共查询到18条相似文献,搜索用时 156 毫秒
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用淀粉糊对白炭黑进行改性得到碳化淀粉包覆改性白炭黑,将其填充乳聚丁苯橡胶(SBR),制得改性白炭黑/SBR复合材料,考察了淀粉含量对SBR混炼胶硫化特性、白炭黑在橡胶中的分散性及复合材料物理机械性能、耐磨性能、抗湿滑性、滚动阻力的影响。结果表明,随着淀粉含量的增加,SBR混炼胶的加工性能提高,白炭黑在橡胶中的分散性能得到改善,耐磨性能下降,抗湿滑性能基本不变; 当淀粉质量分数为5.0%时,改性白炭黑/SBR复合材料的物理机械性能最佳; 当淀粉质量分数为10.0%时,复合材料在应变小于10%时的滚动阻力高于未改性白炭黑/SBR复合材料。 相似文献
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研究反式丁戊橡胶(TBIR)对天然橡胶(NR)/丁苯橡胶(SBR)并用胶性能的影响。结果表明:用15份TBIR替代NR,NR/SBR/TBIR并用胶的NR与SBR相容性改善,拉伸强度和定伸应力略有降低,耐磨性能、耐压缩疲劳性能和耐屈挠疲劳性能提高;用15份TBIR替代SBR,NR/SBR/TBIR并用胶的NR与SBR相容性明显改善,拉伸性能变化不大,耐磨性能、耐压缩疲劳性能和耐屈挠疲劳性能提高;用15份TBIR替代NR/SBR并用胶,NR/SBR/TBIR并用胶的大部分性能介于TBIR单独替代NR与SBR并用胶的性能之间,抗湿滑性能提高,滚动阻力降低;在NR/SBR并用胶中直接加入6份TBIR,NR/SBR/TBIR并用胶的NR与SBR相容性改善,耐磨性能、耐压缩疲劳性能和耐屈挠疲劳性能提高,抗湿滑性能和滚动阻力降低。 相似文献
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采用伊蒙粘土替代部分炭黑,研究伊蒙粘土用量对伊蒙粘土/炭黑/天然橡胶复合材料硫化特性、物理性能、动态力学性能和导热性能的影响。结果表明:随着伊蒙粘土用量增大,混炼胶的Payne效应减弱,最大转矩减小,正硫化时间缩短;硫化胶的耐热老化性能、气密性、抗冲击性能提高;添加5和7份伊蒙粘土的硫化胶物理性能和耐磨性能与未添加伊蒙粘土的硫化胶相当,且明显好于添加10和15份伊蒙粘土的硫化胶;伊蒙粘土可明显提高硫化胶的抗湿滑性能、减小滚动阻力。 相似文献
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采用乳液共混法,用少量淀粉等量替代炭黑,制备淀粉/炭黑/丁苯橡胶(SBR)复合材料,研究了淀粉用量对复合材料抗疲劳性能的影响。结果表明,当丁苯胶乳为100份、炭黑与淀粉的总量为50份时,淀粉最佳替代量为5~8份,在此条件下复合材料的抗疲劳性能大幅度提高;淀粉/炭黑/SBR复合材料的抗疲劳性能与硫化胶的抗切割性能、裤形撕裂强度以及损耗因子有一定的相关性。 相似文献
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淀粉/SBR复合材料的吸水性对力学性能的影响 总被引:4,自引:1,他引:4
研究了淀粉/SBR复合材料以及淀粉/炭黑/SBR复合材料常温下浸水90d时吸水率和静态力学性能的变化,研究结果表明:淀粉用量增加,复合材料的吸水率增加;含20份淀粉的淀粉/SBR复合材料以及淀粉/炭黑/SBR复合材料在常温下浸水90d后,吸水率分别为8.5%和7.5%;淀粉的用量在20份范围内,随着材料浸水时间的延长,淀粉/炭黑/SBR复合材料的力学性能与纯SBR硫化胶和炭黑/SBR复合材料力学性能变化的趋势一致。材料的力学性能浸水30d内有所波动,当浸水至90d时,与未浸水时的相差不大。 相似文献
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固相法改性淀粉/炭黑/丁苯橡胶复合材料的制备与性能研究 总被引:1,自引:0,他引:1
采用固相法制备了淀粉接枝马来酸酐(MAH)和丙烯酸丁酯(BA)的共聚物Starch-gMAH/BA(SMB)。采用机械共混法用15phr的改性淀粉(SMB)代替等量的炭黑(CB),制备了改性淀粉/炭黑/丁苯橡胶复合材料(SMt3/CB/SBR),研究了复合材料的力学性能、热氧老化性能、动态力学性能以及微观形态。结果表明,SMB/CB/SBR复合材料的力学性能优于未改性淀粉/CB/SBR复合材料,拉伸强度及扯断伸长率等性能优于SBR/CB复合材料;且SMB/CB/SBR复合材料具有更好的耐热氧老化性能;与SBR/CB复合材料相比,SMB/CB/SBR复合材料具有更低的滚动阻力;微观形态显示,淀粉经改性后粒子尺寸减小,在SBR基体中的分散性得到改善,与SBR基体的相容性得到提高。 相似文献
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The influence of starch on the properties of carbon‐black‐filled styrene–butadiene rubber (SBR) composites was investigated. When the starch particles were directly melt‐mixed into rubber, the stress at 300% elongation and abrasion resistance decreased evidently with increasing starch amount from 5 to 20 phr. Scanning electron microscopy observations of the abrasion surface showed that some apparent craters of starch particles were left on the surface of the composite, which strongly suggested that the starch particles were large and that interfacial adhesion between the starch and rubber was relatively weak. To improve the dispersion of the starch in the rubber matrix, starch/SBR master batches were prepared by a latex compounding method. Compared with the direct mixing of the starch particles into rubber, the incorporation of starch/SBR master batches improved the abrasion resistance of the starch/carbon black/SBR composites. With starch/SBR master batches, no holes of starch particles were left on the surface; this suggested that the interfacial strength was improved because of the fine dispersion of starch. Dynamic mechanical thermal analysis showed that the loss factor at both 0 and 60°C increased with increasing amount of starch at a small tensile deformation of 0.1%, whereas at a large tensile strain of 5%, the loss factor at 60°C decreased when the starch amount was varied from 5 to 20 phr. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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Jineesh Ayippadath Gopi Sanjay Kumar Patel Arup Kumar Chandra Deba Kumar Tripathy 《Journal of Polymer Research》2011,18(6):1625-1634
Styrene butadiene rubber-organoclay nanocomposites were prepared with Cloisite 15A via melt intercalation. X-ray diffraction
and transmission electron microscopy indicated that the nanostructures are partially exfoliated and intercalated. The nanocomposites
exhibited great improvements in tensile strength and tensile modulus. The incorporation of organoclay gave rise to considerable
reduction of tan delta and increase in storage modulus in the rubbery region. It is shown that after 6 phr (parts per hundred
rubber) clay loading there is not much increase in the properties. The effect of carbon black (N330) on mechanical properties,
dynamic mechanical properties, heat build up, abrasion resistance in the nanocomposites having the optimized clay level (6
phr) was investigated. Optimum results were obtained with the addition of 25 phr carbon black. For comparison with the 6phr
nanoclay and 25phr N330 (high abrasion furnace carbon black) filled SBR composites, 40 phr N330 filled SBR composites was
used. The 6phr organoclay and 25phr N330 filled SBR nanocomposite showed better properties than 40phr carbon filled SBR compound.
These results indicate that 6phr organoclay can be replaced by 15 phr carbon black from the conventional SBR-carbon black
based tire tread compounds. The Dynamic mechanical analyzer (DMA) results revealed that the new tire tread compound gives
better rolling resistance and comparable wet grip resistance and lower heat build up than that of conventional tread compound. 相似文献