vertical profiles and PM_2.5 data were collected both within and above the mixing layer. Absorption coefficient (b_abs) profiles were calculated from the Aethalometer data: in order to do so, an optical enhancement factor (C), accounting for multiple light-scattering within the filter of the new microAeth® Model AE51, was determined for the first time. The value of this parameter C (2.05 ± 0.03 at λ = 880 nm) was calculated by comparing the Aethalometer attenuation coefficient and aerosol optical properties determined from OPC data along vertical profiles. Mie calculations were applied to the OPC number-size distribution data, and the aerosol refractive index was calculated using the effective medium approximation applied to aerosol chemical composition. The results compare well with AERONET data.The BC and b_abs profiles showed a sharp decrease at the mixing height (MH), and fairly constant values of b_abs and BC were found above the MH, representing 17 ± 2% of those values measured within the mixing layer. The BC fraction of aerosol volume was found to be lower above the MH: 48 ± 8% of the corresponding ground-level values.A statistical mean profile was calculated, both for BC and b_abs, to better describe their behaviour; the model enabled us to compute their average behaviour as a function of height, thus laying the foundations for valid parametrizations of vertical profile data which can be useful in both remote sensing and climatic studies.     

Aerodynamics of spinning and non-spinning tennis balls

The aerodynamic properties of a tennis ball are obtained using wind tunnel measurements. In the first phase of this study, the drag coefficient of a variety of new and used non-spinning tennis balls was measured. The measurements were conducted in the Reynolds number range of 85×10³<Re<250×10³, which corresponds to a velocity range of 20<U<60 ms⁻¹ (45<U<135 mph). The data for the new tennis balls revealed that all balls have similar drag coefficients, within the repeatability of the experiment. However, it was shown that a heavily worn ball exhibits a significant decrease in drag coefficient. A simple trajectory plot was used to illustrate the significance of this drop in C_D, on a typical tennis stroke. It was shown that if the drag coefficient of the worn ball was reduced even further, then the ball would travel faster through the air, and give the receiver a significantly shorter time to react to the shot.In the second phase of this study, the drag and lift coefficients of new and used spinning tennis balls was measured. This testing was conducted by placing the ball inside the working section of the wind tunnel, held between two horizontal shafts. The ball was spun at rates up to 2750 rpm, which is representative of a typical top spin shot hit by a professional player. The data showed that the lift coefficient for all the new balls was identical. However, the lift coefficient was generally lower for the heavily worn ball compared with the new ball. A trajectory plot was calculated to illustrate the effect of the lower drag and lift coefficients of the worn ball, compared to the new ball. It was shown that the lift coefficient value has little effect on the reaction time of the receiver. It was also shown that a lower lift coefficient reduces the window of opportunity for the server because the player is less able to utilise the spin to control the shot to ensure that the ball both clears the net and also lands in the service box. This highlights the fact that it may not be in the manufacturers interest to produce a ‘faster’ tennis ball with a lower drag coefficient, because the ball may also have a lower lift coefficient, thus reducing the players ability to play certain strokes.     

Overview of pressure coefficient data in building energy simulation and airflow network programs

Wind pressure coefficients (C_p) are influenced by a wide range of parameters, including building geometry, facade detailing, position on the facade, the degree of exposure/sheltering, wind speed and wind direction. As it is practically impossible to take into account the full complexity of pressure coefficient variation, building energy simulation (BES) and Airflow network (AFN) programs generally incorporate it in a simplified way. This paper provides an overview of pressure coefficient data and the extent to which they are currently implemented in BES–AFN programs. A distinction is made between primary sources of C_p data, such as full-scale measurements, reduced-scale measurements in wind tunnels and computational fluid dynamics (CFD) simulations, and secondary sources, such as databases and analytical models. The comparison between data from secondary sources implemented in BES–AFN programs shows that the C_p values are quite different depending on the source adopted. The two influencing parameters for which these differences are most pronounced are the position on the facade and the degree of exposure/sheltering. The comparison of C_p data from different sources for sheltered buildings shows the largest differences, and data from different sources even present different trends. The paper concludes that quantification of the uncertainty related to such data sources is required to guide future improvements in C_p implementation in BES–AFN programs.     

Measured and predicted performance of prefabricated vertical drains (PVDs) with and without vacuum preloading

This paper presents the effectiveness of vacuum preloading in accelerating the consolidation of PVD improved soft Bangkok clay by comparing with the corresponding results without vacuum preloading. Laboratory tests were conducted using a large scale consolidometer having diameter of 300 mm and height of 500 mm with reconstituted specimens installed with prefabricated vertical drains (PVD) with and without vacuum preloading. In addition, field data were collected from Second Bangkok International Airport (SBIA) site improved by PVD with and without vacuum pressures. Analyses were carried out to compare the compressibility parameters (C_h and k_h/k_s) by back-calculation of laboratory and field settlements using Hansbo (1979) method. From the laboratory tests, the horizontal coefficient of consolidation (C_h) values from reconstituted specimens were 1.08 and 1.87 m²/yr for PVD without and with vacuum pressure, respectively and the k_h/k_s values were 2.7 for PVD only and 2.5 for vacuum-PVD. After the improvement, the water contents of the soft clay were reduced, thereby, increasing its undrained shear strengths. Similarly, the field data analysis based on the back-calculated results showed that the k_h/k_s were 7.2 and 6.6 for PVD without and with vacuum, respectively. The C_h values increased slightly from 2.17 m²/yr for PVD only to 3.51 m²/yr for vacuum-PVD. The time to reach 90% degree of consolidation for soils with vacuum-PVD was one-third shorter than that for soils with PVD only because of higher C_h values. Thus, the addition of vacuum pressure leads to increase horizontal coefficient of consolidation which shortened the time of preloading. The PVDCON software was found to be useful to predict the settlements of the PVD improved ground with and without vacuum preloading.     

Air quality influenced by urban heat island coupled with synoptic weather patterns

Few studies have discussed the association between the urban heat island (UHI) phenomenon and air quality under synoptic weather patterns conducive to UHI. In this study, the authors used statistical analyses to study this association in the Taichung metropolis region. The air quality data obtained from government-owned observation stations and wind field profiles obtained from tethersonde monitoring (performed during 21-29 October 2004) were combined with the simulations of the horizontal wind fields at different heights by the air pollution model (TAPM).The results show that certain specific synoptic weather patterns worsen the air quality and induce the UHI phenomenon: Taichung's UHI appears clearly under the synoptic weather patterns featuring light air or breezes (0.56 m/s ≤ wind speed < 2.2 m/s) mainly from the north and west. Furthermore, under these weather patterns, the concentrations of air pollutants (NO₂, CO₂ and CO) increase significantly (P < 0.05) with the UHI intensity. The convergence usually associated with nocturnal UHI causes the accumulation of O₃ precursors, as well as other air pollutants, thereby worsening the air quality at that time and also during the following daytime period.     

Factors influencing relationships between personal and ambient concentrations of gaseous and particulate pollutants

Previous exposure studies have shown considerable inter-subject variability in personal-ambient associations. This paper investigates exposure factors that may be responsible for inter-subject variability in these personal-ambient associations. The personal and ambient data used in this paper were collected as part of a personal exposure study conducted in Boston, MA, during 1999-2000. This study was one of a group of personal exposure panel studies funded by the U.S. Environmental Protection Agency's National Exposure Research Laboratory to address areas of exposure assessment warranting further study, particularly associations between personal exposures and ambient concentrations of particulate matter and gaseous co-pollutants. Twenty-four-hour integrated personal, home indoor, home outdoor and ambient sulfate, elemental carbon (EC), PM_2.5, ozone (O₃), nitrogen dioxide (NO₂) and sulfur dioxide were measured simultaneously each day. Fifteen homes in the Boston area were measured for 7 days during winter and summer. A previous paper explored the associations between personal-indoor, personal-outdoor, personal-ambient, indoor-outdoor, indoor-ambient and outdoor-ambient PM_2.5, sulfate and EC concentrations. For the current paper, factors that may affect personal exposures were investigated, while controlling for ambient concentrations. The data were analyzed using mixed effects regression models. Overall personal-ambient associations were strong for sulfate during winter (p < 0.0001) and summer (p < 0.0001) and PM_2.5 during summer (p < 0.0001). The personal-ambient mixed model slope for PM_2.5 during winter but was not significant at p = 0.10. Personal exposures to most pollutants, with the exception of NO₂, increased with ventilation and time spent outdoors. An opposite pattern was found for NO₂ likely due to gas stoves. Personal exposures to PM_2.5 and to traffic-related pollutants, EC and NO₂, were higher for those individuals living close to a major road. Both personal and indoor sulfate and PM_2.5 concentrations were higher for homes using humidifiers. The impact of outdoor sources on personal and indoor concentrations increased with ventilation, whereas an opposite effect was observed for the impact of indoor sources.     

Persistence and partitioning of eight selected pharmaceuticals in the aquatic environment: Laboratory photolysis, biodegradation, and sorption experiments

We selected eight pharmaceuticals with relatively high potential ecological risk and high consumption—namely, acetaminophen, atenolol, carbamazepine, ibuprofen, ifenprodil, indomethacin, mefenamic acid, and propranolol—and conducted laboratory experiments to examine the persistence and partitioning of these compounds in the aquatic environment. In the results of batch sunlight photolysis experiments, three out of eight pharmaceuticals—propranolol, indomethacin, and ifenprodil—were relatively easily photodegraded (i.e., half-life < 24 h), whereas the other five pharmaceuticals were relatively stable against sunlight. The results of batch biodegradation experiments using river water suggested relatively slow biodegradation (i.e., half-life > 24 h) for all eight pharmaceuticals, but the rate constant was dependent on sampling site and time. Batch sorption experiments were also conducted to determine the sorption coefficients to river sediments and a model soil sample. The determined coefficients (K_d values) were much higher for three amines (atenolol, ifenprodil, and propranolol) than for neutral compounds or carboxylic acids; the K_d values of the amines were comparable to those of a four-ring polycyclic aromatic hydrocarbon (PAH) pyrene. The coefficients were also higher for sediment/soil with higher organic content, and the organic carbon-based sorption coefficient (log K_oc) showed a poor linear correlation with the octanol-water distribution coefficient (log D_ow) at neutral pH. These results suggest other sorption mechanisms—such as electrochemical affinity, in addition to hydrophobic interaction—play an important role in sorption to sediment/soil at neutral pH.     

Fluoride in drinking water and dental fluorosis

In this study we determined the fluoride content in drinking water and hair of 12-year-old schoolchildren from different Serbian municipalities, i.e. Valjevo, Veliko Gradiste, Kacarevo and Vranjska Banja. The analyses were performed using composite fluoride ion-selective electrode. Average fluoride levels were 0.10, 0.15, 0.79 and 11 ppm in well water, 0.07, 0.10, 0.17 and 0.15 ppm in tap water, 19.3, 21.5, 25.4, and 32.5 ppm in hair samples, in Valjevo, Veliko Gradiste, Kacarevo and Vranjska Banja, respectively. Correlation analysis indicated statistically significant positive relationship between fluoride in wells water and fluoride in hair, for all municipalities: correlation coefficients were 0.54 (p < 0.05), 0.89, 0.97 and 0.99 (p < 0.001), in Vranjska Banja, Valjevo, Veliko Gradiste, and Kacarevo, respectively. Positive correlation was obtained also between fluoride in tap water and hair samples in all regions under the study, with statistical significance only in Valjevo municipality, p < 0.05. Dental examination of schoolchildren confirmed dental fluorosis only in the region of Vranjska Banja. Moreover, in endemic fluorotic region of Vranjska Banja, positive and statistically significant correlations were confirmed between fluoride in well water and dental fluorosis level (r = 0.61; p < 0.01) and additionally between fluoride in hair and dental fluorosis level (0.62; p < 0.01). The primary findings from this study have shown that fluoride content in hair is highly correlated with fluoride content in drinking water and dental fluorosis level, indicating that hair may be regarded as biomaterial of high informative potential in evaluating prolonged exposure to fluorides and to individuate children at risk of fluorosis regardless of the phase of teeth eruption.     

Exposure to pastures fertilised with sewage sludge disrupts bone tissue homeostasis in sheep

The femurs of male and female sheep (Ovis aries), aged 18 months, bred on pastures fertilized twice annually with sewage sludge (2.25 tonnes dry matter/ha; Treated; T)) or on pastures treated with inorganic fertilizer (Control; C) were studied, using peripheral Quantitative Computed Tomography (pQCT) and the three-point bending test. Males were maintained on the respective treatments from conception to weaning and then maintained on control pastures while the females were maintained on the respective treatments until slaughter.T rams exhibited increased total bone mineral density (BMD) at the metaphyseal part of femur (+ 10.5%, p < 0.01) compared with C rams but had a reduced total cross sectional area (CSA, − 11.5%, p < 0.001), trabecular CSA (− 17.1%, p < 0.01) and periosteal circumference (− 5.7%, p < 0.001). In the mid-diaphyseal part, T rams had an increased total BMD (+ 13.8%, p < 0.0001) and stiffness (+ 6.4%, p < 0.01) but reduced total CSA (− 12.1%, p < 0.0001) and marrow cavity (− 25.8%, p < 0.0001), relative to C rams.In ewes although pQCT analysis of neither the metaphyseal nor the mid-diaphyseal part of the female femur bones showed any significant differences with treatment, the biomechanical method revealed a reduction in load at failure (− 17.3%, p < 0.01) and stiffness (− 10.7%, p < 0.05) amongst T ewes. It is concluded that exposure to pollutants present in sewage sludge can perturb bone tissue homeostasis in sheep, but particularly in males.     

Biomonitoring of benzene and 1,3-butadiene exposure and early biological effects in traffic policemen

The objective of this study was to determine benzene and 1,3-butadiene exposure through ambient air and personal air monitoring, as well as through biomarkers of exposure, and to evaluate the potential health risk of exposure through the use of biomarkers of early biological effects in central Bangkok traffic policemen. Ambient air concentrations of benzene and 1,3-butadiene at the roadsides were significantly higher than in police offices used as control sites (p < 0.001). Traffic policemen had a significantly higher exposure to benzene (median 38.62 μg/m³) and 1,3-butadiene (median 3.08 μg/m³) than office policemen (median 6.17 μg/m³ for benzene and 0.37 μg/m³ for 1,3-butadiene) (p < 0.001). Biomarkers of benzene exposure, blood benzene, and urinary metabolite, trans, trans-muconic acid were significantly higher in traffic policemen than office policemen (p < 0.001). No significant difference between traffic and office policemen was found in urinary benzene metabolite, S-phenyl mercapturic acid, or in urinary 1,3-butadiene metabolite, monohydroxy-butenyl mercapturic acid. Biomarkers of early biological effects, 8-hydroxy-2′-deoxyguanosine in leukocytes (8-OHdG), DNA-strand breaks, and DNA-repair capacity, measured as an increase in gamma ray-induced chromosome aberrations were significantly higher in traffic policemen than controls (p < 0.001 for 8-OHdG, p < 0.01 for tail length, p < 0.001 for olive tail moment, p < 0.05 for dicentrics and p < 0.01 for deletions). Multiple regression model including individual exposure, biomarkers of exposure, ages and years of work as independent variables showed that only the levels of individual 1,3-butadiene exposure were significantly associated with 8-OHdG and olive tail moment at p < 0.0001 indicating more influence of 1,3-butadiene on DNA damage. These results indicated that traffic policemen, who are exposed to benzene and 1,3-butadiene at the roadside in central Bangkok, are potentially at a higher risk for development of diseases such as cancer than office policemen.     

Sediment reworking rates in deep sediments of the Mediterranean Sea

Different pelagic areas of the Mediterranean Sea have been investigated in order to quantify physical and biological mixing processes in deep sea sediments. Herein, results of eleven sediment cores sampled at different deep areas (> 2000 m) of the Western and Eastern Mediterranean Sea are presented.²¹⁰Pb_xs and ¹³⁷Cs vertical profiles, together with ¹⁴C dating, are used to identify the main processes characterising the different areas and, finally, controlling mixing depths (SML) and bioturbation coefficients (D_b). Radionuclide vertical profiles and inventories indicate that bioturbation processes are the dominant processes responsible for sediment reworking in deep sea environments.Results show significant differences in sediment mixing depths and bioturbation coefficients among areas of the Mediterranean Sea characterised by different trophic regimes. In particular, in the Oran Rise area, where the Almeria-Oran Front induces frequent phytoplankton blooms, we calculate the highest values of sediment mixing layers (13 cm) and bioturbation coefficients (0.187 cm² yr⁻¹), and the highest values of ²¹⁰Pb_xs and ¹³⁷Cs inventories. Intermediate values of SML and D_b (~ 6 cm and ~ 0.040 cm² yr⁻¹, respectively) characterise the mesothrophic Algero-Balearic basin, while in the Southern Tyrrhenian Sea mixing parameters (SML of 3 cm and D_b of 0.011 cm² yr⁻¹) are similar to those calculated for the oligotrophic Eastern Mediterranean (SML of 2 cm and D_b of ~ 0.005 cm² yr⁻¹).     

Drag coefficients and Strouhal numbers of a port crane boom girder section

This work reports the drag coefficients (C_d) for three wind directions measured in low turbulence flow and in turbulent flow with characteristics of the atmospheric boundary layer wind, and the Strouhal numbers (St) of an approximately trapezoidal flanged section, used in the boom girder of a 100 m high port crane. These experimental results were obtained at the Boundary Layer Wind Tunnel of the Dept. Aeronautica at the Universidad Nacional de La Plata, in the range of Reynolds numbers between 30,000 and 180,000. The drag coefficients in the three studied directions showed a reduction for turbulent flow. Further measurements were carried out for the model with an inclination of 80° relative to the flow direction, the position of the crane boom when out of service, giving practically the same drag coefficients.     

CFD simulations of natural ventilation behaviour in high-rise buildings in regular and staggered arrangements at various spacings

Natural ventilation, which is in line with the concepts of sustainability and green energy, is widely acknowledged nowadays. Prevailing winds in urban areas are unavoidably modified by the increasing number of closely placed high-rise buildings that significantly modify the natural ventilation behaviour. This paper explores the effects of building interference on natural ventilation using computational fluid dynamics (CFD) techniques. The cross-ventilation rate (temporal-average volumetric airflow rate) of hypothetical apartments in a building cluster under isothermal conditions was examined using the standard two-equation k − ? turbulence model. The sensitivity of ventilation rate to wind direction, building separation and building disposition (building shift) was studied. Placing buildings farther away from one another substantially promoted the ventilation rate, cancelling the unfavourable interference eventually when the building separation was about five times the building width (the optimum separation). The characteristic flow pattern leading to this behaviour was revealed. With the adoption of building disposition, the optimum separation could be reduced to three times the building width. In addition, the airflow rates could be doubled with suitable shifts. Building disposition is therefore one of the feasible solutions to improve the natural ventilation performance in our crowded environment.     

Threshold concentrations of biomass and iron for pressure drop increase in spiral-wound membrane elements

In a model feed channel for spiral-wound membranes the quantitative relationship of biomass and iron accumulation with pressure drop development was assessed. Biofouling was stimulated by the use of tap water enriched with acetate at a range of concentrations (1-1000 μg C l⁻¹). Autopsies were performed to quantify biomass concentrations in the fouled feed channel at a range of Normalized Pressure Drop increase values (NPD_i). Active biomass was determined with adenosinetriphosphate (ATP) and the concentration of bacterial cells with Total Direct Cell count (TDC). Carbohydrates (CH) were measured to include accumulated extracellular polymeric substances (EPS). The paired ATP and CH concentrations in the biofilm samples were significantly (p < 0.001; R² = 0.62) correlated and both parameters were also significantly correlated with NPD_i (p < 0.001). TDC was not correlated with the pressure drop in this study. The threshold concentration for an NPD_i of 100% was 3.7 ng ATP cm⁻² and for CH 8.1 μg CH cm⁻². Both parameters are recommended for diagnostic membrane autopsy studies. Iron concentrations of 100-400 mg m⁻² accumulated in the biofilm by adsorption were not correlated with the observed NPD_i, thus indicating a minor role of Fe particulates at these concentrations in fouling of spiral-wound membrane.     

Arsenic bioaccessibility in CCA-contaminated soils: Influence of soil properties, arsenic fractionation, and particle-size fraction

Arsenic bioaccessibility in soils near chromated copper arsenate (CCA)-treated structures has recently been reported, and results have shown that soil properties and arsenic fractionation can influence bioaccessibility. Because of the limited data set of published results, additional soil samples and a wider range of soil properties are tested in the present work. The objectives are: (1) to confirm previous results regarding the influence of soil properties on arsenic bioaccessibility in CCA-contaminated soils, (2) to investigate additional soil properties influencing arsenic bioaccessibility, and to identify chemical extractants which can estimate in vitro gastrointestinal (IVG) bioaccessibility, (3) to determine arsenic speciation in the intestinal phase of the IVG method and, (4) to assess the influence of two particle-size fractions on arsenic bioaccessibility. Bioaccessible arsenic in eight soils collected near CCA-treated utility poles was assessed using the IVG method. Five out of the eight soils were selected for a detailed characterization. Moreover, these five soils and two certified reference materials were tested by three different metal oxide extraction methods (citrate dithionite (CD), ammonium oxalate (OX), and hydroxylamine hydrochloride (HH)). Additionally, VMINTEQ was used to determine arsenic speciation in the intestinal phase. Finally, two particle-size fractions (< 250 μm, < 90 μm) were tested to determine their influence on arsenic bioaccessibility. First, arsenic bioaccessibility in the eight study-soils ranged between 17.0 ± 0.4% and 46.9 ± 1.1% (mean value 30.5 ± 3.6%). Using data from 20 CCA-contaminated soil samples, total organic carbon (r = 0.50, p < 0.05), clay content (r = − 0.57, p < 0.01), sand content (r = 0.48, p < 0.05), and water-soluble arsenic (r = 0.66, p < 0.01) were correlated with arsenic bioaccessibility. The mean percentage of total arsenic extracted from five selected soils was: HH (71.9 ± 4.1%) > OX (58.0 ± 3.1%) > water-soluble arsenic (2.2 ± 0.5%), while the mean value for arsenic bioaccessibility was 27.3 ± 2.8% (n = 5). Arsenic extracted by HH (r = 0.85, p < 0.01, n = 8) and OX (r = 0.93, p < 0.05, n = 5), showed a strong correlation with arsenic bioaccessibility. Moreover, dissolved arsenic in the intestinal phase was exclusively under the form of arsenate As(V). Finally, arsenic bioaccessibility (in mg/kg) increased when soil particles < 90 μm were used.     

Prevalence and predictors of exposure to multiple metals in preschool children from Montevideo, Uruguay

The extent of children's exposure to multiple toxic metals is not well described in many developing countries. We examined metal exposures in young children (6-37 months) from Montevideo, Uruguay and their mothers (15-47 years) participating in a community-based study. Hair samples collected from 180 children and their mothers were analyzed for: lead (Pb), cadmium (Cd), manganese (Mn), and arsenic (As) concentration using inductively coupled plasma-mass spectrometry (ICP-MS). Median metal levels (μg/g) were: Pb 13.69, Mn 1.45, Cd 0.17, and As 0.09 for children and Pb 4.27, Mn 1.42, Cd 0.08, and As 0.02 for mothers. Of the child and maternal samples, 1.7% and 2.9% were below the limit of detection (LOD) for Cd, and 21.3% and 38.5% were below the LOD for As, respectively. Correlations between maternal and child levels ranged 0.38-0.55 (p < 0.01). Maternal hair metal levels were the strongest predictors of metal concentrations in children's hair. Girls had significantly lower As levels than boys (p < 0.01) but did not differ on other metals. In addition, in bivariate logistic regressions predicting the likelihood that the child would be exposed to multiple metals, hemoglobin < 10.5 g/dL (OR = 2.12, p < 0.05), blood lead (OR = 1.17, p < 0.01), and the mother being exposed to two or more metals (OR = 3.34, p < 0.01) were identified as significant predictors of increased likelihood of multiple metal exposure. Older child age (OR = 0.96, p < 0.05), higher maternal education (OR = 0.35, p < 0.01), and higher number of household possessions (OR = 0.83, p < 0.01) were significantly associated with decreased likelihood of multiple metal exposure. Preschool children in Uruguay are exposed to multiple metals at levels that in other studies have been associated with cognitive and behavioral deficits. Sources of exposure, as well as cognitive and behavioral consequences of multiple metal exposure, should be investigated in this population.     

Gas-particle partitioning and seasonal variation of polycyclic aromatic hydrocarbons in the atmosphere of Zonguldak, Turkey

Atmospheric concentrations and gas-particle partition coefficients were determined for polycyclic aromatic hydrocarbons (PAHs) in the atmosphere of Zonguldak, Turkey between May 2007 and April 2008. Total concentrations of PAHs ranged from 0.52 ng m^− 3 to 636 ng m^− 3 in the particle phase and from 5.60 ng m^− 3 to 725 ng m^− 3 in the gas phase. The annual mean concentrations of PAHs in the particle and gas phase were found to be 114 ng m^− 3 and 184 ng m^− 3, respectively. Significant seasonal variations of particle and gas phase PAH concentrations were observed with higher levels during cold period. The distribution of PAHs between the particle and gas phase was investigated and it was found that three ring PAHs were associated primarily with the gas phase, four ring PAHs were distributed almost equally between the two phases and five and six ring PAHs were mainly associated with the particle phase. Gas-particle partition coefficients (K_p) of PAHs have been calculated and correlated with their subcooled liquid vapor pressures (P_Lº). The slopes (m_r) varied from − 0.63 to − 0.23 were far from the theoretical value (−1) due to the short distance between the sampling point and the emission sources. The relationships between temperature and gas phase partial pressures of PAHs were examined using the Clausius-Clapeyron equation and the obtained positive slopes indicated that PAH concentrations increased with decreasing air temperature as a result of high dominance of local emissions.     

Effects of layered structure on the physical and mechanical properties of laminated moso bamboo (Phyllosachys edulis) flooring

The physical and mechanical properties of five different layered structure types of laminated moso bamboo (Phyllosachys edulis) flooring (LBF) were investigated in this study. In addition, the dynamic modulus of elasticity (DMOE) calculated from ultrasonic wave velocity was also investigated. A good correlation between the DMOE and modulus of rupture (MOR) values of the LBF was found (R² = 0.92, p < 0.01). Results indicated that the DMOE can be a predictor of the bending properties of LBF. The mean linear length expansion value of the cross-laminated layered structure type LBF (group V) was higher than those of the other types. Overall, the mean thickness swelling, water absorption, linear width, and thickness expansion values obtained from group V were smaller than those from the other groups. Thus, group V should be of a better quality than the other groups from the viewpoint of its dimensional stability. The cross-laminated type (group V) of a layered structural design affected the MOE and MOR values significantly less than those of the other groups. However, the mean bending strength (87.5 MPa) of group V was suitable for flooring purposes, in addition, concerned to the orthotropic bending properties of group V, defined as the ratio of bending properties parallel to fiber direction (MOE_(para), MOR_(para)) to those perpendicular to fiber direction (MOE_(perp), MOR_(perp)) were 1.28 for MOE_(para) to MOE_(perp) and 1.20 for MOR_(para) to MOR_(perp), respectively.The results suggest that it is feasible to evaluate the bending properties of LBF using the DMOE, and group V should be a better choice than the other groups to meet the basic necessities for flooring purposes.     

A rigorous small area modelling-study for the helicobacter pylori epidemiology

This paper presents an investigation into spatial risk differences over small distances for the Helicobacter pylori infection in the city of Leipzig, Germany and two rural districts. A model, using Bayesian inference, was developed that adjusts the risk for individual-specific factors, and for spatial or individual over-dispersion, respectively. Additionally, the model takes into account conditional spatial autocorrelation. We found a significant positive association to the H. pylori infection risk for: “more than three children live in the household” (OR = 2.4, p = 0.001), “more persons live per sq.m than average” (OR = 1.4, p = 0.03), “home situated at main road” (OR = 1.4, p = 0.04) and “using well water” (OR = 2.3, p = 0.05). A protective effect was identified for “travelled to low prevalence region” (OR = 0.4, p < 0.0001) and “born in Germany” (OR = 0.2, p < 0.0001). Three administrative areas with significantly increased spatial risk were identified: one in the rural district and two in the city of Leipzig. The model explained 24.9% of the total deviance. Contrary to expectations, the largest part of deviance of the data was not explained by the identified significant risk factors, but by individual-specific heterogeneities. We conclude that further - so far not discussed - factors influence the risk and the spatial variation of the H.pylori infection. Furthermore, from the results we speculate about a possible impact of long-time air pollution and surface water.