纳米纤维增强闭孔泡沫材料的力学性能

为研究纳米纤维增强闭孔泡沫材料的力学性能,采用Voronoi随机泡沫模型对闭孔泡沫材料的细观几何结构进行模拟,并将纳米纤维随机分布在泡沫材料的胞壁中,利用改进的自动搜索耦合（ASC）技术将纤维单元与基体单元进行耦合,建立了能够反映纳米纤维增强闭孔泡沫材料细观结构的数值模型。在此基础上,进一步研究了泡沫模型随机度、相对密度以及纳米纤维长径比和质量分数对纳米纤维增强闭孔泡沫材料弹性模量与屈服强度的影响规律。结果表明:由所建立的数值模型得到的纳米纤维增强闭孔泡沫材料的弹性模量和屈服强度与实验值吻合较好;提高泡沫模型的随机度会使复合泡沫材料的弹性模量和屈服强度增加,而当随机度达到0.450以后,材料的弹性模量和屈服强度几乎不再发生变化;当相对密度在0.05~0.30范围内变化时,复合泡沫材料的弹性模量与屈服强度几乎随相对密度的增加呈线性增长;提高纳米纤维长径比和质量分数也会使材料的弹性模量和屈服强度得到提高,但当纤维长径比达到500以后,纤维长径比的增强作用逐渐减弱。所得结论对纳米纤维增强闭孔泡沫材料的制备具有重要意义。      

The effects of manufacturing parameters on geometrical and mechanical properties of copper foams produced by space holder technique

We describe a powder metallurgical space holder method to produce open-cell metallic foams. By changing the values of the main manufacturing parameters such as volume percentage and the particle size of the space holder agent, we produce different copper foam samples which cover a wide range of solid fraction, pore size and cell wall thickness. All the specimens were synthesized based on a series of designed experiments. We demonstrate how the foams’ density, cell size and specific surface area can be accurately controlled using two easily adjustable manufacturing parameters. The three-dimensional structure of these foams was investigated using X-ray micro tomography. The image quality is sufficient to measure local structure and connectivity of the foamed material, and the field of view large enough to calculate material properties. By combining the finite element method with the tomographic images, we calculate the mechanical response of the foams. We show that the foams’ bulk and shear moduli are strongly correlated to their cell size, cell wall thickness and specific surface area. These parameters can be easily controlled during manufacturing.     

考虑界面效应的复合泡沫塑料弹性性能数值仿真预测与试验研究

通过对不同空心陶瓷微珠含量的环氧基复合泡沫塑料进行准静态拉伸实验,研究了填充微珠的体积分数对复合泡沫塑料弹性模量和泊松比的影响.基于其细观结构特征,利用三维立方单胞有限元模型模拟了细观应力/应变场;将内聚力单元引入细观有限元模型,以此来模拟空心微珠与基体材料之间界面相的力学行为.将有限元预测结果以及两种传统的细观解析法与实验数据对比,发现基于界面理想粘接假设的有限元模型和传统细观解析法均过高估计了复合泡沫塑料的弹性模量和泊松比;复合泡沫塑料的弹性性能强烈地依赖于界面相的力学性质,只有考虑界面效应的细观有限元模型才能给出较为精确的预测,从而验证了文中细观建模方法的合理性.     

Numerical prediction of disorder effects in solid foams using a probabilistic homogenization scheme

The present study is concerned with a numerical prediction of uncertainties in the macroscopic mechanical properties of microheterogeneous materials with uncertain microstructure. As a model material, solid foams are employed. The stochastic information on the uncertainty is gained in multiple numerical homogenization analyses of small-scale testing volume elements. The local relative density, the cell size distribution, the cell geometry and the spatial orientation of the testing volume elements are assumed to form the set of the relevant stochastic variables. Selected microstructural cases are analyzed for their macroscopic material response. Based on the probability distributions for the stochastic variables defining the microstructures of the testing volume elements, the probability distributions for the mesoscopic material properties are obtained. For the numerical homogenization of the testing volume elements, an enhanced finite element technique is employed, where the components of the macroscopic deformation gradient are introduced as generalized degrees of freedom. Assuming periodic boundary conditions, the global degrees of freedom interact with the conventional displacement degrees of freedom of the discretized microstructure via special boundary coupling elements. The mesoscopic stresses are obtained in a rather efficient manner as the generalized reaction forces for the global degrees of freedom.     

空心微珠填充聚氨酯泡沫塑料的力学性能

对不同密度和不同填充质量比的空心玻璃微珠填充聚氨酯泡沫塑料进行拉、压实验,研究了微珠对复合泡沫塑料力学性能的影响。实验结果表明:复合泡沫塑料拉伸曲线特征与普通泡沫塑料类似,但具有不同于普通泡沫塑料的压缩应力-应变特性;材料密度越大,微珠对胞体壁的增强效果越好;微珠团聚和界面粘结不良将可能导致材料力学性能的下降。根据有限元模拟结果和试件破坏形貌的观察探讨了材料的变形和破坏机制。      

考虑界面效应的复合泡沫塑料弹性性能数值仿真预测与试验研究

通过对不同空心陶瓷微珠含量的环氧基复合泡沫塑料进行准静态拉伸实验, 研究了填充微珠的体积分数对复合泡沫塑料弹性模量和泊松比的影响。基于其细观结构特征, 利用三维立方单胞有限元模型模拟了细观应力/应变场; 将内聚力单元引入细观有限元模型, 以此来模拟空心微珠与基体材料之间界面相的力学行为。将有限元预测结果以及两种传统的细观解析法与实验数据对比, 发现基于界面理想粘接假设的有限元模型和传统细观解析法均过高估计了复合泡沫塑料的弹性模量和泊松比; 复合泡沫塑料的弹性性能强烈地依赖于界面相的力学性质, 只有考虑界面效应的细观有限元模型才能给出较为精确的预测, 从而验证了文中细观建模方法的合理性。     

复合材料加筋板的动力分析

本文构造了九自由度三角形拟协调罚函数复合材料板单元与六自由度复合材料梁单元,考虑了剪切变形与转动惯量的影响。用这两种单元对复合材料加筋板的自由振动、阻尼特性和瞬态响应问题进行了研究,给出一些有益结果。      

Finite element simulations of crack propagation in functionally graded materials under flexural loading

Cracks in stepped and continuously graded material specimens under flexural loading were investigated via finite element analysis. Calculation of mechanical energy release rates and propagation angles with crack-opening displacement correlation and the local symmetry (K_II = 0) criterion, respectively, provided results most efficiently and accurately, as compared with compliance and J-integral approaches and other deflection criteria. A routine was developed for automatic crack extension and remeshing, enabling simulation of incremental crack propagation. Effects of gradient profile and crack geometry on crack-tip stresses and crack propagation path are examined, and implications of these for optimal design of graded components against failure by fast fracture are discussed.     

Finite element modeling of post-fire flexural modulus of fiber reinforced polymer composites under constant heat flux

In this study, a simple 1D finite element model was developed to predict the temperature evolution and post-fire mechanical degradation of glass fiber reinforced polymers (FRPs) subjected to constant heat fluxes, including 35 kW/m², 50 kW/m², 75 kW/m², and 100 kW/m². A temperature-dependent post-fire mechanical property model was proposed and implemented. The calculated temperature and residual mechanical moduli showed good agreement with the experimental data. By properly selecting the parameters of the model, an effective strategy was demonstrated to design FRP structure with enhanced durability.     

短纤维增强复合泡沫弹性性能数值模拟

采用二元模型对短纤维增强复合泡沫(SFRSF)材料进行了简化模拟,考虑了纤维在空间中分布的随机性,并分别采用不同单元类型在不考虑网格匹配的情况下对纤维和基体单独进行网格划分。之后,采用改进的单元嵌入技术(EET)耦合纤维与基体的自由度,并引入杆单元模拟界面相,描述了材料内部纤维与基体的传载机制,从而建立了能反映材料细观结构的有限元数值模型。在此基础上,研究了碳纤维含量和长度以及空心微珠含量和壁厚对SFRSF杨氏模量的影响规律。结果表明,该数值模型对SFRSF杨氏模量的预测与实验值吻合较好。增加碳纤维的含量和纤维长度能够有效提高SFRSF材料的杨氏模量,适当增加空心微珠壁厚一定程度上可以增加其杨氏模量。     

On mixed-mode fracture of PVC foam

This paper reports on mixed-mode fracture in rigid cellular PVC foam based on experimental and numerical analyses. Experiments were performed on sharp-cracked specimens using the compact-tension-shear (CTS) test loading device. Foams of three different densities were tested. The CTS specimen was, in association with a special loading device, an appropriate apparatus for experimental mixed-mode fracture analysis. Experimentally-obtained fracture toughness results show good consistency. K_IC fracture toughness was marginally different in different directions. The ratio K_{II C}/K_{I C} was found to be between 0.4 and 0.65 depending on the foam density. For mixed-mode loading, Richard's criterion – using experimentally obtained K_{I C} and K_{II C} – was the best in predicting accurately fracture locus and fracture angle. When no experimental data were used, the maximum hoop stress criterion predicted best kinking angle. The principal strain criterion predicted the best fracture locus. Fracture boundary curve and kinking angle were best predicted for low mode II contribution. This revised version was published online in August 2006 with corrections to the Cover Date.     

Asymmetric flexural vibration and thermoelastic stability of FGM circular plates using finite element method

Here, asymmetric free vibration characteristics and thermoelastic stability of functionally graded circular plates are investigated using finite element procedure. A three-noded shear flexible plate element based on the field-consistency principle is used. Temperature field is assumed to be a uniform distribution over the plate surface and varied in thickness direction only. Material properties are graded in the thickness direction according to simple power law distribution. For the numerical illustrations, aluminum/alumina is considered as functionally graded material. The variation in critical buckling load is highlighted considering gradient index, temperature, radius-to-thickness ratios, circumferential wave number and boundary condition of the plate.     

Thermal analysis of the torsion test under hot-working conditions

It is important to estimate the temperature changes in material testing so that the interpretation of test data can be improved and the derived constitutive equations validated. In this paper a finite element thermal analysis of the torsion test under hot-working conditions is carried out and the flow stresses of an aluminum alloy AA5252 are predicted and compared with the data. It is shown that the further flow softening after the peak stresses have been obtained, which is attributed to excessive heat accumulation during testing at high strain rates, can be predicted reasonably by the method presented.     

Effective conductive properties of open-cell foams

The work is devoted to the problem of simulation of the effective electro and thermoconductive properties of open-cell foam materials with slim highly conductive ligaments. The solution of this problem depends on two small parameters: the ratio of the typical length and the cross-section size of the ligaments, and the ratio of the conductivities of the host medium and the ligaments. The principal terms of the asymptotic solutions (with respect to these parameters) for the fields inside the ligaments are obtained and used in the framework of a finite element method for the numerical simulation of the fields inside the representative volume element (RVE) of the foam material. The Laguerre tessellation procedure is applied for simulation of foam microstructures with various distributions of cell-sizes inside the RVE. Effective conductivity constants of the foams are obtained by averaging the detailed fields over the RVE. The number of cells inside the RVE for reliable calculations of the effective conductivities is indicated. Dependences of the effective conductive properties of the foams on the shapes of the ligaments and the distribution law of the cell-sizes are obtained and analyzed.     

Impact and dynamic response of high-density structural foams used as filler inside circular steel tube

Structural foams have good energy absorption properties and are effective in reducing the vulnerability of sandwich structures. This research investigated the impact and dynamic response of three different high-density polymeric structural foams; designated A, B and C for proprietary reasons. Foam-C had the lowest density out of the three; density of foam-B was approximately twice the density of foam-C, while the density of foam-A was about three times the density of foam-C. The cylindrical foam samples were initially impacted at different velocities in a DYNATUP Model 8250 instrumented impact test machine and their energy absorption was characterized from the resulting load–deflection data. Each of the three foams was then modeled as filler inside a circular steel tube of 0.8 mm thickness. Non-linear finite element analysis was performed under displacement controlled quasi-static compressive monotonic loading using PATRAN as pre-processor and ABAQUS Standard commercial software. The area under the load–deflection curve was calculated to obtain the absorbed energy and the crush loads for the three foam fillers were compared. Results indicate that foam-A having the highest density was more effective as filler inside the circular steel tube, with the intermediate density foam-B performing equally well under uni-axial compressive loading. Foam-C, which had the lowest density, was found to be ineffective as filler in this application due to large differences in stiffness between this foam and the enclosed steel tube.

A TA Instruments Model 983 DMA (dynamic mechanical analyzer) was used for obtaining the storage and loss modulus along with the damping and glass transition properties of the different density structural foams. Frequency multiplexing was also used in conjunction with the time–temperature superposition principle for characterizing the long-term behavior of these viscoelastic foams.     

Fabrication and mechanical testing of glass fiber entangled sandwich beams: A comparison with honeycomb and foam sandwich beams

The aim of this paper is the fabrication and mechanical testing of entangled sandwich beam specimens and the comparison of their results with standard sandwich specimens with honeycomb and foam as core materials. The entangled sandwich specimens have glass fiber cores and glass woven fabric as skin materials. The tested glass fiber entangled sandwich beams possess low compressive and shear modulus as compared to honeycomb and foam sandwich beams of the same specifications. Although the entangled sandwich beams are heavier than the honeycomb and foam sandwich beams, the vibration tests show that the entangled sandwich beams possess higher damping ratios and low vibratory levels as compared to honeycomb and foam sandwich beams, making them suitable for vibro-acoustic applications where structural strength is of secondary importance, e.g., internal paneling of a helicopter.     

Characterisation of aluminium matrix syntactic foams under drop weight impact

It is a challenging task to develop a lightweight, and at the same time, strong material with high energy absorption for applications in military vehicles, which are able to withstand impact and blast with minimum injury to occupants. This paper presents a study on aluminium matrix syntactic foams as a possible core material for a protection system on military vehicles. Experimental work was first carried out which covers sample preparation through pressure infiltration and impact tests on aluminium matrix syntactic foams manufactured. Numerical models were then developed using commercial finite element code ABAQUS/Explicit to simulate the dynamic behaviour of the foam. The effect of strain rate on their compressive behaviour was investigated as these properties are vital in terms of the applications of these materials. Characterisation of the foam behaviour under low velocity impact loading and an identification of the underlying failure mechanisms were also carried out to evaluate the effective mechanical performance. It was found that samples subjected to drop weight impact offered a 20–30% higher plateau stresses than those of the samples subjected to quasi-static compression loading. The degree of correlation between the numerical simulations and the experimental results has been shown to be reasonably good.     

聚氯乙烯市场分析及预测

综述了聚氯乙烯树脂国内外发展概况、国内产销平衡、进出口、“八五”发展情况。分析了国内聚氯乙烯制品生产、使用及发展前景,对1992年聚氯乙烯市场进行了预测并提出了调整建议     

空心玻璃微球含量对环氧复合泡沫塑料性能的影响

以空心玻璃微球（HGM）填充环氧树脂制备了密度为0.56~0.91 g/cm3的HGM/环氧复合泡沫塑料。研究了HGM含量对复合泡沫塑料黏度、力学性能、动态力学性能及隔热性能的影响。结果表明:表面偶联处理后增加了HGM的表面亲油性,改善了其与基体树脂间的相容性和界面性能,有利于HGM/环氧复合泡沫塑料性能的提高;体系黏度与HGM含量呈正相关,与温度呈负相关;随着HGM含量的增加,HGM/环氧复合泡沫塑料的压缩强度、弯曲强度和拉伸强度均有一定程度的降低,但是比强度变化不大,材料得到很大程度的轻质化;HGM的引入使得HGM/环氧复合泡沫塑料玻璃化转变温度向低温方向偏移,储能模量呈现先减小后增加的趋势,导热系数由纯环氧树脂的0.203 W/（m·K）减小到HGM含量为40wt%时的0.126 W/（m·K）。HGM/环氧复合泡沫塑料阻尼性能和隔热性能均有所提高。      

Si元素对碳纳米管增强铝基复合泡沫组织与性能的影响

针对金属基复合材料,添加合金元素是提升其综合性能的有效途径.本文通过高能球磨和填加造孔剂法,制备了添加Si元素的碳纳米管(CNTs)增强铝基(CNTs/Al-Si)复合泡沫,通过准静态压缩实验测试其压缩性能和吸能性能,进一步研究烧结温度和不同Si元素含量对CNTs/Al-Si复合泡沫微观组织、压缩性能和吸能性能的影响,...