Tribological performance of carbon nanotube–graphene oxide hybrid/epoxy composites

An investigation is conducted on the effect of the hybrid of multi-wall carbon nanotubes (MWCNTs) and graphene oxide (GO) nanosheets on the tribological performance of epoxy composites at low GO weight fractions of 0.05–0.5 phr. The MWCNT amount is kept constant at 0.5 phr, which is typical for CNT/epoxy composites with enhanced mechanical properties. Friction and wear tests against smooth steel show that the introduction of 0.5 phr MWCNTs into the epoxy matrix increases the friction coefficient and decreases the specific wear rate. When testing the tribological performance of MWCNT/GO hybrids, it is shown that at a high GO amount of 0.5 phr, the friction coefficient is decreased below that of the neat matrix whereas the wear rate is increased above that of the neat matrix. At an optimal hybrid formulation, i.e., 0.5 phr MWCNTs and 0.1 phr GO, a further increase in the friction coefficient and a further reduction in the specific wear rate are observed. The specific wear rate is reduced by about 40% down to a factor of 11 relative to the neat epoxy when the GO content is 0.1 phr.     

Construction of amorphous carbon-coated alpha-Fe2O3 core–shell nanostructure for efficient photocatalytic performance

Journal of Materials Science: Materials in Electronics - Hetero-structured semiconductor composite as an ideal multifunctional photocatalyst has significant advantage for the improvement of...     

3D-assembled graphene–LiFePO4 frameworks with enhanced electrochemical performance

In the on-going development of power sources and energy-storage devices, achieving both high power and large energy capacity with a high discharge rate is still a great challenge. In this paper, three dimension assembled graphene–LiFePO₄ (G–LFP) composites were prepared by one-step hydrothermal method. LiFePO₄ (LFP) particles became smaller and were dispersed uniformly on the graphene sheets after compositing with graphene. Compared to the pristine LFP, the electrochemical properties of the G–LFP are greatly improved, especially the rate capability and the cyclic performance. At 10 C, the G–LFP holds nearly 80 % of the initial capacity and has a flat voltage platform, while for the LFP, its capacity drops down to 65 % and its voltage platform is not noticeable. After 600 cycles at 10 C, the specific capacity of the G–LFP decreases from 135 to 125 mA hg^?1 with a capacity loss of 5.1 %, while it drops from 105  to 86  mA hg^?1 with a capacity loss of 30 % for the LFP. The reason for the improvement of the electrochemical performances could be ascribed to the introduction of graphene which enhances the conductivity and diminishes the LFP size which improves the diffusion of lithium ions.     

Microwave-assisted synthesis of high efficient α-Fe2O3/BiOI composites and its performance in photocatalytic degardation of organic pollutants

Herein, we prepare novel composites of α-Fe₂O₃/BiOI photocatalysts by one step microwave hydrothermal process. The SEM and TEM characterization results suggest microsphere shaped of BiOI with α-Fe₂O₃ nanoparticles decorated on the surface of BiOI nanosheets. According to the results of UV-vis DRS measurements, α-Fe₂O₃/BiOI exhibited more visible light adsorption. The composite exhibited the highest photoactivity for decomposition of methyl orange (MO) and antibiotics tetracycline (Tc) superior to that of the pure α-Fe₂O₃ and BiOI in the visible light. The degradation rate constant is 2.3 times and 2.0 times higher than that of pure BiOI and α-Fe₂O₃ under the same conditions for degradation MO and Tc respectively. The photodegradation performances of α-Fe₂O₃/BiOI composites were also investigated under different light sources irradiation. Based on the analysis results of radical capture experiment, the enhanced photocatalytic efficiency of α-Fe₂O₃/BiOI photocatalyst can be mainly indentified to be the dominant active species of hole (h⁺) and superoxide radical(O₂⁻).     

Improved mechanical properties of magnesium–graphene composites with copper–graphene hybrids

New magnesium nanocomposites reinforced with copper–graphene nanoplatelet hybrid particles have been prepared through the semipowder metallurgy method. Compared with the monolithic Mg, the Mg–1Cu–xGNPs nanocomposites exhibited higher tensile and compressive strength. In tension, nanocomposites revealed substantial enhancement in elastic modulus, 0.2% yield strength, ultimate tensile strength and failure strain (up to +89, +117, +58 and +96% respectively) compared to monolithic Mg. In compression, the nanocomposites showed the greatest improvement in 0.2% yield strength, and the ultimate compressive strength and failure strain (%) (up to +34, +59 and +61% respectively), whilst the compressive elastic modulus first increases and then decreases with an increase in the graphene nanoplatelets (GNPs) contents. The enhanced strength of the composites is likely to result from strengthening mechanisms invoked by the addition of Cu–GNPs hybrids.     

Reduced graphene oxide–nickel oxide composites with high electrochemical capacitive performance

Reduced graphene oxide (RGO)–NiO composites have been fabricated by a simple solvothermal route starting with graphite oxide (GO). The morphology, composition and microstructure of the as-obtained samples are systematically characterized by thermogravimetric (TG) analysis, X-ray diffraction (XRD), and field emission scanning electron microscopy (FESEM). Moreover, the electrochemical performances of composites were evaluated by cyclic voltammogram (CV) and galvanostatic charge–discharge. Interestingly, it was found that the electrochemical performance of the composites could be affected by the mass ratio between RGO and NiO. The composite with the mass ratio up to 79:21 (NiO:RGO) exhibits the highest specific capacitance of 576 F g⁻¹ at 1 A g⁻¹, which is much higher than that of pure NiO (240 F g⁻¹) and pure RGO (98 F g⁻¹). In addition, the cycling measurements showed that RGO–NiO composite exhibited excellent cycling stability with no decay in the available capacity over 1100 cycles. The enhancement in specific capacitance and cycling stability may be attributed to the increased electrode conductivity owing to RGO network, the increased effective interfacial area between NiO and the electrolyte, as well as the contact area between NiO and RGO.     

Preparation,characterization and photocatalytic activity of Bi2O3–MgO composites

A series of Bi₂O₃–MgO composites were synthesized by solvent-thermal method. It was found that the Bi₂O₃–MgO composites perform much better than TiO₂ (P25), Bi₂O₃ and MgO in the photocatalytic degradation of rhodamine B (RhB) in the presence of HCl and under irradiation of visible light (λ > 400 nm). The effects of Bi/Mg molar ratio, crystallization temperature of Bi₂O₃–MgO and reaction conditions on photocatalytic activity were studied. The best performance was observed over the composite with Bi:Mg molar ratio equal to 2:1 that had been subject to crystallization at 120 °C for 20 h. In addition, the photocatalytic efficiency of the composite can be significantly enhanced by the presence of hydrochloric acid. The prepared samples were characterized by XRD and UV–vis DRS techniques. The relationships between the structure and photocatalytic performance of the as-prepared Bi₂O₃–MgO samples were also investigated.     

Hydrothermal synthesis of graphene–CdS composites with improved photoelectric characteristics

Natural flake graphite was used as raw materials to prepare graphite oxide and further treated with ultrasonic oscillation to get graphene oxide. Graphene–CdS composites were prepared by one step hydrothermal synthesis, using cadmium acetate as Cd precursors, sulfourea as S precursors and graphene oxide as support. Graphene–CdS composites were characterized by X-ray diffraction and scanning electron microscopy for the structure and morphology of the composites, and further investigated by transient photocurrent response and cyclic voltammetry. Improved photoelectric characteristics can be obtained over graphene–CdS composites than that of pure CdS nanoparticles due to electron capture and transfer ability of graphene resulting in a more efficient separation of the photoexcited charge carriers from graphene–CdS composites.     

One-step synthesis of mesoporous silica–graphene composites by simultaneous hydrothermal coupling and reduction of graphene oxide

Silica–graphene oxide composites were synthesized by hydrothermal method with simultaneous functionalization and reduction of graphene oxide (GO) in the presence of mesoporous silica. Two types of silica were used in the study, mesoporous synthetic silica (MSU-F) synthesized by sol-gel method and mesoporous mineral silica (meso-celite) from pseudomorphic synthesis. The infrared spectra of the composites showed the disappearance of the carboxyl peak at 1735 cm^-1 which could be due to the reduction of the –COOH group. The enhancement of the band at 1385 cm^–1 is attributed to the vibration of the Si–O–C=O moiety formed by reaction of the –COOH group of GO and the silanol (Si–OH) of silica. The Raman spectra of the composites show a diminished intensity ratio of D to G band indicating that GO was reduced to graphene sheets. The TEM images demonstrate the coupling of silica to GO surface revealing dense loading of silica on GO in planar structure.     

ZnGaNO solid solution–C3N4 composite for improved visible light photocatalytic performance

ZnGaNO solid solution–C₃N₄ composite photocatalyst with visible light response was synthesized through polymerization of melamine in the presence of ZnGaNO solid solution. The composite photocatalyst was characterized by X-ray diffraction, high-resolution transmission electron microscopy (HRTEM), Fourier transform infrared (FT-IR) spectroscopy, UV–vis diffuse reflection spectroscopy, X-ray photoelectron spectroscopy (XPS), Energy dispersed spectrometer (EDS) and BET surface area measurements. The activity of composite photocatalyst g-C₃N₄–ZnGaNO for photodegradation of methyl orange (MO) is higher than that of either single-phase g-C₃N₄ or ZnGaNO solid solution. The as-prepared composite photocatalyst exhibits an improved photocatalytic activity due to enhancement of electron–hole separations at the interface.     

Magnesia supported Au and Ag catalysts for the preparation of few-layer graphene–metal nanocomposites: relationship between catalyst structure and the properties of graphene composites

Magnesia supported Au, Ag, and Au–Ag nanostructured catalysts were prepared, characterized, and used to synthesize few-layer graphene–metal nanoparticle (Gr–MeNP) composites. The catalysts have a mezoporous structure and a mixture of MgO and MgO·H₂O as support. The gold nanoparticles (AuNPs) are uniformly dispersed on the surface of the Au/MgO catalysts, and have a uniform round shape with a medium size of ~8 nm. On the other hand, the silver nanoparticles (AgNPs) present on the Ag/MgO catalyst have an irregular shape, larger diameters, and less uniform dispersion. The Au–Ag/MgO catalyst contains large Au–Ag bimetallic particles of ~20–30 nm surrounded by small (5 nm) AuNPs. Following the RF-CCVD process and the dissolution of the magnesia support, relative large, few-layer, wrinkled graphene sheets decorated with metal nanoparticles (MeNPs) are observed. Graphene–gold (Gr–Au) and graphene–silver (Gr–Ag) composites had 4–7 graphitic layers with a relatively large area and similar crystallinity for samples prepared in similar experimental conditions. Graphene–gold–silver composites (Gr–Au–Ag) presented graphitic rectangles with round, bent edges, higher crystallinity, and a higher number of layers (8–14). The MeNPs are encased in the graphitic layers of all the different samples. Their size, shape, and distribution depend on the nature of the catalyst. The AuNPs were uniformly distributed, had a size of about 15 nm, and a round shape similar to those from Au/MgO catalyst. In Gr–Ag, the AgNPs have a round shape, very different from that of the Ag/MgO catalyst, large size distribution and are not uniformly distributed on the surface. Agglomerations of AgNPs together with large areas of pristine few-layer graphene were observed. In Gr–Au–Ag composites, almost exclusively large bimetallic particles of about 25–30 nm, situated at the edge of graphene rectangles have been found.     

Construction of visible-light-driven ZnBi2O4/Ag2WO4 p–n heterojunction for restraining carrier recombination and improving visible-light photocatalytic performance

Journal of Materials Science: Materials in Electronics - In recent years, spinel materials have been extensively studied by scholars due to their excellent optical response properties. In this...     

Microstructural characterization of electroconductive Si3N4–TiN composites

Electroconductive Si₃N₄–TiN composites from Si and TiN powders have been fabricated by in situ reaction-bonding and post-sintering under N₂ atomosphere. The values of fracture strength and electrical resistivity in the Si₃N₄–50 wt.% TiN composite were 531 MPa and 2.5×10⁻² Ω cm, respectively. The dispersion of TiN particles inhibited the abnormal growth of rod-like Si₃N₄ grains with large size in diameter. An amorphous phase observed in most grain boundaries and triple points is attributed to liquid phase sintering. Many dislocations formed by the difference of thermal expansion coefficients were observed in Si₃N₄ and TiN grains.     

Forming performance and biodegradability of woodfibre–Biopol™ composites

A Taguchi approach to experimental design has been used to analyse the hotpressing and vee-bending of woodfibre–Biopol™ composites. Analysis of the hotpressing process clearly shows that platen temperature is the parameter with the most influence on tensile performance of the composite sheet produced. In bending (a common manufacturing situation), geometric conformance is maximised when forming time is 60 s, forming rate is 250 mm/min and forming radius/thickness ratio is 2 for the composite sheets studied in this paper. A study of the influence of fibre volume fraction on the biodegradability of these sheets show that these composites are highly biodegradable, often degrading at a rate greater than that of pure Biopol™. The results also suggest that a woodfibre mass fraction of ∼15% maximises the degradation of the woodfibre–Biopol™ composites.     

Effect of processing routes on mechanical and thermal properties of copper–graphene composites

In this paper, copper–graphene composites were fabricated by using two different processing routes (ball milling (BM) and ultrasonication) followed by spark plasma sintering. Vickers hardness and anisotropic thermal conductivity of the composites were measured and observed that ultrasonicated fabricated composites gave better result compared with BM composite and even from pure copper. The hardness values obtained for ultrasonicated copper–graphene composite were 69?HV (57% higher) and thermal conductivity 387?W/m?K (13% higher) by using only 0.5?wt-% of graphene, while for pure copper the values were 44?HV and 341?W/m?K. The value of anisotropic thermal conductivity ultrasonicated composites was also 1.97 which is much higher than pure copper 0.94.     

Synergistic photocatalytic removal of organic pollutants in the aqueous medium using TiO2–Co3O4 decorated graphene oxide nanocomposite

Journal of Materials Science: Materials in Electronics - Organic pollutants generated from different industrial sources cause soil and water pollutions, which creates an ecological imbalance. Metal...     

Classical estimates of the effective thermoelastic properties of copper–graphene composites

Significant research effort is concentrated worldwide on development of graphene-based metal-matrix composites with enhanced thermomechanical properties. In this work, we apply two classical micromechanical mean-field theories to estimate the effective thermoelastic properties that can be achieved in practice for a copper–graphene composite. In the modelling, graphene is treated as an anisotropic material, and the effect of its out-of-plane properties, which are less recognized than the in-plane properties, is studied in detail. To address the severe difficulties in processing of graphene-based metal-matrix composites, the copper–graphene composite is here assumed to additionally contain, due to imperfect processing, particles of graphite and voids. It is shown quantitatively that the related imperfections may significantly reduce the expected enhancement of the effective properties. The present predictions are also compared to the experimental data available in the literature.