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铝硅质介孔分子筛Al-MCM-41的合成与水热稳定性评价 总被引:9,自引:1,他引:9
以水玻璃为硅源,铝酸钠为铝源,以十六烷基三甲基溴化铵(C16H33(CH3)3NBr)为模板剂,在水热条件下合成出了Al-MCM-41介孔分子筛.研究了合成母液中SijO2:Al2O3摩尔比对合成Al-MCM-41的影响;合成过程中母液搅拌时间不同对样品孔序度的影响;以及铝引入到MCM-41骨架后,样品的水热稳定性评价.通过对样品的XRD表征和SAXS表征,得到如下结论:随母液中SiO2:Al2O3摩尔比的增加(30~50),Al-MCM-41分子筛孔容变大;母液搅拌时间越长,样品的孔序度越好;把铝引入到MCM-41骨架中,可有效改善MCM-41的水热稳定性. 相似文献
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Min Wu Qing-Qing Zhao Jie Li Hai-Yan Wu Xin-Xin Guan 《Journal of Experimental Nanoscience》2016,11(17):1331-1347
Aluminum-substituted MCM-41 (Al-MCM-41) were hydrothermally synthesised and used as supports to fabricate the mesostructured H3PW12O40 (HPW) solid acid catalysts via an impregnation method. The influences of various HPW loadings on the structures of the catalysts were verified by X-ray diffraction (XRD), nitrogen physisorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), ultraviolet–visible (UV–Vis) spectroscopy and Fourier-transform infrared spectroscopy (FT-IR) measurements and their acidities were evaluated by infrared of pyridine adsorption (Py-IR) and temperature-programmed desorption of ammonia (NH3-TPD) measurements. The optimisation of the reaction conditions for levulinic acid esterification with n-hexanol such as the reaction temperature and time, the reactant molar ratio, and the catalyst dosages was performed to maximise the conversion of levulinic acid. The effects of various HPW loadings on the conversion of levulinic acid were investigated under the optimised and harsh reaction conditions. The reusability of the catalysts was also investigated. The results showed that these catalysts retained the hexagonal mesoporous structure of Al-MCM-41 and the Keggin characteristic of HPW, although their textural parameters decreased with increasing loading of HPW. In particular, the catalysts were found to be efficient in the esterification of levulinic acid with n-hexanol, resulting in hexyl levulinate which could replace the petroleum-derived chemical feedstocks. 相似文献
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硅烷修饰对环氧树脂/纳米介孔MCM-41复合材料性能的影响 总被引:11,自引:0,他引:11
用偶联剂将纳米介孔MCM-41粉体修饰后与环氧树脂溶液共混,制备出环氧树脂/MCM-41纳米复合材料.研究了偶联剂的含量和不同溶剂的修饰对纳米介孔MCM-41粉体分散性和复合材料力学性能的影响.结果表明,加入适量的偶联剂和在极性较小的介质中修饰,可制备出单分散的纳米介孔MCM-41颗粒增强的新型网络复合材料.偶联剂中的有机基团-(CH2)3-NH2不仅进入孔道、修饰了MCM-41的孔壁,而且使介孔分子筛保持了有序的孔道结构.环氧树脂高分子链与偶联修饰后的MCM-41颗粒的内、外表面以强烈的化学键结合,使MCM-41颗粒均匀分散在聚合物基体中,提高了材料的力学性能,其拉伸强度比基体树脂提高了69%,杨氏模量提高了90%. 相似文献
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Jakkidi Krishna Reddy Machiraju Subrahmanyam Bojja Sreedhar 《Materials Research Bulletin》2009,44(7):1540-2050
Ce-Al-MCM-41, TiO2/Al-MCM-41 and TiO2/Ce-Al-MCM-41 materials with varying contents of Ce (by impregnation) and TiO2 loaded (by solid-state dispersion) on Al-MCM-41 support are prepared. The Ce modified and TiO2 loaded composite systems are characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), UV-vis diffuse reflectance spectra (DRS) and X-ray photoelectron spectroscopy (XPS) techniques. The DRS and XPS of low Ce content (0.2-0.5 wt.%) modified Al-MCM-41 samples are showing more characteristic of Ce3+ species wherein cerium in interaction with Al-MCM-41 and that of high Ce (0.8, 3.0 wt.%) content modified samples are showing the characteristic of both Ce4+and Ce3+species. A series of Ce-modified Al-MCM-41 and TiO2 loaded composite catalysts are evaluated for photocatalytic degradation of phenol under UV irradiation. Low Ce content in Ce3+ state on Al-MCM-41 is showing good photoactivity in comparison with high Ce content samples and pure ceria. The composite TiO2/Ce-Al-MCM-41 is showing enhanced degradation activity due decreased rate of electron-hole recombination on TiO2 surface by the redox properties of cerium. The photocatalyst TiO2/Ce-Al-MCM-41 with an optimum of 10 wt.% TiO2 and 0.3 wt.% Ce is showing maximum phenol degradation activity. The possible mechanism of phenol degradation on the composite photocatalyst is proposed. 相似文献
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Xuan Nui Pham Ba Manh Nguyen Hoa Tran Thi Huan Van Doan 《Advanced Powder Technology》2018,29(8):1827-1837
A series of Ag-AgBr/Al-MCM-41 nanocomposites were synthesized by dispersion of Ag-AgBr on mesoporous silica Al-MCM-41 obtained from natural bentonite. The synthesized Ag-AgBr/Al-MCM-41 composites with Ag nanoparticles growing on the surface of Al-MCM-41 were used for photocatalytic oxidative desulfurization of dibenzothiophene. The physical properties of Ag-AgBr/Al-MCM-41 were characterized by X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), Ultraviolet–visible diffuse reflection spectroscopy (UV–Vis DRS), photoluminescence (PL) emission spectra, and X-ray photoelectron spectroscopy (XPS). The photocatalytic activity results showed that in the presence of 40% Ag-AgBr/Al-MCM-41 photocatalyst the oxidative desulfurization of dibenzothiophene reached the maximum efficiency at 99.22% and the photocatalytic activity still keeps high level after four cycles. 相似文献
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Mesoporous Al-MCM-41 materials were synthesized using room temperature ionic liquid 1-cethyl-3-methylimidazolium bromide ([C16mim]Br) as a single template and characterized by X-ray diffraction, N2 adsorption-desorption, ICP-AES, 27Al MAS NMR and TEM technique. These mesoporous materials exhibit hexagonal p6m pore architectures, and possess high surface area and narrow pore distribution. All aluminum in as-synthesized samples exists in tetrahedral coordination. Upon calcination nearly all aluminum still remains the tetrahedral coordination even when the Si/Al ratio is as low as 15. This indicates that the tetrahedral aluminum of Al-MCM-41 is stable. 相似文献
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为了找到制备金属陶瓷惰性阳极材料的合理方法,采用一次烧结和两次烧结这两种制备方法制备惰性阳极材料,比较了这两种方法制备的材料的密度、电导率、腐蚀率、抗弯强度以及抗热震性等性能.通过比较发现两次烧结制备出的材料性能较好.两次烧结得到的阳极试样中金属银能够较好的沿着陶瓷颗粒的轮廓分布,而形成了联通的网状结构.这样的结构不仅能够使得导电电子形成连通的通路,从而提高试样的电导率,还能提高材料的力学性能和抗热震性.两次烧结得到的试样密度要高于一次烧结得到的试样,这对提高试样的抗腐蚀性和电导率有利. 相似文献
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Shuiping Li Qisheng Wu Chong Cui Guosen Lu Changsen Zhang Zhiye Yan 《Materials Science-Poland》2013,31(3):372-377
TiO2/Al-MCM-41 mesoporous materials were prepared via sol-gel method by loading titania onto Al-MCM-41 mesoporous molecular sieve by hydrothermal treatment from coal-series kaolin as raw material. The TiO2/Al-MCM-41 mesoporous materials were characterized by XRD, FT-IR, HRTEM, N2 adsorption-desorption and the photocatalytic degradation of methyl orange solution under visible light irradiation. The results showed that the TiO2/Al-MCM-41 mesoporous materials possessed a high surface area of 369.9–751.3 m2/g and a homogeneous pore diameters of 2.3–2.8 nm. The titania crystalline phase was anatase, and the particles size of TiO2 increased with TiO2 content. The Al-MCM-41 mesoporous materials exhibited excellent photodegradation activity under visible-light irradiation for methyl orange. 相似文献
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Masanobu Kamitakahara Tasuku Yagi Chikara Ohtsuki 《Journal of materials science. Materials in medicine》2009,20(12):2419-2426
A simulated body fluid (SBF) with ion concentrations similar to body fluid, proposed by Kokubo et al., is widely used to evaluate
bone-bonding potential through the formation of an apatite layer. To be confident of the evaluation of the potential for the
apatite formation in SBF, standard substrates are required. Although Na2O–CaO–SiO2 glasses have been focused upon as candidate standard substrates, it has not been clarified whether the preparation conditions
of the glasses affect their apatite formation potential in SBF. In this study, Na2O–CaO–SiO2 glasses were prepared by a conventional melting–quenching method with different melting periods and annealing processes to
examine their properties, including apatite formation in SBF. The Na2O–CaO–SiO2 glasses show reproducible apatite-forming ability when prepared using moderate melting and annealing processes, and can be
useful substrates to test the reproducibility of SBF. 相似文献
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J. Suwanprateeb R. Sanngam T. Panyathanmaporn 《Materials science & engineering. C, Materials for biological applications》2010,30(4):610-617
A comparison between two routes of raw powder preparation, namely spray drying and grinding, for 3D printing of hydroxyapatite was carried out. Hydroxyapatite particles prepared by the spray drying technique were spherical in shape whereas the grinding route gave irregular-shaped agglomerates. Spray-dried powders had higher tap density than milled powders, however milled powders yielded 3DP specimens with greater green density and strength. After sintering at 1300 °C for 1 and 5 h, samples fabricated from milled powders showed a 32% higher in sintered density, a 20% lower in porosity and approximately two times higher flexural modulus and strength than samples fabricated from spray-dried powders. This difference was related to the better packing characteristics of milled powders which promoted improved inter- and intra-particle densification during high temperature sintering compared to the spray-dried powders which yielded only high intra-particle densification, but lower inter-particle densification. 相似文献
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The effects of various amounts of excess niobium ions added to the 18PMN-41PZ-41PT three-component ceramics system on the crystal structure, microstructure, polarization versus electric field, strain versus electric field and piezoelectric properties, have been studied. It was found that addition of niobium ions to 18PMN-41PZ-41PT induced a change in the crystal structure from rhombohedral to tetragonal phase. The excessive niobium ions also formed a micro-second phase which existed in the grain boundary, which could refine and uniform the grain. The refined and uniformed microstructure was found to increase the remanent polarization, saturation strain, planar coupling coefficient, K
p, and mechanical quality factor, the best value of K
p being 69%. 相似文献
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Piezoelectric ceramics of 18PMN-41PZ-41PT were sintered by hot-pressing and normal sintering methods. The microstructure,
density, P-E curve and S-E curve were also compared. The best hot-pressing condition for 18PMN-41PZ-41PT material was obtained at a temperature of 1000
°C and a pressure of 700 kg cm−2; it could achieve 99.66% theoretical density and a fine, uniform microstructure as a result of a 200–300 °C decrease in the
sintering temperature. A higher coercivity was attained with the density increase. The fine, uniform microstructure also enhanced
the increase in polarization and strain. 相似文献
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以高纯钨粉、钛粉和TA2钛片为原料,分别采用液相烧结法和熔渗法制备了Ti含量为10%的W-Ti合金;测量了W-10%Ti合金的密度和杂质(C、N和O)含量,研究了不同方法制备的W-Ti合金的相组成和微观形貌.结果表明,熔渗法制备的W-Ti合金致密度达94%以上,相结构由含有较多富Ti相的固溶体β(W/Ti)组成;液相烧结的合金致密度为90%左右,组织相对均匀;两种方法制备的合金杂质(C、N和O)含量均较低.探讨了液相烧结制备W-10%Ti合金时固溶体扩散形成的机理. 相似文献
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《Materials Letters》2006,60(21-22):2682-2685
The preparation of a Al-MCM-41 mesoporous materials has been carried out using silica-gel and pseudoboehmite as silica and aluminum sources, respectively, and surfactant cetyltrimethylammonium bromide as structure template. The textural properties of the calcined Al-MCM-41 were characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM) and N2 isothermal adsorption measurements. The hexagonal structure parameter ao was calculated based on d(100) XRD reflection as 4.75 nm. TEM images revealed the formation of a well-ordered Al-MCM-41. Accordingly, nitrogen adsorption measurements (BJH) showed a material with very narrow distribution and medium pore diameter of 3.14 nm. Mesopore volume based on adsorbed nitrogen was 0.51 cm3 g− 1. Through a combination of XRD and N2 adsorption data, the thickness of the channel walls of 1.61 nm could be calculated. 相似文献