共查询到19条相似文献,搜索用时 78 毫秒
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丁香油的超临界CO2萃取及其微胶囊的制备 总被引:2,自引:0,他引:2
在70℃和10 MPa条件下通过对丁香花蕾进行超临界CO2萃取得到丁香油,萃取率达19%~21%.气质联用分析结果表明,丁香油中主要化学成分包括丁香酚、β-石竹烯和乙酰基丁香酚等.以丁香油为囊芯,探讨利用干酵母细胞作为囊壁材料制备微胶囊的可行性.通过正交试验考察了包埋温度、包埋时间、丁香油与干酵母配比(芯材比)对微胶囊化丁香油的影响.结果表明,在包埋温度70℃、包埋时间9 h和芯材比为1∶1(w/w)的条件下,微胶囊中丁香油包埋率达到41.26%.通过扫描电镜观察,丁香油微胶囊呈规则的球形,大小均一,颗粒直径在2.0~4.0 μm.在100℃下对经微胶囊化的丁香油加热20 h,其挥发率只有15.04%,远低于相同条件下丁香油的挥发率(58.29%).这种新型的微胶囊化方法,具有制备过程简单、包埋率高和不引入有机溶剂的优点. 相似文献
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超临界CO2萃取胡椒油实验研究与数值模拟 总被引:3,自引:0,他引:3
建立了超临界流体萃取胡椒油实验装置,以CO2为萃取剂,考察了萃取压力、温度、CO2流量及原料颗粒大小等因素对胡椒油萃取率的影响,并由此确定了较佳的萃取工艺条件:压力22—26 MPa,温度313—323 K,胡椒颗粒度30—40目,CO2流量0.3—0.4 m3/h,胡椒油累积萃取率可达80%—90%。基于萃取器微分单元和固态原料颗粒微分单元质量守恒原理,建立了微分方程,利用直线推动力近似理论拟合总传质推动力及平衡吸收常数,化简方程,对实验结果进行了数值模拟。 相似文献
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超临界CO2萃取的研究进展 总被引:2,自引:0,他引:2
超临界CO2流体萃取技术是近年来兴起的一项具有精馏和萃取两过程的高新物质分离精制技术,文章主要通过对各类超临界CO2流体萃取实验的文献报道和实验操作进行分析,对超临界CO2流体革取技术的原理、特点和超临界CO2流体萃取的主要影响因素及其优化方法和经验模型进行了综述。 相似文献
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超临界CO2萃取的研究进展 总被引:3,自引:0,他引:3
通过对各类超临界CO2流体萃取实验的文献报道和实验操作进行分析,对超临界CO2流体萃取技术的原理、特点和超临界CO2流体萃取的主要影响因素及其优化方法和经验模型进行了综述. 相似文献
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超临界CO2萃取沙棘油的实验研究及数值模拟 总被引:14,自引:3,他引:11
本文利用超临界CO2萃取沙棘油,建立了一套实验流程,分别考察了萃取压力、萃取温度以及颗粒大小对萃取率的影响。同时根据萃取器单元的质量守恒建立了微分方程,并对一定萃取条件下的实验结果进行数值模拟。结果表明,本文所建立的数值模型能较好地描述实际萃取行为。 相似文献
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There is a need for scientific research that evaluates the influence of important process variables on the scale up of supercritical technology. For supercritical fluid extraction (SFE), one of these variables is the extractor's bed geometry, which can be defined by the ratio of the bed height (HB) to the bed diameter (DB). A systematic study is needed to select suitable criteria that can be used to obtain similar extraction curves among beds with different geometries. In this study, maintaining a constant ratio of solvent mass to feed mass for two beds with 1-L volumes but different geometries (E-1: HB/DB = 7.1; E-2: HB/DB = 2.7) was confirmed as a successful scale up criterion. For constant values of the temperature, pressure and bed porosity, there is experimental evidence that the mass transfer rate is equal in the two beds when the solvent flow rate is high. When 0.6 kg of clove buds was packed in the beds, the extraction rates were 2.10 ± 0.08 and 2.3 ± 0.1 g extract/min for beds E-1 and E-2, respectively. However, when the solvent flow rate was lower, the extraction rates were 0.93 ± 0.06 and 1.12 ± 0.02 g extract/min for beds E-1 and E-2, respectively. This difference in behavior between the extraction beds is associated with the axial dispersion of the fluid, which is more pronounced when the HB/DB ratio is increased. Thin particles tend to compact in the beds with high HB/DB ratios, which shorten the solvent passage. Non-isothermal profiles and differences in chemical composition of the extracts were also observed: 17% more α-humulene and 9% more eugenol were extracted in E-1 and E-2, respectively. 相似文献
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J. P. Friedrich G. R. List A. J. Heakin 《Journal of the American Oil Chemists' Society》1982,59(7):288-292
Full-fat soyflakes are readily extracted with supercritical carbon dioxide (SC-CO2) at pressures of 3,000~10,000 psig and 50 C. Under these conditions, SC-CO2 has the density of a liquid and the diffusivity of a gas. Therefore, equilibrium solubility is readily achieved in a short-path
batch extractor which permits high gas flow rates. Soybean oil extracted with SC-CO2 is lighter in color and contains less iron and about one-tenth the phosphorus of hexane-extracted crude oil from the same
beans. The lower phosphorus content is reflected in a chromatographic refining loss of 0.6% compared to 1.9% for hexane crude.
Refined oils from hexane and SC-CO2 extraction had equivalent odor and flavor scores initially and after 4 days' storage at 60 C. Carbon dioxide, an ideal solvent
for extraction of food products, is low-cost and readily available from fermentation processes and could free over 20 million
gallons of costly hexane per year for essential energy uses. 相似文献
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Stela Jokić Bence Nagy Zoran Zeković Senka Vidović Mate Bilić Darko Velić Béla Simándi 《Food and Bioproducts Processing》2012,90(4):693-699
A series of operational parameters of supercritical fluid extraction of soybean oil (pressure: 300–500 bar, temperature: 40–60 °C, CO2 mass flow rate: 0.194–0.436 kg/h and characteristic particle size: 0.238–1.059 mm) were investigated in a laboratory scale apparatus. The results show that the extraction yields were significantly affected by applied operational extraction parameters. The increase in pressure, temperature and solvent flow rate improved the extraction yield. The extraction yield increased as the particle size decreased depending on decreasing intra-particle diffusion resistance. To describe the extraction process Sovova's model was used and very good agreement with the experimental results was obtained. Based on the experimental data the internal and external mass transfer coefficients were estimated. To explore the influence of the extractor size on this process, soybean samples were extracted using different extraction basket volumes (0.2 L and 5 L) and related model parameters were examined. The mass transfer coefficient in the fluid phase increased with the increase in extractor size, while the mass transfer coefficient in the solid phase was independent of the extractor size. 相似文献
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超临界CO_2萃取分离桔油中的萜烯和含氧化合物 总被引:1,自引:0,他引:1
以冷榨柑橘精油为原料,采用GC/MS对柑橘精油原料进行定性及定量分析,确定了柑橘精油中的7种萜烯类化合物成分作为分离考察对象。实验探讨了超临界萃取压力、萃取温度、萃取时间和CO2流量等因素对含氧化合物分离效果的影响。实验结果表明,萃取相中萜烯类化合物的回收率总体上随着萃取压力、温度、时间和CO2流量的增大而增大。当萃取压力为12MPa,萃取温度为45℃,萃取时间为4h以及CO2流量为1.0L/min时,分离效果最佳,其萃取相中萜烯类化合物的回收率高达90.03%。 相似文献
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H. Zakizadeh Nei Nei Sh. Fatemi A. R. Salimi A. Vatanara A. Rouholamini Najafabadi 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2009,84(12):1854-1859
BACKGROUND: Supercritical CO2 enrichment of omega3 essential fatty acids (FAs) from Tyulka oil, using a batch process was investigated. Fractional factorial design was applied to evaluate the effects of the five process parameters: pressure (20.26 to 25.33 MPa); temperature (40 to 50 °C); packing fraction (0.5 to 0.7); modifier fraction (2 to 5%); and dynamic time (15 to 25 min), and their binary interactions on the enrichment of extracted omega3 FAs. By employing experimental design and analysis of variance, the variables were evaluated according to the significance of their effect on the yield of extracted omega3. RESULTS: The experimental results confirmed that pressure and dynamic time were the most important factors affecting enrichment of omega3. The amount of modifier in the feed also showed an increasing effect on the response. The binary interaction effects were investigated, and are discussed in detail. CONCLUSION: Optimum conditions were found at 25.33 MPa, 46.65 °C, packing fraction 0.50, modifier 5% and dynamic time 25 min, improving the enrichment of omega3 FAs up to 2.9 times. Copyright © 2009 Society of Chemical Industry 相似文献
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《The Journal of Supercritical Fluids》2001,19(2):149-159
Extraction of egg yolk oil (EYO) from egg yolk powder (EYP) with supercritical CO2 was performed on a laboratory apparatus. Solubility of EYO in supercritical CO2 was measured. The external diffusion and the equilibrium between solid and fluid phases were experimentally found to be the controlling steps during the extraction process. Based on this mechanism, a mathematical model for this extraction process was developed. The model parameters, adsorption equilibrium constant (kp), EYO concentration in solid controlling the transition in the equilibrium (xk) and the overall volumetric mass transfer coefficient (Kfap), were obtained by simulation. The simulation results indicated that xk is 0.56, Kfap is directly proportional to CO2 flow rate with an exponent of 0.548, and the adsorption heat of EYO is 6–9 kJ mol−1. The model was verified by concentration profiles of solid. The extraction process of EYO with supercritical CO2 was conducted on a pilot plant and the developed model could predict satisfactorily the process. 相似文献
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In the present study, a mathematical modeling for extraction of oil from clove buds using supercritical carbon dioxide was performed. Mass transfer is based on local equilibrium between solvent and solid. The model was solved numerically, and model estimation was validated using experimental data. For optimization, the clove oil equilibrium constant between solid and supercritical phase was determined by a theoretical method using fugacity concept, consequently the genetic algorithm for obtaining optimal operational conditions was used. The optimal conditions which obtained the highest amount of clove oil were pressure of 10 MPa and temperature of 304.2 K. 相似文献