共查询到20条相似文献,搜索用时 125 毫秒
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采用次氯酸钠、臭氧及芬顿试剂化学氧化法对焦化废水进行预处理,考察了3种药剂对焦化废水CODCr、氨氮的去除效果及废水可生化性的提高。结果表明,次氯酸钠氧化处理对焦化废水中氨氮的去除率较高,但对废水可生化性的提高不大;臭氧氧化处理对焦化废水中CODCr和氨氮的去除率均较低,但对废水的可生化性提高迅速,反应3 min后废水的可生化性即可由0.068提升到0.281;采用芬顿试剂氧化处理,在较佳条件下,废水的可生化性可达到0.445,但运行成本高。综合考虑,采用臭氧氧化预处理焦化废水更具优势。 相似文献
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医药废水是一种浓度高、可生化性差的难降解废水。本研究医药废水采用“混凝气浮+臭氧氧化+水解酸化”的强化预处理处理方式,有效地促进了生物处理单元对COD的去除,COD平均去除率为86.8%,其次为TN、TP,用以改善可生化性较差的废水进水条件;深度处理中臭氧氧化能够将经生物处理单元处理后废水中残余有机物氧化,结合“砂滤”和“活性炭吸附”单元可以强化系统对COD的去除效果;预处理、深度处理中臭氧投加量分别达到60 g/m3、70 g/m3时,系统处理效果良好。 相似文献
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为了解决电渗析技术处理垃圾渗滤液MBR产水过程中的膜污染问题,采用电絮凝和臭氧氧化2种预处理方式对MBR产水进行预处理,考察2种预处理方式对离子交换膜污染的控制效果。研究结果表明,经过电絮凝预处理后的废水COD和吸光度分别降低26.1%、 14.5%,经过臭氧氧化预处理后的废水COD和吸光度分别降低28.0%、 87.8%,电絮凝和臭氧氧化预处理使得膜电阻比没有经过预处理时分别下降了7.74%和52.87%,臭氧氧化预处理对电渗析过程中膜污染现象的预防效果优于电絮凝技术;采用pH值为11的NaOH溶液可以有效地恢复离子交换膜的性能,清洗后的膜电阻和脱盐效率均可以恢复到初始状态。 相似文献
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Martin R. Jekel 《臭氧:科学与工程》1994,16(1):55-66
There are numerous reports on coagulation/flocculation effects of preozonation, which cannot be interpreted by one single mechanism. About 7 basic processes are presently discussed. This paper presents results from drinking and wastewater treatment, indicating that preozonation effects can be explained with algae flocculation, with the destabilization of particles, and with polymerization of the dissolved organics. In view of the complexity of the systems, it is anticipated that several processes can be responsible, leading to an optimum ozone dosage. 相似文献
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To achieve effective COD removal, the combination of preozonation with biological treatment is necessary for phenolic wastewater treatments. Preozonation of 4-cresol, 2-chlorophenol and 4-nitrophenol solutions can be carried out with high ozone utilization rate using a new gas-inducing reactor. During the preozonation, the phenolic compounds can be completely decomposed with 100% ozone utilization rate. This new gas-inducing reactor is beneficial for the preozonation of phenolic solutions, comparing with a conventional gas-liquid reactor. The BOD5 of preozonized phenolic solution is strongly related to both the degree of decomposition of phenolic compounds and the accumulation of intermediate products in aqueous solution. Based on the high ozone utilization rate, it is suggested that the optimal utilized ozone dose for 4-cresol, 2-chlorophenol and 4-nitrophenol can be chosen as 360, 350 and 400 mg/L, respectively. At those optimal utilized ozone doses, the ratio of BOD5/COD of preozonized 4-cresol, 2-chlorophenol and 4-nitrophenol solutions increase to 0.33, 0.26 and 0.33, respectively. 相似文献
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Activated sludge biological oxidation of municipal wastewaters has been applied under different experimental conditions to observe the effect of preozonation on COD and process kinetics. In all cases, previous application of ozone allows significant improvement of COD level reduction during subsequent biological oxidation. Biomass concentration also exerts a positive influence on COD level reduction. Thus, 54 and 82% COD level reductions are achieved after biological oxidation without and with 30 minutes of preozonation. During the ozonation period, increase of pH from 2 to 9 leads to 15 to 24% COD level reductions, but biological oxidation should be followed at neutral pH since extreme conditions (pH 2 and 9) reduce considerably the biomass concentration and hence the yield of biodegradation. At the conditions investigated herein, there is an optimum ozone dose, 150 mg per liter of wastewater treated, that leads to the maximum COD level reduction in the combined process (chemical plus biological oxidation). Both single biological oxidation and combined with preozonation follows a Monod kinetic model assuming COD as the substrate of biomass. From kinetic results it is confirmed that a combination of chemical and biological oxidation leads to the highest maximum specific rates of COD consumption. 相似文献
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Results from precipitation of an oxygen/peroxide-bleachery effluent from pulp mills with and without preozonation are presented. Reductions in DOC levels by about 60% were achieved at the pH optimum of 5.5 at an AI/D0C ratio of 0.25 g/g. Increasing alum dosages did not improve the elimination. Ozonation at pH 2 reduced COD, DOC, UV and color levels, while under alkaline conditions an increase of color could be obtained. This effect, based on a polymerization of organics, could be improved at low ozone dosages, by reducing the ozone dosage rate, elevating the pH up to 11 and diluting the wastewater. However, the shift towards high and low molecular weight fractions indicated competing degradation reactions, which counteract a suggested improvement of precipitation by preozonation. 相似文献
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In order to evaluate the effect of preozonation on GAC adsorbability and biodegradability and to discuss the performance of BAC, three kinds of batch experiments have been conducted, using humic acid as the test substance. Conclusively, it is recognized that preozonation evidently improves the biodegradability of humic acid, but the equilibrium adsorption constant k, is not changed. However, the adsorption rate is greatly improved. Based on these results and continuous experiments, the characteristics of the removal mechanism of organics by a BAC filter and a GAC filter are compared. 相似文献
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Municipal wastewaters taken from a primary sedimentation tank were subjected to different chemical oxidation processes (ozonation or UV radiation alone or combined with hydrogen peroxide) to observe the evolution of COD and BOD/COD ratios. Ozonation of wastewater led to different increases of COD level reduction depending on pH and carbonate‐bicarbonate ion concentrations. Direct photolysis or hydrogen peroxide alone were found to be inappropriate technologies. On the other hand, advanced chemical oxidation, that is, oxidation with ozone or UV radiation combined with hydrogen peroxide, increased COD level reduction only when wastewater was previously decarbonated. Thus, elimination of carbonate‐bicarbonate ions, increase of pH and addition of hydrogen peroxide (10‐3 M) yield increases COD level reduction rates. Finally, preozonation also allows improvement of wastewater biodegradability. 相似文献
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Rocco A. Mastronardi George P. Fulton Michael Farrar Anthony G. Collins 《臭氧:科学与工程》1993,15(2):131-147
The benefits of preozonation before diatomaceous earth filtration have been demonstrated in a City of New York research program to develop design criteria for treatment of its 300 mgd Croton water supply. In the treatment of a supply where paniculate matter is predominantly of organic origin, preozonation provides two outstanding advantages that are not possible in diatomaceous earth filtration alone. 相似文献
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Phenolic solutions are difficult to treat with coagulation processes because phenol is well soluble in water. However, with suitable preozonation, the ozonized organic components can be removed more effectively by coagulation processes. In order to avoid excessive preozonation, a good control on the degree of preozonation is crucial for practical applications. The degree of preozonation of phenolic solution was evaluated by measuring the phenol decomposition rate, ADMI value and ozone outlet concentration during the ozonation. Three characteristic times were observed, namely (1) ADMI value reaches the peak value during preozonation, (2) the ozone outlet concentration starts increasing, and (3) the ADMI value reaches the discharge standard (500 value, EPA Taiwan). These characteristic times provide the useful means as real-time control parameters on the extent of preozonation. The results of HPLC and GPC show that phenol is almost completely decomposed after 43?min of preozonation. The major components after preozonation are oxalic acid and coupling compounds. The preozonized solution, containing phenol decomposition products, was then subjected to coagulation treatments. The coagulation behavior of preozonized solution is dependent on the extent of preozonation. Three types of coagulant were investigated, namely alum, ferric chloride (FeCl3) and poly aluminum chloride (PAC). Both PAC and FeCl3 are effective coagulants for COD removal. As an example, phenol solution (initial phenol concentration=300?mg/L, C O 3,i=20?mg/L) was preozonized for 50 minutes, followed by FeCl3 coagulation treatment. After preozonation and coagulation processes, the total COD and ADMI removal rates are as high as 70% and 80%, respectively. Most of the coupling compounds and oxalic acid are removed by the coagulant. 相似文献
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Ozone pretreatment studies of organic compounds that are difficult to biodegrade were conducted to evaluate the effects of ozonation on biodegradability of these compounds. Initial testing was conducted in batch activated sludge experiments with and without preozonation to evaluate the impacts of ozonation on the ultimate BOD/COD and ultimate BOD/TOC ratios of these compounds. Experimental results indicated wastewater preozonation to be an effective pretreatment step for some compounds, ineffective for other compounds and detrimental to biological treatment of still other compounds. These same compounds were then investigated in continuous flow, complete–mix activated sludge systems. Complete material balances, including influent, effluent, waste sludge and off–gas specific compound analyses, were conducted so that the actual fate of the compound could be determined. Removal mechanisms of the ozonated or unozonated compound were then determined to be biodegradation, stripping, or sorption to the biomass. Three compounds were investigated: acrylonitrile, 2,4 dinitrophenol, and 1,2 dichloropropane. 相似文献