The origin of hypersaline liquid in the quaternary kakkonda granite, sampled from well WD-1a, kakkonda geothermal system, Japan

Hypersaline metal-rich liquid (ca. 40 wt% total chloride species) was obtained from a depth of 3708 m in the Kakkonda geothermal system. Sampling of well WD-1a was conducted by reverse circulation after a standing time of about 196 hours (with temperature recovering to >500°C). Tritium content and the relationship between δD and δ¹⁸O showed that the river water that was circulated in the well had mixed with an isotopically heavy fluid during the standing time. Phase separation occurred during temperature recovery, concentrating the hypersaline liquid in the bottom of the well. This original hypersaline liquid has a salinity of about 55 wt% NaCl eq., consisting of Na–Fe–K–Mn–Ca chloride, rich in Zn and Pb but poor in Cu, Au and Ag. The fluid originates from the Kakkonda granite and mixed with circulating water from the well in a zone of fine fractures induced by thermal stress during drilling.     

Thermal and petrologic study of the CH-A well from the Chipilapa-Ahuachapán geothermal area, el salvador

Systematic petrological studies were performed at 10-m intervals along the 2700-m-deep Ch-A well. Results show mineralogical variations that define four zones which, in turn, represent different thermal zones. The shallowest zone (Zone l) is characterized by the presence of chalcedony + zeolites + amorphous silica + saponite + montmorillonite + minor amounts of pyrite and calcite; Zone 2 by chlorite + quartz + smectite + zeolites; Zone 3by chlorite + quartz + calcite + epidote + abundant pyrite and hematite + mixed-layeredillite-smectite + chalcopyrite; andZone4 byepidote + clinozoisite + gypsum + sericite + mixed-layered chlorite-illitesmectite + anyhdrite. Fluid inclusion analyses performed at 100-m intervals indicate that a low-to-moderate salinity fluid with ice-melting temperatures of -0.7 to -2.2°C was involved in the hydrothermal alteration of the rocks. At shallow depths, positive values of + 1.6°C were found, which probably indicate an increase in volatile components. Minimum homogenization temperatures gradually increased with depth. They range from 110°C at very shallow depths (153 m) to 244°C at total depth (2700 m); however, peak or maximum temperatures of 265–286°C are found at various depths between 1400 and 2500 m. Bottom-hole fluid inclusion temperatures agree well with static temperatures derived from the Homer (1951) and the Ascencio et al. (1994) methods. Comparisons at other depths show that, in general, Homer temperatures are the lowest and that fluid inclusion temperatures are the highest, except at about 1200 m depth where the Ascencio et al. (1994) method gives the largest values. It is believed that well Ch-A encountered a mineral paragenesis that does not correspond with present thermodynamic conditions of the reservoir and that the geothermal system has undergone natural cooling.     

Hydrogeochemical exploration of geothermal prospects in the Tecuamburro Volcano region, Guatemala

Chemical and isotopic analyses of thermal and nonthermal waters and of gases from springs and fumaroles are used to evaluate the geothermal potential of the Tecuamburro Volcano region, Guatemala. Chemically distinct geothermal surface manifestations generally occur in separate hydrogeologic areas within this 400 km² region: low-pressure fumaroles with temperatures near local boiling occur at 1470 m elevation in a sulfur mine near the summit of Tecuamburro Volcano; non-boiling acid-sulfate hot springs and mud pots are restricted to the Laguna Ixpaco area, about 5 km NNW of the sulfur mine and 350–400 m lower in elevation; steam-heated and thermal-meteoric waters are found on the flanks of Tecuamburro Volcano and several kilometers to the north in the andesitic highland, where the Infernitos fumarole (97°C at 1180 m) is the primary feature; neutral-chloride hot springs discharge along Rio Los Esclavos, principally near Colmenares at 490 m elevation, about 8–10 km SE of Infernitos. Maximum geothermometer temperatures calculated from Colmenares neutral-chloride spring compositions are 180°C, whereas maximum subsurface temperatures based on Laguna Ixpaco gas compositions are 310°C. An exploration core hole drilled to a depth of 808 m about 0.3 km south of Laguna Ixpaco had a bottom-hole temperature of 238°C but did not produce sufficient fluids to confirm or chemically characterize a geothermal reservoir. Hydrogeochemical data combined with regional geologic interpretations indicate that there are probably two hydrothermal-convection systems, which are separated by a major NW-trending structural boundary, the Ixpaco fault. One system with reservoir temperatures near 300°C lies beneath Tecuamburro Volcano and consists of a large vapor zone that feeds steam to the Laguna Ixpaco area, with underlying hot water that flows laterally to feed a small group of warm, chloriderich springs SE of Tecuamburro Volcano. The other system is located beneath the Infernitos area in the andesitic highland and consists of a lower-temperature (150–190°C) reservoir with a large natural discharge that feeds the Colmenares hot springs.     

The Iceland Deep Drilling Project: a search for deep unconventional geothermal resources

The Iceland Deep Drilling Project (IDDP) is a long-term program to improve the economics of geothermal energy by producing supercritical hydrous fluids from drillable depths. Producing supercritical fluids will require the drilling of wells and the sampling of fluids and rocks to depths of 3.5–5 km, and at temperatures of 450–600 °C. The IDDP plans to drill and test a series of such deep boreholes in the Krafla, Nesjavellir and Reykjanes geothermal fields in Iceland. Beneath these three developed high-temperature systems frequent seismic activity continues below 5 km, indicating that, even at supercritical temperatures, the rocks are brittle and therefore likely to be permeable, even where the temperature is assumed to exceed 550–650 °C. Temperature gradients are greater and fluid salinities smaller at Nesjavellir and Krafla than at Reykjanes. However, an active drilling program is underway at Reykjanes to expand the existing generating capacity and the field operator has offered to make available one of a number of 2.5 km deep wells to be the first to be deepened to 5 km by the IDDP. In addition to its potential economic significance, drilling deep at this location, on the landward extension of the Mid-Atlantic Ridge, is of great interest to the international science community. This paper examines the prospect of producing geothermal fluids from deep wells drilled into a reservoir at supercritical temperatures and pressures. Since fluids drawn from a depth of 4000–5000 m may prove to be chemically hostile, the wellbore and casing must be protected while the fluid properties are being evaluated. This will be achieved by extracting the fluids through a narrow retrievable liner called the “pipe”. Modelling indicates that if the wellhead enthalpy is to exceed that of conventionally produced geothermal steam, the reservoir temperature must be higher than 450 °C. A deep well producing 0.67 m³/s steam (2400 m³/h) from a reservoir with a temperature significantly above 450 °C could, under favourable conditions, yield enough high-enthalpy steam to generate 40–50 MW of electric power. This exceeds by an order of magnitude the power typically obtained from a conventional geothermal well in Iceland. The aim of the IDDP is to determine whether utilization of heat from such an unconventional geothermal resource at supercritical conditions will lead to increased productivity of wells at a competitive cost. If the IDDP is an economic success, this same approach could be applied in other high-temperature volcanic geothermal systems elsewhere, an important step in enhancing the geothermal industry worldwide.     

Fluid-inclusion evidence for past temperature fluctuations in the Kilauea East Rift Zone geothermal area, Hawaii

Heating and freezing data were obtained for fluid inclusions in hydrothermal quartz, calcite, and anhydrite from several depths in three scientific observation holes drilled along the lower East Rift Zone of Kilauea volcano, Hawaii. Compositions of the inclusion fluids range from dilute meteoric water to highly modified sea water concentrated by boiling. Comparison of measured drill-hole temperatures with fluid-inclusion homogenization-temperature (T_h) data indicates that only about 15% of the fluid inclusions could have formed under the present thermal conditions. The majority of fluid inclusions studied must have formed during one or more times in the past when temperatures fluctuated in response to the emplacement of nearby dikes and their subsequent cooling. The fluid-inclusion data indicate that past temperatures in SOH-4 well were as much as 64°C hotter than present temperatures between 1000 and 1500 m depth and they were a maximum of 68°C cooler than present temperatures below 1500 m depth. Similarly, the data show that past temperatures near the bottoms of SOH-1 and SOH-2 wells were up to 45 and 59°C, respectively, cooler than the present thermal conditions; however, the remainder of fluid-inclusion T_h values for these two drill holes suggest that the temperatures of the trapped waters were nearly the same as the present temperatures at these slightly shallower depths. Several hydrothermal minerals (erionite, mordenite, truscottite, smectite, chlorite-smectite, chalcedony, anhydrite, and hematite), occurring in the drill holes at higher temperatures than they are found in geothermal drill holes of Iceland or other geothermal areas, provide additional evidence for a recent heating trend.     

Geoelectric study of some indian geothermal areas

The electrical resistivity technique has been used extensively in the Indian sub-continent for the exploration of geothermal areas. The first systematic application of the resistivity method for locating the geothermal reservoir was made in the Puga area, which is situated very close to the collision junction of the Indian and the Asian plates and has numerous hot springs with temperatures varying from 30 to 84°C (boiling point at that altitude). The resistivity depth probes indicated the presence of a conductive zone, with a value of 10–25 ohm·m and a thickness varying from 50 to 300 m over an area of 3 km², which was inferred to correspond to a shallow thermal reservoir. Thermal surveys also revealed a significant anomaly corresponding to this zone, which, when drilled, encountered a reservoir of wet steam with a temperature of up to 135°C, thus confirming the results of the resistivity surveys. Somewhat similar results have been obtained in the adjoining area, where much thicker zones with moderate electrical conductivity have been mapped.Another significant application of the electrical resistivity method has been made in the NNW-SSE extending West Coast geothermal belt of India, which is covered by Traps (Basalts) of the Cretaceous-Eocene. The area is characterized by the existence of a number of hot springs, with temperature up to 70°C, along a 400 km long alignment, associated with steep gravity gradients and an isolated occurrence of native mercury in the zone of a gravity “high”. The enigmatic geology of this area has been mapped, giving quantitative estimates of the thickness of the Traps and inferring the structural features. In addition, the electrical resistivity depth probes have also been used to identify the pre-Trappean geology, thereby locating the probable areas which could act as geothermal reservoirs.This paper presents the results of the electrical resistivity surveys in the form of geoelectric sections for some of the geothemal fields in the Indian sub-continent.     

Hot springs and geothermal gradients in northern Thailand

Chemical geothermometry of hot springs in northern Thailand indicates that many have reservoir temperatures in excess of 150°C and some in excess of 180°C. Measurements of temperatures in abandoned oil wells in Fang Basin indicate geothermal gradients of 70 – 130 mK/m. The high geothermal gradient may be the result of extensional tectonics in northern Thailand, caused indirectly by sea-floor spreading in the Andaman Sea. Relatively high reservoir temperatures and shallow reservoir depths suggest that hot spring areas in northern Thailand may be potential sources of geothermal energy.     

Genesis of the plutonic-hydrothermal system around quaternary granite in the kakkonda geothermal system, Japan

The Kakkonda plutonic-hydrothermal system has as its heat source the Quaternary Kakkonda granite. The Kakkonda granite has a thick (1.3 km) contact-metamorphic zone, known mainly from the geothermal survey well WD-1a (total depth: 3729 m) drilled by the New Energy and Industrial Technology Development Organization (NEDO). The Kakkonda granite is a stock several tens of square kilometers in area with an upper contact about 1.5–3 km deep. It is a composite pluton varying from tonalite to granite. The early-stage granitic rocks are slightly metamorphosed to biotite grade by late-stage granitic rocks. K-Ar ages of separated minerals from the granitic rocks in both stages show the same cooling ages of 0.24–0.11 Ma for hornblende, 0.21–0.02 Ma for biotite, and 0.14–0.01 Ma for potassium feldspar. These are the youngest ages for granite in the world. The K-Ar ages become almost zero at 580°C for biotite and potassium feldspar, and at 350°C for illite. The Kakkonda granite intruded into a regional stress field in which the minimum principal stress was ENE–WSW and nearly horizontal. The regional stress field coincides with that of a previously recognized F2 fracture system before 0.4–0.3 Ma. Both stages of the Kakkonda granite and the contact aureole are fractured by recent tectonism, resulting in a zone of hydrothermal convection from about 2.5–3.1 km depth up to the surface. The boundary between the zone of hydrothermal convection and the underlying zone of heat conduction occurs 250–550 m below the upper contact of the Kakkonda granite, and has a temperature of 380–400°C.     

Hydrothermal alteration in the Aluto-Langano geothermal field, Ethiopia

The hydrothermal mineral assemblages found in eight wells (with a depth range of 1320–2500 m) of the active geothermal field of Aluto-Langano (Ethiopia) indicate a complex evolution of water-rock interaction processes. The zone of upflow is characterized by high temperatures (up to 335°C) and the presence of a propylitic alteration (epidote, calcite, quartz and chlorite, as major phases) coexisting with calcite and clay minerals. The zone of lateral outflow is characterized by mixing of deep and shallow waters and the occurrence of a calcite-clay alteration that overprints a previous propylitic assemblage. Clay minerals have a mushroom-shaped zonal distribution consistent with the present thermal structure of the field. Microprobe analyses have been carried out on chlorite and illite in order to apply several geothermometers. Most of the chlorite is iron-rich chlorite. It is found that the temperatures calculated from the chlorite geothermometer (159–292°C) after Cathelineau and Nieva [Contrib. Mineral. Petrol. 91, 235–244 (1985)] are in good agreement with in-hole measured temperatures (155–300°C). In the upflow zone, temperatures calculated from this geothermometer (217–292°C), together with fluid inclusion data of Valori et al. [Eur. J. Mineral. 4, 907–919 (1992)], and computed saturation indices of alteration minerals, indicate thermal stability or slight heating. On the other hand, evidence of a significant cooling process (up to 171°C) in the outflow zone is provided by the comparison between fluid inclusion homogenization temperature (240–326°C) and in-hole temperature (155–250°C). The apparent salinities (0.8–2.3 wt% NaCl eq.) of the fluid inclusions are generally higher than the salinity of the present reservoir fluid (0.29–0.36 wt% NaCl eq.). Clay minerals (illite, smectite, Ill/S mixed layers, vermiculite and chloritic intergrades) generally occur at temperatures consistent with their stability fields.     

Deposition of amorphous silica in porous packed beds — predicting the lifetime of reinjection aquifers

Predicting deposition rates of dissolved silica in geothermal reinjection aquifers is difficult due to a lack of reliable scaling rates and the complexity of modelling fluid transport simultaneously with deposition. In order to develop techniques, understand the problems and improve our predictive capabilities, we have undertaken field experiments at Wairakei geothermal field, New Zealand, to determine amorphous silica deposition rates in 25 mm diameter pipes packed with 2 mm diameter zirconia beads. These pipes served as model aquifers. Five experiments using flashed fluid containing 530 ppm total silica were completed at temperatures between 71 and 129°C and at flowrates between 0.002 and 0.02 kg s⁻¹. The residence times in the pipes were shorter than the induction period required for silica polymerisation from solution. The scaling rates in the beds, measured over a month, were about 12 mg cm⁻² year⁻¹ and independent of flowrate between 80 and 129°C. Scaling at 129°C was unexpected, because the dissolved silica was expected to be undersaturated with respect to amorphous silica. At 71°C the rates were higher (up to 23 mg cm⁻² year⁻¹) and were proportional to flowrate. At Wairakei the 130°C fluid used in these experiments is disposed of by injection into a reservoir at 80°C. Using our field deposition rates, we estimate that 2.6×10⁵ kg of amorphous silica would precipitate in 10 years around the injection well, assuming an injection rate of 50 kg s⁻¹ into a 100 m thick reservoir of radius 500 m with permeability 100 mdarcy and a porosity of 0.2.     

Geochemistry of thermal waters in the Tengchong volcanic geothermal area, West Yunnan Province, China

The Tengchong volcanic geothermal area is one of the areas in China which has powerful geothermal energy potential. The chemical compositions of the thermal waters discharged in this area were studied to obtain information on boiling and mixing relationships and average reservoir temperatures. Then a conceptual model of the Tengchong volcanic geothermal area was formulated. Hydrothermal areas have reservoir temperatures ranging from 90 to 150°C; such temperatures can be found in up to 60% of the 58 hydrothermal areas. Five hydrothermal areas have high temperatures, with an average reservoir temperature of more than 150°C, and occupy less than 10% of the total. The Hot Sea geothermal field is one of the five high temperature hydrothermal areas where a more detailed investigation was made.     

Chemical variations in hydrothermal minerals of the Los Humeros geothermal system, Mexico

The Los Humeros geothermal system is composed of more than 2200 m of Quaternary altered volcanic rocks and an underlying Cretaceous sedimentary sequence. The low salinity of the fluids discharged at present (Na⁺ and Cl⁻ concentrations <500 ppm), and the excess steam, indicate that the reservoir contains a mixture of steam and dilute groundwater. Water-rock equilibrium is not attained. Hydrothermal minerals are present in veinlets, vugs, and replacing primary minerals. Three mineral zones are recognized: 1) a shallow argillic zone (<400 m depth), 2) a propylitic zone (ranging between 500 and 1800 m) and 3) a skarn zone (>1800 m). Petrographic examination of cuttings from five wells and temperature data indicate at least two stages of hydrothermal activity. Temperature is the main factor that affects the chemical composition of chlorite, epidote and biotite. Fe²⁺ and Al^IV increase in chlorite with temperature [from 1.4 formula position unit (fpu) to 2.8, and from 0.7 to 2.4 fpu, respectively]. The pistacite content of epidote varies from 18 to 33 mol% in high-temperature regions (>270 °C) and from 13 to 26 mol% in low-temperature regions (<250 °C). Biotite displays a slight increase in Al^IV contents (1.55–2.8) and octahedral occupancy (5.93–6.0 fpu) with temperature. Whole rock composition and variations in oxygen fugacity conditions are factors that also affect the concentrations of Fe, Al and Mg in the octahedral sites of chlorite, epidote, biotite and amphiboles. Chemical variations observed in alteration minerals at different depths in the Colapso Central-Xalapazco region could be used as indicators of relict physico-chemical conditions in the reservoir, before the present economic exploitation.     

Research and development of geothermal energy production in Hungary

The basement of the Pannonian (Carpathian) basin is represented by Paleozoic metamorphic and Mesozoic dolomite and limestone formations. The Tertiary basin gradually subsided during the Alpine orogeny down to 6000 m and was filled by elastic sediments with several water horizons.A heat flow of 2.0 to 3.4 μcal/cm²s gives temperature gradients between 45 and 70 °C/km in the basin. At 2000 m depth the virgin rock temperature is between 110 and 150°C. 80 geothermal wells about 2000 m deep have shown the great geothermal potential of the basin.The main hot water reservoir is the Upper Pliocene (Pannonian) sandstone formation. Hot water is produced by wells from the blanket or sheet sand and sandstone, intercalated frequently by siltstone. Between a 100–300 m interval, 3 to 8 permeable layers are exploited resulting in 1–3 m³/min hot water at 80–99°C temperature.Wells at present are overflowing with shut-in pressures of 3–5 atm.The Pannonian basin is a conduction-dominated reservoir. Convection systems are negligible, hot igneous systems do not exist. The assessment of geothermal resources revealed that the content of the water-bearing rocks down to 3000 m amounts to 12,600 × 10¹⁸cal. In the Tertiary sediments 10,560 × 10¹⁸cal and in the Upper Pannonian, 1938 × 10¹⁸cal are stored. In the Upper Pannonian geothermal reservoir, below 1000 m, where the virgin rock temperature is between 70 and 140°C, the stored heat is 768 × 10⁸cal. A 10¹⁸ cal is equivalent to the combustion heat of 100 million tons of oil. The amount of recoverable geothermal energy from 768 × 10⁸cal is 7.42 × 10¹⁸cal, i.e. about 10,000 MW century, not considering reinjection.At present the Pannonian geothermal reservoir stores the greatest amount of identified heat which can be mobilized and used. Hungary has 496 geothermal wells with a nominal capacity of 428 m³/min, producing 1342 MW heat. 147 wells have an outflow temperature of more than 60°C producing 190 m³/min, that is, 845 MW. In 1974 290 MWyear of geothermal energy was utilized in agriculture, district heating and industry.     

Temperature evaluation of the Bugok geothermal system, South Korea

Using a variety of chemical geothermometers and statistical analysis, we estimate the temperature of a possible deeper geothermal reservoir at Bugok, Southern Korea. Shallow thermal aquifers (down to about 400 m depth) are under exploitation in this area; the temperatures (up to 78 °C) of the produced fluids are the highest found in South Korea. Based on hydrochemical data and occurrence, the groundwaters at Bugok can be classified under three groups: Na-SO₄ thermal groundwaters (CTGW) occurring in the central (about 0.24 km²) part of the area; Ca-HCO₃ cold groundwater (SCGW) found in shallow peripheral parts of the CTGW; the intermediate-type groundwater (STGW). The CTGW type is typical of the Bugok thermal waters; they have the highest discharge temperatures and contain very high concentrations of Na (75.1–101.0 mg/L), K (2.9–6.9 mg/L) and SiO₂ (62.0–84.5 mg/L) and are rich in sulfates.The major ion composition of the CTGW suggests that these waters are in partial equilibrium with rocks at depth. The application of various alkali-ion geothermometers yields temperature estimates in the 88–198 °C range for the thermal reservoir. Multiple-mineral equilibrium calculations indicate a similar but narrower temperature range (from about 100 to 155 °C). These estimates for CTGW are significantly higher than the measured discharge temperatures. Considering the heat losses occurring during the ascent of the waters, one can infer the presence of a deeper (around 1.8 km) thermal reservoir in the Bugok area that could be developed for district heating or other direct applications of geothermal heat.     

Exploration of Lahendong geothermal field in North Sulawesi, Indonesia

This paper describes the progress made in developing the geothermal resources at Lahendong, North Sulawesi, Indonesia for utilization in power generation. Exploration of the whole region included a geophysical survey undertaken exclusively by the Volcanological Survey of Indonesia (VSI). A temperature survey at various depths was conducted through gradient boreholes. The results show that the area of anomalous temperature corresponds to the area of low resistivity revealed by the seismic survey. Two shallow exploratory boreholes (300–400 m) drilled by VSI confirmed the existence of the resources. The deep reservoir in Lahendong field extends over an area of 10 km²; the upper parts of the reservoir are presumed to be water dominated (temperatures in excess of 200°C) and to overlie a zone of hot chloride water at an undetermined depth. The potential of Lahendong field is estimated to about 90 MW.In Pelita IV (1984–1989), the fourth 5-year plan, the State Electricity Public Corporation plans to construct a 30 MW geothermal power-plant in the Lahendong field.     

Chemical and isotope characteristics of the Chachimbiro geothermal fluids (Ecuador)

The parent geothermal water proposed for the Chachimbiro geothermal area has calculated values of 2250 mg/L Cl and approximately 5 bar P_CO2. It comes from a reservoir having an estimated temperature of 225–235 °C, although temperatures somewhat higher than 260 °C may be present at the roots of the system. The geothermal reservoir at Chachimbiro is recharged mainly by meteoric water (about 92%) and secondarily by arc-type magmatic water. Carbon and sulfur isotope data support a magmatic origin for the C and S species entering the geothermal system from below, consistent with indications provided by He isotopes.The thermal springs of Na–Cl to Na–Cl–HCO₃ type located in the Chachimbiro area originate through dilution of the parent geothermal water and have reached different degrees of re-equilibration with country rocks at lower temperatures.     

Hydrogeological and isotopic survey of geothermal fields in the Buyuk Menderes graben, Turkey

The main high and low enthalpy geothermal fields in the Buyuk Menderes graben (Western Anatolia) and their reservoir temperatures are as follows: Kizildere (242 °C), Germencik (232 °C), Aydin-Ilicabasi (101 °C), Yılmazkoy (142 °C), Salavatli (171 °C), Soke (26 °C), Denizli -Pamukkale (36 °C), Karahayit (59 °C), Golemezli (101 °C) and Yenice (70 °C). The geothermal systems are controlled by active graben faults. The reservoir rocks in the geothermal fields are the limestone and conglomerate units within Neogene sediments and the marble-quartzite units within Paleozoic metamorphic formations. There are clear δ¹⁸O shifts from the Mediterranean Meteoric Water Line (MMWL) in the Kizildere, Germencik and Aydin fields, where a good relation between high temperatures and δ¹⁸O shift has also been observed, indicating deep circulation and water rock interactions. In the Pamukkale, Karahayit, Golemezli and Yenice fields and in Soke region, low temperatures, small isotope shifts, shallow circulations and mixing with shallow cold water have been noted.     

Numerical investigation of production behavior of deep geothermal reservoirs at super-critical conditions

Numerical simulations have been performed to predict pressure transients in deep geothermal reservoirs at sub- and super-critical temperatures. First, pressure drawdown and buildup tests of reservoirs with different initial conditions were simulated. The calculated pressure responses are dominated by non-linear changes of fluid kinematic viscosity and compressibility. The pressure of a super-critical zone is shown to cause complex behavior. Short- and long-term production tests in both unbounded and bounded reservoirs were then simulated. Unbounded and bounded reservoirs exhibit very similar short-term production behavior near or above the critical temperature (375–400°C). Unbounded reservoirs of low transmissivity (kh = 1 darcy-meter) exhibit long-term production behavior that depends on whether the reservoir is sub-critical (300–375°C) or super-critical (400°C); substantial increases in flowing enthalpy and declines in feedpoint pressure occur at early times in the super-critical reservoir.     

Application of fluid inclusions to the study of Bagnore geothermal field (Tuscany, Italy)

A fluid inclusion study of the hydrothermal minerals in two breccias from two wells in the Bagnore geothermal field (Italy) has provided information on the evolution of the fluids, and has also demonstrated that fluid inclusions can be utilized as geothermometers in this geothermal field. Both breccias come from reservoir zones: one (Bagnore 3bis (Bg 3bis)) was cored at a depth of 3111 m below ground level (b.g.l.), whereas the other (Bagnore 22 (Bg 22)) was ejected during a blow-out, probably from a fractured zone present between 2200 and 2300 m b.g.l. The hydrothermal cement of the breccias is mostly made up of quartz, K-feldspar, Na-rich plagioclase, calcite, chlorite and illite. Fluid inclusion studies were carried out on quartz (Bg 3bis and Bg 22 breccias) and adularia (Bg 22 breccia). Three types of fluid inclusions were recognized in the Bg 3bis breccia. Type I (liquid-rich) inclusions trapped an aqueous fluid with a CO₂ concentration (1.7–2.7 mol/kg) that is significantly higher than present-day fluids (0.5 mol/kg). Type II (liquid-rich) inclusions formed after type I, and trapped a fluid with less CO₂ (0.6–1.0 mol/kg). Type III (vapor-rich) coexist with type I inclusions, and record an early fluid circulation under boiling conditions. The decrease of the CO₂ (and total gas) concentrations from type I inclusions to type II inclusions, and on to present-day conditions can be related to boiling with gas loss and/or mixing. Only one type of fluid inclusion (type II), with moderate CO₂ concentration (0.7–0.3 mol/kg), was found in the Bg 22 breccia. Boiling and/or mixing explain the variation of the CO₂ content in the Bg 22 reservoir fluid from inclusion formation to modern CO₂ concentration (0.3 mol/kg). The absence of any type I inclusions in Bg 22 breccia may be related to non-uniform CO₂ concentrations in different parts of the field. Present-day temperatures (295±10 °C for Bg 3bis and 320±10 °C for Bg 22) are close or equal to fluid inclusion average total homogenization temperatures (around 290 °C for Bg 3bis and 320 °C for Bg 22), suggesting that fluid inclusions can be useful for estimating local temperatures when direct measurements are not available or dubious.     

Chemical and isotopic measurements of geothermal discharges in the Acqui terme district, Piedmont, Italy

Chemical and isotopic studies have been carried out on samples from the Acqui geothermal district (Piedmont, Italy). The results indicate that the waters represent mixtures of meteoric waters and a fossil brine; the contribution of meteoric waters ranges between 93 and 98%. The recharge zone of meteoric waters is most likely in the Voltri-Savona massif at an isotopic recharge altitude of 590 m. On the basis of chemical and isotopic data the reservoir temperature has been estimated at about 200°C. This high value renders the Acqui district possibly the most promising geothermal system in northern Italy.