Investigation of the optimal intermediate water temperature in a combined r134a and transcritical CO2 heat pump for space heating

In this paper, the effect of intermediate water temperature on the performance of a combined R134a and transcritical CO₂ heat pump was studied theoretically and experimentally. The mathematical model was first validated using experimental data and then applied to analyze the performance of the combined system. The results show that there exists an optimal intermediate water temperature (water inlet temperature at the gas cooler) at which the combined system has the highest COP. This optimal intermediate water temperature varies with the ambient air temperature. Furthermore, the effect of intermediate water temperature on individual R134a and transcritical CO₂ subsystems was investigated. The results show that both heating capacity and power consumption in the R134a subsystem increase as the intermediate water temperature increases. However, power consumption in the CO₂ system drops slightly, and heating capacity reaches an optimal value as the intermediate water temperature increases from 15 to 32 °C under ambient air temperatures ranging from −20 to 7 °C.     

Retrofit of lower GWP alternative R449A into an existing R404A indirect supermarket refrigeration system

R404A is going to be phased out from most of the commercial refrigeration systems due to its high GWP value of 3943. R449A (GWP of 1282) has been proposed to replace R404A with only minor system modifications in supermarkets. This paper presents the measurements of a light retrofit replacement of R404A using R449A in a medium temperature indirect refrigeration system (secondary fluid temperature at the evaporator outlet between −9 and −4 °C). It has been demonstrated that with a slight expansion device adjustment and 4% increase of refrigerant charge, R449A can be used in this refrigeration system designed for R404A because of its suitable thermodynamic properties and acceptable maximum discharge temperature. At a secondary fluid temperature at condenser inlet of 30 °C, the COP of R449A nearly matches that of R404A (both were between 1.9 and 2.2), despite having approximately 13% lower cooling capacity. As a conclusion, attending to the GWP reduction and similar energy performance, it was demonstrated using the TEWI methodology that the use of the recently developed refrigerant R449A in these applications can reduce the total CO₂ equivalent emissions of an indirect supermarket refrigeration system designed for R404A refrigerant.     

Comparative performance analysis of the low GWP refrigerants HFO1234yf,HFO1234ze(E) and HC600a inside a roll-bond evaporator

This paper presents the comparative performance analysis of the low GWP refrigerants HFO1234yf, HFO1234ze(E) and HC600a inside a commercial roll-bond evaporator for household refrigerators. The vaporisation performances were evaluated at two evaporation temperatures, −15 and −20 °C, and different refrigerant mass flow rates and compared with those of the traditional refrigerant for domestic refrigeration HFC134a. The performance analysis was carried out using both thermocouples installed on the rear side of the roll-bond evaporator and an IR thermo-camera. Each of the low GWP refrigerants tested can be considered a good substitute for HFC134a, provided that the compressor displacement is adjusted to deliver the proper refrigerant mass flow rate. Only HFO1234yf exhibits performance similar to HFC134a at the same mass flow rate, therefore it can be considered a direct drop-in substitute for HFC134a.     

Energy efficiency evaluation of integrated CO2 trans-critical system in supermarkets: A field measurements and modelling analysis

This paper investigates energy efficiency of an integrated CO₂ trans-critical booster system installed in a supermarket in Sweden. The supermarket has applied several features to improve energy efficiency including space and tap water heating, air conditioning (AC), and parallel compression.Using field measurement data, the system performance is evaluated in a warm and a cold month. Furthermore, this integrated energy system concept is modelled and compared with stand-alone HFC-based energy systems.The results show that the system provides the entire AC demands and recovers a great share of the available heat, both with high COP values. The comparative analysis shows that integrated CO₂ system uses about 11% less electricity than stand-alone HFC solutions for refrigeration (i.e. indirect HFC), heating and AC in North of Europe.Energy efficiency analysis of the integrated CO₂ system proves that this system is an environmentally friendly all-in-one energy efficient solution suitable for cold climate supermarkets.     

Performance comparison of absorption heating cycles using various low-GWP and natural refrigerants

Absorption heating is potential in building energy saving and emission reduction. To overcome the problems of conventional absorption working fluids and to explore more alternatives, absorption heating cycles using various low-GWP and natural refrigerants are compared. Property models of different working fluids have been chosen and developed with good accuracies. The models of single-effect and compression-assisted cycles are built with verified accuracies. Simulations revealed that H₂O–LiBr has the best heating performance, but is highly restricted by crystallization and freezing. NH₃–H₂O has good performance and wide applicable range, but has the concern of toxicity. Among the HFC-based fluids, R161-DMF has the highest COP of 1.448–1.496 when generation temperature is above 145 °C, 1.414–1.674 when evaporation temperature is above 8 °C, 1.745–1.409 when condensation temperature is below 52 °C, otherwise R152a-DMF performs the best. R134a-DMF has quite similar performance to R152a-DMF, while R32-DMF has the lowest COP in the whole temperature ranges. In the compression-assisted cycle, the minimum generation temperature can be reduced from 92–130 °C to 65–80 °C, and the minimum evaporation temperature can be reduced from −8 to 6 °C to −20 to −12 °C under a compression ratio of 2.0. Primary energy efficiency of R161-DMF can be increased to 1.146–1.327 under generation temperature of 65–130 °C, and to 1.117–1.330 under evaporation temperature of −10 to 10 °C.     

Comparative assessment of HFC134a and some refrigerants as alternatives to CFC12

A composite plot relating evaporating temperature T_EV, condensing temperature T_CO, pressure ratio (PR) and theoretical Rankine coefficient of performance (COP)_RR is presented for HFC134a. The theoretical performance of HFC134a has been comparatively assessed along with HCFC22, HFC134, HFC152a, HCFC124 and HCFC142b as alternatives to CFC12 by using the standard refrigeration parameters including pressure ratio, specific compressor displacement, theoretical Rankine coefficient of performance, shaft power per ton of refrigeration. A discussion of the practical implications of the choice of the alternatives to CFC12 is also presented.     

Bioactivity of calcium phosphate coatings prepared by electrodeposition in a modified simulated body fluid

The purpose of this study was to investigate bioactivity of calcium phosphate coatings prepared by electrodeposition in a modified simulated body fluid (SBF). Calcium phosphates were electrodeposited on commercially pure titanium substrates in the modified SBF at 60 °C for 1 h maintaining the cathodic potentials of − 1.5 V, − 2 V, and − 2.5 V (vs. SCE). Subsequently, the calcium phosphate coatings were transformed into apatites during immersion in the SBF at 36.5 °C for 5 days. The apatites consisted of needle-shaped crystallites distributed irregularly with different grain sizes. As the coatings were electrodeposited at higher cathodic potential, the crystallite of the apatites got denser and the grain sizes of the apatites became bigger during subsequent immersion in the SBF. However, as the coatings were electrodeposited at higher cathodic potential, the coatings were transformed into apatites with lower crystallinity and the Ca/P atomic ratio of the apatites got higher than 1.67, that of stoichiometric hydroxyapatite, after subsequent immersion in the SBF. In addition, CO₃²⁻ ions contained in the modified SBF were incorporated in the calcium phosphate coating during electrodeposition and had an influence on transforming the calcium phosphate into bonelike apatite during subsequent immersion in the SBF showing that CO₃²⁻ incorporated in the apatites disturbed crystallization of the apatites. These results revealed that the coating electrodeposited at − 2.0 V (vs. SCE) in the modified SBF containing CO₃²⁻ ions was the most bioactive showing transformation into carbonate apatite similar to bone apatite.     

Commercial refrigeration – An overview of current status

Commercial refrigeration comprises food freezing and conservation in retail stores and supermarkets, so, it is one of the most relevant energy consumption sectors, and its relevance is increasing. This paper reviews the most recent developments in commercial refrigeration available in literature and presents a good amount of results provided these systems, covering some advantages and disadvantages in systems and working fluids. Latest researches are focused on energy savings to reduce CO₂ indirect emissions due to the burning of fossil fuels. They are focused on system modifications (as dedicated subcooling or the implementation of ejectors), trigeneration technologies (electrical, heating and cooling demand) and better evaporation conditions control. Motivated by latest GWP regulations that are intended to reduce high GWP HFC emissions; R404A and R507 are going to phase out. Besides hydrocarbons and HFO, CO₂ appears as one of the most promising HFC replacements because its low contribution to global warming and high efficiencies when used in transcritical and low-stage of cascade systems.     

Blends of carbon dioxide and HFCs as working fluids for the low-temperature circuit in cascade refrigerating systems

This paper describes an analysis on the performances of a cascade refrigeration cycle operated with blends of carbon dioxide (CO₂, or R744) and hydrofluorocarbons (HFC) as the low-temperature working fluid. The aim of this work was to study the possibility of using carbon dioxide mixtures in those applications where temperatures below CO₂ triple point (216.58 K) are needed. The analysis was carried out by developing a software based on the Carnahan–Starling–De Santis (CSD) equation of state (EoS) using binary interaction parameters derived from our experimental data. The properties of the investigated blends (R744/R125, R744/R41, R744/R32, R744/R23) were used to simulate the behavior of a cascade cycle using ammonia (R717) as the high-temperature-circuit working fluid and operating at evaporating temperatures down to −70 °C. The use of a suction–liquid heat exchanger on the low-temperature side of the circuit was also investigated. Results show that the R744 blends are an attractive option for the low-temperature circuit of cascade systems operating at temperatures approaching 200 K.     

Experimental study of R450A drop-in performance in an R134a small capacity refrigeration unit

The Kigali amendment to the Montreal Protocol has highlighted the hydrofluorocarbons (HFCs) phase out as a priority to reduce the future global mean temperature increase. R134a is the most abundant HFC in the atmosphere and therefore it must be substituted using environmentally benign alternatives. In the short term, blends of HFCs and hydrofluoroolefins can replace R134a. This paper experimentally evaluates R450A (GWP of 547), a non-flammable mixture of R1234ze(E) and R134a, in an R134a small capacity refrigeration system. The controlled experimental conditions cover evaporating temperatures from −15 to 12.5 °C and condensing temperature of 25, 30 and 35 °C (36 tests in total for each refrigerant). The experimental results showed that with only a thermostatic expansion valve adjustment the average R450A cooling capacity and COP are 9.9% and 2.9% lower than those measured using R134a. Besides, the observed compressor discharge temperature values of R450A are not greater than that of R134a.     

Performance comparison between the combined R134a/CO2 heat pump and cascade R134a/CO2 heat pump for space heating

In this paper, the performance of combined R134a/CO₂ and cascade R134a/CO₂ systems for space heating was studied and compared under specific operating conditions. A mathematical model was developed for this purpose and was verified by experimental data. The effects of key parameters such as water feed temperature, water supply temperature and ambient temperature on the performance of the two systems were further investigated. Results showed that cascade and combined systems had different preferable application conditions. The cascade system performed better at low ambient temperatures while the combined system performed better under conditions of high ambient temperature and high hot water temperature differences between the system inlet and outlet. A correlation was established and an operating condition coefficient was proposed to determine which system should be used for any given set of working conditions.     

Itraconazole Formation Using Supercritical Carbon Dioxide

A new method of preparing Itraconazole (C₃₅H₃₈Cl₂N₈O₄), a synthetic triazole antifungal agent, was developed using supercritical carbon dioxide (SC CO₂) while eliminating the use of toxic solvents. Dissolution amounts of the product were measured in gastric fluid and compared to those of conventional drug formulations. Different operating conditions (five levels of treatment temperature ranging between 110–140°C, four levels of treatment pressure ranging between 30–400 atm, and four different treatment times ranging from 10–60 minutes) were tested in order to produce a desired Itraconazole product, which does not degrade during the product formation and has the highest extent of dissolution in gastric fluid after one hour. Itraconazole dissolution of 100% at one‐hour was achieved for the drug produced at the optimum treatment condition: 135°C, 300 atm, and 30 minutes. Extent of dissolution obtained from this solvent and detergent‐free process is 10% higher than that of the conventional method involving toxic organic solvents. Itraconazole produced using SC CO₂ should provide minimal side effects in human body.     

Experimental evaluation of a CO2 transcritical refrigeration plant with dedicated mechanical subcooling

CO₂ transcritical refrigeration cycles require optimization to reach the performance of conventional solutions at high ambient temperatures. Theoretical studies demonstrated that the combination of a transcritical cycle with a mechanical subcooling cycle improves its performance; however, any experimentation with CO₂ has been found. This work presents the energy improvements of the use of a mechanical subcooling cycle in combination with a CO₂ transcritical refrigeration plant, experimentally. It tested the combination of a R1234yf single-stage refrigeration cycle with a semihermetic compressor for the mechanical subcooling cycle, with a single-stage CO₂ transcritical refrigeration plant with a semihermetic compressor. The combination is evaluated at two evaporating levels of the CO₂ cycle (0 and −10 °C) and three heat rejection temperatures (24, 30 and 40 °C). The optimum operating conditions and capacity and COP improvements are analysed with maximum increments on capacity of 55.7% and 30.3% on COP.     

Customizing Metal-Organic Frameworks by Lego-Brick Strategy for One-Step Purification of Ethylene from a Quaternary Gas Mixture

One-step purification of ethylene (C₂H₄) from a quaternary gas mixture of C₂H₆/C₂H₄/C₂H₂/CO₂ by adsorption is a promising separation process, yet developing adsorbents that synergistically capture various gas impurities remains challenging. Herein, a Lego-brick strategy is proposed to customize pore chemistry in a unified framework material. The ethane-selective MOF platform is further modified with customized binding sites to specifically adsorb acetylene and carbon dioxide, thus one-step purification of C₂H₄ with high productivity of polymer-grade product (134 mol kg⁻¹) is achieved on the assembly of porous coordination polymer-2,5-furandicarboxylic acid (PCP-FDCA) and PCP-5-aminoisophthalic acid (IPA-NH₂). Computational studies verify that the low-polarity surface of this MOFs-based platform provides a delicate environment for C₂H₆ recognition, and the specific binding sites (FDCA and IPA-NH₂) exhibit favorable trapping of C₂H₂ and CO₂ via C H^δ+···O^δ− and C^δ+···N^δ− electrostatic interactions, respectively. The proposed Lego-brick strategy to customize binding sites within the MOFs structure provides new ideas for the design of adsorbents for compounded separation tasks.     

Effectiveness of modified atmosphere packaging in preserving a prepared ready‐to‐eat food

The effectiveness of modified atmosphere packaging (MAP) was evaluated for a combination prepared food (Korean braised green peppers with dry anchovies). From a preliminary storage test of the ready‐to‐eat dish at 10°C, the aerobic bacterial count on the green peppers was selected as a primary quality index. The effect of MAP with different CO₂ concentrations on the product quality at 10°C was also studied. MAP with a CO₂ concentration of ≥30% extended the lag time and/or reduced the growth rate of bacteria. Finally, the effect of different storage temperatures (5, 10, 15 or 20°C) on the shelf life of the product was investigated. Mathematical modelling of bacterial growth curves under stretch‐wrap air packaging and MAP with 60% CO₂/40% N₂ showed that MAP increased the hypothetical minimum temperature in the square root model that describes the temperature dependence of the lag time and growth rate. MAP conditions of 60% CO₂/40% N₂ extended the shelf life at 10°C by 130% (to 18.4 days) relative to that achieved with stretch‐wrap air packaging (7.9 days) based on the time taken to reach the quality limit of an aerobic bacterial count of 10⁵ CFU/g. The relative extension of shelf life achieved with MAP was greater at lower temperatures. Copyright © 2008 John Wiley & Sons, Ltd.     

The natural fluid nitrous oxide—an option as substitute for low temperature synthetic refrigerants

A theoretical investigation was performed concerning the coefficient of performance (COP) of cascade refrigerating systems using N₂O as refrigerant for the low temperature cascade stage and various natural refrigerants like ammonia, propane, propene, carbon dioxide and nitrous oxide itself for the high temperature stage. The basis of the comparison was a conventional R23/R134a-cascade refrigerating system for heat rejection temperatures of +55, +35 and +25 °C for air cooling, cooling tower water cooling and city water cooling, respectively. It can be stated that such an application of N₂O at the primary stage and ammonia or hydrocarbons as refrigerants at the secondary stage in refrigerating systems achieves similar COP-values compared to the R23/R134a-cascade refrigerating system, whereas CO₂ and N₂O in a transcritical cycle in general perform worse.An application of N₂O in a two-stage compression cycle with interstage injection and city water cooling at low and high interstage temperatures has a nearly equal COP as a conventional R23/R134a-cascade refrigerating system and is an interesting alternative for small laboratory refrigerating systems.     

Experimental assessment of R134a and its lower GWP alternative R513A

Lower GWP refrigerants are essential to mitigate the impact of refrigeration systems on climate change. HFO/HFC mixtures are currently considered to replace HFCs in refrigeration and air conditioning systems. The aim of this paper is to present the main operating and performance differences between R513A (GWP of 573) and R134a (GWP of 1300), the most used refrigerants for medium evaporation temperature refrigeration systems and mobile air conditioners. To perform the experimental comparison, 36 tests are carried out with each refrigerant at evaporating temperatures between −15 and 12.5°C and condensing temperatures between 25 and 35°C. The conclusion of the experimental comparison is that R513A can substitute R134a with only a thermostatic expansion valve adjustment, achieving better performance and higher cooling capacity. The discharge temperature of R513A is always lower than that of R134a.     

Energy improvements of CO2 transcritical refrigeration cycles using dedicated mechanical subcooling

In this work the possibilities of enhancing the energy performance of CO₂ transcritical refrigeration systems using a dedicated mechanical subcooling cycle are analysed theoretically. Using simplified models of the cycles, the modification of the optimum operating conditions of the CO₂ transcritical cycle by the use of the mechanical subcooling are analysed and discussed. Next, for the optimum conditions, the possibilities of improving the energy performance of the transcritical cycle with the mechanical subcooling are evaluated for three evaporating levels (5, −5 and −30 °C) for environment temperatures from 20 to 35 °C using propane as refrigerant for the subcooling cycle. It has been observed that the cycle combination will allow increasing the COP up to a maximum of 20% and the cooling capacity up to a maximum of 28.8%, being both increments higher at high evaporating levels. Furthermore, the results indicate that this cycle is more convenient for environment temperatures above 25 °C. Finally, the results using different refrigerants for the mechanical subcooling cycle are presented, where no important differences are observed.     

Comparitive analysis of an automotive air conditioning systems operating with CO2 and R134a

This paper evaluates performance merits of CO₂ and R134a automotive air conditioning systems using semi-theoretical cycle models. The R134a system had a current-production configuration, which consisted of a compressor, condenser, expansion device, and evaporator. The CO₂ system was additionally equipped with a liquid-line/suction-line heat exchanger. Using these two systems, an effort was made to derive an equitable comparison of performance; the components in both systems were equivalent and differences in thermodynamic and transport properties were accounted for in the simulations. The analysis showed R134a having a better COP than CO₂ with the COP disparity being dependent on compressor speed (system capacity) and ambient temperature. For a compressor speed of 1000 RPM, the COP of CO₂ was lower by 21% at 32.2°C and by 34% at 48.9°C. At higher speeds and ambient temperatures, the COP disparity was even greater. The entropy generation calculations indicated that the large entropy generation in the gas cooler was the primary cause for the lower performance of CO₂.     

R-407H as drop-in of R-404A. Experimental analysis in a low temperature direct expansion commercial refrigeration system

This work analyses experimentally the possibility of using the reduced GWP refrigerant R-407H (HFC family, GWP = 1378) as drop-in substitute of R-404A (HFC family, GWP = 3945) in low temperature centralized direct expansion refrigeration system. The experimental plant and the test methodology are described. It covered top up or partial drop-in and energy consumption tests at −20 °C of product temperature and 25, 35 and 45 °C of condensing temperature using a small-scale supermarket under laboratory conditions. It has been measured that the use of R-407H instead of R-404A is favourable from the point of view of energy efficiency. Reductions in the energy consumption of up to 7.7% (compressor) and 4.0% (whole system) have been measured. However, there is an increment in the compressor's discharge temperature of up to 13.8 K. In addition, the operation of the system with both refrigerants was correct.