共查询到18条相似文献,搜索用时 265 毫秒
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对聚丙烯基紫外/红外双波长荧光防伪纤维进行高温处理,研究了处理温度及处理时间对双波长荧光纤维的表面形态、结晶性能、荧光性能和力学性能的影响。结果表明:经高温处理后,双波长荧光防伪纤维的表面形貌无显著变化;在120℃高温下对双波长荧光纤维处理≤48 h时,纤维的结晶度随处理时间的延长而逐渐增大;而当处理时间达到72 h时,纤维结晶度略有减小;随高温处理时间的延长或随处理温度的升高,双波长荧光纤维的荧光强度总体上呈现出不断下降之势;高温处理后荧光纤维力学性能有所下降,但会随着时间的延长而趋于稳定。 相似文献
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针对织物在加工、后处理以及服用过程中经常会遇到化学试剂作用的问题,研究了聚乳酸纤维在不同pH值、温度、时间等条件下的耐酸碱性。利用强力仪、扫描电镜(SEM)等测试仪器,测试分析了经酸碱液处理的聚乳酸纤维。结果表明:在影响聚乳酸纤维耐酸碱性的温度、时间和pH值三个因素中,pH值和温度起主要作用;热碱液对聚乳酸纤维强度影响很大,高温长时间的强酸性条件对纤维的损伤也较大;100℃、pH值为11、处理90 min时,纤维已失去纤维功能。从化学原理上分析了酸碱对聚乳酸纤维性能的影响,并从理论上解释了聚乳酸经酸碱水解的机制。 相似文献
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研究了热定形温度与时间对聚乳酸短纤维力学性能及卷曲性能的影响。研究结果表明:聚乳酸短纤维的热定形温度应不高于120℃;随着热定形时间的增加,聚乳酸短纤维的卷曲率、卷曲回复率都明显增大,而卷曲弹性率下降。 相似文献
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利用混杂原理,先将玄武岩纤维与聚乳酸纤维混合制成针刺毡,再与聚乳酸树脂复合,以提高树脂基体对增强体结构的渗透和结合性能。采用正交试验法,以混杂针刺毡中聚乳酸纤维含量、复合层压压力、复合层压温度为影响因素,讨论了混杂复合层压工艺对复合材料力学性能的影响。结果表明,采用混杂复合工艺有利于复合材料力学性能的改善,且混杂纤维含量在一定范围内时,复合材料的力学性能会随着混杂纤维含量的增加而线性增强,同时复合层压压力的增加也有利于复合材料力学性能的改善;采用混杂复合工艺时,复合层压温度对复合材料力学性能的影响规律不同于传统层压复合时复合层压温度对复合材料力学性能的影响,复合层压温度过高不利于复合材料力学性能的提高。 相似文献
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《纤维素科学与技术》2015,(3):36-42
研究人发角蛋白液改性高碘酸钠氧化棉织物的整理工艺,测试并分析人发角蛋白浓度、整理液p H、整理时间和整理温度对氧化棉织物力学性能和防紫外线性能的影响,并采用SEM和FT-IR分析表征了氧化棉织物经人发角蛋白液整理后的微观形貌和化学结构。结果表明,人发角蛋白整理能显著提高氧化棉织物的防紫外线性能,其力学性能也略有提高;整理后,人发角蛋白在纤维表面吸附成膜并与纤维发生共价交联反应。 相似文献
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《高科技纤维与应用》2015,(5)
采用生物酶催化接枝的方法处理PPTA纤维表面,运用正交实验方法探讨了最佳反应条件。对处理前后PPTA纤维进行了红外、X射线光电子能谱、扫描电镜、力学性能和拉曼表征。结果发现:改性后纤维表面出现了环氧官能团,表面碳元素物质分数明显降低,氧元素物质分数明显增加;改性后纤维表面粗糙度有了显著提高,纤维与环氧树脂间的界面剪切强度提高了34%,而纤维力学性能没有受到明显影响。其最佳反应条件为反应温度48℃、酶质量浓度0.01 mg/ml、单体质量分数5%、氧化剂质量浓度0.03 g/ml和p H值6.9。 相似文献
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Huihui Zhang Rong Wang Gesheng Yang Yuanyuan Xu Huili Shao 《Polymer Engineering and Science》2016,56(4):373-379
The UV‐excitable fluorescent poly(lactic acid) (PLA) fibers were spun by the traditional melt spinning process, and the effects of the fluorescent powder content (w(FP)) and draw ratio (DR) on the structure and properties of the fluorescent PLA fibers were investigated, respectively. The results showed that the emission spectra of fluorescent PLA fibers were peaked at 530 nm after UV excitation, indicating the PLA fibers would emit green light under UV light. With the increasing of w(FP), the relative fluorescence intensity of PLA fibers increased gradually, whereas more and larger protrusions were formed on the fiber surface due to the agglomeration of fluorescent powder, both the crystallinity and mechanical properties of fluorescent PLA fiber showed the decreasing trend with the increase of w(FP). With the increase of DR, the tensile strength of fluorescent PLA fibers increased gradually, whereas the relative fluorescence intensity of PLA fibers increased firstly and then decreased, and the highest fluorescence intensity was obtained when the DR was 3.6. In addition, the confocal laser scanning microscope can be used well to simulate the 3D distribution of fluorescent powder among the PLA fibers. POLYM. ENG. SCI., 56:373–379, 2016. © 2016 Society of Plastics Engineers 相似文献
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Biodegradable composites of poly(butylene succinate‐co‐butylene adipate) reinforced by poly(lactic acid) fibers
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Biodegradable composites of poly(butylene succinate‐co‐butylene adipate) (PBSA) reinforced by poly(lactic acid) (PLA) fibers were developed by hot compression and characterized by Scanning electron microscopy (SEM), differential scanning calorimetry (DSC), dynamic mechanical analyzer, and tensile testing. The results show that PBSA and PLA are immiscible, but their interface can be improved by processing conditions. In particular, their interface and the resulting mechanical properties strongly depend on processing temperature. When the temperature is below 120 °C, the bound between PBSA and PLA fiber is weak, which results in lower tensile modulus and strength. When the processing temperature is higher (greater than 160 °C), the relaxation of polymer chain destroyed the molecular orientation microstructure of the PLA fiber, which results in weakening mechanical properties of the fiber then weakening reinforcement function. Both tensile modulus and strength of the composites increased significantly, in particular for the materials reinforced by long fiber. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43530. 相似文献
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通过挤出共混、造粒、注射成型的方式制备了黄麻纤维填充聚乳酸(PLA)复合材料,研究了复合材料的力学性能以及黄麻与PLA之间的微观界面形貌。结果表明:黄麻的加入,并没有很好地改善黄麻/PLA复合材料的拉伸强度和弯曲强度;碱处理后的黄麻与PLA之间的界面性能有所改善;碱处理黄麻的加入,改善了黄麻/PLA复合材料的断裂伸长率与冲击韧性。 相似文献
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Different chemically modified (including treatments with alkali alone and a combination of alkali and silane coupling agent) corn fibers (CFs) have been used as reinforcements in polylactic acid (PLA) matrix to improve the mechanical and thermal properties of the CF/PLA composites. A comparative study has been made to find out how the two treatments affect the mechanical and thermal properties such as tensile, flexural, and impact strengths and glass transition temperature (Tg), crystallinity, and heat deflection temperature (HDT) of the CF/PLA composites. Scanning electron microscopy analyses have been conducted to evaluate the fiber–matrix adhesion. It has been observed that the treatment with a combination of alkali and silane is more efficient in strengthening fiber–matrix bonding, and thus more significantly improving the tensile and flexural strengths, crystallinity, Tg, and HDT of the CF/PLA composites than the treatment with alkali alone. However, alkali treatment produces the optimal impact strength. Mechanisms have been proposed to interpret the observed changes in mechanical and thermal properties as a result of fiber treatments. It is inferred that the surface treatment of CFs with a combination of alkali and silane may also be applied in other CF–polymer composite systems. POLYM. COMPOS., 37:3499–3507, 2016. © 2015 Society of Plastics Engineers 相似文献
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Flax fiber‐reinforced polylactic acid (PLA) biocomposites were made using a new technique incorporating an air‐laying nonwoven process. Flax and PLA fibers were blended and converted to fiber webs in the air‐laying process. Composite prepregs were then made from the fiber webs. The prepregs were finally converted to composites by compression molding. The relationship between the main process variables and the properties of the biocomposite was investigated. It was found that with increasing flax content, the mechanical properties increased. The maximum tensile strength of 80.3 MPa, flexural strength of 138.5 MPa, tensile modulus of 9.9 GPa and flexural modulus of 7.9 GPa were achieved. As the molding temperature and molding time increased, the mechanical properties decreased. The thermal and morphological properties of the biocomposites were also studied. The appropriate processing parameters for the biocomposites were established for different fiber contents. POLYM. COMPOS., 34:1611–1619, 2013. © 2013 Society of Plastics Engineers 相似文献
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Pierre Ovlaque MReza Foruzanmehr Saïd Elkoun Mathieu Robert 《Polymer Engineering and Science》2020,60(6):1377-1388
This study aimed at investigating the reinforcement effect of milkweed (MW) floss, a smooth and homogeneous natural fiber with a wide hollow lumen, on bio-based polymer composites. First, MW floss was thoroughly characterized in terms of morphology, surface roughness, and tensile and thermal resistance. Then, MW floss was compared to flax fibers, one of the most widely used natural fibers in the composite industry. Subsequently, bio-based composites made of polylactic acid (PLA) and 1 wt% MW floss were produced by injection molding and compared to composites reinforced with 1 wt% of flax fibers. Finally, thermal behavior, mechanical properties, and impact resistance of composites were determined. Results showed that MW floss, with respect to flax fibers, exhibits lower tensile modulus, ultimate tensile strength, surface roughness as well as a shorter critical length. Nonetheless, and despite the lower intrinsic properties of MW floss, UTS and impact resistance of MW/PLA composites were found to be 60% and 15% higher than those of Flax/PLA composites, respectively. In addition, micrographs of MW/PLA interface revealed a lack of adhesion in MW/PLA, which should be overcome by surface treatment in upcoming work. 相似文献
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以聚甲醛(POM)切片为原料,在200~210℃进行熔融纺丝制得POM长丝。利用DSC、Olympus偏光显微镜、单纱电子强力仪测定了POM纤维结晶度、熔点、取向度和纤维的机械性能;研究了后处理对POM纤维性能的影响以及拉伸对POM纤维耐酸碱性能的影响。结果表明:(1)POM纤维耐碱性良好,拉伸可以提高POM纤维结晶度、取向度、断裂强度以及耐酸性,但是使断裂伸长率减小;最佳拉伸温度在110℃左右,拉伸倍率在6~8之间。(2)热定形温度对POM纤维结晶度和熔点影响不大,延长热定形时间使POM结晶度、熔点降低;最佳热定形条件为在140℃下热定形4min。(3)经过拉伸热定形后的POM纤维的最大断裂强度和断裂伸长率分别为7.41cN/dtex和19.2%。 相似文献