Pulsed Nd：YAG laser cladding of high silicon content coating on low silicon steel

A pulsed Nd:YAG (yttrium aluminum garnet) laser-based technique was employed to clad low silicon steel with preplaced Si and Fe mixed powders for high Si content. The surface morphology, microstructural evolution, phase composition, and Si distribution, within the obtained cladding coatings, were characterized by optical microscopy (OM), field emission scanning electron microscopy (FE-SEM), with associated energy dispersive spectroscopy (EDS), transmission electron microscopy (TEM), and X-ray diffraction (XRD). The microhardness was also measured along the depth direction of the specimens. A crack-and pore-free cladding coating through excellent metallurgical bonding with the substrate was successfully prepared on low silicon steel by means of optimized sin-gle-track and multi-track laser cladding. The phases of the coating are α-Fe, γ-Fe, and FeSi. The high microhardness of the la-ser-cladding zone is considered as an increase in Si content and as the refined microstructure produced by the laser treatment. The Si contents of the cladding coatings were about 5.8wt/ in the single-track cladding and 6.5wt/ in the multi-track cladding, respectively.     

Nd:YAG激光和CO2激光熔敷性能比较研究

从Maxwell方程和Hagen-Ruben公式出发,计算了Nd：YAG激光(波长为1．06μm)和CO2激光(波长为10．6μm)在金属中的吸收率和穿透深度,并做了Nd：YAG激光与CO2激光的熔敷试验比较．结果表明：Nd：YAG激光在金属中吸收率约为CO2激光的3倍,更适于激光熔敷;CO2激光在金属中穿透力约为Nd：YAG激光的3倍,更适于激光相变淬火．     

冷扎Q235钢/激光熔覆合金钢摩擦磨损

通过对9SiCr钢表面进行合金激光熔覆处理,在摩擦磨损实验机上对熔覆合金钢与Q235钢配副进行了摩擦磨损性能实验.通过摩擦磨损实验研究了参数如载荷、滑动距离、滑动速度、润滑条件等对Q235钢与熔覆合金钢的磨损量的影响,熔覆合金钢与Q235钢的磨损量与压力和滑动速度成正比.Ni合金钢的耐磨性比Co合金钢要好.通过扫描电镜分析了熔覆合金磨损机理,熔覆合金钢磨损主要以磨粒为主,同时表面存在大量凹坑,而Q235钢以磨粒和塑性变形为主.     

20#钢表面镍基添Y2O3激光熔覆层及其高温磨损行为

采用激光熔覆法,在20#钢表面制备出添Y2O3的镍基合金粉末的熔覆涂层．分析了熔覆层的相组成、高温耐磨性能;观察了熔覆层显微形貌．结果表明：所制得的熔覆层组织均一、致密,与基体形成了良好的冶金结合．添加Y2O3的熔覆层硬度提高到基体的3．9倍,高温耐磨率仅是基体的1／4．熔覆层耐磨能力增强的主要原因是熔覆层与基体良好的冶金结合,镍基合金良好性能,组织细化以及硼化物、硼碳化物等析出相的强化作用．     

Microstructures of laser cladding of intermetallic-ceramic composite coatings

The microstructures of laser cladding of (Ni-24.5%(atom fraction)Al)+5O%(mass haction)WC coatingsbefore and after aging was comparetively studied by using SEM and TEM. It is shown that dissolving of WC and reprecipitating in the forms of WC and W,Coccurred during laser cladding, and intermetallic γ' (Ni3Al) orderly precipitatefrom metastable supersaturant Ni-matrix solid solution after heat treatment. The structures are favorable for coating'sproperties.     

激光熔覆铜基自生复合材料设计及其涂层研究

为了提高铝合金的耐磨性，利用铜合金体系存在液相分离现象等冶金性质，在铝合金表面设计了自生铜基复合材料体系，并采用激光熔覆技术对其进行了验证和优化。设计的较理想材料体系为Cu-16Ni-6Fe-8Co-7Mo-4Cr-3Si，由其得到的激光熔覆复合材料中存在大量的自生硬质颗粒增强体，其熔覆涂层具有良好耐磨性，其耐磨性甚至优于汽车发动机缸盖阀门座圈QZ5铸铁合金。     

Investigation on laser cladding of MoSi2 powder on steel

The feasibility of the fabrication of coatings for elevated-temperature structural applications by laser cladding MoSi2 pow- der on steel was investigated. A dense and crack-free fine coating, well-bonded with the substrate has been obtained by this technique This coating consists of FeMoSi, Fe2Si and a small amount of MosSi3 due to dilution of the substrate in the coating. The microstructure of the coating is characterized of typical fine dendrites, The dendrites are composed of FeMoSi primary phase, and the interdendritic areas are two eutectic phases of FeMoSi and Fe2Si. The hardness of the coating reaches 845 Hv0.5, 3.7 times larger than that of the steel substrate （180 Hv05）.     

激光熔覆铜基合金涂层中的液相分离行为

为了研究铜基合金激光熔覆中的液相分离行为,根据液相分离理论在ZL104铝合金表面成功制备了具有液相分离特性的铜基合金涂层,并采用扫描电镜等对涂层中液相分离形成的分离相(硬质强化相)的形态特征与分布规律进行了观察,研究了不同分离相的形成机制与液相分离行为.研究表明,涂层中的分离相通常呈弥散分布和偏聚2种典型形态.熔池温度较高时分离相表现出"富Mo核心 包围相"的2层复合结构,呈边缘粗糙的不规则近球状形貌,这是由异质形核诱发的液相分离所形成的;温度稍低时强的表面能约束则是影响液相分离的主要因素,并使分离相呈光滑球状形态.当表面能过高时在对流等因素作用下分离相问会发生严重的碰撞凝并,最终形成大块偏聚体.     

激光熔覆原位自生TiC-VC复合增强铁基合金层的研究

利用钛铁、钒铁、石墨等组分,采用5kW横流CO₂激光器在低碳钢板上熔覆制备出原位自生TiC-VC复合碳化物颗粒增强Fe基合金层.利用金相显微镜、X射线衍射仪、电子探针及滑动磨损试验机,研究了合金熔覆层的显微组织及性能.研究结果表明,通过钛铁、钒铁与石墨之间的反应,可以得到TiC-VC复合碳化物增强相,细小的TiC-VC复合碳化物颗粒弥散分布在Fe基体之中,合金熔覆层的耐磨性在一定范围内随增强颗粒的增加而提高.     

Microstructure and corrosion properties of laser cladding MoNi based alloy coatings

Mo-based alloys are widely used for their excellent wear and corrosion resistance as well as high temperature resistance.Mo-NiCrBSi and Mo-Ni alloy coatings were prepared on 1020 water wall tube by laser cladding technology in the present study.The microstructure and phase compositions were analyzed by means of the scanning electron microscopy(SEM),energy-dispersive spectroscopy(EDS)and X-ray diffractometry(XRD).The corrosion properties of the coatings were evaluated by an electrochemical experiment at room temperature in 3.5 wt.%NaCl electrolyte.With increasing content of Mo,the structure homogeneity in Mo-Ni coatings deteriorated,the grain size increased,the average hardness and the corrosion resistance declined,due to the more content of harmful phases.Compared to the Mo-Ni coatings,the overall performance was better for the Mo-NiCrBSi,which had the higher hardness contributed by the element B and Si as well as the better corrosion resistance due to the addition of Cr.