共查询到20条相似文献,搜索用时 31 毫秒
1.
Haijun Yu Xiaoyi Xu Xuesi Chen Tiancheng Lu Peibiao Zhang Xiabin Jing 《应用聚合物科学杂志》2007,103(1):125-133
The poly(vinyl alcohol)/poly(N‐vinyl pyrrolidone) (PVA–PVP) hydrogels containing silver nanoparticles were prepared by repeated freezing–thawing treatment. The silver content in the solid composition was in the range of 0.1–1.0 wt %, the silver particle size was from 20 to 100 nm, and the weight ratio of PVA to PVP was 70 : 30. The influence of silver nanoparticles on the properties of PVA–PVP matrix was investigated by differential scanning calorimeter, infrared spectroscopy and UV–vis spectroscopy, using PVA–PVP films containing silver particles as a model. The morphology of freeze‐dried PVA–PVP hydrogel matrix and dispersion of the silver nanoparticles in the matrix was examined by scanning electron microscopy. It was found that a three‐dimensional structure was formed during the process of freezing–thawing treatment and no serious aggregation of the silver nanoparticles occurred. Water absorption properties, release of silver ions from the hydrogels and the antibacterial effects of the hydrogels against Escherichia coli and Staphylococcus aureus were examined too. It was proved that the nanosilver‐containing hydrogels had an excellent antibacterial ability. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 125–133, 2007 相似文献
2.
Mahnaz Shahverdi Bahareh Baheri Mashallah Rezakazemi Elahe Motaee Toraj Mohammadi 《Polymer Engineering and Science》2013,53(7):1487-1493
Poly(vinyl alcohol) (PVA)/zeolite 4A mixed matrix composite membranes supported on polypropylene microfiltration membranes were prepared by solution casting method and crosslinked with glutaraldehyde to investigate their pervaporation (PV) separation properties of water–ethylene glycol mixtures. Scanning electron microscopy images showed homogeneous distribution of zeolite nanoparticles within the polymer matrix without any visible macroscopic voids at the zeolite–polymer interface. The PV experiments were accomplished to investigate the effects of water concentration (10–40 wt%) and temperature (60–80°C) on separation performance of the membranes. It was found out that 5 wt% loading of the 4A nanoparticles into the PVA matrix is optimal to obtain the best separation performance. The experimental results revealed that loading of zeolite 4A enhanced the membrane performance [both permeation flux (5%) and separation factor (32%) at 5 wt% zeolite loading]. POLYM. ENG. SCI., 2013. © 2012 Society of Plastics Engineers 相似文献
3.
Modified poly(vinyl alcohol)/chitosan blended membranes for isopropanol dehydration via pervaporation: Synthesis optimization and modeling by response surface methodology
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Box–Behnken (BB) design of response surface methodology (RSM) was effectively applied to optimize fabrication conditions of modified poly(vinyl alcohol) (PVA) and chitosan (CS) blended pervaporation (PV) membranes. The PVA/CS membranes were crosslinked either by chemical reaction with glutaraldehyde (GA) or by heat‐treating at different temperatures. The main objectives were to determine the optimal levels of fabricating parameters and also to investigate interactions among the variables. CS content in the blended membranes, concentration of crosslinking agent and heat‐treating temperature were the fabrication parameters, the main effects and interaction effects of which on membrane structure and PV performance toward isopropanol (IPA)/water dehydration were investigated, and for which regression models were established. The modified PVA/CS blended membranes were characterized by means of scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) as well as X‐ray diffraction (XRD). It was found that the CS content is the most significant factor influencing flux and separation factor among the three studied variables and the experimental results are in excellent accordance with predicted values from the developed RSM regression models. The RSM results indicated that under preparation conditions of 80 wt % CS in the blended membrane, 0.58 wt % GA concentration, and 77 °C heat‐treating temperature, the maximum separation factor of 5222.8 and the normalized flux of 9.407 kg µm/m2h can be acquired with feed content of 85 wt % IPA at 25 °C, showing that the prepared membrane is highly efficient for PV dehydration of IPA. The models were satisfactorily validated against experimental data. Furthermore, the optimum membrane presents excellent separation performance at different feed compositions and temperatures. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134, 44587. 相似文献
4.
Yang Zhang Ying Wan Yuanteng Shi Guoyuan Pan Hao Yan Jian Xu Min Guo Longxin Qin Yiqun Liu 《Journal of Polymer Research》2016,23(5):105
This study focuses on the modification of a commercial nanofiltration (NF) membrane by an in-situ reaction to load silver nanoparticles (AgNPs) for anti-biofouling. Poly (vinyl alcohol) (PVA) was coated onto the NF membrane firstly, and silver salt was then deposited on the surface of PVA layer. Through thermal reduction, AgNPs with 10–20 nm in diameter were formed and immobilized onto the membrane surface by the interaction between AgNPs and PVA, as confirmed by UV–vis absorption spectrum, SEM and XPS analysis. Compared to the pristine NF90 membrane, the PVA composite membranes (NF90-PVA) and AgNPs (NF90-PVA-AgNPs) modified membranes exhibit lower water flux and slightly higher salt rejection. Release of silver ion experiments were assessed via batch method, and the results indicate silver ion can be released from the AgNPs modified membrane continuously and steadily, which may be responsible for the improved and long-time antibacterial ability of the membrane. Due to the simplicity of the method, the ability to immobilize the AgNPs to avoid leaching out, and the strong antibacterial activity, this NF90-PVA-AgNPs composite membrane displays potential applications in industrial water-treatment. 相似文献
5.
Asmaa Selim Andras Jozsef Toth Daniel Fozer Eniko Haaz Nóra Valentínyi Tibor Nagy Orsolya Keri Lászlo Péter Bakos Imre Miklós Szilágyi Peter Mizsey 《中国化学工程学报》2019,27(7):1595-1607
Pervaporation is an important membrane separation method of chemical engineering. In this work,silver-nanoparticles-poly(vinyl alcohol) nanocomposite membranes(AgNPs-PVA) are produced for the sake of improving its potentials for pervaporation of ethanol–water mixture so that the usual opposite trend between membrane selectivity and permeation can be reduced. The nanocomposite membranes are fabricated from an aqueous solution of poly(vinyl alcohol) with silver nanoparticles via the in-situ generation technique in the absence of any reducing agent. Successful generation of the nano size silver is measured by the UV–vis spectrum showing a single peak at 419 nm due to the plasmonic effect of silver nanoparticles. Our nanocomposite AgNPs-PVA membranes are characterized using scanning electron microscope(SEM), Fourier-transform infrared(FT-IR) spectroscopy, X-ray diffraction and thermogravimetric analysis(TGA). The pervaporation tests of our new AgNPs-PVA membranes show good results since at a higher temperature and higher ethanol concentration in the feed, the prepared membranes are highly permeable for the water having stable selectivity values and therefore our membranes show better performance compared to that of the other PVA-based nanocomposite membranes. 相似文献
6.
Using Na+ form of perfluorosulfonic acid (PFSA) and poly(vinyl alcohol) (PVA) as coating materials, polysulfone (PSf) hollow fiber ultrafiltration membrane as a substrate membrane, PFSA‐PVA/PSf hollow fiber composite membrane was fabricated by dip‐coating method. The membranes were post‐treated by two methods of heat treatment and by both heat treatment and chemical crosslinking. Maleic anhydride (MAC) aqueous solution was used as chemical crosslinking agent using 0.5 wt % H2SO4 as a catalyst. PFSA‐PVA/PSf hollow fiber composite membranes were used for the pervaporation (PV) separation of isopropanol (IPA)/H2O mixture. Based on the experimental results, PFSA‐PVA/PSf hollow fiber composite membrane is suitable for the PV dehydration of IPA/H2O solution. With the increment of heat treatment temperature, the separation factor increased and the total permeation flux decreased. The addition of PVA in PFSA‐PVA coating solution was favorable for the improvement of the separation factor of the composite membranes post‐treated by heat treatment. Compared with the membranes by heat treatment, the separation factors of the composite membranes post‐treated by both heat treatment and chemical crosslinking were evidently improved and reached to be about 520 for 95/5 IPA/water. The membranes post‐treated by heat had some cracks which disappeared after chemical crosslinking for a proper time. Effects of feed temperature on PV performance had some differences for the membranes with different composition of coating layer. The composite membranes with the higher mass fraction of PVA in PFSA‐PVA coating solution were more sensitive to temperature. It was concluded that the proper preparation conditions for the composite membranes were as follows: firstly, heated at 160°C for 1 h, then chemical crosslinking at 40°C for 3 h in 4% MAC aqueous solution. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
7.
Zeolitic imidazolate frameworks (ZIF‐8) nanoparticles were successfully synthesized and embedded into a chitosan (CS) polymeric matrix to prepare CS/ZIF‐8 mixed‐matrix membranes (MMMs) in order to investigate the effect of ZIF‐8 addition as novel filler on the dehydration performance of the CS polymeric membrane. MMMs were evaluated using pervaporation (PV) dehydration of isopropanol (IPA). The synthesized ZIF‐8 nanoparticles and MMMs were characterized by X‐ray diffraction, scanning electron microscopy, energy‐dispersive X‐ray spectroscopy, Fourier transform infrared spectroscopy, and a swelling study. The PV performance of the prepared MMMs with different ZIF‐8 loadings for IPA dehydration was investigated. For the ZIF‐8/CS MMMs, at the optimum loading the total flux increases significantly with low separation factor reduction. The good PV performance of the ZIF‐8‐incorporated CS membranes for dehydration of IPA is demonstrated. 相似文献
8.
Zhanbin Wang Jiahao Liu Houchao Shan Guozhen Li Ze Wang Zhihao Si Di Cai Peiyong Qin 《应用聚合物科学杂志》2020,137(42):49308
In this study, Schiff base network (SNW)-1 nanoparticles with high hydrophilicity and large specific surface area were used to prepare polyvinyl alcohol (PVA)-based mixed matrix membranes (MMMs), which were evaluated for ethanol dehydration. Because of the low difference of density between SNW-1 and PVA, the as-prepared nanoparticles can be uniformly distributed into the PVA active layer. The effects of SNW-1 loading, feed temperature, and water concentration on pervaporation (PV) performance were further studied. The results showed the MMM with 10 wt% of SNW-1 loading exhibited a separation factor of 1,501 and a permeation flux of 187 g m−2 h−1 for feeding 95 wt% ethanol/water binary solution at 75°C. Overall, the SNW-1/PVA MMMs showed great prospect in ethanol dehydration via PV. 相似文献
9.
B. Vijaya Kumar Naidu S. D. Bhat M. Sairam A. C. Wali D. P. Sawant S. B. Halligudi N. N. Mallikarjuna T. M. Aminabhavi 《应用聚合物科学杂志》2005,96(5):1968-1978
The pervaporation (PV) separation performance of ZSM‐5‐ and Na‐Y‐type zeolite‐filled sodium alginate (NaAlg) membranes were compared with those of pure NaAlg and semi‐interpenetrating polymer network (semi‐IPN) membranes of poly(vinyl alcohol) (PVA) with polyaniline (PANI) for the dehydration of acetonitrile. The PV separation characteristics of the zeolite‐filled membranes showed a dependence on the nature of the zeolites. The variation of the acidity function of the ZSM‐5 zeolite had an influence on the flux and selectivity of the membranes when compared to unfilled membranes. The crosslinked membranes were characterized by differential scanning calorimetry, X‐ray diffraction, scanning electron microscopy, and Fourier transform infrared spectroscopy. Increasing the PANI content of the semi‐IPN network increased the separation selectivity. Among the NaAlg membranes, the plain NaAlg membrane showed the highest selectivity of 414 at 30 mass % water in the feed mixture, whereas the Na‐Y‐ and ZSM‐5 (40)‐filled NaAlg membranes exhibited much lower values of selectivity, that is, 7.3 and 4.3, respectively for 30 mass % water in the feed. When the flux and selectivity data of ZSM‐5 (250)‐filled NaAlg membranes were compared with that of Na‐Y‐ or ZSM‐5 (40)‐filled NaAlg membranes, a noticeable increase in the selectivity for the ZSM‐5 (250)‐filled NaAlg membrane was observed, but a somewhat comparable flux was observed compared to the plain NaAlg membrane. For the first time, PANI was polymerized with PVA to yield a semi‐IPN. The total flux and water flux increased systematically, whereas the selectivity decreased greatly from 251.87 to 5.95 with increasing amounts of water in the feed. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 96: 1968–1978, 2005 相似文献
10.
Poly(vinyl alcohol) (PVA) blended with poly(ethylene glycol) (PEG) was crosslinked with tetraethoxysilane (TEOS) to prepare organic–inorganic PVA/PEG/TEOS hybrid membranes. The membranes were then used for the dehydration of ethanol by pervaporation (PV). The physicochemical structure of the hybrid membranes was studied with Fourier transform infrared spectra (FT‐IR), wide‐angle X‐ray diffraction WXRD, and scanning electron microscopy (SEM). PVA and PEG were crosslinked with TEOS, and the crosslinking density increased with increases in the TEOS content, annealing temperature, and time. The water permselectivity of the hybrid membranes increased with increasing annealing temperature or time; however, the permeation fluxes decreased at the same time. SEM pictures showed that phase separation took place in the hybrid membranes when the TEOS content was greater than 15 wt %. The water permselectivity increased with the addition of TEOS and reached the maximum at 10 wt % TEOS. The water permselectivity decreased, whereas the permeation flux increased, with an increase in the feed water content or feed temperature. The hybrid membrane that was annealed at 130°C for 12 h exhibited high permselectivity with a separation factor of 300 and a permeation flux of 0.046 kg m?2 h?1 in PV of 15 wt % water in ethanol. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 2007 相似文献
11.
Srikant S. Kulkarni Arjumand A. Kittur Mrityunjaya I. Aralaguppi Mahadevappa Y. Kariduraganavar 《应用聚合物科学杂志》2004,94(3):1304-1315
Hybrid membranes were prepared using poly(vinyl alcohol) (PVA) and tetraethylorthosilicate (TEOS) via hydrolysis and cocondensation reaction for the pervaporation separation of water‐isopropanol mixtures. The resulting membranes were characterized by Fourier transform infrared spectroscopy, wide‐angle X‐ray diffraction, and differential scanning calorimetry. The glass transition temperature of these membranes varied from 100 to 120°C with increasing TEOS content. Effects of crosslinking density and feed compositions on the pervaporation performances of the membranes were studied. The membrane containing 1.5:1 mass ratio of TEOS to PVA gave the highest separation selectivity of 900 at 30°C for 10 mass % of water in the feed mixture. It was found that the separation selectivity and permeation flux data are strongly dependent on the water composition of the feed and operating temperature. However, the membrane with the highest crosslinking density showed unusual pervaporation properties. The overall activation energy values were calculated using the Arrhenius‐type equation. The activation energy values for the permeation and diffusion varied from 49.18 to 64.96 and 55.13 to 67.31 kJ/mol, respectively. Pervaporation data have also been explained on the basis of thermodynamic quantities. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 94: 1304–1315, 2004 相似文献
12.
Polyacrylamide‐grafted sodium alginate (PAAm‐g‐Na‐Alg) copolymeric membranes have been prepared, characterized, and used in the pervaporation separation of 10–80 mass % water‐containing tetrahydrofuran mixtures. Totally three membranes were prepared: (1) neat Na‐Alg with 10 mass % of polyethylene glycol (PEG) and 5 mass % of polyvinyl alcohol (PVA), (2) 46 % grafted PAAm‐g‐Na‐Alg membrane containing 10 mass % of PEG and 5 mass % of PVA, and (3) 93 % grafted PAAm‐g‐Na‐Alg membrane containing 10 mass % of PEG and 5 mass % of PVA. Using the transport data, important parameters like permeation flux, selectivity, pervaporation separation index, swelling index, and diffusion coefficient have been calculated at 30°C. Diffusion coefficients were also calculated from sorption gravimetric data of water–tetrahydrofuran mixtures using Fick's equation. Arrhenius activation parameters for the transport processes were calculated for 10 mass % of water in the feed mixture using flux and diffusion data obtained at 30, 35, and 40°C. The separation selectivity of the membranes ranged between 216 and 591. The highest permeation flux of 0.677 kg/m2 h was observed for 93% grafted membrane at 80 mass % of water in the feed mixture. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 272–281, 2002 相似文献
13.
Saeedeh RazaviAnahid Sabetghadam Toraj Mohammadi 《Chemical Engineering Research and Design》2011,89(2):148-155
In the present work, dehydration of isopropanol was investigated by novel organic-inorganic nanocomposite membranes which were prepared through sol-gel reaction of polyvinyl alcohol (PVA) with γ-aminopropyl-triethoxysilane (APTEOS) and tetraethoxysilane (TEOS). The PVA chains were crosslinked by mixing silane coupling agents. This reaction between polymer chains and silanols agents could control degree of swelling of the nanocomposite membranes in aqueous isopropanol (IPA) solutions. The membranes were characterized by SEM and ATIR. Effects of APTEOS content in the membranes, feed concentration and temperature on pervaporation (PV) performance were investigated. It was found out that separation factor and permeation flux increase with increasing APTEOS content in the membranes. Arrhenius-type relationship was used for describing the temperature dependence of permeation flux. It was also found out that separation factor decreases with increasing temperature. 相似文献
14.
Mukund G. Mali Veeresh T. Magalad Gavisiddappa S. Gokavi Tejraj M. Aminabhavi K. V. S. N. Raju 《应用聚合物科学杂志》2011,121(2):711-719
Mixed matrix membranes of poly(vinyl alcohol) and poly(vinyl pyrrilidone) blends were prepared by loading with phosphomolybdic acid (PMA) and their pervaporation (PV) properties were investigated for the PV separation of isopropanol. Membrane performance shown a dependence on the extent of PMA loading. The 4 wt % PMA‐loaded blend membrane had the highest separation factor of 29991, which declined considerably at higher loading. The flux of 4 wt % PMA‐loaded membrane was lower than that of nascent blend membrane. Feed water composition and temperature influenced the PV performance. Solubility selectivity was higher than diffusion selectivity. Degree of swelling was smaller after PMA loading exhibiting better separation ability. The PV results were analyzed using the Flory‐Huggins theory and sorption was dominated by Langmuir's mode. © 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2011 相似文献
15.
Fumed SiO2 nanoparticle reinforced biopolymer blend nanocomposites with high dielectric constant and low dielectric loss for flexible organic electronics
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Kalim Deshmukh M. Basheer Ahamed Kishor Kumar Sadasivuni Deepalekshmi Ponnamma Mariam Al‐Ali AlMaadeed Rajendra R. Deshmukh S. K. Khadheer Pasha Anji Reddy Polu K. Chidambaram 《应用聚合物科学杂志》2017,134(5)
In the present study, fumed silica (SiO2) nanoparticle reinforced poly(vinyl alcohol) (PVA) and poly(vinylpyrrolidone) (PVP) blend nanocomposite films were prepared via a simple solution‐blending technique. Fourier transform infrared spectroscopy (FTIR), ultraviolet–visible spectroscopy (UV–vis), X‐ray diffraction (XRD), and scanning electron microscopy (SEM) were employed to elucidate the successful incorporation of SiO2 nanoparticles in the PVA/PVP blend matrix. A thermogravimetric analyzer was used to evaluate the thermal stability of the nanocomposites. The dielectric properties such as dielectric constant (?) and dielectric loss (tan δ) of the PVA/PVP/SiO2 nanocomposite films were evaluated in the broadband frequency range of 10?2 Hz to 20 MHz and for temperatures in the range 40–150 °C. The FTIR and UV–vis spectroscopy results implied the presence of hydrogen bonding interaction between SiO2 and the PVA/PVP blend matrix. The XRD and SEM results revealed that SiO2 nanoparticles were uniformly dispersed in the PVA/PVP blend matrix. The dielectric property analysis revealed that the dielectric constant values of the nanocomposites are higher than those of PVA/PVP blends. The maximum dielectric constant and the dielectric loss were 125 (10?2 Hz, 150 °C) and 1.1 (10?2 Hz, 70 °C), respectively, for PVA/PVP/SiO2 nanocomposites with 25 wt % SiO2 content. These results enable the preparation of dielectric nanocomposites using a facile solution‐casting method that exhibit the desirable dielectric performance for flexible organic electronics. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 44427. 相似文献
16.
Biplab Bhowmick Dibyendu Mondal Dipanwita Maity Md. Masud Rahaman Mollick Mrinal Kanti Bain Nirmal Kumar Bera Dipak Rana Sanatan Chattopadhyay Dipankar Chattopadhyay 《应用聚合物科学杂志》2013,129(6):3551-3557
Polyaniline (PANI)‐Ag nanocomposites were synthesized by in situ chemical polymerization approach using ammonium persulfate and silver nitrate as oxidant. Characterizations of nanocomposites were done by ultraviolet–visible ( UV–vis), Fourier transform infrared (FTIR), X‐ray diffraction (XRD), scanning electron microscopy, and transmission electron microscopy (TEM). UV–vis, XRD and FTIR analysis established the formation of PANI/Ag nanocomposites and face‐centered‐cubic phase of silver. PANInanofibers were of average diameter ~ 30 nm and several micrometers in length. Morphological analysis showed that the spherical‐shaped silver nanoparticles decorate the surface of PANI nanofibers. Silver nanoparticles of average diameter ~ 5–10 nm were observed on the TEM images for the PANI‐Ag nanocomposites. Such type of PANI‐Ag nanocomposites can be used as bistable switches as well as memory devices. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci., 2013 相似文献
17.
Poly(ether sulfone) supported hybrid poly(vinyl alcohol)–maleic acid–silicone dioxide membranes for the pervaporation separation of ethanol–water mixtures
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Microporous poly(ether sulfone) (PES) supported hybrid polymer–inorganic membranes were prepared by the crosslinking of poly(vinyl alcohol) (PVA), maleic acid (MA), and SiO2 via an aqueous sol–gel route and a solution‐casting method. The membrane performance was tested for the pervaporation separation of ethanol–water mixtures from 20 to 60 °C with a feed ethanol concentration of 96 wt %. The membrane characterization results reveal that different SiO2 loadings affected the crystallinity and roughness of the membranes. The PVA–MA–SiO2 membrane containing 10 wt % SiO2 showed that SiO2 nanoparticles were well dispersed within the polymer matrix; this resulted in significant enhancements in both the flux and selectivity. The membrane achieved a high water permeability of 1202 g·μm·m?2 h?1 kPa?1 and a selectivity of 1027 for the separation of a 96 wt % ethanol‐containing aqueous solution. This enhanced membrane performance might have been due to the dense crosslinking membrane network, increased free volume, and uniform distribution of SiO2 nanoparticles. Both the water and ethanol fluxes increased with the feed water concentration and temperature. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 44839. 相似文献
18.
Poly(vinyl alcohol) as well as its grafted copolymer membranes with polyacrylonitrile (PAN‐g‐PVA) were prepared and used to separate water and dimethyl formamide mixtures by the pervaporation technique. The three following membranes were prepared: (1) pure PVA; (2) 46% grafted PAN‐g‐PVA; and (3) 93% grafted PAN‐g‐PVA. Pervaporation separation experiments were carried out at 25°C for the feed mixture containing 10 to 90% water. By use of the transport data, permeation flux, separation selectivity, swelling index, and diffusion coefficients have been calculated. By increasing the grafting of the membrane, flux decreased, whereas separation selectivity increased slightly over that of pure PVA membrane. Arrhenius activation parameters for transport processes were calculated for 10 mass % water containing feed mixture by using flux and diffusion data obtained at 25, 35, and 45°C. Transport parameters were discussed in terms of sorption‐diffusion principles. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 4091–4097, 2004 相似文献
19.
The pervaporation separation of water–isopropanol mixtures was carried out using carboxymethylated poly(vinyl alcohol) (CMPVA) composite membranes. Carboxymethylated PVA (CMPVA) was synthesized by reacting PVA with various concentrations of monochloroacetic acid. Substitution efficiency of the CMPVA ranged from 12–32%. The cross‐sectional structure of the composite membrane for pervaporation was confirmed by scanning electron microscopy (SEM) exhibiting a 20‐μm active skin layer. Glass transition temperature of the CMPVA was in the range of 74–84°C, and decreased with increasing substitution efficiency. Degree of swelling and permeation flux for water–isopropanol in pervaporation increased with the substitution degree of carboxymethylation. CMPVA composite membrane, having 16% substitution efficiency, showed the following pervaporation performance; permeation flux of 831 g/m2 h and separation factor of 362 measured at 80°C and 85 wt % feed isopropanol concentration. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 72: 241–249, 1999 相似文献
20.
In this study, silver nanoparticles were prepared by the reduction of silver nitrate in SDS+ isopentanol/styrene/H2O reverse microemulsion system using sodium citrate as reducing agent. The Ag/PS nanocomposite particles were prepared by in situ emulsion polymerization of the styrene system containing silver nanoparticles that did not separate from the reaction solution. The polymerization dynamic characteristic was studied, at the same time, silver nanparticles and the encapsulation of composite particles were characterized by Fourier‐transform‐infrared spectroscopy (FTIR), transmission electron microscopy (TEM), X‐ray diffraction (XRD) measurement, UV–vis diffuse reflectance spectroscopy, and X‐ray photoelectron spectroscopy (XPS). The results of TEM and UV–vis absorption spectra showed that well‐dispersed silver nanoparticles have a narrow size distribution. XRD showed that Ag and Ag/PS nanocomposite particles were less than 10 and 20 nm in size, which is similar to those observed by TEM. The results of XPS spectra revealed that the microemulsion system can stabilize the silver nanoparticles from aggregation and provided supporting evidence for the polystyrene encapsulated silver nanoparticle structure. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci, 2008. 相似文献