脱油沥青和SBS复合改性70号道路沥青的研究

利用脱油沥青(DOA)和SBS调和70号道路沥青生产改性沥青是一条解决DOA应用的有效途径。对DOA和SBS调和商品70号沥青制备改性沥青进行了试验研究,结果表明:在固定SBS,糠醛抽出油均为4%的商品70号沥青中外掺2.5%~1 0.0%的DOA,随着DOA含量的增加得到的改性沥青软化点升高,针入度和5℃延度减小,黏度增大。DOA调和比例为2.5%~5.0%的改性沥青的性质均满足SBS改性沥青1-D级标准。对DOA掺量为5.0%、7.5%的改性沥青和改性沥青原样进行了流变行为表征学测定,结果表明SBS改性沥青中添加DOA后复数模量增大,相位角减小,车辙因子增大,改性沥青的性能显著改善。此外,黏温性能研究表明掺兑DOA后SBS改性沥青的高温性能得到了改善。     

TLA改性沥青流变和老化性能的研究

采用动态剪切流变仪（DSR）对不同掺量的11A改性沥青的流变性能进行了研究,并通过薄膜烘箱老化（TFOT）和紫外老化（uv）试验研究了TLA对沥青老化性能的影响。结果表明：加入TLA后,沥青的复数模量增大,相位角减小,TLA的掺量每增加10％,PG高温区间基本上升1个等级,大大提高了沥青的高温稳定性和降低了其温度敏感性。与未改性沥青相比,TLA改性沥青TFOT和UV老化后的软化点增量和粘度变化指数显著减小,TFOT老化后的残留针入度比明显增大,TLA的加入有效地改善了沥青的热氧老化和紫外老化性能。     

SBS改性沥青性能探究

论文以30#、50#低标号沥青作为基质沥青,采用SBS对基质沥青进行改性,SBS改性实验结果表明:当SBS掺量为0-6%时,随着SBS掺量的增加,30#与50#改性沥青的针入度逐渐降低,软化点逐渐升高,即改性沥青的高温性能提高,改性沥青的抗老化性能以及高温延度得到明显改善;但SBS对改性沥青的低温性能影响较小。     

玄武岩纤维沥青胶浆性能研究

针对玄武岩纤维的优良特性,进行沥青胶结料和玄武岩纤维之间的作用研究。研究结果表明：胶浆的针入度随着玄武岩纤维掺量的增加而减小,随着温度的升高而增大;针入度指数随纤维掺量的增加而增大,沥青肢浆的感温性得到改善;胶浆的软化点随纤维掺量的增加而减小,在纤维掺量为4％时,接近高粘沥青的软化点水平;胶浆的延度随纤雏掺量的增加而减小。     

资源集约型橡胶沥青加工工艺研究

为了研究剪切时间和剪切温度等生产工艺,以及胶粉用量、化学添加剂等对橡胶沥青性能的影响,分别改变生产工艺和胶粉及添加剂用量,制备橡胶改性沥青,并研究其基本性能指标。主要研究结论如下:随着剪切时间的延长,黏度先增大后减小,针入度逐渐增大,延度先增大然后基本保持不变,软化点基本不变,离析值变小。随着加工温度的升高,针入度明显增大,软化点降低,从而降低了其高温性能。随着胶粉掺量的增加,体系的黏度增大,限制了沥青体系的流动性,同时针入度减小,延度下降。交联剂含量的增加能够减小离析值,提高改性沥青的高温贮存稳定性。活化剂使胶粉与沥青两者的相容性提高,降低了改性沥青的耐感温性能和耐老化性能,但是高温储存稳定性得以改善。综合工艺以及配方设计等研究成果,通过掺加胶粉25%,硫化剂0.5%(占胶粉含量),活化剂0.3%,在180℃,4 000 r/min的剪切乳化机中剪切45 min,可制备高温贮存性能良好的资源集约型橡胶沥青。     

表面活性类温拌剂对SBS改性沥青性能影响

选用表面活性类温拌剂,掺入SBS改性沥青中,制得温拌改性沥青.通过针入度、软化点、延度、黏度、沥青气动回弹试验、低温弯曲蠕变试验(BBR)等探究不同掺量的表面活性类温拌剂对SBS改性沥青各方面性能的影响.结果表明:表面活性类温拌剂使得SBS改性沥青的针入度减小、软化点和延度增加、黏度有所下降,蠕变变形量降低、蠕变恢复能...     

岩沥青改性沥青及沥青混合料路用性能研究

为了了解新疆岩沥青的路用性能,在沥青胶结料中掺入不同量的岩沥青,进行针入度、延度扣软化点试验,对加入岩沥青后的沥青混合料进行了车辙试验、低温弯曲试验、浸水马歇尔试验、冻融劈裂试验、疲劳试验,并与SBS改性沥青及沥青混合料的试验结果进行了比较。结果发现掺入岩沥青后,沥青胶结料的的高温稳定性和抗老化性得到了较大程度的提高,掺入量为15%的岩沥青改性沥青混合料动稳定度、冻融劈裂强度比、劲度模量较基质沥青分别提高了3.5倍、0.34倍、2.89倍,说明其高温稳定性、水稳定性、抗疲劳性有了较大的提高,而低温弯曲破坏强度提高了0.18倍,反映出其低温抗裂性也得到了一定程度的改善,表明掺入岩沥青的沥青混凝土具有良好的路用性能。     

水滑石/废橡胶粉复合改性沥青的制备及其性能研究

以克拉玛依90号沥青作为基质沥青、废橡胶粉和水滑石（LDHs）作为改性剂,制备了LDHs/废橡胶粉复合改性沥青,在废橡胶粉加入量不变的条件下,考察LDHs加入量对复合改性沥青的物理性能、抗紫外老化性能和流变性能的影响。结果表明：当废橡胶粉加入量（w）为15%时,随着LDHs的加入,复合改性沥青的软化点升高,针入度和延度有所下降,两种改性剂相互结合,使复合改性沥青的物理性能得到改善,并且满足国家聚合物改性沥青标准的要求,考虑到改性剂成本,选取LDHs加入量（w）为3%～4%;LDHs的加入使复合改性沥青的软化点增量减小,残留针入度比和延度保留率上升,表明LDHs可明显提高复合改性沥青的抗紫外老化性能;LDHs的加入可使复合改性沥青复数模量和车辙因子增加,相位角下降,说明LDHs可提高复合改性沥青的抗车辙性能。     

天然沥青复合SBS改性沥青的性能研究

天然沥青具有高含量的沥青质和胶质,将其掺入石油沥青中能够改善基质沥青的组成和结构,从而使改性沥青混合料获得良好的路用性能。对天然沥青复合SBS改性沥青的性能进行研究,研究结果表明:随着天然沥青掺量的增加,改性沥青的软化点呈上升趋势,黏度逐渐增大,而针入度随着天然沥青掺量的增加逐渐减小,天然沥青掺量为5%时,经过适当的调合,可以生产出常规性能指标基本符合JTG F40-2004《公路沥青路面施工技术规范》聚合物改性沥青I-D规格产品。     

硅藻土改性沥青混合料性能试验研究

采用室内试验评价了硅藻土改性沥青及其混合料的性能,结果显示:硅藻土掺量越大,沥青稠度越大,25℃针入度越小;硅藻土可改善沥青抗老化性能,13%~17%掺量时抗老化效果最好;硅藻土可提高沥青软化点,15%~17%掺量时,软化点最大;硅藻土会降低沥青10℃延度,不利于胶结料低温性能。随着硅藻土掺量的增加,沥青混合料冻融劈裂强度比增大,当掺量超过15%以后,几乎不再增大;动稳定度先增大后减小,在17%掺量左右时增大幅度最大;在15%~17%掺量时,混合料低温性能改善作用最明显,当超过17%时,改善作用下降甚至没有改善作用。     

A Study on Xinjiang Asphaltite as an Asphalt Modifier. Part II: Rheological Evaluation of Modified Asphalt Binders

Modified asphalt binders with varying Xinjiang asphaltite contents between 4% and 16% were prepared in laboratory. Dynamic shear rheometer temperature sweep and time sweep tests, bending beam rheometer tests, some conventional tests including penetration and softening point were performed to analyze the rheological properties of these asphalt binders and evaluate Xinjiang asphaltite potential as asphalt modifier. Test results showed with the Xinjiang asphaltite content increasing, complex shear modulus increased and phase angle decreased, which indicated Xinjiang asphaltite could improve the elasticity and deformation resisting of binders. Fatigue failure life of asphalt binders grew exponentially with Xinjiang asphaltite content. Moreover, Xinjiang asphaltite had an adverse effect on the low temperature performances of asphalt binders based on measured creep stiffness and m-value. Based on these test results modification mechanism of Xinjiang asphaltite was analyzed. It is thus suggested that Xinjiang asphaltite is better suitable as a high temperature resistant and anti-fatigue asphalt modifier material.     

沥青软化点温度下的粘弹特征

本文对30余个沥青样品进行了动态剪切扫描试验,探讨了软化点环境下的沥青的粘弹性状态。试验发现：在软化点温度条件下,纯沥青与改性沥青处于两种不同的流变状态,石油沥青粘弹组成中粘性分量居多,相位角多在80o以上;而SBS改性沥青则保持较低的模量值和相位角,弹性仍保持为一个明显的特质。同时,利用Shapiro-Wilk正态检验发现,在a=0.05置信水平下,不管老化状态如何,纯沥青软化点对应一个稳定的复数模量,在荷载100Pa、频率10rad/s的实验条件下,该模量均值为13033.7Pa,标准差为2104.7Pa。并利用这种等模量规律求取纯沥青的软化点,证明了与实测软化点的良好关联性。需要更多数据以验证本文的初步结论。     

沥青结合料高温指标浅析

沥青结合料的高温性能密切关系到沥青路面性能的优劣。以沥青常规试验为基础得到老化前后的沥青常规指标：25℃针入度、软化点、60℃动力粘度及当量软化点,以沥青混合料车辙实验验证用这四种指标评价沥青高温性能是否可靠。发现老化前沥青的60℃动力粘度与动稳定度排序较一致。相关系数为0.756;老化后沥青的60℃动力粘度及当量软化点与动稳定度排序完全一致。相关系数分别为O.741、0.959。研究认为RTFOT沥青的当量软化点可以更准确地反映沥青的高温性能。     

Rheological and aging properties of warm mix asphalt binders containing expanded vermiculite

The scope of this study was to investigate the high and intermediate temperature rheological and aging properties of warm mix asphalt binders modified by organo-expanded vermiculites. The rotational viscosity, complex modulus, and rutting parameter (G^*/δ) increased and the penetration and phase angle decreased after modification of 3% organo-expanded vermiculites, indicating that the high temperature rheological properties of the warm mix asphalt binder have been improved. The warm mix asphalt binders containing 3% organo-expanded vermiculites demonstrate the lowest value of phase angle and the highest value of complex modulus compared with the studied binders. In addition, as a result of the rolling thin film oven test, the viscosity aging index of warm mix asphalt binder decreases, while the retained penetration increases obviously with the introduction of organo-expanded vermiculites. The warm mix asphalt binder with 3% organo-expanded vermiculites has more pronounced improvements in aging resistance in comparison with other studied modified warm mix asphalt binders.     

A Laboratory Investigation on the Rheological Properties of Aged and Unaged Organic Wax Modified Asphalt Binders

Different proportions of Sasobit (Sasol Wax, Hamburg, Germany) content were blended with 60–70 penetration grade asphalt binder type and were subjected to physical and rheological tests in order to determine the influence of Sasobit on asphalt binder. The test results indicated that Sasobit had different effects on temperature susceptibility of binders. Frequency sweep test showed that binders containing Sasobit had higher complex modulus compared to the control binders. In addition, lower phase angle values were observed for Sasobit-modified binders. FTIR analysis showed changes in the microstructure and weight distribution of Sasobit-modified binders.     

沥青胶结料基本高温性能指标相关性研究

高温稳定性是沥青胶结料重要技术要求之一。针入度、软化点、60℃动力黏度和针入度指数是工程中最为常用的高温性能评价指标。为探究这些高温性能指标的区分度和关联性,对34种源于不同工程的沥青胶结料进行检测,基于聚类分析法和灰色关联分析法对试验数据进行分析。结果表明,60℃动力黏度指标相比针入度和软化点指标能够更有效地区分不同沥青胶结料的高温性能;70号基质沥青和高黏度改性沥青的60℃动力黏度与软化点关联度高,但SBS改性沥青60℃动力黏度与其他高温性能指标的关联度低;考虑到动力黏度能够客观表征流变特性,建议在实际工程中可将60℃动力黏度列为强制性指标。     

纳米CaCO3改性沥青与SBS改性沥青综合比较研究

选择纳米CaCO3和SBS为改性剂,研究其对基质沥青的改性作用。针对改性剂的特性确定了相应的制备工艺。通过针入度、软化点、延度、布氏粘度扣动态剪切流变试验及混合料试验评价了改性沥青的路用性能。结果表明纳米CaCO3改性沥青路用性能得到了显著改善。最后对三种典型掺量的改性沥青性价比进行了对比分析,认为纳米CaCO3改性沥青在低等级路面使用中具有较高的性价比。     

Road Asphalt Prepared by High Softening Point De-oiled Asphalt From Residuum Solvent Deasphalting

Solvent deasphalting process is an effective pretreatment upgrading technology for vacuum residuum. The rational use of the de-oiled asphalt with high softening point needs to be solved when the process was applied to upgrade the residue oil. Preparation of the hard paving asphalt with low penetration by adding a certain proportion of high softening point de-oiled asphalt to the commodity 70# paving asphalt was investigated. The performance and The feasibility of the preparation 50# paving asphalt with high softening point de-oiled asphalt has been also discussed. The experimental results showed that the properties of the blend asphalt were changed in different extent with the different proportion between 70# paving asphalt and high softening point de-oiled asphalt. The rheological behavior tests showed that the anti-rutting performance of blending asphalt could be improved due to the addition of de-oiled asphalt. The qualified 50# paving asphalt could be prepared from the de-oiled asphalt and the commodity 70# paving asphalt with the appropriate blending ratio.     

不同掺量岩沥青改性沥青混合料性能试验研究

利用天然岩沥青作改性剂,对AH-70基质沥青进行改性,采用AC-13型沥青混合料进行配合比设计,分别对0、5％、7．5％、10％掺量的岩沥青改性沥青混合料的动态模量进行试验研究,结果表明在一定温度控制下,掺加不同剂量的岩沥青改性剂,对沥青混合料动态模量均有较大的改善。在相同温度和频率下,随着岩沥青掺量的增加,动态模量逐渐增大,当岩沥青掺量达5％时,混合料动态模量满足法国高模量沥青混凝土的标准。