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1.
Plasma surface treatment has been extensively applied in the textile industry for the modification of polymer materials. In this study low‐temperature plasma (LTP) is used for surface treatment of polyamide/polyurethane (PA/PU) knitted fabric. The envisaged plasma effect is an increase in the surface energy of the treated textile, leading toward improved hydrophilic properties. The knitted fabric was treated by LTP using three non polymerizing gases: oxygen, air, and carbon dioxide. After plasma treatment, wettability of samples was tested through their wicking properties measuring capillary rise after water bath contact. The PA/PU knitted fabric samples treated with different plasma gases exhibited different hydrophilic performances. The influence of plasma variables (discharge power, time, pressure) was investigated. Although the chemical characteristics of elastan (PU) and nylon (PA) threads are different, the study has demonstrated that plasma treatment can in the same time alter the surface‐wetting behavior of both the components of the knitted fabric. It was also shown how these treatments can be regulated to produce the desired level of hydrophilicity dependently on the request application. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2008 相似文献
2.
Fernando Ribeiro Oliveira Marta Fernandes Noémia Carneiro António Pedro Souto 《应用聚合物科学杂志》2013,128(5):2638-2647
The use of microcapsules has increased in several different areas, namely, textile applications. They have been used as a possible means of introducing new properties, namely, in medical care by antibiotics, skin moisturizers, and other drugs and for thermal comfort. In this study, we examined the influence of dielectric barrier discharge (DBD) plasma treatment on the adhesion of phase‐change material (PCM) microcapsules on wool fabric. Several experimental techniques were used to evaluate the wool surface modification after plasma treatment and the influence of the microcapsules' resistance to washing conditions, namely, the determination of the static and dynamic contact angles, surface energy, and adhesion work; X‐ray photoelectron spectroscopy; Fourier transform infrared spectroscopy; differential scanning calorimetry; and scanning electron microscopy. Chemical and physical characterization of the wool fiber in the fabric confirmed significant surface modification. The plasma treatment greatly increased the hydrophilicity, surface energy, and adhesion work of the wool fabric; this proved that more microcapsules were adsorbed on the fabric and more microcapsules remained on the fabric surface after the washing procedures. © 2012 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
3.
The influence of processing parameters on wettability improvement and its uniformity of wool fabric treated by atmospheric pressure plasma jet (APPJ) was explored. A woven wool fabric was treated by APPJ under various treatment conditions such as different treatment time, different oxygen flow rate, and different jet‐to‐substrate distance. The water absorption time of wool fabric was measured to determine wettability improvement. The diffusion photo of water droplet on wool fabric surface was taken by digital camera to reflect wettability uniformity. After APPJ treatment, SEM observation showed that the scales on the wool fiber surface directly facing plasma jet pores were destroyed than those on the other fiber surface. XPS analysis showed that the carbon concentration substantially decreased. The concentration of oxygen and nitrogen significantly increased and but the concentration of sulfur and silicon did not obviously changed. With the addition of oxygen gas, more polar groups such as hydroxyl and carboxyl produced on wool fiber surface. The water absorption time of wool fabric greatly reduced indicating wettability improvement. The diffusion of water droplet on wool fabric surface was also larger and more homogenous suggesting uniform plasma treatment. It was concluded that the wettability improvement and its uniformity of the treated wool fabric increased and then decreased with the increasing oxygen flow rate and jet‐to‐substrate distance, and increased with the increasing treatment time. Therefore to achieve reasonable wettability and its uniformity of the wool fabric treated by APPJ, plasma treatment conditions have to be carefully chosen. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
4.
《Journal of Adhesion Science and Technology》2013,27(11):1469-1470
The influence of the gas type, air or nitrogen, and the treatment time in an RF glow discharge treatment on the shrink resistance properties of knitted wool fabric and wetting properties of keratin fibres were studied. Wetting properties were determined by means of contact angle measurements on single keratin fibres. This method allows measuring accurately the influence of the plasma gas type and treatment time on fibre hydrophilicity, and its modification with the time elapsed after plasma treatment. The modification of the surface properties should be taken into account, especially, when a biopolymer after-treatment is applied to achieve wool shrink resistance. Surface chemical changes were studied by means of XPS. Topographical changes in the wool fibre surface were observed by scanning electron microscopy (SEM) and surface damage was evaluated by means of the Herbig sac formation. Both air and nitrogen plasma treatments impart shrink resistance to wool fabric and hydrophilic properties to the keratin fibres. Even short exposure times are found to be enough to decrease drastically the advancing water contact angle and, therefore, to increase the shrink resistance effect. Slight differences were observed between the air and nitrogen plasma treatments. The time elapsed after the plasma treatment promotes an increase of the advancing contact angle and a decrease of chitosan adsorption. The plasma treatments studied here modify chemically the epicuticle but it is not removed. 相似文献
5.
Muncheul Lee Myung Sun Lee Tomiji Wakida Takako Tokuyama Goichi Inoue Shinzo Ishida Toshihiko Itazu Yukino Miyaji 《应用聚合物科学杂志》2006,100(2):1344-1348
In a previous article, we reported on the ozone‐gas treatment of wool and silk fabrics in relation to the gas‐phase processing of textile fabrics. The treatment incorporated an oxygen element into the fiber surface and contributed to an increase in water penetration into the fabric. In this study, nylon 6 and polyester fabrics were treated with ozone gas in the same way as that of the wool and silk fabrics. The treatment incorporated much more oxygen into the fiber surface in the form of ? COH and ? COOH, as shown by electron spectroscopy for chemical analysis. Water penetration increased considerably with treatment, and the apparent dyeing rate and equilibrium dye uptake were also improved, especially for the polyester fabric, despite an increase in the crystallinity. Therefore, it seemed that the treatment brought about a change not only in the fiber surface but also in the internal structure of the fibers (the crystalline and amorphous regions) with regard to the dyeing behavior. Further, the mechanical characteristics of the ozone‐gas‐treated polyester and nylon 6 fabrics were measured with a Kawabata evaluation system apparatus. The shearing modulus and hysteresis widths increased with treatment, especially for the polyester fabric. Therefore, it was clear that the treatment caused a change in the fabric hand to crisp. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 1344–1348, 2006 相似文献
6.
Microwaves are high frequency radio waves which are capable of penetrating many materials and causing heat to be generated in the process. To investigate the effect of microwave irradiation on the physical property, chemical structure, surface morphological structure, and fine structure of wool fabric, wool fabric was treated with microwave irradiation under variety of conditions in terms of the power and the time of microwave treatment. The breaking strength, breaking elongation, and whiteness of the treated wool fabric in different humid state were investigated. The structures of the untreated and treated wool were investigated with Fourier transform infrared spectroscopy (FTIR), X‐ray diffraction (XRD), scanning electron microscopy (SEM), and Laser Raman spectroscopy (LRS). The results show that the physical properties of the treated wool fabrics were changed with microwave irradiation time and power. The chemical structure had not significant change. The surface morphological structure, the concentration of cystine S S bonds and crystallinity of the treated wool were changed. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
7.
Polyester knit fabrics were treated with phase‐change‐material microcapsules by a pad–dry–cure method with a polyurethane binder. The treated fabrics were evaluated in terms of the thermal properties, air permeability, moisture vapor permeability, moisture regain, low‐stress mechanical properties, and hand, with respect to the add‐on of microcapsules. The surface morphology of the treated fabrics was investigated with scanning electron microscopy. The low‐stress mechanical properties of the treated fabrics, including the tensile, shear, bending, surface, and compression properties, were measured with the Kawabata evaluation system for fabrics (KES‐FB). As the add‐on increased, the heat storage capacity of the treated fabrics increased. The treated fabric with 22.9% add‐on was capable of absorbing 4.44 J/g of heat. The air permeability and moisture vapor permeability decreased, whereas the moisture regain increased, with an increase in the add‐on. The tensile linearity and geographical roughness increased, whereas the resilience, bending, and shear properties decreased with an increase in the add‐on. The fabrics became stiffer, less smooth, and less full as the add‐on increased, and thus the total hand value decreased. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 910–915, 2005 相似文献
8.
Atmospheric plasma treatment as an environmentally friendly method was employed to modify the surface properties and improve the absorption of natural cationic dye on to nylon 6 fabric. Nylon fabric was treated in atmospheric air plasma, and the surface characteristics of the fabric were evaluated using attenuated total reflection Fourier Transform‐infrared analysis, scanning electron microscopy, and a wicking test. The effects of plasma treatment and mordanting with copper sulfate on the dye uptake of the samples were investigated. Plasma‐treated and mordanted samples showed the highest colour strength when dyed. The antibacterial activity of samples was evaluated according to AATCC test method 100‐2004. Premordanting with copper sulfate showed a synergistic effect on the antibacterial properties of the dyed fabric. The plasma‐treated and copper‐sulfate‐mordanted sample showed acceptable antibacterial activity against both gram‐negative and gram‐positive bacteria when dyed with an extract from Berberis vulgaris, berberine. 相似文献
9.
In this study, transglutaminase (TGase)‐mediated crosslinking of gelatin on the surface of wool and its effect on the properties of wool fabric were investigated. For the wool fabric used in this study, gelatin (3 g/L) treatment for 1 h combined with 20 U/g of fabric microbial TGase reduced the area shrinkage of KMnO4‐pretreated wool fabric from 6.53 ± 0.06 to 1.92 ± 0.15%, which was more effective than that treated with gelatin alone (in which the area shrinkage was reduced to 4.02 ± 0.10%). At the same time, the tensile strength recovered from 267 ± 2.0 to 335 ± 2.1 N. The antifelting ability of treated wool fabric exhibited better washing durability. Scanning electron micrographs showed that the gelatin material smoothed the wool fiber surface by coating or filling the raised scales of the wool with TGase. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
10.
The present study is performed with an objective to acquire a deeper understanding of the properties of nickel‐plated polyester fabric after conducing low temperature plasma (LTP) treatment. LTP treatment with oxygen and argon gases was employed to render a hydrophilic property of woven polyester fabrics and facilitate the absorption of a palladium catalyst to provide a catalytic surface for electroless nickel plating. The properties of LTP‐induced electroless nickel‐plated polyester fabrics were evaluated by various standard testing methods in terms of both physical and chemical performances. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
11.
In this study, the effects of air‐plasma and N2‐plasma treatment on the hybrid polytetrafluoroethylene (PTFE)/cotton fabric and a phenolic resin were investigated in detail. The tribological properties of the untreated and plasma‐treated hybrid PTFE/cotton fabric/phenolic composites were investigated. The results indicated that air‐plasma‐treated hybrid PTFE/cotton fabric/phenolic composites exhibited better antiwear and friction reduction properties. The combination of scanning electron microscopy and Fourier transform infrared spectroscopy analysis illustrated that hybrid PTFE/cotton fabric/phenolic composites treated with air‐plasma possessed more integrated structure and more functional groups, which plausibly contributed to the better tribological properties of the hybrid PTFE/cotton fabric/phenolic composites treated with air‐plasma. POLYM. COMPOS., 2009. © 2008 Society of Plastics Engineers 相似文献
12.
Low‐temperature plasma processing for the enhancement of surface properties and dyeability of wool fabric
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In the present investigation, wool fabric was treated with a low‐temperature air plasma. The plasma discharge power and treatment time were varied. The effect of plasma treatment on various fabric properties such as wettability, wickability, dyeability, crease recovery angle, breaking strength, and elongation at break was investigated. Surface morphology was studied using SEM micrographs. The fabric became substantially hydrophilic even with a short duration of air plasma treatment of 30 s with improvement in dye uptake and in the rate of dyeing when dyed at a lower temperature. Under these treatment conditions, aging was almost nil in a dry environment, even after 45 days, whereas some aging was observed in a humid (75% relative humidity) environment. A 20% increase in the breaking strength and 24% increase in the elongation at break were observed with reduction in wrinkle recovery angle to 133–144° from 169° for untreated fabric. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43097. 相似文献
13.
In this study, wool fibers are modified by low frequency plasma polymerization of acrylic acid regarding to its' hydrophobic character due to cuticular cells at their surfaces. Variables of the plasma glow discharge processes were power (40–100 W) and exposure time (5–45 min). The effect of plasma modification in the performance properties of wool were investigated on the basis of hydrophilicity of wool, average wrinkle recovery angle, and breaking strength. The surface chemical structures of fabrics were examined with x‐ray photoelectron spectroscopy. The hydrophobic wool fabric became hydrophilic after all plasma treatments except one (40W–5 min). Average wrinkle recovery angle of the treated fabrics were between 157 and 178°, while that of untreated fabric was 180°. The treated fabrics had a little bit lower angles according to the untreated fabric. However, even the lowest value as 157° means that the fabric has a good crease resistance property. The breaking strengths of fabrics were increased up to 26% after the plasma treatments. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2010 相似文献
14.
This research aims to enhance the self‐cleaning properties of fibre‐blended fabric using surface pretreatment prior to the application of titanium dioxide nanoparticles. To this end, the polyester/wool fabric was modified, in that the wool fibres were oxidised with potassium permanganate and the polyester fibres were hydrolysed with lipase before nano processing. Butane tetracarboxylic acid was also used to enhance the adsorption of the nanoparticles and also to stabilise them on the fabric surface. The self‐cleaning properties of the fabric were examined through staining of the fabric with CI Basic Blue 9 and then discolouring by exposing to ultraviolet and daylight irradiation. Some other properties of the treated fabrics, such as water drop absorption, crease recovery angle and bending were investigated and are discussed in detail. The colour changes of different samples indicated an appropriate discoloration on the titanium dioxide‐treated fabrics after ultraviolet and daylight irradiation. Overall, the surface pretreatment of the wool and polyester fibres improved the self‐cleaning properties of the fabric significantly. 相似文献
15.
Wool is a naturally occurring composite fiber consisting of keratin and keratin‐associated proteins as the key molecular components. The outermost surface of wool comprises a lipid layer that renders the surface hydrophobic, which hinders certain fabric processing steps and moisture management properties of wool fabrics. In this study, Linde Type A (LTA) nano‐zeolite (a Na+‐, Ca2+‐, and K+‐exchanged type A zeolite) was integrated onto the surface of wool using 3‐mercaptopropyl trimethoxy silane as a bridging agent. The resultant surface morphology, hydrophilicity, and mechanical performance of the treated wool fabrics were evaluated. Notably, the surface hydrophilicity of wool increased dramatically. When wool was treated with a dispersion of 1 wt % zeolite and 0.2 wt % silane, the water contact angle decreased from an average value of 148° to 50° over a period of approximately 5 min. Scanning electron microscopic imaging indicated good coverage of the wool surface with zeolite particles, and infrared spectroscopic evaluation demonstrated strong bonding of the zeolite to wool keratins. The zeolite application showed no adverse effects on the tensile and other mechanical properties of the fabric. This study indicates that zeolite‐based treatment is potentially an efficient approach to increasing the surface hydrophilicity and modifying other key surface properties such as softness of wool and wool fabrics. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42392. 相似文献
16.
The surface and adhesion properties of different molecular weight poly(ethylene glycol) (PEG) (400, 1500, and 3000 g/mol) on untreated and air‐atmospheric plasma‐treated PET woven fabrics were studied, with the aim of developing durable hydrophilic PET fibrous structures. PEG application was carried out by padding of the PET fabric in aqueous solution of PEG followed by curing and drying. The surface properties of the PEG‐coated PET fabrics were then characterized using wicking test to measure the water contact angle (θ°) and capillary weight (Wc), and using atomic force microscopy (AFM) images in the tapping mode. Results showed that without a prior air‐atmospheric plasma treatment of the PET fabric, the water contact angle decreased and capillary weight increased with the three PEGs, implying an increase in the hydrophilicity of both inner and outer PET fabric fiber surface. Air‐plasma treatment of the PET fabrics before PEG coating increases further the hydrophilicity of the inner fabric fiber surface: the capillary weight was almost doubled in the case of the three PEGs. Best results were obtained with PEG 1500: water contact angle decreasing from 82° to 51°, and the capillary weight increasing from 11 mg to 134 mg. Moreover, wash fastness test at room temperature and at 80°C confirms improved adhesion of PEG‐1500 to the plasma‐treated PET woven fabric surface, while under the same conditions the plasma‐treated PET without PEG loses completely its hydrophilic character. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011. 相似文献
17.
Naturally colored cotton, in accordance with currently increasing interest in ecological textile products and methods, has increased in popularity. Commerce is another of the primary reasons along with interest in environmentally friendly and niche‐concept approaches. However, the color palette is limited; no bleaching or dyeing process is used. Instead, only a pretreatment to make the fibers hydrophilic is necessary. This can be induced with several different methods. In this respect, atmospheric‐plasma treatments have emerged as an alternative. In this study, knitted and naturally colored cotton fabrics were treated with argon and air atmospheric plasma. The hydrophilicity, wickability, surface friction coefficient, air permeability, water vapor permeability, thermal conductivity, thermal resistance, and fastness were investigated. The surfaces of untreated and plasma‐treated fabrics were analyzed with Fourier transform infrared/attenuated total reflectance and scanning electron microscopy to detect and compare the chemical and morphological modifications. The results revealed that atmospheric‐plasma treatments are capable of modifying the surface of naturally colored cotton fabrics without any important loss in the color strength or fastness and thermal properties. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
18.
Wool fabrics were pretreated with hydrogen peroxide in the presence of different stabilisers; namely, sodium silicate, magnesium sulphate and imino disuccinic acid sodium salt. The effect of stabiliser type and concentration on the properties of the treated wool were studied. Imino disuccinic acid sodium salt was found to be the most effective stabiliser for hydrogen peroxide when added to the bleaching bath of wool fabric. The effect of after‐treatment of the pre‐oxidised wool fabric with commercially produced lipoprotein lipase enzyme on its dyeability with acid and reactive dyes, as well as on some of its physico‐mechanical properties, was assessed. Chemical and microscopic analyses were conducted to assess changes in the chemical composition of wool treated with this system. Wool fabrics treated with hydrogen peroxide/imino disuccinic acid sodium salt/lipoprotein lipase enzyme exhibit improved wettability and, hence, dyeability with both acid and reactive dyes, as well as enhanced resistance to felting shrinkage and pilling, without severe deterioration in the fabric’s inherent properties. 相似文献
19.
Poly(ethylene terephthalate) fabric was treated by plasma initiated in various gases: nitrogen, oxygen, air, carbon dioxide and ammonia. Plasma-treated fabric showed a considerable change in surface structure and wettability. It was observed that the change in the surface structure of the polyester fibres was closely dependent on the gas type and treatment conditions. The wetting time of plasma treated fabric considerably drops in comparison to untreated fabric and the best results were obtained by treatment in nitrogen, oxygen and air plasma. A good correlation exists between change in the surface structure of the fabric and its wettability. Infra-red a.t.r. spectroscopy showed some differences in the spectra of plasma treated fabrics but these changes are only moderately dependent on the gas type and plasma conditions. Modification of the surface structure of the polyester fibres depends on the current frequency within the studied range of 0.05–100 kHz. 相似文献
20.
Prasanta Kumar Panda Deepali Rastogi Manjeet Jassal Ashwini K. Agrawal 《应用聚合物科学杂志》2012,124(5):4289-4297
Wool fabrics were treated with atmospheric pressure helium glow discharge plasma in an attempt to improve felting and dyeing behavior with cold brand reactive dyes using cold pad‐batch method at neutral pH. On glow plasma treatment, the hydrophilicity of wool surface and its resistance toward felting was greatly improved without any significant damage to the cuticle layer. The color strength of the plasma treated dyed wool on the surface (in terms of K/S) was found to be nearly double of the color strength of dyed untreated wool fabric. However, the corresponding total dye uptake of the treated wool increased by a much lower value of 40%–50%. The reason behind this altered dyeing behavior was investigated by studying the dye kinetics using infinite bath and surface characteristics using SEM and SIMS. It was found that the glow plasma treatment greatly transformed the chemical surface of the wool fibers. It resulted in uniform removal of hydrophobic cuticular layer, which resulted in better diffusion of the dye molecules into the fiber, and formation of hydrophilic ? NH2 groups near the surface, which helped in anchoring the dye molecules close to the surface giving higher color strength than expected. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 相似文献