共查询到20条相似文献,搜索用时 15 毫秒
1.
Eileen De Guire Laura Bartolo Ross Brindle Ram Devanathan Elizabeth C. Dickey Justin Fessler Roger H. French Ulrich Fotheringham Martin Harmer Edgar Lara-Curzio Sarah Lichtner Emmanuel Maillet John Mauro Mark Mecklenborg Bryce Meredig Krishna Rajan Jeffrey Rickman Susan Sinnott Charlie Spahr Changwon Suh Adama Tandia Logan Ward Rick Weber 《Journal of the American Ceramic Society》2019,102(11):6385-6406
Data-driven science and technology have helped achieve meaningful technological advancements in areas such as materials/drug discovery and health care, but efforts to apply high-end data science algorithms to the areas of glass and ceramics are still limited. Many glass and ceramic researchers are interested in enhancing their work by using more data and data analytics to develop better functional materials more efficiently. Simultaneously, the data science community is looking for a way to access materials data resources to test and validate their advanced computational learning algorithms. To address this issue, The American Ceramic Society (ACerS) convened a Glass and Ceramic Data Science Workshop in February 2018, sponsored by the National Institute for Standards and Technology (NIST) Advanced Manufacturing Technologies (AMTech) program. The workshop brought together a select group of leaders in the data science, informatics, and glass and ceramics communities, ACerS, and Nexight Group to identify the greatest opportunities and mechanisms for facilitating increased collaboration and coordination between these communities. This article summarizes workshop discussions about the current challenges that limit interactions and collaboration between the glass and ceramic and data science communities, opportunities for a coordinated approach that leverages existing knowledge in both communities, and a clear path toward the enhanced use of data science technologies for functional glass and ceramic research and development. 相似文献
2.
Collin J. Wilkinson Anthony V. DeCeanne Marc Dittmer Christian Ritzberger Markus Rampf John C. Mauro 《Journal of the American Ceramic Society》2023,106(6):3418-3425
Predicting the effects of ceramic microstructures on macroscopic properties, such as the Knoop hardness, has long been a difficult task. This is particularly true in glass–ceramics, where multiple unique crystalline phases can overlap with a background glassy phase. The combination of crystalline and glassy phases makes it difficult to quantify the percent crystallinity and to predict properties that are the result of the chemical composition and microstructure. To overcome this difficulty and take the first step to build a system for characterizing glass-ceramics, we predict the Knoop hardness based on scanning electron microscopy images using two computational techniques. The first technique is a computer vision algorithm that allows for physical insights into the system because the features used in a predictive model are extracted from the images. The second technique is machine learning with convolutional neural networks that are trained through transfer learning, allowing for more accurate predictions than the first method but with the downside of being a black box. Discussion of the relative merits of the models is included. 相似文献
3.
Isabel González‐Triviño Mónica Benítez‐Guerrero Juan Carda Castelló Belén Moreno José Pascual‐Cosp 《International Journal of Applied Ceramic Technology》2018,15(3):775-782
The large amount of generated waste determines the importance of their valorization. Red mud is the residue of the Bayer process, which stored cumulative value raises 2.7 Bt. This paper describes an easy way to produce a ferrimagnetic glass‐ceramic frit, using bauxite residue, fly ash and glass cullet as raw materials. The synthesized frit consists of faceted and dendritic agglomerated crystals of magnetite and titanomagnetite embedded in a glass matrix, which exhibits a saturation magnetization (MS) of 6.3 emu/g, a remanent magnetization (MR) of 2.7 emu/g and a coercive field (HC) of 347 Oe. Furthermore, it presents Vickers hardness value of HV = 5.55 ± 0.16 GPa and fracture toughness value of KIC = 1.64 ± 0.34 MPa·m1/2. 相似文献
4.
Xiao-Jie Guo Xiao-Ting Xin Weichao Bao Xin-Gang Wang Qing-Qing Yang Yi Zeng Guo-Jun Zhang Fangfang Xu 《Journal of the American Ceramic Society》2022,105(9):5984-5993
Raising the configurational entropy in a solid solution ceramic is regarded as a promising strategy to improve the mechanical properties of ceramics, especially when five or more elements are mixed to form so-called high-entropy ceramics. However, in this study, we report that the binary (TiZr)C solid solution ceramics can demonstrate high hardness comparable or even superior to high-entropy ceramics. Followed by a carbothermal reduction synthesis of carbide powders, the bulk ceramics were synthesized by hot pressing. Via increasing the hot pressing temperature to 2200°C, a full solid solution of equimolar (TiZr)C was obtained in contrast to phase separation at lower sintering temperatures, for example, 2000 and 2100°C. The dislocation networks are observed in the single-phase (TiZr)C ceramic and should be the product of competition between enthalpy and entropy in a binary full solid solution. These defects finally contribute to the high nano-hardness of 41.9 ± 1.4 GPa (H) and the Vickers hardness of 22.0 ± 0.6 GPa (HV at 49 N). 相似文献
5.
Single CaO accelerated densification and microstructure control of highly transparent YAG ceramic 下载免费PDF全文
Le Zhang Tianyuan Zhou Farida A Selim Hao Chen 《Journal of the American Ceramic Society》2018,101(2):703-712
In this work, a small amount of CaO single dopant was adopted to realize the densification and microstructure control of fine grained YAG ceramic with excellent optical quality, by a simple solid‐state reaction and one‐step vacuum sintering method. Then, highly transparent YAG ceramics (T = 84.4% at 1064 nm) were obtained just after vacuum sintering at 1820°C for 8 hours. The average grain size was only 2.7 μm, when the total amount of CaO was as low as 0.045 wt%. The effect of CaO on the microstructural evolution and optical property of the as‐fabricated YAG ceramics was systematically investigated in detail. It was found that CaO dopant promoted both densification and grain growth of YAG ceramics when the sintering temperature was lower than 1660°C, however, it dramatically inhibited grain growth when the sintering temperature was further increased. 相似文献
6.
Sealing glass‐ceramics with near‐linear thermal strain,part III: Stress modeling of strain and strain rate matched glass‐ceramic to metal seals 下载免费PDF全文
Steve Dai Brenton Elisberg James Calderone Nathan Lyon 《Journal of the American Ceramic Society》2017,100(8):3652-3661
Thermal mechanical stresses of glass‐ceramic to stainless steel (GCtSS) seals are analyzed using finite element modeling over a temperature cycle from a set temperature (Tset) 500°C to ?55°C, and then back to 600°C. Two glass‐ceramics having an identical coefficient of thermal expansion (CTE) at ~16 ppm/°C but very different linearity of thermal strains, designated as near‐linear NL16 and step‐like SL16, were formed from the same parent glass using different crystallization processes. Stress modeling reveals much higher plastic strain in the stainless steel using SL16 glass‐ceramic when the GCtSS seal cools from Tset. Upon heating tensile stresses start to develop at the GC‐SS interface before the temperature reaches Tset. On the other hand, the much lower plastic deformation in stainless steel accumulated during cooling using NL16 glass‐ceramic allows for radially compressive stress at the GC‐SS interface to remain present when the seal is heated back to Tset. The qualitative stress comparison suggests that with a better match of thermal strain rate to that of stainless steel, the NL16 glass‐ceramic not only improves the hermeticity of the GCtSS seals, but would also improve the reliability of the seals exposed to high‐temperature and/or high‐pressure abnormal environments. 相似文献
7.
Qiannan Mao Binbin Zheng Yongze Yu Jiejie Chen Jianwang Zhang Hao Luo Shaofei Wen Shifeng Zhou 《Journal of the American Ceramic Society》2017,100(10):4622-4628
The effective removal of hydroxyl groups (OH) is receiving the attention of scientists interested in developing high‐performance photonic glass. Previous approaches rely on stringent control of the various drying techniques which meet with limited success in silicate glass obtained by the sol‐gel method. Here, we present a novel in situ strategy to remove structural OH groups, based on the self‐limited nanocrystallization‐triggered local chemical reaction between OH and F? in the glassy phase. The experimental data revealed that a more than 100‐fold increase in the emission intensity can be realized. Moreover, the mechanism was discussed and it can be attributed to the effective removal of structural OH with especially strong binding energy. The results suggest an innovative avenue for the development of photonic glasses with efficient luminescence, excellent optical transmission, and improved reliability. 相似文献
8.
Transparent Alumina: A Light-Scattering Model 总被引:11,自引:2,他引:9
A model based on Rayleigh–Gans–Debye light-scattering theory has been developed to describe the light transmission properties of fine-grained, fully dense, polycrystalline ceramics consisting of birefringent crystals. This model extends light transmission models based on geometrical optics, which are valid only for coarse-grained microstructures, to smaller crystal sizes. We verify our model by measuring the light transmission properties of fully dense (>99.99%), polycrystalline α-Al2 O3 (PCA) with mean crystal sizes ranging from 60 to 0.3 μm. The remarkable transparency exhibited by PCA samples with small crystal sizes (<2 μm) is well explained by this model. 相似文献
9.
Nonlinear negative transmittance at a CW 980‐nm laser diodes pumping in Yb3+:CaF2 nanocrystals‐embedded glass ceramics 下载免费PDF全文
Zhi Chen Sinan Lai Hang Zhang Hong Jia Ting Wang Qiuqun Chen Guoping Dong Chun Jiang Jianrong Qiu 《Journal of the American Ceramic Society》2017,100(2):612-619
Cooperative upconversion luminescence (CUCL) occurs in spectral regions in which single ions do not have energy levels. However, all results reported so far are concentrated on luminescence properties from Yb3+ ions‐doped various hosts. Here, we report the observation of nonlinear negative transmittance (NNT) at continuous‐wavelength (CW) 980‐nm laser diodes (LDs) pumping in silicate oxyfluoride glass ceramics (GCs)‐containing CaF2:Yb3+ nanocrystals. The unique optical nonlinearity is analyzed based on energy‐level transitions, dynamic evolution, rate equation, and power transmission equation, which can be explained as the cooperative optical absorption for the intense CUCL of Yb3+ ions. The NNT in the CaF2:Yb3+ nanocrystals‐embedded GCs can be tailored with the power of a CW 980‐nm LDs, which possesses potential for the development of future optical limiters and switches. 相似文献
10.
Gary S. Thompson Peter A. Henderson Martin P. Harmer George C. Wei William H. Rhodes 《Journal of the American Ceramic Society》2004,87(10):1879-1882
The effect of a localized SiO2 codoping on the conversion of polycrystalline, MgO-doped Al2 O3 tubes to single-crystal sapphire was investigated. Codoping with SiO2 before sintering intentionally triggered abnormal grain growth, which resulted in the full conversion of tube surfaces to single crystal without adversely affecting densification to a almost pore-free, translucent state. The degree of surface conversion was strongly dependent on experimental variables, which included furnace temperature and codoping amount. Surface-converted tubes had excellent physical properties, which included good thermal cycling resistance and optical properties superior to unconverted, polycrystalline Al2 O3 . 相似文献
11.
Microwave dielectric properties of SnO‐SnF2‐P2O5 glass and its composite with alumina for ULTCC applications 下载免费PDF全文
Indira J. Induja Mailadil T. Sebastian 《Journal of the American Ceramic Society》2017,100(6):2632-2640
Ultralow‐temperature sinterable alumina‐45SnF2:25SnO:30P2O5 glass (Al2O3‐SSP glass) composite has been developed for microelectronic applications. The 45SnF2:25SnO:30P2O5 glass prepared by melt quenching from 450°C has a low Tg of about 93°C. The SSP glass has εr and tanδ of 20 and 0.007, respectively, at 1 MHz. In the microwave frequency range, it has εr=16 and Qu × f=990 GHz with τf=?290 ppm/°C at 6.2 GHz with coefficient of thermal expansion (CTE) value of 17.8 ppm/°C. A 30 wt.% Al2O3 ‐ 70 wt.% SSP composite was prepared by sintering at different temperatures from 150°C to 400°C. The crystalline phases and dielectric properties vary with sintering temperature. The alumina‐SSP composite sintered at 200°C has εr=5.41 with a tanδ of 0.01 (1 MHz) and at microwave frequencies it has εr=5.20 at 11 GHz with Qu × f=5500 GHz with temperature coefficient of resonant frequency (τf)=?18 ppm/°C. The CTE and room‐temperature thermal conductivity of the composite sintered at 200°C are 8.7 ppm/°C and 0.47 W/m/K, respectively. The new composite has a low sintering temperature and is a possible candidate for ultralow‐temperature cofired ceramics applications. 相似文献
12.
Kevin Urman 《Polymer》2007,48(6):1659-1666
Phosphate glass (Pglass)/polymer hybrids are a relatively new class of materials that combine the advantages of classical polymer blends and composites without their disadvantages. In the case of highly interacting Pglass/polymer (i.e., polyamide 6) hybrids, counter-intuitive properties that are difficult to explain are often observed. To shed light into the origins of the special behavior of the hybrids, we investigated the molecular relaxation processes in the hybrids using broadband dielectric spectroscopy. The dielectric loss spectra were fitted with the Havriliak-Negami equation and the characteristic relaxation times of the hybrid and the pure components were observed. The temperature dependence of the characteristic relaxation times was described using either the Vogel-Fulcher-Tammann, for the α-relaxations, or an Arrhenius type equation, for the β- and γ-relaxations. The addition of Pglass greatly accelerated both the α- and β-relaxations of the polyamide 6. However, the γ-relaxation was found to be independent of Pglass composition. This suggests partial miscibility in the solid state, which was confirmed via NMR spectroscopy. The unexpected dramatic change in the β-relaxation process in the 10 vol.% Pglass hybrid suggests that blending can change the local environment of polyamide 6 due to the nanoscale morphology of this system as confirmed by TEM and NMR. It is thought that the fraction of miscible Pglass disrupts the hydrogen bonding between polyamide 6 chains and thereby reduces coordinated, multiple chain motion. In turn, this produces a plasticization effect and possible modification of the polyamide 6's crystalline structure in the Pglass/polyamide 6 hybrids. 相似文献
13.
Aiswarya Dash Sumit Kumar Pal Indranil Banerjee Subhabrata Chakraborty 《International Journal of Applied Ceramic Technology》2018,15(1):223-231
Rare‐earth‐doped upconversion nano‐phosphor shows new possibilities in the field of bioimaging because of its unique properties like higher penetration depth, low signal to noise ratio (SNR), good photo stability, and zero auto fluorescence. The oxyfluoride glass system is the combination of both fluoride and oxide where fluoride host offers high optical transparency due to low phonon energy and oxide network offers high physical stability. Thus, in the present work, an attempt has been made to synthesize 1 mol% Er3+ doped SiO2‐CaF2 glass ceramic nano‐particles through sol‐gel route. The synthesized glass ceramic particles were heat treated at 4 different temperatures starting from 600°C to 900°C.The X‐ray diffraction (XRD) analysis and Transmission electron microscopy (TEM) analysis confirmed the formation of CaF2 nano‐crystals in the matrix which is 20‐30 nm in size. The vibrational spectroscopic analysis of the glass ceramics sample has been investigated by Fourier transform infrared (FTIR) spectroscopy. The UV‐Visible‐NIR spectroscopy analysis was carried out to analyze the absorption intensity in the near infrared region. Upon 980 nm excitation, the sample shows red emission corresponds to 4F9/2→4I15/2 energy level transition. The prepared nano‐particles showed excellent biocompatibility when tasted on MG‐63 osteoblast cells. 相似文献
14.
《Journal of the European Ceramic Society》2022,42(1):202-206
MgO-doped-Al2O3 ceramic discs were fabricated by flash sintering (FS) and pressureless sintering (PS). The results showed that MgO-doped Al2O3 exhibited typical characteristics of flash sintering under an electric field in excess 2500 V/cm. Compared with the PS- fabricated specimen, the flash sintered specimens exhibited sub-micron grains (≤760 nm) and homogeneous microstructures. The relative density of the ?ash sintered MgO-doped Al2O3 ceramics increased with current density, reaching 99.91 % when the current density increased to 7 mA/mm2. The FS-fabricated sample exhibited higher hardness (21.02 GPa) and fracture toughness (3.46 MPa m1/2) than PS-fabricated sample. 相似文献
15.
Due to the numerous increase of the building energy consumption and huge volume of industrial wastes produced in China, the development of thermal insulation materials is quite needed. Herein, foam glass ceramic, a kind of thermal insulation materials, was fabricated by using solid wastes high alumina fly ash and waste glass as the main raw materials. First, in this study the proportion scheme of this research was designed by using Factsage 7.1 and the foaming agent was CaSO4. Secondly, the decomposition of calcium sulfate and the influence of process parameters, namely the sintering temperature and the foaming agent additive amount, on the microstructure and mechanical properties of foam glass ceramic were investigated. The experimental results showed that when the proposed foam glass ceramic was sintered at between 1180 and 1220?°C, it exerted excellent macro and micro properties. The optimum parameters were 2% CaSO4 addition and sintering temperature of 1200?°C, and the corresponding bulk density and compress strength values were 0.98?g/cm3 and 9.84?MPa, respectively. Overall these results indicated that the preparation of foam glass ceramic made up a promising strategy for recycling industrial waste into new kind of building insulation materials. 相似文献
16.
The role of ceramic and glass science research in meeting societal challenges: Report from an NSF‐sponsored workshop 下载免费PDF全文
Katherine T. Faber Tewodros Asefa Monika Backhaus‐Ricoult Richard Brow Julia Y. Chan Shen Dillon William G. Fahrenholtz Michael W. Finnis Javier E. Garay R. Edwin García Yury Gogotsi Sossina M. Haile John Halloran Juejun Hu Liping Huang Steven D. Jacobsen Edgar Lara‐Curzio James LeBeau William E. Lee Carlos G. Levi Igor Levin Jennifer A. Lewis Don M. Lipkin Kathy Lu Jian Luo Jon‐Paul Maria Lane W. Martin Steve Martin Gary Messing Alexandra Navrotsky Nitin P. Padture Clive Randall Gregory S. Rohrer Anatoly Rosenflanz Tobias A. Schaedler Darrell G. Schlom Alp Sehirlioglu Adam J. Stevenson Toshihiko Tani Veena Tikare Susan Trolier‐McKinstry Hong Wang Bilge Yildiz 《Journal of the American Ceramic Society》2017,100(5):1777-1803
Under the sponsorship of the U.S. National Science Foundation, a workshop on emerging research opportunities in ceramic and glass science was held in September 2016. Reported here are proceedings of the workshop. The report details eight challenges identified through workshop discussions: Ceramic processing: Programmable design and assembly; The defect genome: Understanding, characterizing, and predicting defects across time and length scales; Functionalizing defects for unprecedented properties; Ceramic flatlands: Defining structure‐property relations in free‐standing, supported, and confined two‐dimensional ceramics; Ceramics in the extreme: Discovery and design strategies; Ceramics in the extreme: Behavior of multimaterial systems; Understanding and exploiting glasses and melts under extreme conditions; and Rational design of functional glasses guided by predictive modeling. It is anticipated that these challenges, once met, will promote basic understanding and ultimately enable advancements within multiple sectors, including energy, environment, manufacturing, security, and health care. 相似文献
17.
18.
Simultaneous control of the chemical state and local environment of Cr dopant in glass for extended emission 下载免费PDF全文
Jiejie Chen Yongze Yu Hao Luo Liting Lin Shifeng Zhou 《Journal of the American Ceramic Society》2018,101(1):159-166
Control of the chemical state and local environment of Cr dopant in glass through self‐limited nanocrystallization is presented. Interesting wavelength‐tunable and ultra‐broadband near‐infrared luminescence with the full width at half maximum of about 380 nm from obtained Cr‐activated glass‐ceramics are demonstrated. The results indicate that the presented method may be an effective means of fabricating multifunctional optical gain materials and wideband fiber light sources. 相似文献
19.
Naveen Prakash Binghui Deng Ross J. Stewart Charlene M. Smith Jason T. Harris 《Journal of the American Ceramic Society》2022,105(6):4304-4320
Glass–ceramics (GCs), obtained by controlled crystallization of a specially formulated precursor glass, are interesting materials that show great promise in obtaining superior properties compared to those of the precursor glass. Controlled crystallization enables creation of a microstructure with multiple phases which impacts macroscale properties in interesting ways. The present work develops microstructure-scale computational models using the theory of peridynamics to investigate the increase in fracture toughness of GCs compared to traditional glass. Computational modeling is a promising tool to probe microstructural mechanics, but such studies in the literature are scarce. In this work, the theory of peridynamics, a non-local theory of continuum mechanics, is applied to simulate crack propagation through microstructural realizations of a model lithium-disilicate glass–ceramic. The crystalline and glassy phases within the microstructure are explicitly considered, with the size and shape of crystals inspired by experimental data. Multiple toughening mechanisms are revealed, which are functions of crystallinity and morphology, and the impact on fracture toughness is demonstrated. Crack path tortuosity is studied, and it is found that an optimum level of crack path tortuosity can be obtained in the range of 0.6–0.8 crystallinity. Numerical results are shown to agree well with previously published experimental and modeling results. 相似文献
20.
Leonardo Resende Naira M. Balzaretti Altair S. Pereira Marcos A. Z. Vasconcellos Silvio Buchner 《Journal of the American Ceramic Society》2021,104(6):2552-2559
In this work, high-density lithium disilicate (LS2) vitreous systems were produced by melting and quenching under high pressure (7.7 GPa) following two distinct experimental routes. In the first case, LS2 glass was remelted at 7.7 GPa and 1600°C and, then, quenched. In the second case, a stoichiometric mixture of precursor oxides (Li2O and SiO2) was melted at 1600°C and 7.7 GPa before quenching. A reference LS2 glass sample was produced at atmospheric pressure using conventional melting and quenching procedure. The samples were characterized by X-ray diffraction, differential thermal analysis, and instrumented ultramicro hardness measurements. X-ray diffraction confirmed that all samples were amorphous and thermal analysis suggests that different glassy structures were produced depending on the route of synthesis. Hardness and elastic modulus of the glasses produced under high pressure were higher than those of the reference glass, reflecting the irreversible densification effect induced by the high-pressure processing. 相似文献