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纤维素/[BMIM]Cl溶液的流变性能对其湿法纺丝工艺有着重要的参考价值,浓度、温度等因素对其流变行为有很大的影响。利用AR-1000型流变仪对纤维素/[BMIM]Cl溶液的静态流变行为进行了研究,为离子液体法纺制纤维素纤维提供理论依据。 相似文献
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粘接技术在轴瓦修复中的应用胡其生(江西铜业公司东乡铜矿科协,江西省东乡县,331812)自1980年开始,我们将粘接技术应用于巴氏合金轴瓦的修复中,先后修复了φ2700X2100球磨机主轴瓦和ZJK-3×1.5卷扬机轴瓦,取得了令人满意的粘接效果。粘... 相似文献
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厚浆型涂料是一类具有触变性,流变性的涂料,其粘度测试方法不同用于普遍型涂料。本文介绍用上海天平仪器厂生产的NDJ-1型旋转粘度计测试厚浆型醇涂料的粘度和流变指数的方法。 相似文献
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在40℃,不同浓度的硫酸氢铵盐的条件下,测定了甲基丙烯酯-二甲苯-水体系的液液平衡数据。对所测数据用Eisen-Jofe方程进行了关联,关联结果与实验值符合较好。 相似文献
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杂环取代联苯聚醚酮的流变行为 总被引:1,自引:0,他引:1
用日本岛津AG-2000A毛细管流变仪,研究了自制的杂环取代联苯型聚醚酮的流变行为。求出了表观流动活化能,考察了巴氏效庆和非牛顿行为,对其加工行为进行了分析。 相似文献
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HDPE 5200B性能研究及加工工艺探讨 总被引:1,自引:1,他引:0
通过综合分析国内外几种高密度聚乙烯中空吹塑专用树脂的性能,确定了5200B的生产定位,并对加工工艺进行了探讨,北京燕山石油化工有限公司开发的5200B为均聚高分子量树脂,其熔体流动指数为0.2-0.5g/10min,密度为0.957-0.963g/cm^3,分了量分布在16左右,具有力学性能好,耐热性能高的特点;与共聚物相比具有突出的刚性,与其他均聚中空料相比有较高的耐环境应力开裂值,适用于生产5-50L一般用途的中空制品,5200B加工温度应选择在180℃左右。 相似文献
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Ternary blends of polypropylene (PP), ethylene–octene copolymer (mPE), and high‐density polyethylene (HDPE) were prepared based on the phase behavior and physical properties of mPE/HDPE binary blends, and the results were interpreted in terms of morphology and both rheological and mechanical properties of the ternary blends as well as the binary blends. It was found that when mPE encapsulates HDPE in the PP matrix, compared to the encapsulation of mPE by HDPE, better blend properties were obtained, presumably because of the compatibilizing effect of mPE between PP and HDPE. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 179–188, 2004 相似文献
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HDPE管材专用树脂的流变性能 总被引:1,自引:1,他引:0
应用动态流变仪、毛细管流变仪和转矩流变仪,对新型双峰高密度聚乙烯(HDPE)管材专用树脂 6380 M进行流变性能测试分析,并与国内外相同压力等级的HDPE管材专用树脂进行比较。结果表明,6380 M的各种流变性能与进口管材专用树脂相当,而与单峰HDPE管材专用树脂相比具有弹性模量低、零切黏度低、拉伸黏度低的流变特性,从而对其加工性能产生影响。6380 M流动性好,其临界剪切速率高,但熔体强度不及单峰HDPE。 相似文献
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Some oxygen containing groups (mainly the CO group) are formed on the molecular chain of high density polyethylene (HDPE) during electron beam irradiation in air. The affinity between HDPE and sericite‐tridymite‐cristobalite (STC), the dispersion of STC in the HDPE matrix, and the mechanical properties of the HDPE/STC blend are improved quite a lot by the introduction of polar groups. Compared with HDPE, the tensile and impact strength of electron beam irradiated HDPE (30 kGy)/STC (60/40) are increased to 29.0 MPa and 518 J/m, respectively, from 24.5 MPa and 215 J/m; the tensile and impact strength of irradiated HDPE (30 kGy)/STC (50/50) are 31.1 MPa and 424 J/m, respectively. The Ceast impact test showed that the increase of impact strength was mainly due to the strong interfacial adhesion between irradiated HDPE and STC, thus preventing the spreading of cracks over wide areas. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 243–249, 2000 相似文献
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We investigated the effect of reactive blending on the mechanical properties and morphology of high‐density polyethylene (HDPE)/plasticized starch blends. HDPE was chemically modified to enhance the compatibility with the plasticized starch. The modified HDPE, HDPE‐g‐glycidyl methacrylate (GMA), was synthesized by melt reaction of HDPE in the presence of dicumyl peroxide (DCP). A finer dispersion of starch in the HDPE matrix was achieved compared to that in the unmodified HDPE. The amount of GMA groups in the modified HDPE enhanced the miscibility of HDPE/starch blends. We also observed that the amount of glycerin improves the mechanical properties of blends. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 3313–3320, 2001 相似文献
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高分子量HDPE薄膜级树脂的开发 总被引:7,自引:3,他引:4
综述了国内外高分子量高密度聚乙烯薄膜级树脂的性能、生产工艺、代表牌号、市场、应用领域和发展趋势,重点介绍了几种代表性的生产工艺,并根据我国该薄膜级树脂生产和消费现状,提出了今后发展的建议。 相似文献
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弹性体对HDPE/E-TMB共混物性能的影响 总被引:1,自引:0,他引:1
用自制增韧母料(E-TMB)与高密度聚乙烯(HDPE)热机械共混分别制得HDPE/E-TMB的J系列共混物和S系列共混物,研究了E—TMB中乙丙弹性体M与丁苯弹性体N质量比对共混物力学性能及熔体质量流动速率(MFR)的影响。结果表明,共混物熔体的MFR随母料中N用量的增加逐渐减小;当E-TMB中m(M)/m(N)=80/20时,J类共混物的综合力学性能最好;当m(M)/m(N)=0/100时,s类共混物的力学性能最好。 相似文献
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Karla I. Martínez Rosario González-Mota Juan José Soto-Bernal Iliana Rosales-Candelas 《应用聚合物科学杂志》2021,138(14):50158
Different types of commercial polyethylene films, low-density polyethylene (LDPE), high-density polyethylene (HDPE), and biodegradable polyethylene (BIO-PE), were exposed to UV-B radiation at different exposure time and domestic composting during spring and fall at ambient conditions. The effects of UV-B radiation and domestic composting on LDPE, HDPE, and BIO-PE degradation were characterized by FTIR spectroscopy. LDPE, HDPE, and BIO-PE exposed to UV-B radiation underwent photo oxidation reactions leading to the formation of carbonyl (CO) and vinyl (CH2CH) groups and hydrophilic surface modification. Also, the exposure of LDPE, HDPE, and BIO-PE to domestic composting at ambient conditions at different seasons suffered biodegradation reactions leading to the formation of polysaccharides. In both different seasons LDPE, HDPE, and BIO-PE underwent partial biodegradation, remaining in the domestic composting as unwanted polymer debris. However, biodegradation in domestic composting is not recommended as feasible disposal routes for nonbiodegradable and commercially labeled as biodegradable PE. 相似文献
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Polyolefin binary and ternary blends were prepared from polypropylene (PP), an ethylene–α‐olefin copolymer (mPE), and high‐density polyethylene (HDPE) on the basis of the viscosity ratio of the dispersed phase to the continuous phase. In PP/mPE/HDPE blends, fibrils were observed when the dispersed‐phase (mPE/HDPE) viscosity was less than that of PP, or when the viscosity of mPE was less than that of PP, although the viscosity of mPE/HDPE was greater than that of PP. The notched impact strength and mechanical properties such as the yield strength, flexural modulus, and hardness of PP/mPE binary blends further increased with the addition of HDPE according to the type of HDPE. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 4027–4036, 2004 相似文献