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染料敏化太阳电池是由透明导电玻璃、纳米晶TiO2多孔薄膜、电解质溶液以及镀Pt对电极构成的"三明治"式结构.染料敏化太阳电池基底的选择对DSSC电池的光电性能和成本具有重要研究价值和实用意义.本文对当前染料敏化太阳电池研究领域常用基底进行了比较和工艺分析. 相似文献
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染料敏化纳米薄膜太阳电池的新型对电极研究 总被引:1,自引:0,他引:1
研究了用金属基板和塑料薄膜制作的4种新型对电极和由这些对电极构成的染料敏化纳米薄膜太阳电池的性能。由不锈钢、镍片和导电聚合物膜为基材的对电极构成的太阳电池的光电转换效率近5%;不锈钢对电极可以通过降低内阻来改善大面积染料敏化纳米薄膜太阳电池的光电转换效率。此外,测试了这些金属基板和塑料薄膜在电解质溶液中的耐腐蚀性和稳定性;考察了由不锈钢和导电聚合物膜对电极构成的染料敏化纳米薄膜太阳电池的长期性能稳定性,并提出了改善这些新型对电极的长期性能稳定性的途径。 相似文献
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叙述了染料敏化纳米ZnO薄膜太阳电池的研究进展。主要讨论了电子注入、dye/Zn2 的团聚等影响染料敏化纳米ZnO薄膜太阳电池效率的关键问题。最后给出了提高此类太阳电池效率的可能途径。 相似文献
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Hun ParkWoong-Rae Kim Hyo-Tae JeongJae-Joon Lee Ho-Gi KimWon-Youl Choi 《Solar Energy Materials & Solar Cells》2011,95(1):184-189
Highly ordered TiO2 nanotube arrays fabricated by anodization are very attractive to dye-sensitized solar cells (DSCs) due to their superior charge percolation and slower charge recombination. However, the efficiency of TiO2-nanotube-based DSCs is 6.89%, which is still lower than that of TiO2-nanoparticle-based DSCs. We have suggested the transplanting the highly ordered TiO2 nanotube arrays to FTO glass to improve the performance of TiO2-nanotube-based DSCs. DSCs based on transplanted TiO2 nanotube arrays and TiO2 nanoparticles were fabricated by same process and materials to exclude the unexpected factors. In TiO2 thickness of ca. 15 μm, the efficiency of 2.91% in front-side illuminated DSCs based on TiO2 nanotube arrays was higher than those in back-side illuminated DSCs based on TiO2 nanotube arrays and in front-side illuminated DSCs based on TiO2 nanoparticle. Front-side illuminated DSCs based on TiO2 nanotube arrays having various thicknesses were successfully fabricated. The efficiency in DSCs having 20.0 μm thick TiO2 nanotube arrays was improved to 5.36% by TiCl4 treatment. 相似文献
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Kinji Onoda Supachai Ngamsinlapasathian Takuya Fujieda Susumu Yoshikawa 《Solar Energy Materials & Solar Cells》2007,91(13):1176-1181
The photovoltaic properties of dye-sensitized solar cells (DSCs) based on several types of substrates, FTO, Ti and stainless steel, were investigated. The sheet resistances of the substrates were correlated to the photovoltaic properties. The efficiency of the DSC using Ti substrate was higher than that of the DSCs using stainless steel and FTO. For the large-size DSCs based on FTO, the metal track is an important component to retain the decrease in cell performance due to the relatively high sheet resistance of FTO. To minimize the internal resistance of DSCs, the Ti sheet was used as a support of nano-crystalline TiO2 due to the low sheet resistance. Although the IPCE of DSCs based on Ti substrate was lower than that of DSCs based on FTO in the range from 400 to 500 nm, the DSC based on Ti substrate showed the higher IPCE in red region due to the light reflecting on Ti substrate. The efficiency of 3.2% for the DSC based on Ti substrate was obtained with a Jsc , Voc 0.75 V, and FF 0.610. This result shows that the Ti plate has superiority for producing the large DSCs without metal track and reduces the cost of DSCs. 相似文献
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We reported on the synthesis, characterization, and photovoltaic/electrochemical properties of Pt/acetylene-black (AB) cathode as well as their application in dye-sensitized solar cells (DSCs). The Pt/AB electrode was prepared through a thermal decomposition of H2PtCl6 on the AB substrate. SEM and TEM observations showed that the Pt nanoparticles were homogeneously dispersed on the AB surface. The Pt-loading content in the Pt/AB electrode was only about 2.0 μg cm−2, which was much lower than 5–10 μg cm−2 generally used for the Pt electrode in DSCs. Electrochemical measurements displayed a low charge-transfer resistance of 1.48 Ω cm2 for the Pt/AB electrode. Furthermore, when this low-Pt-loading electrode was used as the cathode of DSCs, an overall light-to-electricity energy conversion efficiency of 8.6% was achieved, showing commercially realistic energy conversion efficiency in the application of DSCs. 相似文献
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本文对小型空调器的冷凝废热进行了计算和分析,研制出了循环式小型空调器冷凝废热热水器,测试和应用表明,循环式小型空调器冷凝废热热水器是一种可以市场化的产品。 相似文献
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Stand-alone graphene-based films were prepared from graphene oxide (GO) nanoplatelets and their use as counter-electrodes (CEs) in dye-sensitized solar cells (DSCs) was investigated. The graphene-based CEs were produced by spray deposition of GO and chemically reduced GO, followed by thermal annealing under an inert atmosphere. These GO-based CEs were shown to have similar transparency as a reference CE made of Pt. Consistent with impedance data from symmetrical half-cells, DSCs assembled with such GO-based CEs exhibited relative efficiencies of ca. 75% comparatively to the reference Pt CE. The possibility of obtaining transparent (transmittance higher than 80%) and reasonable catalytic films for DSCs (energy conversion efficiency of 2.64%) from GO nanoplatelets was demonstrated. The need for reduction of the graphene oxide nanoplatelets prior to deposition was not observed, allowing for a simplified CE manufacturing process. However, further work is still needed to equal or surpass the performance of Pt CEs. 相似文献
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Application of mesoporous carbon to counter electrode for dye-sensitized solar cells 总被引:3,自引:0,他引:3
Guiqiang Wang 《Journal of power sources》2009,194(1):568-573
The mesoporous carbons were prepared by the carbonation of the triblock copolymer F127/phloroglucinol-formaldehyde composite self-assembled in an acid medium and employed as the catalyst for triiodide reduction in dye-sensitized solar cells (DSCs). The characteristics of mesoporous carbon were analyzed by scanning electron microscopy, transmission electron microscopy, N2 sorption measurement and X-ray diffraction. The mesoporous carbon with low crystallinity exhibited Brunauer-Emmett-Teller surface area of 400 m2 g−1, pore diameter of 6.8 nm and pore volume of 0.63 cm3 g−1. The photovoltaic performances of DSCs with mesoporous carbon counter electrode were improved by increasing the carbon loading on counter electrode due to the charge-transfer resistance of mesoporous carbon counter electrode decreasing with the increase of the carbon loading. However, further carbon loading increase has no obvious effect on the photovoltaic performance of DSCs with carbon electrode when carbon loading exceeds 300 μg cm−2. The overall conversion efficiency of 6.18% was obtained by DSCs composed of mesoporous carbon counter electrode with the carbon loading of 339 μg cm−2. This value is comparable to that of DSCs with conventional platinum counter electrode. 相似文献
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Hyunwoong SeoMin-Kyu Son Jin-Kyoung KimInyoung Shin Kandasamy PrabakarHee-Je Kim 《Solar Energy Materials & Solar Cells》2011,95(1):340-343
Dye-sensitized solar cells (DSCs) have been put forward as a potential low-cost alternative to the widely used silicon solar cells, which are subject to cost limitations. However, some problems need to be solved in order to enhance the efficiency of DSCs. In particular, the electron recombination occurred by the contact between the transparent conductive oxide (TCO) and a redox electrolyte is one of the main limiting factors of efficiency. Accordingly, a compact layer plays an important role in realizing highly efficient DSCs because it improves the adhesion of the TiO2 to the TCO and provides a larger contact area and more effective electron transfer by preventing electron recombination. In this work, the fabrication of a TiO2 compact layer using Ti sputter deposition and acid-treatment was investigated rather than the conventional method, which uses a TiCl4 aqueous solution. The acid-treatment of the sputtered Ti film actively oxidized the Ti particles. As a result, such a cell exhibited an additional 1.3% in total efficiency compared to the standard DSC without a compact layer. These improvements are not inferior to those obtained by the conventional fabrication method using a TiCl4 aqueous solution. 相似文献
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氧化钛纳米管对DSCs电池性能的影响 总被引:1,自引:0,他引:1
主要从DSCs的工作原理出发,比较了TiO2纳米管(特别是规则和单晶纳米管)相比于传统的TiO2纳米颗粒作为DSCs的半导体氧化物的优点;介绍了TiO2纳米管的不同制备工艺过程;比较了不同制备工艺的优缺点;并指出了目前TiO2纳米管DSCs的研究和应用中的问题. 相似文献
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Supachai Ngamsinlapasathian Thammanoon Sreethawong Yoshikazu Suzuki Susumu Yoshikawa 《Solar Energy Materials & Solar Cells》2006,90(14):2129-2140
The effects of indium tin oxide (ITO) and ITO/SnO2 conducting substrates on photovoltaic properties of dye-sensitized solar cells (DSCs) using nanocrystalline TiO2 were studied. The decrease in fill factor of the DSCs was correlated to the increase in resistance of conducting substrate. The heat stability of ITO conducting glass was improved by depositing SnO2 on ITO layer. The efficiency of the cells using double layered ITO/SnO2 substrate remarkably increased comparing with that of the cells using ITO substrates. It is worth mentioning that increasing in sintering time, which enhanced the electronic contact between substrate and TiO2, also modified the cell performance of MP-TiO2 cells. Our experimental finding suggests that 3000 Å ITO substrate, which was covered by 1000 Å SnO2 layer, exhibited the best properties for the DSCs. 相似文献