Thermal performance analysis of an electrochromic vacuum glazing with low emittance coatings

Thermal performance of an electrochromic (EC) vacuum glazing (VG) was modelled under ASTM standard winter conditions. The EC VG comprised three 0.5 m by 0.5 m glass panes with a 0.12 mm wide evacuated space between two 4 mm thick panes sealed contiguously by a 6 mm wide indium based edge seal with either one or two low-emittance (low-e) coatings supported by a 0.32 mm diameter square pillar grid spaced at 25 mm. The third glass pane on which the 0.1 mm thick EC layer was deposited was sealed to the evacuated glass unit. The whole unit was rebated by 10 mm within a solid wood frame. The low-e coating absorbed 10% of solar energy incident on it. With the EC VG installed with the EC component facing the outdoor environment, for an incident solar radiation of 300 W m⁻², simulations demonstrated that when the EC layer is opaque for winter conditions, the temperature of the inside glass pane is higher than the indoor air temperature, due to solar radiation absorbed by the low-e coatings and the EC layer, the EC VG is a heat source with heat transferred from the glazing to the interior environment. When the emittance was lower to 0.02, the outdoor and indoor glass pane temperatures of the glazing with single and two low-e coatings are very close to each other. For an insolation of 1000 W m⁻², the outdoor glass pane temperature exceeds the indoor glass pane temperature, consequentially the outdoor glass pane transfers heat to the indoor glass pane.     

Predicted thermal performance of triple vacuum glazing

The simulated triple vacuum glazing (TVG) consists of three 4 mm thick glass panes with two vacuum gaps, with each internal glass surface coated with a low-emittance coating with an emittance of 0.03. The two vacuum gaps are sealed by an indium based sealant and separated by a stainless steel pillar array with a height of 0.12 mm and a pillar diameter of 0.3 mm spaced at 25 mm. The thermal transmission at the centre-of-glazing area of the TVG was predicted to be 0.26 W m⁻² K⁻¹. The simulation results show that although the thermal conductivity of solder glass (1 W m⁻¹ K⁻¹) and indium (83.7 W m⁻¹ K⁻¹) are very different, the difference in thermal transmission of TVGs resulting from the use of an indium and a solder glass edge seal was 0.01 W m⁻² K⁻¹. This is because the edge seal is so thin (0.12 mm), consequently there is a negligible temperature drop across it irrespective of the material that the seal is made from relative to the total temperature difference across the glazing. The results also show that there is a relatively large increase in the overall thermal conductance of glazings without a frame when the width of the indium edge seal is increased. Increasing the rebate depth in a solid wood frame decreased the heat transmission of the TVG. The overall heat transmission of the simulated 0.5 m by 0.5 m TVG was 32.6% greater than that of the 1 m by 1 m TVG, since heat conduction through the edge seal of the small glazing has a larger contribution to the total glazing heat transfer than that of the larger glazing system.     

Low emittance coatings and the thermal performance of vacuum glazing

The thermal performances of vacuum glazings employing coatings with emittance between 0.02 and 0.16 were simulated using a three-dimensional finite volume model. Physical samples of vacuum glazings with hard and soft coatings with emittance of 0.04, 0.12 and 0.16 were fabricated and their thermal performance characterised experimentally using a guarded hot box calorimeter. Good agreement was found between experimental and theoretical thermal performances for both a vacuum glazing with a soft coating (emittance 0.04) and those with hard coatings (emittance 0.12 and 0.16). Simulations showed that for a low value of emittance (e.g. 0.02), the use of two low-emittance coatings gives limited improvement in thermal performance of the glazing system. The use of a single high performance low-emittance coating in a vacuum glazing has been shown to provide excellent performance.     

Comparison of vacuum glazing thermal performance predicted using two- and three-dimensional models and their experimental validation

Thermal performance of vacuum glazing predicted by using two-dimensional (2-D) finite element and three-dimensional (3-D) finite volume models are presented. In the 2-D model, the vacuum space, including the pillar arrays, was represented by a material whose effective thermal conductivity was determined from the specified vacuum space width, the heat conduction through the pillar array and the calculated radiation heat transfer between the two interior glass surfaces within the vacuum gap. In the 3-D model, the support pillar array was incorporated and modelled within the glazing unit directly. The predicted difference in overall heat transfer coefficients between the two models for the vacuum window simulated was less than 3%. A guarded hot box calorimeter was used to determine the experimental thermal performance of vacuum glazing. The experimentally determined overall heat transfer coefficient and temperature profiles along the central line of the vacuum glazing are in very good agreement with the predictions made using the 2-D and 3-D models.     

Effect of glass thickness on the thermal performance of evacuated glazing

Flat evacuated glazing consists of two plane glass panes separated by a narrow internal evacuated space. Separation in the space is maintained by an array of support pillars typically 0.32 mm in diameter and 0.12 mm high arranged on a regular square grid with an inter-pillar separation of up to 40 mm. A detailed three-dimensional finite volume model has been employed to determine the variation of thermal performance of an evacuated glazing as a function of glass pane thickness. It was predicted that for evacuated glazing of dimensions of 0.3 m by 0.3 m and 0.5 m by 0.5 m, reducing glass pane thickness gave improved thermal performance. For evacuated glazings with dimensions of 1 m by 1 m, the opposite was predicted.     

The effect of glass coating emittance and frame rebate on heat transfer through vacuum and electrochromic vacuum glazed windows

The thermal performance of an electrochromic vacuum glazing and a vacuum glazing with a range of low-emittance coatings and frame rebate depths were simulated for insolations between 0 and 1000 W m⁻² using a three-dimensional finite volume model. The vacuum glazing simulated comprised two 0.4 m×0.4 m glass panes separated by a 0.12 mm wide evacuated space supported by a 0.32 mm diameter pillar array spaced at 25 mm. The two glass sheets were sealed contiguously by a 6 mm wide metal edge seal and had either one or two low-emittance coatings. For the electrochromic vacuum glazing, a third glass pane on which an electrochromic layer was deposited was assumed to be sealed to an evacuated glass unit, to enable control of visible light transmittance and solar gain and thus improve occupant thermal comfort. It is shown that for both vacuum glazing and electrochromic vacuum glazings, when the coating emittance value is very low (close to 0.02), the use of two low-emittance coatings only gives limited improvement in glazing performance. The use of a single currently expensive low-emittance coating in both systems provided acceptable performance. Deeper frame rebate depths gave significant improvements in thermal performance for both glazing systems.     

Environmental assessment of electrochromic glazing production

The life cycle analysis method was used to determine the environmental impacts associated with the production of an electrochromic (EC) glazing (called ECD). This paper describes the inventory analysis for all the basic materials used during the manufacture of the ECD, i.e. K-Glass, tungsten oxide (WO₃), poly-methyl methacrylate (PMMA), propylene carbonate (PC), lithium perchlorate (LiClO₄) and acetic silicone sealant. K-Glass, PC and PMMA account for the 98% of the total device mass and the CO₂ emissions during their production processes are 810 g. The total embodied energy was estimated to be 49 MJ/ECD, with 32.1 MJ/unit of them derived from the K-Glass. The comparison of the total embodied energies of the ECD and various insulating glass units concluded that mass-produced EC glazings could easily compete with them in terms of environmental performance, anticipating cost attenuation and overall thermal and optical behavior. The above analysis could be implemented for the reduction of the embodied energy of the ECD life cycle, since it is proposed as an energy saving device.     

Thermal conductance measurement on vacuum glazing

A method is described for measuring the thermal conductance of vacuum glazing that is well-suited for integration into the manufacturing process of such devices. The sample of vacuum glazing to be measured, initially at elevated temperature, is placed in contact with a second sample of vacuum glazing with a known thermal conductance. The external surfaces of the glazings are then cooled by forced flow of air at room temperature, and a measurement is made of the rate of decrease of the temperature of the contacting glass sheets of the two samples. The method is simple to implement, and can be automated. The results obtained with the method are quite reproducible. The measurement can be made as the production samples of vacuum glazing cool at the completion of the manufacturing process, resulting in significant savings in time and labour compared with other methods.     

A modified pump-out technique used for fabrication of low temperature metal sealed vacuum glazing

A modified pump-out technique, incorporating a novel pump-out hole sealing process, has been developed that enables a high level of vacuum to be achieved between the panes of a vacuum glazing. The modified pump-out method provides several potential opportunities for the fabrication of a vacuum glazing with improved thermal performance. In particular, improved flexibility for production of a wide range of glazing sizes may allow a lower cost of manufacture to be achieved by avoiding the expense of a high vacuum oven which would otherwise be required for commercial production of high performance, large-scale vacuum glazings.The thermal performance of the vacuum glazing fabricated using the pump-out technique was characterized using a guarded hotbox calorimeter and theoretically analyzed using a finite volume model. The excellent experimentally determined thermal performance of the fabricated vacuum glazing was in good agreement with that predicted theoretically.     

Durability of electrochromic glazing

Fundamental properties of all-solid-state electrochromic windows to control the solar energy have been investigated. This system comprises of multilayer represented as Glass/ITO/NiO/Inorganic Electrolyte (Ta₂O₅, etc.)/ WO₃/ITO/ Adhesive Film/ Glass. Of the various electrochromic systems examined so far, the most important features are their environmental stability and the possibility of large area applications. Our system can control the visible transmittance between 72.6% and 17.6% and has a cyclic life over 100000 cycles at 60°C. Based on the accelerated weathering tests, the stability of the system is estimated to be over five years for outdoor applications. For the problem of scaling up, some technical aspect is given and the prototype window of size 40×60 cm is exemplified. The present system could be more suitable for architectural and automobile applications in the near future by developing production technology.     

Theoretical and experimental analysis of the vacuum pressure in a vacuum glazing after extreme thermal cycling

Details of theoretical and experimental studies of the change in vacuum pressure within a vacuum glazing after extreme thermal cycling are presented. The vacuum glazing was fabricated at low temperature using an indium-copper-indium edge seal. It comprised two 4 mm thick 0.4 m by 0.4 m glass panes with low-emittance coatings separated by an array of stainless steel support pillars spaced at 25 mm with a diameter of 0.4 mm and a height of 0.15 mm. Thermal cycling tests were undertaken in which the air temperature on one side of the sample was taken from −30 °C to +50 °C and back to −30 °C 15 times while maintaining an air temperature of 22 °C on the other side. After this test procedure, it was found that the glass to glass heat conductance at the centre glazing area had increased by 10.1% from which the vacuum pressure within the evacuated space was determined to have increased from the negligible level of less than 0.1 Pa to 0.16 Pa using the model of Corrucini. Previous research has shown that if the vacuum pressure is less than 0.1 Pa, the effect of conduction through the residual gas on the total glazing heat transfer is negligible. The degradation of vacuum level determined was corroborated by the change in glass surface temperatures.     

The effect of glazing shape upon the thermal performance of buildings

The great incidence that glazing has in a building energy conservation makes it one of the most important parameters to be taken into account especially in commercial buildings, where the surface occupied by glass areas is very important. So, different shapes of glass areas and their influence in the energy consumption of a commercial building are studied in this paper. Horizontal glazing (with different heights) and vertical glazing (with the same area as the horizontal ones), separated by opaque areas are considered in a base case building. A traditional wall and a curtain-wall are considered, and the different annual consumptions per conditions unit surface, both in winter and summer, are obtained.     

Temperature-induced stresses in vacuum glazing: Modelling and experimental validation

A temperature difference across a sample of vacuum glazing causes differential expansion of one glass sheet relative to the other. In vacuum glazing with a fused edge seal, this results in tensile and compressive stresses in the glass sheets, and bending of the structure. The physical origins of these stresses and deflections are discussed, and a finite element model is used to determine their magnitude. The model has been validated by comparison with experimental data for a well-characterised sample of vacuum glazing under accurately defined external conditions. Modelling data are presented for two glazing designs which have properties that are characteristic of the extremes of performance of this type of glazing. It is shown that mechanical edge constraints can profoundly alter the spatial distribution of stresses in the glazing.     

Stresses in vacuum glazing fabricated at low temperature

This paper reports an experimental and theoretical study of the stresses in and durability of vacuum glazing fabricated at low temperature using an indium based edge seal. For the first time a finite-element model with support pillars incorporated directly, enabled the stresses in the whole structure to be explicitly calculated. Experimental validations of the finite element model predictions were undertaken. Modelling results are presented for a case with American Society of Testing and Materials standard winter boundary conditions. It was found that, for the particular system studied, the predicted stress level in the structure is essentially the same for indium sealed and solder glass sealed vacuum glazing, and the magnitude of stress values in the indium seal is comparable with that dictated by the indium strength characteristics.     

Spectrally selective laminated glazing consisting of solar control and heat mirror coated glass: preparation, characterization and modelling of heat transfer

In this study, solar control coatings were prepared by sequential depositions of thin films of ZnS (40 nm)–CuS (150 nm) and ZnS (40 nm)–Bi₂S₃ (75 nm)–CuS (150 nm) from chemical baths on 3 mm thick commercial sheet glass. These were laminated to 3 mm thick clear glass or commercially available SnO₂ based heat mirror coating of sheet resistance 15 Ω on float glass of 3 mm thickness using a poly(ethylene vinyl acetate), EVA, sheet of 0.36 mm thickness in a vacuum process at 120 °C for 30 min. In total, the thickness of the glazing was 6.35 mm. The glazings possess visible transmittance, weighted for D65 solar spectra and sensitivity of the human eye for daylight vision, of 36% or 14% with solar absorptance of 71% or 78% depending on the coating type, i.e ZnS–CuS or ZnS–Bi₂S₃–CuS-heat mirror respectively. The solar heat gain coefficient (SHGC) was evaluated for these glazings at exterior temperatures of 15 and 32 °C for an exterior convective heat transfer coefficient (h_ex) of 6–100 Wm⁻² K⁻¹ using a mathematical model. The model predicts the extent of reduction in SHGC through the presence of the heat mirror coating as a function of h_ex and hence helps to decide on the relative benefit, which may be derived through their use in different locations. Though the deposition technique mentioned here involves longer duration compared with vacuum techniques, it may be developed into a low throughput, low-capital alternate technology for small-scale production.     

Complex multimaterial insulating frames for windows with evacuated glazing

The thermal performance of a complex multimaterial frame consisting of an exoskeleton framework and cavities filled with insulant materials enclosing an evacuated glazing was simulated using a two-dimensional finite element model and the results were validated experimentally using a guarded hot box calorimeter. The analysed 0.5 m by 0.5 m evacuated glazing consisted of two low-emittance film coated glass panes supported by an array of 0.32 mm diameter pillars spaced 25 mm apart, contiguously sealed by a 10 mm wide metal edge seal. Thermal performance of windows employing evacuated glazing set in various complex multimaterial frames were analysed in detail. Very good agreement was found between simulations and experimental measurements of surface temperatures of the evacuated glazing window system. The heat loss from a window with an evacuated glazing and a complex multimaterial frame is about 80% of that for a window comprised of an evacuated glazing set in a single material solid frame.     

Daylighting performance of an electrochromic window in a small scale test-cell

In this paper, the results of an experimental investigation aimed at assessing the performance of electrochromic (EC) windows with respect to daylighting control in buildings are presented. The research is performed under real weather conditions by a small scale test-cell equipped with a small area double glazing unit (DGU) where one pane consists of an EC device with visible transmittance τ_v ranging from 6.2 to 68.1% and the other of an ordinary clear float glass (τ_v ≈90%). Experimental tests are carried out as a function of time, weather conditions, test-cell orientation and switching strategies. These data are integrated with spectrophotometric measurements. Results show that the angle selectivity of the glazing combined with its active switching effect allows a wide range of selectable transmission states to suit the latitude and orientation of a building in relation to the local climatic conditions. For south facing windows and under the involved climatic conditions EC glazing driven by a dynamic control strategy can be very effective in reducing discomfort glare caused by high window brightness. Glare reduction can be realized contemporarily maintaining the work plane illuminance to adequate level for computer based office tasks so without compromising much of the available daylight. Furthermore, since EC glazing is never switched to heavily darkened states (τ_v >20%), colour rendering of inside objects should be always acceptable, although internal illuminance level could be slightly lower than to what users prefer in relation to the correlated colour temperature of the incoming light. These results change when considering west orientation for which high-luminance direct sunlight patches are registered on the work-plane even for EC glazing switched to its lowest transmitting state letting suppose that EC windows cannot provide full control of uncomfortable direct sunlight effects without integration of additional shading devices.     

Numerical investigation of parabolic trough receiver performance with outer vacuum shell

The useful heat gain of a parabolic collector system is directly dependent on the heat loss from the absorber at its operating temperature. Selective coatings with evacuated/non evacuated glass tubes are employed to control radiative and convective heat losses. A concentric glass shell under vacuum is investigated for its thermal performance as this method circumvents the need for direct sealing between the glass envelope and the metal receiver to maintain vacuum and its related technical challenges. The performance is compared against a non evacuated receiver and its influence under different wind velocities; emissivities are calculated by a one dimensional theoretical model and solved by an iterative method.     

Characterization of ion diffusion and transient electrochromic performance in PECVD grown tungsten oxide thin films

Electrochromic tungsten oxide thin films were synthesized by plasma-enhanced chemical vapor deposition (PECVD). Film density and electrochromic performance were controlled by the degree of ion bombardment. A moderate degree of ion bombardment was optimal, and the refractive index was shown to be a sensitive indicator of electrochromic performance. Chronoamperometry in concert with optical transmission was used to determine diffusion and absorption coefficients using both H⁺ and Li⁺ containing electrolytes. The absorption coefficients were similar for both ions, scaling with the degree of intercalation to 50,000 cm⁻¹ in the opaque state. The diffusion coefficients for optimized films were found to be relatively insensitive to the degree of ion intercalation, with values of 10⁻⁹ and 10⁻¹⁰ cm²/s for H⁺ and Li⁺, respectively. These values are about an order of magnitude greater than values reported for vacuum-deposited films, which was attributed to low relative density in the PECVD films. The diffusion and absorption coefficients were incorporated into a model that successfully reproduced transient optical performance.     

Evaluation of electrochromic windows impact in the energy performance of buildings in Mediterranean climates

Old buildings refurbishment is essential for the global improvement of building energy indicators. Within this context, the paper focuses on the energy savings that may occur when using electrochromic (EC) windows, an interesting emerging technology alternative to shading devices to control solar gain in buildings located in Mediterranean climates. The EC windows technology is briefly presented and the optical properties adjustments of the glasses are discussed according to the operated range. The EC window dynamic behavior and the different control strategies are modeled and implemented in the ESP-r building simulation program. The EC window impact in the energy needs for heating and cooling is studied, considering different ambient parameters (exterior dry bulb temperature, interior dry bulb temperature and incident radiation) and set points for the EC control. A comparison of several windows solutions (single, double-glazing and EC windows), the type of building, internal gains from occupancy, lighting and equipment and the orientation of windows are considered for discussion through the analysis of the energy needs for heating and cooling. It is concluded that for this climate the best positive results are obtained when the EC are used in the west façade. For the south façade the results show no significant advantages in using EC windows.