R2R gravure and inkjet printed RF resonant tag

The fabrication of passive circuitry by gravure and inkjet printing is studied. A chipless inductively coupled RF resonant tag is analyzed as a test structure. A floating-bridge layout is employed to provide high yield when fabricated by roll-to-roll (R2R) printing. The conducting first layer and insulating second layer are R2R gravure printed with silver nanoparticle ink and a thermally cross-linkable dielectric ink, respectively. Above 10 MS/m conductivity is obtained for the first layer, which passes three times through the 5 m long drying unit at 5 m/min speed. The floating bridge is inkjet printed with silver nanoparticle ink and the prototype tag is measured over a reading distance of ca. 2 cm. An equivalent circuit model is presented and the model parameters are optimized to obtain a best fit to the measured frequency response. This indirect measurement provides an estimate of 4.3 μm for the thickness of the dielectric layer sandwiched between the conducting top and bottom layers. Application possibilities for the all-printed RF resonant tag are outlined.     

Contactless read-out of printed memory

Contactless read-out of inkjet printed programmable memory is demonstrated. The memory is arranged as a conducting comb pattern consisting of parallel lines adjacent to a common electrode. The information content of the memory is stored in memory bits, which modulate the electrical surface-area of the lines. The data is read-out capacitively by sweeping the tip of a printed circuit board over the memory. The memory bits were printed using silver nanoparticle ink and switched from an initial, high-resistance state to a low-resistance state using rapid electrical sintering, and furthermore, from the low-resistance state to an open-circuit state via fuse-like action. This read-out approach offers potential for low-cost memory applications as well as e.g. resistance-change sensors.     

Tuning the viscosity of halogen free bulk heterojunction inks for inkjet printed organic solar cells

For the solution processing of organic photovoltaics on an industrial scale, the exclusion of halogenated solvents is a necessity. However, the limited solubility of most semiconducting polymer/fullerene blends in non-halogenated solvents results in ink formulations with low viscosities which poses limitations to the use of roll-to-roll compatible deposition processes, such as inkjet printing. We propose to add polystyrene as a rheological modifier to increase the viscosity of bulk heterojunction (BHJ) non-halogenated inks. The printing and performance of P3HT/PCBM photoactive layer inks are characterized as a function of polystyrene concentration and three different molecular weights. Addition of 1 wt% polystyrene provided a near two-fold gain in viscosity, with the largest viscosity gains coming from the polymer with the highest molecular weight. However, this coincided with greater viscoelastic behavior, which reduced the jetting performance of the inks. Differences in solvent compatibility of the polystyrene/P3HT/PCBM ternary blend resulted in phase separation upon layer drying, whereby polystyrene segregated to the layer-air interface to form an isolated domain or network like topology. Nevertheless, a 1.7-fold increase in dynamic viscosity was obtained for devices with printed BHJ layers containing polystyrene at the expense of a 20% reduction in OPV performance. The improved viscosity and good printing behavior achieved with small additions of polystyrene demonstrates its potential to overcome the limited viscosity resulting from typical non-halogenated ink formulations for semiconducting polymers. These results offer a step forward to the industrialization of inkjet printing as an effective deposition technique for functional layers of organic electronics.     

Utilizing inkjet printing to fabricate electrical interconnections in a system-in-package

The printed interconnections for encapsulated electronic packages using nanoparticle metal inks and polymer dielectrics have been demonstrated. The printing has utilized a digital printing method, inkjet printing. The printing process has been adopted rather well, but process yield improvement required more attention to the control of individual manufacturing stages and error sources. The sources for possible errors can be roughly divided into separate groups: the substrate-ink interaction and treatment procedure related, ink jetting related, and moving stage related. In this paper, the individual stages were taken under consideration. The process performance was studied using statistical methods. The affecting factors were classified, and designed experiments were carried out to determine the most significant factors and to create a model to describe the behavior. According to the models, optimized process parameters were achieved, and implemented in practice.     

高精度数码喷墨打印技术及在印刷电子上的应用

文章介绍了高精度数码喷墨打印技术的设备,材料和打印工艺及其在印刷电子上的应用。重点介绍了纳米银墨水的结构、性能、烧结条件和电性能以及打印性能及其在制备导电线路上的应用,探讨了喷头孔径及基材的表面性能对打印线路的影响。最后,介绍了挠性PCB的打印。     

Inkjet printed thin and uniform dielectrics for capacitors and organic thin film transistors enabled by the coffee ring effect

The deposition of a thin and uniform dielectric layer is required for high performance printed capacitors and thin film transistors (TFTs), however this is difficult to achieve with printing methods. We have demonstrated inkjet-printed dielectrics with a uniform thickness from 70 nm to 200 nm by taking advantage of the coffee ring effect. A high capacitance per unit area of 230 pF/mm² is achieved from capacitors with linear morphologies fully printed onto flexible substrates. We also demonstrate organic TFTs with an average mobility of 0.86 cm²/Vs and a source drain current of 57 μA obtained with a supply voltage of 15 V. This performance was shown to be consistent, with a standard deviation of 15% obtained from hundreds of printed organic TFTs on PET substrates. This consistency was further validated by the production of functional NAND, NOR, AND and OR logic gates. Our results demonstrate that the coffee ring effect, which is usually viewed as undesirable, can enable higher performance in printed electronic devices.     

Direct writing of inkjet-printed short channel organic thin film transistors

A direct-writing fabrication process for fully inkjet-printed short-channel organic thin-film transistors (OTFTs) has been developed. Channels as narrow as 800 nm between two printed Ag electrodes were achieved by printing a special Ag ink on an SU-8 interlayer, which can be partially dissolved by the solvents used in the Ag ink. The ridge formed along the printed Ag line edges due to redistribution of the interlayer material during the drying process limits the ink spread, and separates neighboring printed lines, and is the key to defining an ultra-narrow channel for transistor fabrication. The short-channel OTFTs fabricated using this technique have demonstrated well-defined linear and saturation regimes. An extracted mobility of 0.27 cm²/Vs with an on/off ratio of 10⁵ was obtained at a driving voltage of −12 V. The excellent performance of these devices demonstrates the potential of this technique in fabrication of short-channel devices using standard printing technologies.     

Environmental protection of inkjet-printed Ag conductors

Electrically conductive silver nanoparticle ink patterns were fabricated using the inkjet printing method. Two different polymer films were used as the substrate materials. The patterns were exposed to humidity and salt fog and the electrical performance (sheet resistance and RF performance) as well as mechanical endurance (adhesion) were measured before and after the environmental tests. The electrical properties of the printed structures remained good in all the measurable samples. The adhesion between the ink and a substrate material appeared to be a greater challenge in harsh environments. Protection capabilities of one dip coated and one hot laminated barrier materials were evaluated during the environmental tests. The results showed that there is a need for environmental protection in printed electronics. Especially the laminated barrier films can offer a potential solution for shielding printed electronics in harsh environments as they can provide good mechanical protection, and can easily be integrated in roll-to-roll process.     

Inkjet printed System-in-Package design and manufacturing

Additive manufacturing technology using inkjet offers several improvements to electronics manufacturing compared to current non-additive masking technologies. Manufacturing processes can be made more efficient, straightforward and flexible compared to subtractive masking processes, several time-consuming and expensive steps can be omitted. Due to the additive process, material loss is minimal, because material is never removed as with etching processes. The amounts of used material and waste are smaller, which is advantageous in both productivity and environmental means. Furthermore, the additive inkjet manufacturing process is flexible allowing fast prototyping, easy design changes and personalization of products. Additive inkjet processing offers new possibilities to electronics integration, by enabling direct writing on various surfaces, and component interconnection without a specific substrate. The design and manufacturing of inkjet printed modules differs notably from the traditional way to manufacture electronics. In this study a multilayer inkjet interconnection process to integrate functional systems was demonstrated, and the issues regarding the design and manufacturing were considered.     

The design challenge in printing devices and circuits: Influence of the orientation of print patterns in inkjet-printed electronics

We present a morphological and electrical analysis of inkjet-printed two-dimensional films of silver nanoparticle inks arranged at different orientation to the raster-scan-based printing process. Different parameters causing morphological and functional irregularities in the inkjet-deposited films as a function of their orientation to the printing process are introduced in detail and the relevance for the field of printed electronics is discussed. Researchers have demonstrated the manufacturing of various microelectronic devices using inkjet printing. Nearly all of the devices are based on simple rectilinear geometries. Usually, these geometries have a preferential orientation that is exactly (i) along the deposition process or exactly (ii) perpendicular to the deposition process. So far, it was assumed that the geometrical and functional characteristics are identically for the both cases. However, we show empirically that this is not the case and help to understand the conditions that lead to the differences.     

Inkjet printed micropump actuator based on piezoelectric polymers: Device performance and morphology studies

All inkjet printed piezoelectric actuators based on poly(vinylidene fluoride-co-trifluoroethylene) (P(VDF–TrFE)) for applications as pump actuators in microfluidic lab-on-a-chip systems (LOC) are manufactured and investigated in terms of their morphology and actuator performance. Furthermore, a pump demonstrator with an all-printed P(VDF–TrFE) actuator is characterized here for the first time. The actuators are manufactured in a fully additive and flexible way by successive inkjet printing of a P(VDF–TrFE) film sandwiched between two silver electrodes on a polyethylene terephthalate (PET) substrate. Different from most current micropumps where actuator elements are fabricated separately, no additional joining step is required in the manufacturing approach employed here. Actuator performance is investigated by measurements of piezoelectric d₃₁ coefficients as well as remanent polarization P_rem for different thermal treatments of the as-printed P(VDF–TrFE) films. A strong dependence of the device performance on the annealing temperature is found with maximum values for d₃₁ and P_rem of approximately 10 pm V⁻¹ and 5.8 μC cm⁻², respectively. Morphology investigations of the printed films by differential scanning calorimetry (DSC), X-ray diffraction (XRD) and Atomic Force Microscopy (AFM) indicate an increased degree of crystallinity of the piezoelectric β-phase for samples annealed at temperatures above 110 °C, which coincides with improved device performance. A basic pumping function with pump rates of up to 130 μL min⁻¹ is demonstrated, which is promising for future applications in LOC. Furthermore, the process chain and characterization presented here can be employed to design and manufacture also other P(VDF–TrFE)-based devices and allows the combination with additional printed on-chip functionalities in future LOC.     

Fully printed electronics on flexible substrates: High gain amplifiers and DAC

We propose a novel simple Fully-Additive printing process, involving only depositions, for realizing printed electronics circuits/systems on flexible plastic films. This process is Green (non-corrosive chemicals), On-Demand (quick-to-print), Scalable (large-format printing) and Low-Cost vis-à-vis Subtractive printing, a complex deposition-cum-etching process that otherwise requires expensive/sophisticated specialized IC-like facilities and is Un-Green, Not-On-Demand, Un-scalable and High-Cost. The proposed Fully-Additive process features printed transistors with high (∼1.5 cm²/Vs) semiconductor carrier-mobility, ∼3× higher than competing state-of-the-art Fully-Additive processes and comparable to Subtractive processes. Furthermore, passive elements including capacitors, resistors, and inductors, and two metal-interconnect layers are likewise Fully-Additive printed–to our knowledge, to-date the only Fully-Additive process capable of realizing complex circuits/systems on flexible plastic films.Several analog and mixed-signal circuits are demonstrated, including proposed and conventional differential amplifiers, and a charge-redistribution 4-bit digital-to-analog converter (DAC). The proposed amplifier embodies a novel positive-cum-negative feedback to simultaneously significantly improve the gain and reduce susceptibility to process variations. To improve the speed and reduce the area of the DAC, the parasitic capacitors therein are exploited. The Fully-Additive proposed amplifier and DAC are benchmarked against reported realizations (all Subtractive-based processes), and are shown to be highly competitive despite its realization based on the simple low-cost proposed Fully-Additive process.     

Up-scaling of the manufacturing of all-inkjet-printed organic thin-film transistors: Device performance and manufacturing yield of transistor arrays

All-inkjet-printed thin-film transistors (TFTs) have been demonstrated in literature using mainly laboratory inkjet equipment, simple one-channel layout and only a low number of manufactured TFT devices. We report on the development and the up-scaling of the manufacturing of all-inkjet-printed TFT arrays using industrial inkjet equipment. The manufacturing of the TFTs was carried out in ambient condition without the need for cleanroom environments or inert atmospheres and at a maximum temperature of 150 °C enabling the use of flexible polymer films as substrate. Arrays of 924 TFTs were manufactured on an area of about DIN A4 (297 × 420 mm²). This allows the consideration of statistics, e.g. to determine the process yield as a function of device design and layout. We present process yields for all-inkjet-printed TTFs up to 82% demonstrating the potential of the developed all-inkjet-printing process.     

中国印刷电子产业现状与前景展望

介绍了印刷电子的基本定义,印刷电子所涉及的产业领域,以及国外对印刷电子技术的研发投入情况。重点介绍了国内自2009年以来印刷电子的发展情况,特别是产业技术开发情况。分析了中国发展印刷电子产业的优势,并对未来印刷电子对中国一些产业领域的影响做了预测。     

Integration of a graphene ink as gate electrode for printed organic complementary thin-film transistors

We demonstrate a new electrode gate based on graphene ink for complementary printed organic metal oxide semiconductor (CMOS) technology on flexible plastic substrates. The goal is to replace the standard silver electrode gate. Devices made with graphene were enhanced and showed a high field-effect mobility of 3 cm² V⁻¹ s⁻¹ for P-type and 0.9 cm² V⁻¹ s⁻¹ for the N-type semiconductors. The improvement is attributed to the increase of the electrical capacitance of the organic dielectric (CYTOP) due to the graphene layer. A seven-stage ring oscillator was made with high oscillation frequencies of 2.1 kHz at 40 V corresponding to a delay/gate value of 34 μs. These performances are promising for use of low cost printed electronic applications.     

Significant effect of the molecular formula in silver nanoparticle ink to the characteristics of fully gravure-printed carbon nanotube thin-film transistors on flexible polymer substrate

Single-walled carbon nanotubes (SWNTs) are a valuable material for use in not only nanoelectronics but also printed electronics because of their stability, tunable operation speed, and scalability. However, the device characteristics of fully printed, SWNT-based thin film transistors (SWNT-TFTs) often have large variations, and the fundamental cause of these inconsistencies are not yet well understood. Therefore, fully printed SWNT-TFT-based electronic devices have not been practically realized in the market. In this study, the significant variation in the electrical parameters of printed SWNT-TFTs that is caused by minor molecular variations in the formulation of silver nanoparticle-based ink is reported. Strikingly, a very small difference in the chemical structure between ethylene glycol and diethylene glycol in the silver nanoparticle-based ink, which is used to print drain-source electrodes in the SWNT-TFTs, with everything else identical, induced a difference of approximately 70 meV in the barrier height between the drain-source electrodes and the SWNT layer at 300 K. The modification of the absorbed polymer binder in the silver nanoparticle ink due to the additive is the major cause of the observed barrier height difference. These results allow for a better understanding of the relationship between the ink rheology at the molecular level and the printed device properties, and enable a more precise design and control of device properties which will have profound impacts on printed electronic devices.     

In-plane conduction characterisation and charge transport model of DMSO co-doped,inkjet printed Poly(3,4-ethylenedioxythiophene): Polystyrene sulfonate (PEDOT:PSS)

The technologically important inkjet printed poly(3,4-ethylenedioxythiophene): polystyrene sulfonate (PEDOT:PSS) films, at different extents of co-doping with dimethyl sulfoxide DMSO, have been studied in terms of in-plane charge transport and electric field force microscopy (EFM). Similarly to past studies of spin coated PEDOT:PSS films, room temperature conductivity is enhanced by a factor of 10³ to 130 S cm⁻¹ on the addition of 5% DMSO, Hall probe analysis demonstrated a decrease in contact resistance from 10⁶ Ω to 10⁴ Ω whilst variable-temperature conductivity analysis shows an increase in the VRH exponent from 0.25 to 0.5 signifying a charge transport evolution from Mott Variable Range Hopping in 3-dimensions to a pseudo 1-dimensional Variable Range Hopping. In addition, electric field force microscopy (EFM) showed a corresponding threefold increase in PEDOT grain size. Further analysis was conducted to determine the hopping length and the ratio of the hopping length versus localization length in the electron transport model.     

松下MicroP2存储卡和摄像机高低码流记录的应用实践

本文就电视新闻采访中使用的P2格式高清摄像机存储卡的安全性问题提出有一定参考价值的建议,并结合松下公司最新推出的 MicroP2存储卡在实际应用当中的体会与读者交流分享。     

Stable fully-printed polymer resistive read-only memory and its operation in mobile readout system

The read-only memory (ROM) is a key component for a wide range of printed electronics applications. The resistive type ROM based on conductive polymer poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonate) (PEDOT: PSS) would be a promising technology of choice, which can be “manufactured-on-demand” via digital printing for high throughput and material saving. However, the instability issues associated with the conventional PEDOT: PSS and its interface with contact electrodes would be a critical hurdle preventing the technology from practical applications. This work proves that, by removing the hydrophilic acidic groups in conventional PEDOT: PSS, these instability issues can be well addressed. The ROM tags fabricated based on the modified PEDOT: PSS of neutral pH and inkjet printed silver electrodes present extremely stable performance under both aging and electrical stress tests in air ambient. A self-designed memory readout circuit board, communicating with mobile phone through near field communication, is also implemented to demonstrate the feasibility of using the ROM tags in real mobile systems. It is shown that, without any encapsulation, the ROMs can have stable output under high humidity condition (>60% RH), after either being stored in the ambient condition for 30 days or being operated after 20000 reading cycles.     

A comparative assessment of surface microstructure and electrical conductivity dependence on co-solvent addition in spin coated and inkjet printed poly(3,4-ethylenedioxythiophene):polystyrene sulphonate (PEDOT:PSS)

This study focuses on the fabrication of poly(3,4-ethylenedioxythiophene):polystyrene sulphonate (PEDOT:PSS) thin films by inkjet printing and investigates the developed surface morphology and electrical conductivity of the printed films as a function of the concentration of dimethyl sulfoxide (DMSO), added as conduction enhancing co-solvent, and Surfynol, added as a surfactant. The printed films are compared with PEDOT:PSS films fabricated by the traditional spin coating technique. Measurements of the surface tension justify including surfactant as a processing additive, where addition of 1% Surfynol results in substantial decrease of the surface tension of the PEDOT:PSS solution, whilst it also increases film surface roughness by an order of magnitude for both fabrication methods. The addition of 5 wt% DMSO is shown to result in a 10³ decrease in sheet resistance for both spin coated and inkjet printed films with both processing routes demonstrating decrease in surface roughness and coarsening of PEDOT grains as a function of the co-solvent concentration, whilst X-ray photon spectroscopy showed an increase in the surface PEDOT to PSS ratio from 0.4 to 0.5. Inkjet printed films have lower sheet resistance than the corresponding spin coated films, whilst atomic force microscopy reveals a coarser surface morphology for the inkjet printed films. The findings in this work point out at the decrease of sheet resistance due to coarsening of PEDOT grains which is linked to a decrease of surface roughness for small RMS values associated with the PEDOT grains. However, the higher surface roughness generated when Surfynol surfactant was added was not detrimental to the film’s in-plane conductivity due to the fact that these higher roughness values were unrelated to the PEDOT grains.