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试验研究以纳米碳酸钙替代活性硅粉在NR/SBR内胎中的应用效果。结果表明,以纳米碳酸钙等量替代活性硅粉,胶料的综合物理性能有所提高;以25份纳米碳酸钙替代20份活性硅粉,可改善胶料的加工性能,提高内胎的拉断伸长率和撕裂强度,降低内胎胶成本,内胎气密性略有提高。 相似文献
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Preparation,structure, and properties of a novel rectorite/styrene–butadiene copolymer nanocomposite
Rectorite/styrene–butadiene copolymer (SBR) nanocomposite was prepared by cocoagulating SBR latex and rectorite/water suspension. Transmission electron microscopy showed that the layers of rectorite were well dispersed in the SBR matrix and the aspect ratio (width/thickness) of it was higher than that of montmorillonite (MMT). X‐ray diffraction indicated that the nanocomposite produced by this method was of neither intercalated type nor exfoliated type. The gas barrier properties and mechanical properties of the novel nanocomposites were excellent. The nanocomposites are expected to be candidates for tire tube or inner materials. Rectorite appears to be a promising filler for the nanocomposite. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 324–328, 2005 相似文献
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Jineesh Ayippadath Gopi Sanjay Kumar Patel Arup Kumar Chandra Deba Kumar Tripathy 《Journal of Polymer Research》2011,18(6):1625-1634
Styrene butadiene rubber-organoclay nanocomposites were prepared with Cloisite 15A via melt intercalation. X-ray diffraction
and transmission electron microscopy indicated that the nanostructures are partially exfoliated and intercalated. The nanocomposites
exhibited great improvements in tensile strength and tensile modulus. The incorporation of organoclay gave rise to considerable
reduction of tan delta and increase in storage modulus in the rubbery region. It is shown that after 6 phr (parts per hundred
rubber) clay loading there is not much increase in the properties. The effect of carbon black (N330) on mechanical properties,
dynamic mechanical properties, heat build up, abrasion resistance in the nanocomposites having the optimized clay level (6
phr) was investigated. Optimum results were obtained with the addition of 25 phr carbon black. For comparison with the 6phr
nanoclay and 25phr N330 (high abrasion furnace carbon black) filled SBR composites, 40 phr N330 filled SBR composites was
used. The 6phr organoclay and 25phr N330 filled SBR nanocomposite showed better properties than 40phr carbon filled SBR compound.
These results indicate that 6phr organoclay can be replaced by 15 phr carbon black from the conventional SBR-carbon black
based tire tread compounds. The Dynamic mechanical analyzer (DMA) results revealed that the new tire tread compound gives
better rolling resistance and comparable wet grip resistance and lower heat build up than that of conventional tread compound. 相似文献
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研究了莱茵新Rhenosin TT100时NR/BR/SBR胎面胶硫化特性、物理机械性能和发黑与其它配合剂在肢料中的分散性以度耐磨性能的影响。结果表明,谈助剂加入NR/BR/SBR配方中可以明显改善炭黑等配合剂在胶料中的分散性,提高挤出胎面肢断面的致密性,提高了撕裂性能、耐磨性。轮胎实际里程试验表明,采用2份Rhenosin TT100的胎冠肢的轮胎耐磨性优异。 相似文献
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Using industrial technologies, we prepared a sodium montmorillonite (Na‐MMT) slurry and an irradiated styrene–butadiene rubber (SBR) latex, and then spray dried them to produce a novel, ultrafine fully vulcanized powder SBR (UFPSBR)/Na‐MMT nanocompound powder in which the nanoscale UFPSBR particles and exfoliated Na‐MMT were isolated and stuck together. When the UFPSBR/Na‐MMT nanocompound powder was mixed with crude SBR, the exfoliated Na‐MMT was disorderly dispersed in the SBR matrix because of the carrier nature of the UFPSBR particle, which is compatible with SBR and disperses easily in the SBR matrix, and the SBR/UFPSBR/Na‐MMT ternary nanocomposite was prepared. When compared with SBR/Na‐MMT binary composites, the SBR/UFPSBR/Na‐MMT ternary nanocomposite has a shorter vulcanization time, higher strength, and better flame retardancy because of the good dispersion of exfoliated Na‐MMT in the SBR matrix with a Na‐MMT loading range of 4 phr. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2013 相似文献
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试验研究环保低味精细胎面再生胶在轿车子午线轮胎胎面胶中的应用。结果表明,在SBR/BR胎面胶中添加5份环保低味精细胎面再生胶,并适当提高硫化体系用量,胶料物理性能完全满足胎面胶性能要求,成品轮胎高速性能和耐久性能优良,生产成本降低。 相似文献
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The natural rubber/styrene butadiene rubber/organoclay (NR/SBR/organoclay) nanocomposites were successfully prepared with different types of organoclay by direct compounding. The optimal type of organoclay was selected by the mechanical properties characterization of the NR/SBR/organoclay composites. The series of NR/SBR/organoclay (the optimal organoclay) nanocomposites were prepared with various organoclay contents loading from 1.0 to 7.0 parts per hundreds of rubber (phr). The nearly completely exfoliated organoclay nanocomposites with uniform dispersion were confirmed by transmission electron microscopy (TEM) and X‐ray diffraction (XRD). The results of mechanical properties measurement showed that the tensile strength, tensile modulus, and tear strength were improved significantly when the organoclay content was less than 5.0 phr. The tensile strength and the tear strength of the nanocomposite with only 3.0 phr organoclay were improved by 92.8% and 63.4%, respectively. It showed organoclay has excellent reinforcement effect with low content. The reduction of the score and cure times of the composites indicated that the organoclay acted as accelerator in the process of vulcanization. The incorporation of a small amount of organoclay greatly improved the swelling behavior and thermal stability, which was attributed to the good barrier properties of the dispersed organoclay layers. The outstanding performance of co‐reinforcement system with organoclay in the tire formulation showed that the organoclay had a good application prospect in the tire industry, especially for the improvement of abrasion resistance and the reduction of production cost. © 2010 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
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The flammability of montmorillonite (MMT)/SBR nanocomposites, prepared by the technique of cocoagulating rubber latex and clay aqueous suspension, was investigated. Flammability studies, performed on the cone calorimeter, showed that the maximum heat release rate (HRR) of SBR decreased from 1987 to 1442 kw/m2 with the introduction of nanoclay (20 phr). This nanocomposite had the lowest mass loss rate and the largest amount of char upon combustion compared with conventional SBR composites with the same clay loading and pure SBR. The permeability properties of MMT/SBR composites were also measured. It was deduced that the lowered permeability was responsible for the reduced mass loss rate and hence the lower HRR. Unfortunately, the oxygen index (OI) of the nanocomposites was not as high as expected. Combination of Mg(OH)2 and clay was effective for the improvement of both mechanical properties and OI. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 97: 844–849, 2005 相似文献
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Homogeneous and stable dispersion of layered silicates in their rubber nanocomposite is a matter of interest as it can significantly affect the material properties. Herein we propose a facile and easily industrialised approach for preparing highly dispersed montmorillonite (MMT)/rubber nanocomposites by the latex compounding method. Furthermore, an efficient way of enhancing the interlayer spaces of organically modified MMT (f-MMT) with alkyl-ammonium chains while mixing the styrene butadiene rubber (SBR) is reported. The f-MMT embedded SBR matrix shows a remarkable improvement of the modulus and tensile strength even in the low loading rate, which is ascribed to the well dispersion of the f-MMT enhancing interfacial interaction with the rubber matrix. Furthermore, we manufactured the practical pneumatic tire using f-MMT/SBR nanocomposite with outstanding wear resistance, grip performance and low-rolling resistance for the green tire application, opening up enormous opportunities to prepare high-performance rubber composites for future engineering applications. 相似文献