共查询到17条相似文献,搜索用时 671 毫秒
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测量了一批不同组分的铌酸钾锂晶体Raman光谱,发现晶体中位于C格位的Li离子浓度对晶体Raman光谱产生了强烈的影响:低Li含量晶体中[NbO6]^7-八面体所对应的3个Raman特征光谱线没有发生峰分裂,在100~400cm^-1范围出现的小峰与C格位Li离子浓度相关;当晶体中Li离子浓度增加时,与v5所对应的Raman峰在散射几何为X(ZY)Z对应的光谱中加宽.v2振动模式在两种散射几何中均出现分裂峰,并在100~400cm^-1范围出现小峰数量增多;当Li离子浓度接近晶体化学组分时,微扰进一步加强,v5所对应峰分裂成3个峰,v1和v2振动模式发生部分分裂,在100~400cm^-1范围小峰更为突出. 相似文献
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利用离子注入技术和氧气氛围高温退火制备了不同掺锌剂量的铌酸锂样品,并研究了锌离子浓度以及退火状态对铌酸锂晶体紫外和红外波段特性的影响。紫外波段,锌离子的注入使铌酸锂晶体的吸收边红移,退火后吸收边均与纯铌酸锂晶体的相同,锌离子的注入降低了铌酸锂晶体的透射率;红外波段,纯铌酸锂晶体分别在3486 cm-1、2851 cm-1和2917 cm-1处出现主次吸收峰,掺锌样品的主吸收峰位置与纯铌酸锂晶体相比发生微小的红移,X切向铌酸锂样品有明显的次吸收峰,而退火前Z切向铌酸锂样品的次吸收峰不明显,退火后吸收峰变锐利。锌离子的注入以及退火状态对铌酸锂晶体的透射率有影响,分别增强和减弱X切向和Z切向铌酸锂晶体的透射率。 相似文献
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采用激光烧结制备铌酸锂陶瓷的研究.采用CO2激光直接辐照铌酸锂陶瓷素坯,激光功率为150 W,烧结温度为980 ℃左右.与采用传统固相反应烧结技术制备的铌酸锂陶瓷相比,激光烧结制备的铌酸锂陶瓷相对介电常数降低、易于极化、压电常数d33为6 pC/N.通过X射线衍射、扫描电镜和拉曼光谱表征,分析了激光烧结铌酸锂陶瓷的物相、显微结构和性能改变的机理. 相似文献
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CdZnTe晶片中的Zn组分的研究 总被引:2,自引:0,他引:2
用X 射线双晶衍射、光致发光谱和红外透射光谱研究了CdZnTe 晶体中的Zn 的组分.研究表明透射光谱的Syllaios经验公式结果与X 射线双晶衍射和光致发光谱精确测量结果对比,偏差小于4% .透射光谱可以做为测量Zn 组分的常规方法 相似文献
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通过适当的工艺措施,采用传统布里奇曼法生长了尺寸为φ30mm×120mm的Cd0.8Mn0.2Te晶体.对晶体进行了X射线粉末衍射、X射线双晶摇摆曲线、紫外-可见光光谱、红外透过率及电阻率测试.测试结果表明,晶体结构为立方型,半峰宽较低,吸收边为720nm,对应禁带宽度为1.722eV,晶体的红外透过率和电阻率都较高.并讨论了晶体中的缺陷对红外透过率和电阻率的影响. 相似文献
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通过适当的工艺措施,采用传统布里奇曼法生长了尺寸为φ30mm×120mm的Cd0.8Mn0.2Te晶体.对晶体进行了X射线粉末衍射、X射线双晶摇摆曲线、紫外-可见光光谱、红外透过率及电阻率测试.测试结果表明,晶体结构为立方型,半峰宽较低,吸收边为720nm,对应禁带宽度为1.722eV,晶体的红外透过率和电阻率都较高.并讨论了晶体中的缺陷对红外透过率和电阻率的影响. 相似文献
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用cw-Ti:sapphire激光对不同组成的熔体中生长得到的铌酸钾锂晶体进行了倍频性能研究。实验结果表明,只有当晶体中Li离子含量达到一定值时,铌酸钾锂晶体才具有非线性光学效应;晶体中Li离子含量越高,倍频性能越好,Li2O浓度为26mol%的熔体中生长得到的铌酸钾锂晶体的倍频实验的结果表明,该晶体能对820-960nm的近红外cw-Ti:sapphire激光倍频实现蓝绿光输出,具有较好的倍频性能。 相似文献
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Youbao Wan Junhao Chu Shaoling Guo Lingxian Bo Tianyan Yu Bingkun Yu 《Journal of Infrared, Millimeter and Terahertz Waves》2001,22(1):197-205
The potassium lithium niobate crystals have been grown up. The shapes of solid-melt interfaces which maintaining the steady growth of the potassium lithium niobate crystals have been described. The optical transmission spectrum of the crystal has been surveyed. The perfected crystals showed good Second Harmonic Generation properties. 相似文献
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研究了纯LiNbO_3晶体和由已二酸与苯甲酸的混合摩尔比分别为30%和80%时的质子源质子交换制作的LiNbO_3晶体的拉曼散射光谱.实验结果表明,纯LiNbO_3晶体的拉曼光谱在O~1000 cm~(-1)的波数范围内有11个拉曼峰,这些拉曼振动模式主要由[NbO_6]氧八面体的振动产生的;而质子掺杂的LiNbO_3晶体的拉曼光谱,在谱线的形状和数量方面,除了与纯LiNbO_3晶体的拉曼峰相同外,还发现了一个与晶体本征缺陷相关的局域模672cm~(-1)峰,它的相对强度随着本征缺陷的程度的增加而增大,同时掺质子的浓度较大时,多数拉曼谱峰位置向高波数方向稍微移动.实验还表明,掺杂质子浓度越大,波导的模数越多,表面折射率变化、波导深度越大.Abstract: The Raman spectra of pure and proton — exchanged LiNbO_3 crystals were investigated,and those protonated crystals were fabricated by proton source which was formed by a mixture of adipic and benzoic.And two concentration rates of 30% and 80% were applied,respectively.The experimental results show that there are eleven Raman peaks in the 0~
1000cm~(-1) frequency region of the pure LiNbO_3 crystal,and those Raman peaks belong to [NbO_6] octahedron lattice vibration.For the Raman spectra of protonated LiNbO_3 crystals,besides the same Raman peaks as the pure LiNbO_3 crystal in shape and number,a local Raman peak 672 cm~(-1) is found and attributed to the intrinsic defects.Higher H~+ concentration in the protonated crystal leads to more intrinsic defects and a higher relative intensity of the local Raman peak 672 cm~(-1).Meanwhile,when the H~+ concentration is higher,the frequency of some Raman peaks of the protonated crystals will shift to high wave number distinctly,and both the change of the surface refractive index and the waveguide depth are larger. 相似文献
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A. Brillante I. Bilotti C. Albonetti J.‐F. Moulin P. Stoliar F. Biscarini D. M. de Leeuw 《Advanced functional materials》2007,17(16):3119-3127
We report confocal micro‐Raman spectra of the organic semiconductor α‐sexithiophene (T6) on bulk crystals and on thin films grown on technologically relevant substrates and devices. We show that the two polymorphs, which are clearly identified by their lattice phonon spectra, may coexist as physical impurities of one inside the other in the same crystallite. Spatial distribution of the two phases is monitored by Raman phonon mapping of crystals grown upon different conditions. Raman microscopy has then been extended to T6 thin films grown on silicon oxide wafers. We identify the crystal phase in thin films whose thickness is just 18 nm. The most intense total‐symmetric Raman vibration is still detectable for a two‐monolayer thick film. Comparative analysis between micro‐Raman and AFM of T6 thin films grown on field effect transistors shows that electrode‐channel steps favour the nucleation and growth of T6 molecules on the substrate, at least below 50 nm. 相似文献
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S. A. Nikitov A. V. Grigor’evskii V. I. Grigor’evskii I. M. Kotelyanskii V. A. Luzanov E. N. Mirgorodskaya S. G. Suchkov 《Journal of Communications Technology and Electronics》2011,56(7):888-899
Two-dimensional phononic crystals are fabricated on the surface of a lithium niobate crystal. A numerical method is developed
for calculating the frequency dependences of the transmission and reflection coefficients of a surface acoustic wave for a
rectangular region with two-dimensional periodic structure on the surface of an elastic body. Measurements of the frequency
dependences of the reflection and transmission coefficients are performed for propagation in the part of the lithium niobate
crystal surface on which two-dimensional phononic crystals were fabricated. Forbidden zones are found in the transmission
spectra of the waves transmitted through phononic crystals. It is shown that, if the width of the incident wave beam is less
than the width of the region with the two-dimensional periodic structure (the two-dimensional phononic crystal), then a resonant
increase in the transmission coefficient arises near the center of the rejection band. 相似文献
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功能晶体材料NaEr(WO4)2单晶的生长与性能研究 总被引:14,自引:1,他引:13
首次生长具有白钨结构的NaEr(WO4)2晶体。测量得晶体在UV波段的截止波长为326nm,此NaY(WO4)2(321nm)晶体要长。这是由于Er^3 具有较大的极化力造成的。测量了NaEr(WO4)2红外透过光谱和喇曼光谱,并对晶格振动模式进行了分析。所有这些性质和同结构的NaY(WO4)2晶体进行了比较。 相似文献
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铌酸锂晶体光学电场传感器为全介质结构,具有宽带宽、对被测电场干扰小的优点,但其灵敏度较低。因此,分析了晶体几何尺寸对传感器灵敏度的影响机理,得出通过增加沿外加电场方向的晶体尺寸同时减少晶体横截面上沿外加电场垂直方向的晶体尺寸来提高传感器的灵敏度。使用COMSOL仿真分析了铌酸锂晶体不同厚度、宽度、长度对晶体内部电场强度的影响,得出晶体厚度从15 mm减小到3 mm和宽度从3 mm增加到22 mm时,晶体内部电场强度分别提高约5.1倍和12.3倍;晶体长度从15 mm变化到55 mm时,晶体内部的电场强度变化仅约为5%。设计并研制出晶体尺寸分别为3 mm×3 mm×42.2 mm (x×y×z),3 mm×6 mm×42.2 mm (x×y×z),6 mm×6 mm×42.2 mm(x×y×z)的三只铌酸锂晶体电场传感器,并搭建工频电场测试平台,测试得出三只电场传感器的灵敏度分别为0.243 mV/(kV·m-1)、0.758 mV/(kV·m-1)、0.150 mV/(kV·m-1)。当晶体厚度和长度一定且晶体宽度从3 ... 相似文献