Experimental investigation of the performance and emissions of a heavy-duty diesel engine fueled with waste cooking oil biodiesel/ultra-low sulfur diesel blends

The major obstacle to biodiesel commercialization is the high cost of raw materials. Biodiesel from waste cooking oil is an economical source and thus an effective strategy for reducing the raw material cost. Using waste cooking oil also solves the problem of waste oil disposal. This study investigated the emissions of polycyclic aromatic hydrocarbons (PAHs), carcinogenic potencies and regulated matters, and brake specific fuel consumption from a heavy-duty diesel engine under the US-HDD transient cycle for five test fuels: ultra-low sulfur diesel (ULSD), WCOB5 (5 vol% biodiesel made from waste cooking oil + 95 vol% ULSD), WCOB10, WCOB20, and WCOB30. Experimental results indicate using ULSD/WCOB blends decreased PAHs by 7.53%-37.5%, particulate matter by 5.29%-8.32%, total hydrocarbons by 10.5%-36.0%, and carbon monoxide by 3.33%-13.1% as compared to using ULSD. The wide usage of WCOB blends as alternative fuels could protect the environment.     

Experimental study and empirical correlation development of fuel properties of waste cooking palm biodiesel and its diesel blends at elevated temperatures

In this experimental work, the density, dynamic viscosity and higher heating value of methyl ester based waste cooking palm-biodiesel oil (WMEPB) was investigated under varying temperature and blend ratio condition with No. 2 diesel fuel. The transesterified fatty acid methyl ester of palm vegetable oil collected from local food and beverage shops was used as neat biodiesel. Four different fuel blends (20%, 40%, 60% and 80% by volume mixing with base diesel) were studied along with base No. 2 diesel fuel and pure biodiesel. Tests for dynamic viscosity and density were performed in the temperature range 0–130 °C for each fuel sample whereas the higher heating values were determined at 25 °C room temperature condition. It is found that pure biodiesel has the highest density and dynamic viscosity at a given temperature whereas it exhibits lowest combustion heating value among the six fuels. Moreover, the density for each fuel sample decreases linearly with the increase in temperature. On the other hand, the dynamic viscosity decreases exponentially with the temperature for each fuel sample. In addition, based on the experimental results, regression correlations have been proposed for the density, dynamic viscosity, and higher heating value of the fuels. Subsequently, comprehensive error analyses of these proposed correlations were performed. In particular, the correlation for density and dynamic viscosity were respectively compared with Kay's mixing rule and Grunberg-Nissan mixing rule theory in order to validate their applicability. It is found that density correlations predicted within ±0.3% average error band. And, as high as 72.2% of the dynamic viscosity data were in the range of ±5% average error while the remaining data fell within ±10% error range. And finally, through a comparative study with the available fuel property results of fresh methyl ester palm biodiesel, it is found that available existing correlations derived from fresh palm biodiesel studies can not accurately predict the fuel properties of same waste biodiesel and its blends with diesel.     

基于不同原料生物柴油混合燃料的发动机性能研究

对一台TDI柴油机燃用花椒籽、棉籽、棕榈和餐饮废油脂4种不同原料制成的生物柴油(以10%体积比分别与柴油混合制成)的动力性、经济性和排放特性进行了试验研究,探讨了4种生物柴油对发动机性能的影响。研究结果表明:在燃用4种生物柴油时,棕榈油制生物柴油的功率和纯柴油基本一致,其余混合燃料的功率都比纯柴油略有下降;4种混合燃料的油耗与纯柴油基本一致;与纯柴油相比,生物柴油混合燃料的碳烟、CO、HC排放均较低,而NOx排放略高。     

Analysis of blended fuel properties and engine performance with palm biodiesel–diesel blended fuel

Depleting fossil fuel sources accompanied by continuously growing energy demands lead to increased interest in alternative energy sources. Blended biodiesel–diesel fuel has been approved as a commercial fuel at a low blending ratio. However, problems related to fuel properties are persistent at high blending ratios. Hence, in this study, the feasibility of biodiesel produced from palm oil was investigated. Characterization of blended fuel properties with increasing palm biodiesel ratio is conducted to evaluate engine performance test results. The qualifying of blended fuel properties was used to indicate the maximum blending ratio suitable for use in unmodified diesel engines according to the blended fuel standard ASTM D7467. The property test results revealed that blended fuel properties meet blended fuel standard requirements at up to 30% palm oil biodiesel. Furthermore, blending is efficient for reduction of the pour point from 14 °C for unblended biodiesel to less than 0 °C at a 30% biodiesel blending ratio. However, the energy content reduces by about 1.42% for each 10% increment of biodiesel. Engine test results demonstrated that there was no statistically significant difference for engine brake thermal efficiency among tested blended fuels compared to mineral diesel, and the lowest engine cyclic variation was achieved with blended fuel B30.     

Biodiesel production from waste cooking oil using heterogeneous catalysts and its operational characteristics on variable compression ratio CI engine

In the present work, the optimum biodiesel conversion from waste cooking oil to biodiesel through transesterification method was investigated. The base catalyzed transesterification under different reactant proportions such as the molar ratio of alcohol to oil and mass ratio of catalyst to oil was studied for optimum production of biodiesel. The optimum condition for base catalyzed transesterification of waste cooking oil was determined to be 12:1 and 5 wt% of zinc doped calcium oxide. The fuel properties of the produced biodiesel such as the calorific value, flash point and density were examined and compared to conventional diesel. The properties of produced biodiesel and their blend for different ratios (B20, B40, B60, B80 and B100) were comparable with properties of diesel oil and ASTM biodiesel standards. Tests have been conducted on CI engine which runs at a constant speed of 1500 rpm, injection pressure of 200 bar, compression ratio 15:1 and 17.5, and varying engine load. The performance parameters include brake thermal efficiency, brake specific energy consumption and emissions parameters such as Carbon monoxide (CO), Hydrocarbon (HC), Oxides of Nitrogen (NOx) and smoke opacity varying with engine load (BP). Diesel engine's thermal performance and emission parameters such as CO, HC, and NOx on different biodiesel blends demonstrate that biodiesel produced from waste cooking oil using heterogeneous catalyst was suitable to be used as diesel oil blends and had lesser emissions as compared to conventional diesel.     

Exergy analysis of small DI diesel engine fueled with waste cooking oil biodiesel

ABSTRACT

This study investigates the merits of exergy analysis over energy analysis for small direct injection (DI) diesel engine using the blend of waste cooking oil biodiesel and petroleum diesel. Taguchi’s “L’ 16” orthogonal array has been used for the design of experiment. The engine tested at different engine speeds, load percentages, and blend ratios, using the waste cooking oil biodiesel. Basic performance parameters and fuel input exergy, exergetic efficiency (second law efficiency), exergy associated with heat transfer, exergy associated with the exhaust gas and destruction of exergy are calculated for each blend of waste cooking oil biodiesel and diesel. Results show that the optimum operating conditions for minimum brake-specific fuel consumption (BSFC) and exergy destruction are achieved when engine speed at 1900 rev/min, load percentage is 75%, and the engine is fueled with B40.     

发动机燃用生物柴油的性能研究

通过对比研究了柴油机燃用餐饮废弃油炼制的生物柴油、柴油及B50时在高原地区的动力性、经济性及排放特性。研究结果表明：在柴油机不进行任何调整的情况下,全负荷时,燃用生物柴油的发动机动力性降低6.8%,B50降低3%;燃用生物柴油有效燃油消耗率升高了13.8%;燃用B50在高速高负荷时柴油机热效率提高2.5%;无论在全负荷还是在部分负荷工况下,燃用生物柴油均能大幅度降低柴油机烟度、CO和HC排放,但会引起NOx排放量的上升。     

The evaluation of a direct injection diesel engine operating with waste cooking oil biodiesel in point of the environmental and enviroeconomic aspects

In this study, the environmental and enviroeconomic analyzes were implemented to the single-cylinder, four-stroke, direct-injection diesel engine operating with diesel fuel, waste cooking oil biodiesel and their blends (B5, B10, B20, and B30) under different fuel injection pressures (170–220 bars) and engine speeds (1000–3200 rpm) and at full load conditions. The environmental and enviroeconomic analyzes results showed that B20 was the worst fuel at the other fuel injection pressures, while diesel fuel was the worst fuel at the original fuel injection pressure. It was determined that B100 gave the best results among the other fuels the entire engine operating conditions.     

Effect of metal based additive on performance emission and combustion characteristics of diesel engine fuelled with biodiesel

This study investigates the use of ferric chloride (FeCl₃) as a fuel borne catalyst (FBC) for waste cooking palm oil based biodiesel. The metal based additive was added to biodiesel at a dosage of 20 μmol/L. Experiments were conducted to study the effect of ferric chloride added to biodiesel on performance, emission and combustion characteristics of a direct injection diesel engine operated at a constant speed of 1500 rpm at different operating conditions. The results revealed that the FBC added biodiesel resulted in a decreased brake specific fuel consumption (BSFC) of 8.6% while the brake thermal efficiency increased by 6.3%. FBC added biodiesel showed lower nitric oxide (NO) emission and slightly higher carbon dioxide (CO₂) emission as compared to diesel. Carbon monoxide (CO), total hydrocarbon (THC) and smoke emission of FBC added biodiesel decreased by 52.6%, 26.6% and 6.9% respectively compared to biodiesel without FBC at an optimum operating condition of 280 bar injection pressure and 25.5^o bTDC injection timing. Higher cylinder gas pressure, heat release rate and shorter ignition delay period were observed with FBC added biodiesel at these conditions.     

Performance, emission and combustion characteristics of biodiesel fuelled variable compression ratio engine

Experiments has been carried out to estimate the performance, emission and combustion characteristics of a single cylinder; four stroke variable compression ratio multi fuel engine fuelled with waste cooking oil methyl ester and its blends with standard diesel. Tests has been conducted using the fuel blends of 20%, 40%, 60% and 80% biodiesel with standard diesel, with an engine speed of 1500 rpm, fixed compression ratio 21 and at different loading conditions. The performance parameters elucidated includes brake thermal efficiency, specific fuel consumption, brake power, indicated mean effective pressure, mechanical efficiency and exhaust gas temperature. The exhaust gas emission is found to contain carbon monoxide, hydrocarbon, nitrogen oxides and carbon dioxide. The results of the experiment has been compared and analyzed with standard diesel and it confirms considerable improvement in the performance parameters as well as exhaust emissions. The blends when used as fuel results in the reduction of carbon monoxide, hydrocarbon, carbon dioxide at the expense of nitrogen oxides emissions. It has found that the combustion characteristics of waste cooking oil methyl ester and its diesel blends closely followed those of standard diesel.     

Study on the spray characteristics of methyl esters from waste cooking oil at elevated temperature

In Taiwan, millions of tons of waste cooking oil are produced each year, and less than 20% of it, about 150,000 ton/a, is reclaimed and reused. Most waste oil is flushed down the drain. Utilizing waste cooking oil to make biodiesel not only reduces engine exhaust gas pollution, but also replaces food-derived fuels, and reduces ecologic river pollution. This study employed two-stage transesterification to lower the high viscosity of waste oil, utilized emulsion to reduce the methyl ester NOx pollution, and used methanol to enhance the stability and viscosity of emulsified fuel. To further analyze spray characteristics of fuels, this experiment built a constant volume bomb under high temperature, used high speed photography to analyze spray tip penetration, spray angle, and the Sauter mean diameter (SMD) of fuel droplets, and compared the results with fossil diesel. The experimental results suggested that, two-stage transesterification can significantly lower waste oil viscosity to that which is close to fossil diesel viscosity. At a temperature above 300 °C, waste cooking oil methyl esters had a water content of 20%, spray droplet characteristics were significantly improved, and NOx emission dropped significantly. The optimal fuel ratio suggested in this experiment was waste cooking oil methyl ester 74.5%, methanol 5%, water 20%, and composite surfactant Span–Tween 0.5%.     

An outcome of quaternary fuel blended Fe3O4-doped reduced graphene oxide nanocomposite on the diesel engine

The study includes the use of alcohols in conjunction with diesel as a binary fuel and biodiesel. In addition, this study was conducted on quaternary fuels (premium diesel, waste cooking biodiesel, n-butanol, and bioethanol), including Fe₃O₄ (iron(III) oxide)-doped reduced graphene oxide (rGO) nanocomposite to reduce the use of fossil fuels, their cost, and energy demand. It includes 10% bioethanol, 5%–20% n-butanol, 25 ppm Fe₃O₄-doped rGO nanocomposite, and 20% and 100% waste cooking biodiesel, all of which have been tested in a diesel engine to ensure that they are suitable for use. The findings were compared to those obtained with premium diesel, ranging from 50% to 100% at full engine load conditions. In comparison to 100% premium diesel fuel, the fuel blend (Blend G) had 37.50% brake thermal efficiency and 0.46% (brake-specific energy consumption), as well as lower rates of 316.2% carbon monoxide, 198.80% hydrocarbon, and 80.01% smoke with 28.10% higher oxides of nitrogen (NOx). Adding 20% n-butanol to premium diesel, as well as waste cooking biodiesel, bioethanol, and Fe₃O₄-doped rGO nanocomposite fuel blends, was used in this study to improve the performance of the diesel engine and reduce some of the NOx emissions. In the near future, these fuel blends may be a viable alternative combination for the diesel engine.     

Performance and emission evaluation of a diesel engine fueled with methyl esters of rubber seed oil

Recent concerns over the environment, increasing fuel prices and scarcity of its supply have promoted the interest in development of the alternative sources for petroleum fuels. At present, biodiesel is commercially produced from the refined edible vegetable oils such as sunflower oil, palm oil and soybean oil, etc. by alkaline-catalyzed esterification process. This process is not suitable for production of biodiesel from many unrefined non-edible vegetable oils because of their high acid value. Hence, a two-step esterification method is developed to produce biodiesel from high FFA vegetable oils. The biodiesel production method consists of acid-catalyzed pretreatment followed by an alkaline-catalyzed transesterification. The important properties of methyl esters of rubber seed oil are compared with other esters and diesel. Pure rubber seed oil, diesel and biodiesel are used as fuels in the compression ignition engine and the performance and emission characteristics of the engine are analyzed. The lower blends of biodiesel increase the brake thermal efficiency and reduce the fuel consumption. The exhaust gas emissions are reduced with increase in biodiesel concentration. The experimental results proved that the use of biodiesel (produced from unrefined rubber seed oil) in compression ignition engines is a viable alternative to diesel.     

Use of palm oil-based biofuel in the internal combustion engines: Performance and emissions characteristics

Palm oil (PO) was treated using different methods in order to use and test it as fuel in Compression Ignition (CI) engines. The treatments include PO preheated and preparation of PO/diesel oil blends, using mixtures of PO with waste cooking oil (WCO), which are converted into esters by a transesterification process. The purpose of this study is to evaluate the potential of the palm oil-based biofuels to replace diesel oil in CI engines.Tests were conducted in a single cylinder, four-stroke, air-cooled, direct injection diesel engine (no engine modifications were required). Experiments were initially carried out with diesel oil for providing baseline data. All the tested fuels have a low heating value compared to diesel fuel. A high fraction of PO in diesel fuel decreases the heating value of the blend. The brake thermal efficiency increases for the PO/Diesel blends. HC emissions for all those fuels except for the PO/Diesel blends are found lower, while CO emissions rise for all types of fuels. NO_x emissions are higher at low load, but lower at full load, for the engine fueled with PO and lower both at middle and full load for the engine fueled with the esters.     

Performance,emission and combustion characteristics of a variable compression ratio engine using methyl esters of waste cooking oil and diesel blends

The performance, emission and combustion characteristics of a single cylinder four stroke variable compression ratio multi fuel engine when fueled with waste cooking oil methyl ester and its 20%, 40%, 60% and 80% blends with diesel (on a volume basis) are investigated and compared with standard diesel. The suitability of waste cooking oil methyl ester as a biofuel has been established in this study. Bio diesel produced from waste sun flower oil by transesterification process has been used in this study. Experiment has been conducted at a fixed engine speed of 1500 rpm, 50% load and at compression ratios of 18:1, 19:1, 20:1, 21:1 and 22:1. The impact of compression ratio on fuel consumption, combustion pressures and exhaust gas emissions has been investigated and presented. Optimum compression ratio which gives best performance has been identified. The results indicate longer ignition delay, maximum rate of pressure rise, lower heat release rate and higher mass fraction burnt at higher compression ratio for waste cooking oil methyl ester when compared to that of diesel. The brake thermal efficiency at 50% load for waste cooking oil methyl ester blends and diesel has been calculated and the blend B40 is found to give maximum thermal efficiency. The blends when used as fuel results in reduction of carbon monoxide, hydrocarbon and increase in nitrogen oxides emissions.     

A comprehensive study on performance,emission and combustion behavior of a compression ignition engine fuelled with WCO (waste cooking oil) emulsion as fuel

This work aims at evaluating the performance, emission and combustion of a diesel engine fuelled with WCO (waste cooking oil obtained from palm oil) and its emulsion as fuel. A single cylinder water-cooled diesel engine was used. Base data was generated with diesel and neat WCO as fuels. Subsequently, WCO oil was converted into its emulsion and tested. Neat WCO resulted in higher smoke, hydrocarbon and carbon monoxide emissions as compared to neat diesel. Significant reduction in all emission was achieved with the WCO emulsion. Cylinder peak pressure and maximum rate of pressure rise were found to be higher with WCO emulsion as compared to neat WCO mainly at high power outputs. Ignition delay was found as higher with neat WCO and its emulsion. It is concluded that WCO emulsion can be used in diesel engines without any modifications in the engine with superior performance and reduced emissions at high power outputs.     

Biofuels and their potential to aid the UK towards achieving emissions reduction policy targets

The potential of biofuels contributing to the UK emission reduction targets in the formulated UK Low Carbon Transition Plan (LCTP) and the UK’s obligation in the wider EU emissions reduction targets are assessed using four scenarios. The scenarios were evaluated using hybrid lifecycle assessment developed in a multi-regional input–output (MRIO) framework. In the hybrid MRIO LCA framework, technology-specific processes in the biofuels and fossil fuels LCA systems are integrated into a generalised 2-region (UK and Rest of the World) environmental-economic input–output framework in order to account for economy-wide indirect GHG emissions in the biofuels and fossil fuels LCA systems in addition to other indirect impacts such as indirect land use change. The lifecycle greenhouse gas emissions of biodiesel (soybean, palm, rape, waste cooking oil) and bio-ethanol (sugarcane, sugarbeet, corn) were assessed and compared to fossil fuel (diesel and petrol) baseline. From one of the scenarios, biodiesel production from waste cooking oil and bioethanol from sugarbeet offer the biggest potential for emissions savings relative to fossil fuel equivalent and offering a maximum emission savings of 4.1% observed with a biofuel market share of 10% reached in 2020. It was also established that under current biofuel feedstock mix, to achieve the 6% emissions saving primarily from biofuels as proposed in the LCTP, 23.8% of the transport fuels market would be required to be held by biofuels by 2020.     

我国生物质能源现代化应用前景展望(四)——生物质能源转化生命周期分析

生物质种类不同,转化为运输燃料的途径也是多种多样,生命周期排放的温室气体和能耗也不相同。总结对比主要生物质转化途径的全生命周期分析(LCA)结果,有助于明确需要进一步改进的技术难题和方向。生物质转化为醇类燃料时,使用E85比使用传统汽油的碳排放明显下降,纤维素生化转化途径排放的二氧化碳当量值约为传统汽油的0.2~0.7倍,热化学途径约为传统汽油的0.6~0.9倍,玉米干法为传统汽油的0.8~1倍。油脂类生物质转化为酯类燃料时,生物柴油减排温室气体的效果,动物油脂地沟油、棕榈油豆油、椰子油菜籽油。动物油脂、地沟油生产生物柴油可减排温室气体70%~90%,以植物为原料的生物柴油可减排10%~90%。生物质转化为烃类燃料时,菜籽油基喷气燃料可减排温室气体13%~55%,F-T合成油比油脂加氢具有更好的减排效果,BTL通常可减排80%以上的温室气体,CBTL的减排效果与掺入生物质的比例有关,热解汽柴油的温室气体减排率为58%~70%。对于微藻生物燃料工艺过程,在微藻产率和含油量不太低的情况下,池子系统的温室气体排放低于石油柴油。     

Synergistic effect of hydrogen and waste lubricating oil on the performance and emissions of a compression ignition engine

The demand for energy is increasing every year. For a long time, fossil fuels have been used to satiate this energy demand. However, using hydrocarbon-based fossil fuels has led to an enormous rise of carbon dioxide levels in the atmosphere resulting in global warming. It is therefore necessary to look for alternatives to fossil fuels. The research carried out till date have shown biomass and waste-derived fuels as plausible alternatives to fossil fuels. The biomass feedstock includes jatropha oil, Karanja oil, cottonseed oil, and hemp oil among others and wastes include used cooking oil, used engine oil, used tire and used plastics etc. In this study, the authors aim to explore waste lubrication oil as a fuel for the diesel engine. The used lubrication oil was pyrolyzed and diesel-like fuel with 80% conversion efficiency was obtained. A blend of the fuel and diesel in the ratio of 80:20 on volume basis was prepared. Engine experiments at various load conditions was carried out with the blend. As compared to diesel, a 2% increase in thermal efficiency, 6.3%, 16.1% and 13.6% decrease in smoke, CO and HC emissions & 3.2% and 1.8% increase in NOx and CO₂ emission were observed at full load with the blend. With an aim to further improve the engine performance and reduce the overall emissions from the engine exhaust, a zero-carbon fuel namely gaseous hydrogen was inducted in the intake manifold. The flow rate of hydrogen was varied from 3 to 12 Litres per minute (LPM). As compared to diesel, at maximum hydrogen flow rate the thermal efficiency increased by 12.2%. HC, CO and smoke emissions decreased by 42.4%, 51.6% and 16.8%, whereas NOx emissions increased by 22%. The study shows that the combination of pyrolyzed waste lubricant and hydrogen were found to be suitable as a fuel for an unmodified diesel engine. Such fuel combination can be used for stationary applications such as power backups.     

Effect of injection parameters on the combustion and emission characteristics in a common-rail direct injection diesel engine fueled with waste cooking oil biodiesel

The objective of this paper was to study the effects of the injection pressure and injection timing on the combustion and emission characteristics in a single-cylinder common-rail direct injection (CRDI) diesel engine fueled with waste cooking oil (WCO) biodiesel and commercial diesel fuel. The fuel property including fatty acid composition for the biodiesel were measured and compared with those of the conventional diesel fuel. The engine tests were conducted at two injection pressures (80 and 160 MPa) and different injection timings from −25 to 0 crank angle degree (CAD) after top dead center (aTDC) under two different engine loads. The results showed that the indicated specific fuel consumption (ISFC) with respect to the injection timings of the biodiesel was higher than that of the diesel fuel under all experimental conditions. The peak cylinder pressure and the peak heat release rate of the biodiesel were slightly lower, while the ignition delay was slightly longer under all operating conditions. In terms of emissions, the biodiesel had benefits in reduction of smoke, carbon monoxide (CO), hydrocarbon (HC) emissions especially with high fuel injection pressure. The nitrogen oxide (NO_x) emissions of the biodiesel were relatively higher than those of the diesel under all experimental conditions.