Solar syngas production from CO2 and H2O in a two-step thermochemical cycle via Zn/ZnO redox reactions: Thermodynamic cycle analysis

Solar syngas production from CO₂ and H₂O is considered in a two-step thermochemical cycle via Zn/ZnO redox reactions, encompassing: 1) the ZnO thermolysis to Zn and O₂ using concentrated solar radiation as the source of process heat, and 2) Zn reacting with mixtures of H₂O and CO₂ yielding high-quality syngas (mainly H₂ and CO) and ZnO; the ZnO is recycled to the first, solar step, resulting in net reaction βCO₂ + (1 − β)H₂O → βCO + (1 − β)H₂. Syngas is further processed to liquid hydrocarbon fuels via Fischer-Tropsch or other catalytic processes. Second-law thermodynamic analysis is applied to determine the cycle efficiencies attainable with and without heat recuperation for varying molar fractions of CO₂:H₂O and solar reactor temperatures in the range 1900-2300 K. Considered is the energy penalty of using Ar dilution in the solar step below 2235 K for shifting the equilibrium to favor Zn production.     

Ultrasonic spray pyrolysis synthesis of Ag/TiO2 nanocomposite photocatalysts for simultaneous H2 production and CO2 reduction

Simultaneous photocatalytic hydrogen production and CO₂ reduction (to form CO and CH₄) from water using methanol as a hole scavenger were investigated using silver-modified TiO₂ (Ag/TiO₂) nanocomposite catalysts. A simple ultrasonic spray pyrolysis (SP) method was used to prepare mesoporous Ag/TiO₂ composite particles using TiO₂ (P25) and AgNO₃ as the precursors. The material properties and photocatalytic activities were compared with those prepared by a conventional wet-impregnation (WI) method. It was found that the samples prepared by the SP method had a larger specific surface area and a better dispersion of Ag nanoparticles on TiO₂ than those prepared by the WI method, and as a result, the SP samples showed much higher photocatalytic activities toward H₂ production and CO₂ reduction. The optimal Ag concentration on TiO₂ was found to be 2 wt%. The H₂ production rate of the 2% Ag/TiO₂–SP sample exhibited a six-fold enhancement compared with the 2% Ag/TiO₂–WI sample and a sixty-fold enhancement compared with bare TiO₂. The molar ratio of H₂ and CO in the final products can be tuned in the range from 2 to 10 by varying the reaction gas composition, suggesting a viable way of producing syngas (a mixture of H₂ and CO) from CO₂ and water using the prepared Ag/TiO₂ catalysts with energy input from the sun.     

Chemical effects of added CO2 on the extinction characteristics of H2/CO/CO2 syngas diffusion flames

Chemical effects of added CO₂ on flame extinction characteristics are numerically studied in H₂/CO syngas diffusion flames diluted with CO₂. The two representative syngas flames of 80% H₂ + 20% CO and 20% H₂ + 80% CO are inspected according to the composition of fuel mixture diluted with CO₂ and global strain rate. Particular concerns are focused on impact of chemical effects of added CO₂ on flame extinction characteristics through the comparison of the flame characteristics between well-burning flames far from extinction limit and flames at extinction. It is seen that chemical effects of added CO₂ reduce critical CO₂ mole fraction at flame extinction and thus extinguish the flame at higher flame temperature irrespective of global strain rate. This is attributed by the suppression of the reaction rate of the principal chain branching reaction through the augmented consumption of H-atom from the reaction CO₂ + H→CO + OH. As a result the overall reaction rate decreases. These chemical effects of added CO₂ are similar in both well-burning flames far from extinction limit and flames at extinction. There is a mismatching in the behaviors between critical CO₂ mole fraction and maximum flame temperature at extinction. This anomalous phenomenon is also discussed in detail.     

CO2 and H2O reduction by solar thermochemical looping using SnO2/SnO redox reactions: Thermogravimetric analysis

The thermochemical dissociation of CO₂ and H₂O from reactive SnO nanopowders is studied via thermogravimetry analysis. SnO is first produced by solar thermal dissociation of SnO₂ using concentrated solar radiation as the high-temperature energy source. The process targets the production of CO and H₂ in separate reactions using SnO as the oxygen carrier and the syngas can be further processed to various synthetic liquid fuels. The global process thus converts and upgrades H₂O and captured CO₂ feedstock into solar chemical fuels from high-temperature solar heat only, since the intermediate oxide is not consumed but recycled in the overall process. The objective of the study was the kinetic characterization of the H₂O and CO₂ reduction reactions using reactive SnO nanopowders synthesized in a high-temperature solar chemical reactor. SnO conversion up to 88% was measured during H₂O reduction at 973 K and an activation energy of 51 ± 7 kJ/mol was identified in the temperature range of 798-923 K. Regarding CO₂ reduction, a higher temperature was required to reach similar SnO conversion (88% at 1073 K) and the activation energy was found to be 88 ± 7 kJ/mol in the range of 973-1173 K with a CO₂ reaction order of 0.96. The SnO conversion and the reaction rate were improved when increasing the temperature or the reacting gas mole fraction. Using active SnO nanopowders thus allowed for efficient and rapid fuel production kinetics from H₂O and CO₂.     

Comparative study on the effect of CO2 and H2O dilution on laminar burning characteristics of CO/H2/air mixtures

A study on the effect of CO₂ and H₂O dilution on the laminar burning characteristics of CO/H₂/air mixtures was conducted at elevated pressures using spherically expanding flames and CHEMKIN package. Experimental conditions for the CO₂ and H₂O diluted CO/H₂/air/mixtures of hydrogen fraction in syngas from 0.2 to 0.8 are the pressures from 0.1 to 0.3 MPa, initial temperature of 373 K, with CO₂ or H₂O dilution ratios from 0 to 0.15. Laminar burning velocities of the CO₂ and H₂O diluted CO/H₂/air/mixtures were measured and calculated using the mechanism of Davis et al. and the mechanism of Li et al. Results show that the discrepancy exists between the measured values and the simulated ones using both Davis and Li mechanisms. The discrepancy shows different trends under CO₂ and H₂O dilution. Chemical kinetics analysis indicates that the elementary reaction corresponding to peak ROP of OH consumption for mixtures with CO/H₂ ratio of 20/80 changes from reaction R3 (OH + H₂ = H + H₂O) to R16 (HO₂+H = OH + OH) when CO₂ and H₂O are added. Sensitivity analysis was conducted to find out the dominant reaction when CO₂ and H₂O are added. Laminar burning velocities and kinetics analysis indicate that CO₂ has a stronger chemical effect than H₂O. The intrinsic flame instability is promoted at atmospheric pressure and is suppressed at elevated pressure for the CO₂ and H₂O diluted mixtures. This phenomenon was interpreted with the parameters of the effective Lewis number, thermal expansion ratio, flame thickness and linear theory.     

Controllable proton and CO2 photoreduction over Cu2O with various morphologies

Simultaneous photocatalytic reduction of water to H₂ and CO₂ to CO was observed over Cu₂O photocatalyst under both full arc and visible light irradiation (>420 nm). It was found that the photocatalytic reduction preference shifts from H₂ (water splitting) to CO (CO₂ reduction) by controlling the exposed facets of Cu₂O. More interestingly, the low index facets of Cu₂O exhibit higher activity for CO₂ photoreduction than high index facets, which is different from the widely-reported in which the facets with high Miller indices would show higher photoactivity. Improved CO conversion yield could be further achieved by coupling the Cu₂O with RuO_x to form a heterojunction which slows down fast charge recombination and relatively stabilises the Cu₂O photocatalyst. The RuO_x amount was also optimised to maximise the junction's photoactivity.     

Investigation of novel mixed metal ferrites for pure H2 and CO2 production using chemical looping

The mixed metal oxides NiFe₂O₄ and CoFe₂O₄ are candidate materials for the Chemical Looping Hydrogen (CLH) process, which produces pure and separate streams of H₂ and CO₂ without the use of complicated and expensive separations equipment. In the CLH process, syngas reduces a metal oxide, oxidizing the H₂ and CO in the syngas to H₂O and CO₂, and “stores” the chemical energy of the syngas in the reduced metal oxide. The reduced metal oxide is then oxidized in steam to regenerate the original metal oxide and produce H₂. In this study, we report thermodynamic modeling and experimental results regarding the syngas reduction and H₂O oxidation of NiFe₂O₄ and CoFe₂O₄ to determine the feasibility of their use in the CLH process. Modeling predicts the oxidation of nearly all the CO and H₂ in syngas to H₂O and CO₂ during the reduction step for both materials, and regeneration of the mixed metal spinel phase during oxidation with excess H₂O. Laboratory tests in a packed bed reactor confirmed over 99% conversion of H₂ and CO to H₂O and CO₂ during reduction of NiFe₂O₄ and CoFe₂O₄. Powder XRD analysis of the reduced materials showed, in accordance with thermodynamic predictions, the presence of a spinel phase and a metallic phase. High reactivity of the reduced NiFe₂O₄ and CoFe₂O₄ with H₂O was observed, and XRD analysis confirmed re-oxidation to NiFe₂O₄ and CoFe₂O₄ under the conditions tested. When compared with a conventional Fe-based CLH material, the mixed metal spinels showed a higher extent of reduction under the same conditions, and produced four times the H₂ per mass of active material than the Fe-based material. Analysis of the H₂ and CO consumed in the reduction and the H₂ produced during the oxidation showed over 90% conversion of the H₂ and CO in syngas back to H₂ during oxidation.     

Laminar burning velocities and flame stability analysis of H2/CO/air mixtures with dilution of N2 and CO2

Experimental measurement of the laminar burning velocities of H₂/CO/air mixtures and equimolar H₂/CO mixtures diluted with N₂ and CO₂ up to 60% and 20% by volume, respectively, were conducted at different equivalence ratios and conditions near to the sea level, 0.95 atm and 303 ± 2 K. Flames were generated using contoured slot-type nozzle burners and Schlieren images were used to determine the laminar burning velocity with the angle method. Numerical calculations were also conducted using the most recent detailed reaction mechanisms for comparison with the present experimental results. Additionally, a study was conducted to analyze the flame stability phenomenology that was found in the present experiments. The increase in the N₂ and CO₂ dilution fractions considerably reduced the laminar burning velocity due to the decrease in heat release and increase in heat capacity. At the same dilution fractions this effect was higher for the case of CO₂ due to its higher heat capacity and dissociation effects during combustion. Flame instabilities were observed at lean conditions. While the presence of CO in the fuel mixture tends to stabilize the flame, H₂ has a destabilizing effect which is the most dominant. A higher N₂ and CO₂ dilution fraction increased the range of equivalence ratios where unstable flames were obtained due to the increase in the thermal-diffusive instabilities.     

Role of CO2 in the CH4 oxidation and H2 formation during fuel-rich combustion in O2/CO2 environments

The effect of CO₂ reactivity on CH₄ oxidation and H₂ formation in fuel-rich O₂/CO₂ combustion where the concentrations of reactants were high was studied by a CH₄ flat flame experiment, detailed chemical analysis, and a pulverized coal combustion experiment. In the CH₄ flat flame experiment, the residual CH₄ and formed H₂ in fuel-rich O₂/CO₂ combustion were significantly lower than those formed in air combustion, whereas the amount of CO formed in fuel-rich O₂/CO₂ combustion was noticeably higher than that in air. In addition to this experiment, calculations were performed using CHEMKIN-PRO. They generally agreed with the experimental results and showed that CO₂ reactivity, mainly expressed by the reaction CO₂ + H → CO + OH (R1), caused the differences between air and O₂/CO₂ combustion under fuel-rich condition. R1 was able to advance without oxygen. And, OH radicals were more active than H radicals in the hydrocarbon oxidation in the specific temperature range. It was shown that the role of CO₂ was to advance CH₄ oxidation during fuel-rich O₂/CO₂ combustion. Under fuel-rich combustion, H₂ was mainly produced when the hydrocarbon reacted with H radicals. However, the hydrocarbon also reacted with the OH radicals, leading to H₂O production. In fact, these hydrocarbon reactions were competitive. With increasing H/OH ratio, H₂ formed more easily; however, CO₂ reactivity reduced the H/OH ratio by converting H to OH. Moreover, the OH radicals reacted with H₂, whereas the H radicals did not reduce H₂. It was shown that OH radicals formed by CO₂ reactivity were not suitable for H₂ formation. As for pulverized coal combustion, the tendencies of CH₄, CO, and H₂ formation in pulverized coal combustion were almost the same as those in the CH₄ flat flame.     

缺陷态Bi2MoO6光热催化CO2和H2O还原成CO的性能

在不同温度下采用乙二醇溶剂热合成法合成Bi₂MoO₆催化剂(BMO-x,x=140、160、180),BMO-160在450℃下煅烧的样品为BMO。用XRD、BET、SEM、EDS、UV-visDRS、XPS、in-situ DRIFTS等表征方法研究其理化特性,建立BMO和BMO-x(x=140、160、180)催化剂的反应性能与孔道结构、材料形貌和缺陷空位的构效关系。结果表明,适宜的溶剂合成温度可以形成更高的孔隙率,调控氧空位的占比,有助于产生更好的催化性能。其中,BMO-160的CO产率更高,这是由于在160℃溶剂热合成温度下制备的样品形貌更优,氧空位占比适中。     

Influence of CO2, CH4, and initial temperature on H2/CO laminar flame speed

The objective of this study is to investigate the impact of syngas composition by varying the H₂/CO ratio (1:3, 1:1, and 3:1 by volume), the CO₂ dilution (0%–40%), and methane addition (0%–40%) on laminar flame speed. Thus, laminar flame speeds of premixed syngas–air mixtures were measured for different equivalence ratios (0.8–2.2) and inlet temperatures (295–450 K) using the Bunsen-burner method. It was found that laminar flame speed increases with increasing H₂/CO ratio, while CO₂ dilution or CH₄ addition decreased it. The location of the maximum flame speed shifts to richer mixtures with decreasing H₂/CO ratio, while it shifts to leaner mixtures with the addition of CH₄ due to its inherent slower flame speed. The location of the maximum flame speed is also shifted towards leaner mixtures with the addition of CO₂ due to the preponderance of the reduction of the adiabatic flame temperature with increasing dilution. Comparison between experimental and numerical results shows a better agreement using a modified mechanism derived from GRI-Mech 3.0. A correlation, based on the experimental results, is proposed to calculate the laminar flame speed over a wide range of equivalence ratios, inlet temperatures, and fuel content.     

Hydrogen production from coal gasification for effective downstream CO2 capture

The coal gasification process is used in commercial production of synthetic gas as a means toward clean use of coal. The conversion of solid coal into a gaseous phase creates opportunities to produce more energy forms than electricity (which is the case in coal combustion systems) and to separate CO₂ in an effective manner for sequestration. The current work compares the energy and exergy efficiencies of an integrated coal-gasification combined-cycle power generation system with that of coal gasification-based hydrogen production system which uses water-gas shift and membrane reactors. Results suggest that the syngas-to-hydrogen (H₂) system offers 35% higher energy and 17% higher exergy efficiencies than the syngas-to-electricity (IGCC) system. The specific CO₂ emission from the hydrogen system was 5% lower than IGCC system. The Brayton cycle in the IGCC system draws much nitrogen after combustion along with CO₂. Thus CO₂ capture and compression become difficult due to the large volume of gases involved, unlike the hydrogen system which has 80% less nitrogen in its exhaust stream. The extra electrical power consumption for compressing the exhaust gases to store CO₂ is above 70% for the IGCC system but is only 4.5% for the H₂ system. Overall the syngas-to-hydrogen system appears advantageous to the IGCC system based on the current analysis.     

Preferential oxidation of CO in H2 stream on Au/CeO2–TiO2 catalysts

A series of Au catalysts supported on CeO₂–TiO₂ with various CeO₂ contents were prepared. CeO₂–TiO₂ was prepared by incipient-wetness impregnation with aqueous solution of Ce(NO₃)₃ on TiO₂. Gold catalysts were prepared by deposition–precipitation method at pH 7 and 65 °C. The catalysts were characterized by XRD, TEM and XPS. The preferential oxidation of CO in hydrogen stream was carried out in a fixed bed reactor. The catalyst mainly had metallic gold species and small amount of oxidic Au species. The average gold particle size was 2.5 nm. Adding suitable amount of CeO₂ on Au/TiO₂ catalyst could enhance CO oxidation and suppress H₂ oxidation at high reaction temperature (>50 °C). Additives such as La₂O₃, Co₃O₄ and CuO were added to Au/CeO₂–TiO₂ catalyst and tested for the preferential oxidation of CO in hydrogen stream. The addition of CuO on Au/CeO₂–TiO₂ catalyst increased the CO conversion and CO selectivity effectively. Au/CuO–CeO₂–TiO₂ with molar ratio of Cu:Ce:Ti = 0.5:1:9 demonstrated very high CO conversion when the temperature was higher than 65 °C and the CO selectivity also improved substantially. Thus the additive CuO along with the promoter and amorphous oxide ceria and titania not only enhances the electronic interaction, but also stabilizes the nanosize gold particles and thereby enhancing the catalytic activity for PROX reaction to a greater extent.     

Catalytic conversion of CH4 and CO2 to synthesis gas on Ni/SiO2 catalysts containing Gd2O3 promoter

A series of Ni/SiO₂ catalysts containing different amounts of Gd₂O₃ promoter was prepared, characterized by H₂-adsorption and XRD, and used for carbon dioxide reforming of methane (CRM) and methane autothermal reforming with CO₂ + O₂ (MATR) in a fluidized-bed reactor. The results of pulse surface reactions showed that Ni/SiO₂ catalysts containing Gd₂O₃ promoter could increase the activity for CH₄ decomposition, and Raman analysis confirmed that reactive carbon species mainly formed on the Ni/SiO₂ catalysts containing Gd₂O₃ promoter. In this work, it was found that methane activation and reforming reactions proceeded according to different mechanisms after Gd₂O₃ addition due to the formation of carbonate species. In addition, Ni/SiO₂ catalysts containing Gd₂O₃ promoter demonstrated higher activity and stability in both CRM and MATR reactions in a fluidized bed reactor than Ni/SiO₂ catalysts without Gd₂O₃ even at a higher space velocity.     

Integrated fossil fuel and solar thermal systems for hydrogen production and CO2 mitigation

In most current fossil-based hydrogen production methods, the thermal energy required by the endothermic processes of hydrogen production cycles is supplied by the combustion of a portion of the same fossil fuel feedstock. This increases the fossil fuel consumption and greenhouse gas emissions. This paper analyzes the thermodynamics of several typical fossil fuel-based hydrogen production methods such as steam methane reforming, coal gasification, methane dissociation, and off-gas reforming, to quantify the potential savings of fossil fuels and CO₂ emissions associated with the thermal energy requirement. Then matching the heat quality and quantity by solar thermal energy for different processes is examined. It is concluded that steam generation and superheating by solar energy for the supply of gaseous reactants to the hydrogen production cycles is particularly attractive due to the engineering maturity and simplicity. It is also concluded that steam-methane reforming may have fewer engineering challenges because of its single-phase reaction, if the endothermic reaction enthalpy of syngas production step (CO and H₂) of coal gasification and steam methane reforming is provided by solar thermal energy. Various solar thermal energy based reactors are discussed for different types of production cycles as well.     

Catalytic CO2 reforming of CH4 over Cr-promoted Ni/char for H2 production

The objective of the study is to investigate the catalytic performance of Cr-promoted Ni/char in CO₂ reforming of CH₄ at 850 °C. The char obtained from the pyrolysis of a long-flame coal at 1000 °C was used as the support. The catalysts were prepared by incipient wetness impregnation methods with different metal precursor doping sequence. The characterization of the composite catalysts was evaluated by XRD, XPS, SEM-EDS, TEM, H₂-TPR, CO₂-TPD, CH₄-TPSR, and CO₂-TPO. The results indicate that the catalyst prepared by co-impregnation of Ni and Cr possess higher activity than those by sequential impregnation. The optimal loading of Cr on 5 wt% Ni/char is 7.8 wt‰. Moreover, the molar feed ratio of CH₄/CO₂ has a considerable effect on both the stability and the activity of Cr–Ni/char. The main effect of Cr is the great enhance of the adsorption to CO₂. It is interesting that the conversions of CH₄ and CO₂ over Cr-promoted Ni/char and Ni/char decrease initially, following by a steady rise as the reaction proceeds with time-on-stream (TOS). In addition, cyclic tests were conducted and no distinct deterioration in the catalytic performance of the catalysts was observed. On the basis of the obtained results, nickel carbide was speculated to be the active species which was formed during the CO₂ reforming of CH₄ reaction.     

An oxy-fuel mass-recirculating process for H2 production with CO2 capture by autothermal catalytic oxyforming of methane

A new oxy-fuel H₂ generation process with CO₂ avoidance is provided. The process utilizes mass recirculation of CO and H₂O to the oxyforming reactor. A comparison between non-recirculating and mass-recirculating oxyforming reactor operation is given. Main benefits of mass recirculation are emphasized. The oxyforming reactor is integrated with the H₂ and CO₂ separators, fuel cell and O₂ generator. In the process C/O is equal to 0.5 while C/H determines the temperature level in the reactor. The reaction system includes combustion, steam reforming and water–gas shift reactions. The oxyforming process is found to be mass transport controlled with O₂ as the limiting reactant. It is emphasized that under MR conditions the decomposition of H₂/CO₂ by water–gas shift reaction is suppressed by means of CO/H₂O-enrichment and hence MR conditions allow for higher temperatures beneficial to endothermic steam reforming reaction. Under MR conditions the thermodynamic equilibrium limits are overcome and all reactions are forced to proceed to the completion which enables 100% selectivities to H₂ and CO₂. The effects of operation parameters such as temperature, flow rate, pressure and composition are examined. The derived S-terms enable for the concise interpretation of the effect of pressure on the concentration gradients transverse to the flow. The consistent control algorithm of the oxyforming reactor is provided.     

High capacity potassium-promoted hydrotalcite for CO2 capture in H2 production

This paper presents an experimental study for a newly modified K₂CO₃-promoted hydrotalcite material as a novel high capacity sorbent for in-situ CO₂ capture. The sorbent is employed in the sorption enhanced steam reforming process for an efficient H₂ production at low temperature (400–500 ^°C). A new set of adsorption data is reported for CO₂ adsorption over K-hydrotalcite at 400 °C. The equilibrium sorption data obtained from a column apparatus can be adequately described by a Freundlich isotherm. The sorbent shows fast adsorption rates and attains a relatively high sorption capacity of 0.95 mol/kg on the fresh sorbent. CO₂ desorption experiments are conducted to examine the effect of humidity content in the gas purge and the regeneration time on CO₂ desorption rates. A large portion of CO₂ is easily recovered in the first few minutes of a desorption cycle due to a fast desorption step, which is associated with a physi/chemisorption step on the monolayer surface of the fresh sorbent. The complete recovery of CO₂ was then achieved in a slower desorption step associated with a reversible chemisorption in a multi-layer surface of the sorbent. The sorbent shows a loss of 8% of its fresh capacity due to an irreversible chemisorption, however, it preserves a stable working capacity of about 0.89 mol/kg, suggesting a reversible chemisorption process. The sorbent also presents a good cyclic thermal stability in the temperature range of 400–500 °C.     

Solar energy powered Rankine cycle using supercritical CO2

A solar energy powered Rankine cycle using supercritical CO₂ for combined production of electricity and thermal energy is proposed. The proposed system consists of evacuated solar collectors, power generating turbine, high-temperature heat recovery system, low-temperature heat recovery system, and feed pump. The system utilizes evacuated solar collectors to convert CO₂ into high-temperature supercritical state, used to drive a turbine and thereby produce mechanical energy and hence electricity. The system also recovers heat (high-temperature heat and low-temperature heat), which could be used for refrigeration, air conditioning, hot water supply, etc. in domestic or commercial buildings. An experimental prototype has been designed and constructed. The prototype system has been tested under typical summer conditions in Kyoto, Japan; It was found that CO₂ is efficiently converted into high-temperature supercritical state, of while electricity and hot water can be generated. The experimental results show that the solar energy powered Rankine cycle using CO₂ works stably in a trans-critical region. The estimated power generation efficiency is 0.25 and heat recovery efficiency is 0.65. This study shows the potential of the application of the solar-powered Rankine cycle using supercritical CO₂.     

Experimental study on the performance of solar Rankine system using supercritical CO2

An experimental study is carried out to investigate the performance of a solar Rankine system using supercritical CO₂ as a working fluid. The testing machine of the solar Rankine system consists of an evacuated solar collector, a pressure relief valve, heat exchangers and CO₂ feed pump, etc. The solar energy powered system can provide electricity output as well as heat supply/refrigeration, etc. The system performance is evaluated based on daily, monthly and yearly experiment data. The results obtained show that heat collection efficiency for the CO₂-based solar collector is measured at 65.0–70.0%. The power generation efficiency is found at 8.78–9.45%, which is higher than the value 8.20% of a solar cell. The result presents a potential future for the solar powered CO₂ Rankine system to be used as distributed energy supply system for buildings or others.