高磷鲕状赤铁矿直接还原同步脱磷研究

对含铁品位为43.58%、含磷0.83%的鄂西某宁乡式高磷鲕状赤铁矿进行了直接还原焙烧脱磷试验研究。研究了焙烧温度、还原剂用量、焙烧时间、脱磷剂用量对直接还原铁指标的影响。在还原剂用量17.5%, TS用量50%, NCP用量2.5%, 焙烧时间60 min, 一段磨矿粒度为-0.074 mm粒级占89.56%, 磁选磁场强度为87.58 kA/m; 二段磨矿粒度为-0.025 mm粒级占100%, 磁选磁场强度为87.58 kA/m时可得到铁品位91.58%, 回收率84.96%, 磷品位0.049%的直接还原铁磁选精矿。     

某低品位铁矿石选矿试验

试验用极贫铁矿石铁品位为13.90%,有害元素磷含量为0.86%,磁性铁占总铁的46.04%,主要以磁赤铁矿、磁铁矿形式存在,磁赤铁矿、磁铁矿以半自形变晶结构为主,嵌布粒度大于0.1 mm的超过75%,约有5%的磁赤铁矿的嵌布粒度小于0.05 mm。为确定该矿石的开发利用工艺,进行了选矿试验研究。结果表明,矿石采用3阶段磨选流程处理,在一段磨矿细度为-0.076 mm占38.5%、弱磁选磁场强度为115 kA/m,二段磨矿细度为-0.076 mm占74%、弱磁选磁场强度为115 kA/m,三段磨矿细度为-0.043 mm占92%、弱磁选磁场强度为115 kA/m的情况下,获得了铁品位为60.12%、铁回收率为40.22%的铁精矿,铁精矿硫、磷含量均较低,满足产品质量要求。     

海南某褐铁矿石还原焙烧—磁选试验

海南某低硫、磷褐铁矿石铁品位为39.28%,主要组成矿物褐铁矿含量占73.86%,主要脉石矿物石英含量占14.94%。矿石中褐铁矿粒度较细,多呈不规则状和鲕状集合体,且有包裹细粒石英的现象,这种复杂的嵌布关系大大增大的铁矿物的回收难度。为确定该矿石的高效开发利用工艺,进行了加工工艺条件研究。结果表明,矿石(-0.074 mm占98%)与焦煤(-0.074 mm占98%)混合造球后经焙烧—磨矿—弱磁选工艺处理,在焦煤用量为15%,焙烧温度为1 200℃,焙烧时间为60 min,焙烧产品磨矿细度为-0.045 mm占66%,弱磁选磁场强度为88 k A/m情况下,获得了铁品位为92.54%、铁回收率为74.19%的铁精矿。造球焙烧—磨矿—弱磁选工艺是实现该资源高效开发利用的有效工艺。     

关宝山铁矿石搅拌磨细磨—磁选—反浮选试验

鞍钢关宝山铁矿石属矿物嵌布关系复杂、嵌布粒度粗细不均的铁矿石,为实现矿石的高效利用,采用搅拌磨细磨—磁选—反浮选工艺对现场二段球磨给矿进行磨矿细度、药剂制度等工艺参数研究。结果表明,铁品位为45.90%的矿样在搅拌磨细磨至-0.043 mm占85%的情况下,采用1次弱磁选(磁场强度为100 k A/m)、1次强磁选(背景磁感应强度为0.7 T)、混磁精矿1粗1精3扫反浮选流程处理,反浮选中淀粉用量为685 g/t、氧化钙用量为1 000 g/t、RA715总用量为455 g/t(粗选为320 g/t、精选为135 g/t),获得了铁品位为66.23%、铁回收率为85.87%的铁精矿。     

贵州某褐铁矿磁化焙烧—磁选试验

贵州某褐铁矿石为低硫磷褐铁矿石,铁品位为47.14%,铁矿物主要有褐铁矿,纤铁矿、硬锰矿、软锰矿、黄铁矿少量,褐铁矿呈不规则胶状、土状分布,与脉石矿物共生关系密切,磨矿过程不仅难以实现有用矿物与脉石矿物的有效分离,而且容易泥化,因而直接强磁选或重选均难以获得理想的分选指标。为解决该褐铁矿石资源的开发利用问题,采用磁化焙烧—磁选工艺对该矿石进行了选矿试验。结果表明,在无烟煤(2~0 mm)与矿样(3~0 mm)质量比为5%,焙烧温度为850℃,保温时间为40 min,焙烧产物的磨矿细度为-0.074 mm占97.5%,中磁选磁场强度为218.95 kA/m情况下,可获得铁品位为66.23%、铁回收率为97.53%的铁精矿。     

白云鄂博铁矿石阶段磨矿弱磁选工艺生产超级铁精矿试验

白云鄂博铁矿为铁、铌、稀土共伴生矿,铁品位为30.70%,Re O、Nb2O5含量分别为5.43%和0.11%,主要有用矿物磁铁矿含量为37.46%,83.06%的铁以磁铁矿的形式存在;脉石矿物以碳酸盐、闪石、辉石及萤石为主,次为石英、长石及黑云母等。为充分利用好矿石中铁矿物的自然禀赋,对矿石进行了超级铁精矿生产工艺研究。结果表明,矿石采用3个阶段磨矿—弱磁选工艺处理,一段磨矿细度为-0.074 mm占98.0%,弱磁粗选磁选强度为200 k A/m;二段磨矿细度为-0.038 mm占93.9%,弱磁精选1、弱磁精选2的磁选强度分别为90 k A/m和70 k A/m;三段磨矿细度为-0.030 mm占93.0%,弱磁精选3磁选强度为60 k A/m的情况下,最终获得铁品位为70.50%、铁回收率为67.58%、Si O2含量为0.35%的含微量Nb、RE的超级铁精矿,可作为制备直接还原铁的原料。     

云南某褐铁矿直接还原—弱磁选试验

为确定云南某低品位难选褐铁矿的开发利用方案,对有代表性矿样进行了直接还原—弱磁选试验。结果表明:在试样、褐煤、CaO质量比为100∶20∶15,焙烧温度为1 150℃,焙烧时间为50 min,一段磨矿细度为-0.045mm占86.66%,一段弱磁选磁场强度为199.04 kA/m,二段磨矿细度为-0.045 mm占99.73%,二段弱磁选磁场强度为111.46 kA/m条件下,可获得铁品位为93.17%、铁回收率为88.43%的金属铁粉。对试验确定条件下焙烧产物的XRD和SEM分析表明,铁矿物被直接还原成了颗粒饱满、形状规则的单质铁,粒径大多在50μm左右,与脉石的界面清晰,为磨矿过程中较好地实现铁颗粒与脉石矿物的解离创造了条件。对最终金属铁粉的主要化学成分分析表明,该金属铁粉杂质含量低,满足炼钢质量要求。     

国外某褐铁矿石磁化焙烧—磨矿—弱磁选试验

国外某褐铁矿石铁品位为54.12%,褐铁矿多呈疏松、多孔的胶状分布,少部分呈块状或鲕状分布。采用单一浮选和重选工艺不能获得合格铁精矿。为给该矿石开发利用提供依据,进行了磁化焙烧—磨矿—磁选试验,考察了焙烧温度、焙烧时间、烟煤用量、磨矿细度、磁场强度对精矿指标的影响。结果表明:在烟煤用量为15%、焙烧温度为850℃、焙烧时间为60 min,焙烧产品自然冷却后经球磨磨细至-0.074 mm占90%,在磁场强度为160 k A/m条件下弱磁选,可获得铁品位为64.65%、回收率为86.05%的精矿。     

高炉灰与高磷鲕状赤铁矿共还原回收铁的研究

为考察高炉灰作为还原剂用于高磷鲕状赤铁矿石还原焙烧的可能性,以鄂西某铁品位为42.72%的鲕状赤铁矿石和河北某铁品位为23.96%、固定碳含量为32.83%的高炉灰为原料,进行了共还原焙烧回收铁试验。结果表明：在高炉灰用量为30%、共还原焙烧温度为1 150 ℃、焙烧时间为60 min、还原产品磨矿细度为-0.043 mm占96%、磁选磁场强度为87.58 kA/m条件下,可获得铁品位为91.88%、回收率为88.38%、磷含量为0.072%的还原铁。不同高炉灰用量下焙烧产品的XRD分析结果表明：随高炉灰用量的增加,铁的衍射峰逐渐增强,增加高炉灰用量有利于含铁矿物被还原成金属铁,但还原铁产品磷含量也升高。高炉灰作为还原剂用于高磷鲕状赤铁矿共还原焙烧,为高效利用高炉灰和难选铁矿石提供了一种新思路,又可以降低鲕状赤铁矿石直接还原焙烧的成本,同时减轻高炉灰对环境的污染,具有较高的经济和环境效益。     

磁化焙烧-磁选回收某褐铁矿中铁的试验研究

某褐铁矿原矿铁品位39.28%,其中褐铁矿矿物含量占73.86%,具有一定的回收价值。以焦煤为还原剂,采用磁化焙烧-磁选的工艺回收其中的铁,试验主要考察了磁化焙烧温度、时间、还原剂加入量、磨矿细度、磁场强度对铁精矿选别指标的影响。确定最佳工艺条件为:磁化焙烧温度800℃,焦煤加入量4%,焙烧时间40 min,焙烧样磨矿至-0.037 mm 90%,磁场强度设置192 KA/m进行磁选,最终可获得磁选精矿铁品位59.76%、铁回收率73.31%的良好指标。     

Current situation and future trend of China rare earth luminescent material industry

<正>Rare earth luminescent material is one of the most important application sectors of rare earths.China enjoys the exceptional advantage to develop rare earth luminescent material for its abundant rare earth resources.After several decades'endeavor,China's rare earth luminescent material industry,headed by rare earth phosphor for lamp and LED and high efficient rare earth energy-saving light source,has been gradually developed into a scale industry.China has become a major production base of rare earth phosphor for lamps and rare earth     

China rare earth market review

正June 1~10,2014Rare earth market remained weak.Quoted price of rare earth products was similar to that in May.There was no sign of recovery in downstream market.The market of NdFeB magnetic materials and phosphor was depressed.Catalyst,polishing powder and ceramic industries remained inactive.Demand from downstream industry was soft.Consumers purchased on their needs.Suppliers had strong intention to sell.Prices of rare earth products     

Annual Report analysis of Chinese rare earth-related listed companies in 2013

<正>Chinese rare earth-related listed companies have published their 2013 annual reports.It can be understood from their reports that production and operation activities of Chinese rare earth-related companies were still heavily affected by macro economy and industrial policies.They basically followed the steps of national economy.In 2013,world economy recovered slowly but the economy     

Market opportunities and challenges for rare earth polishing powder

正1.Status of rare earth polishing powder Rare earth polishing powder with high content of cerium oxide began to replace iron oxide for glass polishing and became one of the key materials in glass polishing process since 1940.Compared with traditional iron oxide,rare earth polishing powder has many advantages,such as fast polishing rate,high polishing quality and long service life.It can achieve good surface quality and improve operation conditions.For example,in lens polishing,the polishing work that cerium     

Baotou Research Institute of Rare Earths developed a new RE alloy preparation technology

正Pyrometallurgy Laboratory of Baotou Research Institute of Rare Earths had independently developed a new preparation technology of rare earth alloy for NdFeB.The alloy can remarkably enhance the coercivity of NdFeB magnet but also evidently reduce the production cost of the magnet.The new master alloy was prepared in the kA pilot-scale electrolytic cell by the independent technology.The rare earth master alloy can be used as the raw material for NdFeB.Compared     

矿用防爆轴流对旋主要通风机叶片ANSYS模态分析及应用

高效节能矿用防爆对旋主要通风机的叶片是主要通风机运行的关键部件,叶片在运行时不断受到气流的作用力,从而使叶片产生振动,当叶片振动的频率与叶片的固有频率接近时,容易产生共振从而导致叶片的断裂。一旦叶片断裂时,对主要通风机的安全运行产生致命的影响,从而导致矿山、化工等企业发生重大事故,将会产生不可估量的损失。基于有限元分析软件ANSYS,对高效节能矿用防爆轴流对旋主要通风机叶片进行模态分析及产生对应的六阶模态频率,对主要通风机叶片的运行频率、固有频率及产生的共振问题进行了原理分析,并且解决了叶片频率共振的问题,从而为主要通风机叶片结构设计提供理论依据,并对主要通风机叶片的安全运行提供保障。     

2013 NdFeB export analysis

<正>China totally exported nearly 24,000 tonsof NdFeB products during 201 3,including 18,825 tons of permanent magnet,valued USD 1.34 billion at an average price of 71.4 USD/kg;3,277 tons of NdFeB magnetic powder,valued USD 1 01 million at an average price of 30.9 USD/kg;1,334 tons of strip casting ribbon,with total export value of USD 74million at an average price of 55.3 USD/kg;and 586     

Market and recycling of NiMH battery

<正>Market status and future trend of NiMH battery1.Global market of small NiMH battery Global market size of small NiMH batteries declined year on year since 2011.The trend will continue to 2018,at the rate of 5%to 10%annually.Demand for small NiMH batteries will be stable gradually.Many electrical apparatuses are powered by the built-in lithium battery today,which is the main reason for the shrunk market of small NiMH batteries.But,for some products,small NiMH     

China rare earth market review

正September 1-10,2014 Affected by the National Day holiday,rare earth transaction was stagnant and the market showed a weak steady state.As there was no good news for downstream market,some products with flat demand would likely rally slightly for some time to     

唐口煤矿深部复杂开采工作面瓦斯分源涌出规律研究

研究工作面瓦斯涌出规律对工作面瓦斯治理有重要意义。为了得到唐口煤矿深部3号煤层复杂开采条件下工作面回采时期瓦斯涌出时空演化规律,选取6304工作面作为对象,采用实测方法研究6304工作面瓦斯涌出规律。结果表明:6304工作面瓦斯涌出量为6.534 m³/min,其中煤壁占34.27%,落煤占29.62%,采空区占36.11%;沿工作面倾向由低到高,瓦斯浓度整体为上升趋势,其中1—76号架工作面瓦斯浓度小于0.20%,76—102号架瓦斯浓度上升明显,最大为0.387%;上隅角的后部采空区是工作面的瓦斯主要涌出源,上隅角1号测点瓦斯浓度0.78%,上隅角周边3号、5号、7号、8号、9号测点瓦斯浓度平均为0.643%;周期来压时,上隅角瓦斯相对平时较高。研究为针对性的瓦斯分源监控与灾害防治提供基础。