A high-power low-pressure iodine lamp pumped by glow discharge

We present the working characteristics of a high-power UV-VUV electric-discharge lamp filled with a working mixture of helium and iodine vapor (He-I₂) at a low pressure (0.1–1.5 kPa) and pumped by a dc glow discharge at a power of 15–200 W. The power of the total output UV radiation and the main emission peak at λ = 206.2 nm were studied as dependent on the electric power supplied to the glow discharge and on the partial pressure of helium in the He-I₂ mixture. The emission characteristics of the glow discharge plasma were studied in the spectral range from 200 to 350 nm. In this range, the lamp is operating predominantly on a resonance emission line of excited iodine atoms (λ = 206.2 nm, FWHM = 0.10–0.12 nm) and on a system of electronic-vibrational bands of excited iodine molecules with the main peak at λ = 342 nm. The contribution of the resonance emission due to excited iodine atoms to the total UV emission from the glow discharge plasma does not exceed 50%. The optimum partial pressure of helium is within 400–800 Pa. The total UV radiation power of the lamp operating in the optimum regime reaches 25 W at an efficiency of η ≤15%.     

A xenon-iodine electric discharge bactericidal lamp

We present the working characteristics of a continuous UV lamp emitting at λ=206 nm, pumped by a longitudinal glow discharge. The pressure of the working Xe-I₂ gas-vapor mixture was within 0.1–10 kPa. The power deposited in the discharge was varied within 10–130 W. The current-voltage characteristics, the emission spectra in a 200–600 nm wavelength range, the line emission intensity as a function of the power deposited in the discharge plasma, and the partial pressure of xenon in the lamp were studied. It is established that the lamp operates in the range of 206–342 nm on a resonance line of iodine at 206 nm and on the bands at 253 nm [XeI(B-X)] and 342 nm [I₂(B-X)]. Not less than half of the output UV emission power is concentrated in the bactericidal spectral interval (around λ=206 nm). The total UV emission power of the lamp reaches 6–7 W at an efficiency of ≤5%.     

Short-wavelength XeBr-Br gas discharge lamp

The output characteristics of a small-size gas-discharge lamp emitting in the 160–300 nm wavelength range are reported. The working medium—a mixture of xenon and bromine vapor—was excited in a longitudinal glow discharge in a quartz tube with an interelectrode distance of 100 mm. The emission spectrum is formed by the molecular lines of xenon bromide at 282 nm [XeBr(B-X)] and 220 nm [XeBr(D-X)] and the atomic resonance lines of bromine at 163.3 and 157.6 nm. An increase in the partial pressure of xenon in the working mixture from 130 to 800 Pa is accompanied by a decrease in the intensity of emission lines due to atomic bromine and an increase in the intensity of emission from xenon bromide molecules. The operation regime was optimized with respect to the energy supplied to the glow discharge and the working gas mixture pressure and composition. The optimum partial pressure of xenon is within 600–800 Pa, and that of bromine vapor, within 50–100 Pa. The average total VUV-UV output radiation power reached 7 W.     

Shortwave krypton-bromine excimer low-pressure lamp

The emission characteristics are reported for a small short-wavelength (UV) lamp filled with a krypton-bromine mixture and pumped by longitudinal glow discharge at a 100-mm distance between electrodes in a quartz tube with an internal diameter of 14 mm. The emission spectrum is formed by the resonance atomic lines of bromine (163.3 and 157.6 nm) and the molecular lines of bromine (Br₂) and krypton bromide (KrBr). An increase in the partial pressure of bromine in the working mixture from 50 to 270 Pa is accompanied by a decrease in the intensity of emission lines due to atomic bromine and leads to the formation of VUV-UV continuum based on the molecular bands due to Br₂ and KrBr. The operation regime was optimized with respect to the glow discharge current and the gas mixture pressure and composition. The optimum partial pressure of krypton is within 500–800 Pa, and that of bromine vapor is within 100–250 Pa. The average total VUV-UV output radiation power reached 5 W at an efficiency of 8–10%.     

The effect of water vapor on the characteristics of a pulsed-periodic ultraviolet radiation source

The effect of a small admixture of water vapor on the optical characteristics of an UV radiation source using a He-air-H₂O mixture as the working medium was studied. The gas mixture was excited in a short-pulse transverse volume discharge operating at a charging voltage of U _ch ≤10 kV. As the partial pressure of helium was varied in the 10–45 kPa range at an air pressure of P(air)=130 Pa and the water vapor pressure within P(H₂O)=50–100 Pa, the main optical emission from plasma in the UV wavelength range was concentrated in a broad band peaked at λ_max=309.7 nm and was two times greater than the intensity of the base emission bands of the nitrogen molecule in this spectral range (λ=337.1 and 315.9 nm, N₂(C-B)). Adding water vapor to the He-air mixture increases the spectral range of the UV source toward shortwave region, which is related to a spontaneous decay of the products of dissociation of water molecules.     

Excited nitrogen molecule formation in a DC-glow-discharge-pumped excimer lamp

The plasma in an excimer lamp operating in the λ=258 nm [Cl₂(D′-A′)] and 175 nm [ArCl(B-X)] modes using an Ar-Cl₂ gas mixture excited with a longitudinal dc glow discharge was studied by the method of spectroscopic diagnostics. In the presence of small air admixtures (P≤30 Pa) in the working medium, the plasma exhibits the formation of excited nitrogen molecules decaying with the emission of molecular bands in the 193–271 nm wavelength range. The emission intensities of both molecular and excimer bands were measured and the conditions were determined under which the excited nitrogen molecules most significantly affect the optical characteristics of the discharge.     

A planar excimer-halogen radiation source pumped by transverse RF discharge

We present the characteristics of a planar source of wideband shortwave radiation pumped by transverse RF (f=1.76 MHz) discharge in a Kr/Xe/Cl₂ mixture (P≤500 Pa). The spectral characteristics of the plasma emission were studied in the wavelength interval of 130–600 nm. The oscillograms of the voltage, current, and output radiation intensity and the diagrams of the output power depending on the gas pressure, partial composition of the working gas mixture, and discharge power are presented. It is established that the source produces emission predominantly in the spectral interval of 170–330 nm, representing a system of the molecular emission bands XeCl(D, B-X), KrCl(B-X), Cl₂(D′-A′), and Cl₂**. For a maximum output power in the UV-VUV range, the optimum working gas mixture is Kr/Xe/Cl₂ with the partial pressures P(Kr)/P(Xe)/P(Cl₂)=150–200/150–200/20–40 Pa. The maximum power irradiated within a solid angle of 4π via two output holes with a total area of S≤ 100 cm² reaches 30–40 W. In the region of a threshold with respect to the transverse discharge initiation, there are narrow peaks of plasma emission that are probably related to the jumps in the density of electrons and the positive and negative ions at the boundary between the plasma and the RF discharge layer.     

UV emission from capacitive discharge in inert gas-iodine vapor mixture

We have studied the optical characteristics of capacitive discharge in binary mixtures of helium, neon, argon, and krypton with iodine vapor in a spectral range of 180–300 nm. It is established that the main power of UV radiation from the discharge plasma is concentrated in the emission lines at 183.0 and 206.2 nm. The intensity of emission due the spectral lines of iodine atom was optimized with respect to the inert gas type and partial pressure. The optimum results were obtained using He-I₂ mixture with partial pressures of helium within 0.8–2.0 kPa and iodine vapor below 50–60 Pa. Being excited with a trains of nanosecond current pulses at a repetition rate of 10–100 Hz, the capacitive discharge emitted pulses with duration not exceeding 400–500 ns.     

Pulsed microwave radiator for the band system λ=175 nm ArCl(B-X)/236 nm XeCl(D−X)/258 nm Cl2*/308 nm XeCl(B-X)

Parameters of a multiwave radiator pumped with transverse volume discharge in an Ar-Xe-Cl₂ mixture at a pressure of P=5–30 kPa were optimized. It is shown that, at a partial xenon pressure in the mixture below 0.4 kPa, the discharge may serve a multiwave radiation source operating on the electron-vibrational transitions with λ=175 nm ArCl(B-X), 236 nm XeCl(D-X), 258 nm Cl₂(D′-A′), and 308 nm XeCl(B-X). The emission line intensities have comparable values, which may be of interest for applications in the short-wave pulsed photometry, microelectronics, and photochemistry.     

The optimum characteristics of a halogen lamp pumped by transverse RF discharge

We report on the optimized characteristics of a small-size bactericidal lamp pumped by transverse RF (f=1.76 MHz) discharge, operating on a system of the molecular emission bands of chlorine in a wavelength range of 195–310 nm. The spectral characteristics of the plasma emission were measured and the intensity of chlorine emission bands were studied as functions of the total pressure and partial composition of a helium-chlorine mixture. Oscillograms of the pumping current and output radiation intensity were measured and the total output radiation power was determined. It is established that the lamp radiates predominantly in a bactericidal wavelength interval on an electron-vibrational transition at 200 nm in Cl₂** molecules. The optimum partial pressures of helium and chlorine are 100–300 and 90–120 Pa, respectively. The maximum output power of UV emission from the side cylindrical surface of the lamp reached 10 W. The lamp can be used in photochemistry, ecology, genetics, and medicine.     

The emission characteristics of low-pressure water vapor discharge UV emitters

We have studied the characteristics of UV emission sources operating on low-pressure normal (H₂O) and heavy (D₂O) water vapor excited by periodic-pulsed and glow discharges. The emission in a 300–330 nm wavelength interval has been studied in detail for water vapor pressures ranging from 50 to 2500 Pa. A comparison of the characteristics of emission from discharge plasma at low (50–150 Pa) and elevated (2.0–2.5 kPa) water vapor pressures reveals significant differences in the character of emission spectra, which can be related to the different types of emitting species (hydroxy radicals versus small clusters of such radicals and water molecules). Discharge current and emission intensity pulses in the periodic-pulsed discharge regime have been measured.     

A pulsed-periodic low-pressure volume discharge in a krypton-chlorine gas mixture

The initiation conditions and characteristics of a volume discharge in a krypton-chlorine mixture at low pressures (P≤1.0 kPa) were studied. It is shown that a constant voltage of U _ch 1.0 kV applied to a spherical anode-flat cathode system gives rise to a pulsed-periodic discharge with a pulse repetition rate of 1–50 kHz. The current-voltage characteristics of the discharge, the spectra of emission in a wavelength interval of Δ λ=130–350 nm, and oscillograms of the current and the total output emission intensity were studied as dependent on the partial composition and pressure of the krypton-chlorine mixture. It is shown that the discharge is a selective source of emission in the electronic-vibrational bands with λ=257 nm [Cl₂(D′-A′)], 222 nm [KrCl(B-X)], and 200 nm [C1₂**]. The volume discharge in the Kr-Cl₂ mixture can be used for the development of pulsed-periodic low-pressure excimer-halogen lamps.     

A high-frequency UV-VUV radiation source operating on a mixture of argon with chlorine molecules

We present the working optical characteristics of a short-wavelength electric-discharge lamp operating at 150–270 nm (UV-VUV spectral range). The working medium is a mixture of argon with chlorine molecules (Ar-Cl₂) excited in a high-frequency transverse discharge between a metal electrode and a semitransparent nickel grid with an interelectrode distance of 2.2 cm. The proposed UV-VUV radiation source operates on the broadened emission lines of chlorine (Cl₂) and argon chloride (ArCl) molecules, which form a continuum in the 150–270 nm wavelength range. The source operation was optimized depending on the pumping power and the pressure and composition of the Ar-Cl₂ mixture. For a discharge excitation power within 50–300 W, the optimum working media were Ar-Cl₂ mixtures with the partial pressures P(Ar) = 300?400 Pa and P(Cl₂) = 30?40 Pa. The average total output power of the UV-VUV radiation extracted from the optimized source amounted to 15 W.     

Synthesis and properties of rare earth doped lamp phosphors

Red, blue and green emitting lamp phosphors such as Eu³⁺ doped Y₂O₃ (red phosphor), Eu²⁺ doped Ba_0·64Al₁₂O_18·64, BaMgAl₁₀O₁₇ and BaMg₂Al₁₆O₂₇ (blue phosphors) and Ce_0·67Tb_0·33MgAl₁₁O₁₉ and Eu²⁺, Mn²⁺ doped BaMgAl₁₀O₁₇ (green phosphors) have been prepared by the combustion of the corresponding metal nitrates (oxidizer) and oxalyl dihydrazide/urea/carbohydrazide (fuel) mixtures at 400°–500°C within 5 min. The formation of these phosphors has been confirmed by their characteristic powder X-ray diffraction patterns and fluorescence spectra. The phosphors showed characteristic emission bands at 611 nm (red emission), 430–450 nm (blue emission) and 515–540 nm (green emission). The fine-particle nature of the combustion derived phosphors has been investigated using powder density, particle size and BET surface area measurements. Paper presented at the poster session of MRSI AGM VI, Kharagpur, 1995     

Silica Glasses and Optical Fibers Prepared by Plasma Chemical Vapor Deposition Using Bromide Precursors

Silica glasses containing substitutionally incorporated bromine, up to 1.5 wt %, are prepared by plasma chemical vapor deposition from bromide precursors at a pressure on the order of 130 Pa. The absorption spectra of the Br-doped glasses show bands at 215, 248, and 400 nm. In the concentration range studied, the bromine dopant causes no additional losses within the optical-fiber communication windows. In the spectrum of germanosilicate glass prepared from bromides, the absorption band at 1.38 m consists of four Gaussian components, peaked at 1.38, 1.39, 1.42, and 1.43 m. Single-mode germanosilicate fibers prepared from bromides exhibit enhanced UV sensitivity, which make them potentially attractive for producing devices based on fiber gratings formed by periodic modulation of the refractive index of the fiber core.     

Characteristics and plasma parameters of a short-wavelength low-pressure discharge lamp

We have studied the working optical characteristics and electron kinetic coefficients of a short-wavelength, electric discharge exciplex-halogen UV-VUV lamp employing a mixture of argon and chlorine with a total pressure of P = 0.5–10 kPa. The lamp operates on a system of broadened electron-vibrational bands of ArCl (175 nm) and chlorine (200, 258 nm) molecules, which overlap to form a continuum in the spectral range of 160–260 nm. It is established that the optimum mixtures are those with p(Ar) − p(Cl₂) = (2–4)−(0.15–0.30) kPa. The average output power of the short-wavelength radiation is 1–2 W at an efficiency of ∼5%. The electron energy distribution functions (EDFs) and the discharge plasma parameters have been calculated by solving the Boltzmann equation for a gas mixture with the experimentally determined optimum composition in the range of E/P values from 1 to 200 V/(cm Torr), where E is the electric field strength and P is the total gas pressure. Using the obtained EDFs, the electron transport characteristics, specific discharge power losses for the main elementary processes, and rate constants of electron processes are determined.     

Structural and chemical changes of thermally treated bone apatite

The thermal behaviour of the animal by-product meat and bone meal (MBM) has been investigated in order to assess how it is affected structurally and chemically by incineration. Initially composed of intergrown collagen and hydroxyapatite (HAP), combustion of the organic component is complete by 650 °C, with most mass loss (50–55%) occurring by 500 °C. No original proteins were detected in samples heated at 400 °C or above. Combustion of collagen is accompanied by an increase in HAP mean crystallite size at temperatures greater than 400 °C, from 10 nm to a constant value of 120 nm at 800 °C or more. Newly formed crystalline phases appear beyond 400 °C, and include β-tricalcium phosphate, NaCaPO₄, halite (NaCl) and sylvite (KCl). Crystallite thickness as judged by small angle X-ray scattering (SAXS) increases from 2 nm (25–400 °C) to 8–9 nm very rapidly at 550 °C, and then gradually increases to approximately 10 nm. The original texture of HAP within a collagen matrix is progressively lost, producing a porous HAP dominated solid at 700 °C, and a very low porosity sintered HAP product at 900 °C.     

Thermoluminescent behaviour of diamond films subjected to UV irradiation

The thermoluminescent behaviour of diamond films subjected to UV irradiation was studied by using an UV lamp of 254 nm wavelength. The UV irradiation was achieved by placing the samples 15 cm away from an UV source for different periods. The thermoluminescent signal was integrated from 0 to 350°C at a linear heating rate of 10°C/s in a N₂ atmosphere. The corresponding luminescence spectra show an excitation band centered at 450 nm while the emission band is centered around 500 nm at room temperature. The diamond films were synthesized on molybdenum substrates by the combustion flame technique and characterized by Raman spectroscopy and scanning electron microscopy. Received: 31 May 1999 / Reviewed and accepted: 22 July 1999     

Low temperature growth of SnO2 nanowires by electron beam evaporation and their application in UV light detection

For the first time, high quality tin oxide (SnO₂) nanowires have been synthesized at a low substrate temperature of 450 °C via vapor–liquid–solid mechanism using an electron beam evaporation technique. The grown nanowires have shown length of 2–4 μm and diameter of 20–60 nm. High resolution transmission electron microscope studies on the grown nanowires have shown the single crystalline nature of the SnO₂ nanowires. We investigated the effect of growth temperature and oxygen partial pressure on SnO₂ nanowires growth. Variation of substrate temperature at a constant oxygen partial pressure of 4 × 10⁻⁴ mbar suggested that a temperature equal to or greater than 450 °C was the best condition for phase pure SnO₂ nanowires growth. The SnO₂ nanowires grown on a SiO₂ substrate were subjected to UV photo detection. The responsivity and quantum efficiency of SnO₂ NWs photo detector (at 10V applied bias) was 12 A/W and 45, respectively, for 12 μW/cm² UV lamp (330 nm) intensity on the photo detector..     

Synthesis of doubly functional nanowhiskers from a colloid solution including a V–Ti complex precursor

In this study, we synthesized vanadium (V) nanoparticles precursor (NH₄)₅[(VO)₆(CO₃)₄(OH)₉]·10H₂O a two-phase system of toluene and water. Colloid solution including titanium(IV) isopropoxide and polyvinylpyrrolidone (PVP) was subsequently deposited onto the nanoparticles to form urchin-like structures in a toluene solution as the vanadium–titanium (V–Ti) complex precursor. Calcining the urchin-like precursor at 700 °C generated nanowhiskers of the Ti/V oxide complex after annealing process. These nanowhiskers were characterized using transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron microscopy (XPS). Films of the Ti/V oxide nanowhisker structure exhibited good visible transparency and a large change in transmittance at near-infrared (NIR) wavelengths before and after the metal–insulator phase transition. For a 44-nm-thick single-layer nanowhisker thin film, the transmittances at 700 nm in the metallic (M) and semiconductive (S) states were 75 and 72.2 %, respectively; the NIR switching efficiency (ΔT ₂₀₀₀) increased from 17 to 21.3 % at 2000 nm under UV light irradiation. In addition, the nanowhisker thin film of the Ti/V oxide complex significantly enhanced the photodecomposition of methylene blue under UV irradiation, relative to that of the unmodified TiO₂. The dual functions of this material—thermochromicity and photocatalytic behavior—suggest that it might have interesting applications in energy-saving smart windows.