Effect of hydrogen addition on criteria and greenhouse gas emissions for a marine diesel engine

Hydrogen remains an attractive alternative fuel to petroleum and a number of investigators claim that adding hydrogen to the air intake manifold of a diesel engine will reduce criteria emissions and diesel fuel consumption. Such claims are appealing when trying to simultaneously reduce petroleum consumption, greenhouse gases and criteria pollutants. The goal of this research was to measure the change in criteria emissions (CO, NO_x, and PM_2.5) and greenhouse gases such as carbon dioxide (CO₂), using standard test methods for a wide range of hydrogen addition rates. A two-stroke Detroit Diesel Corporation 12V-71TI marine diesel engine was mounted on an engine dynamometer and tested at three out of the four loads specified in the ISO 8178-4 E3 emission test cycle and at idle. The engine operated on CARB ultra-low sulfur #2 diesel with hydrogen added at flow rates of 0, 22 and 220 SLPM.     

Experimental study of the performances of a modified diesel engine operating in homogeneous charge compression ignition (HCCI) combustion mode versus the original diesel combustion mode

Homogeneous charge compression ignition (HCCI) combustion mode provides very low NO_x and soot emissions; however, it has some challenges associated with hydrocarbon (HC) emissions, fuel consumption, difficult control of start of ignition and bad behaviour to high loads. Cooled exhaust gas recirculation (EGR) is a common way to control in-cylinder NO_x production in diesel and HCCI combustion mode. However EGR has different effects on combustion and emissions, which are difficult to distinguish. This work is intended to characterize an engine that has been modified from the base diesel engine (FL1 906 DEUTZ-DITER) to work in HCCI combustion mode. It shows the experimental results for the modified diesel engine in HCCI combustion mode fueled with commercial diesel fuel compared to the diesel engine mode. An experimental installation, in conjunction with systematic tests to determine the optimum crank angle of fuel injection, has been used to measure the evolution of the cylinder pressure and to get an estimate of the heat release rate from a single-zone numerical model. From these the angle of start of combustion has been obtained. The performances and emissions of HC, CO and the huge reduction of NO_x and smoke emissions of the engine are presented. These results have allowed a deeper analysis of the effects of external EGR on the HCCI operation mode, on some engine design parameters and also on NO_x emission reduction.     

An experimental investigation on engine performance and emissions of a single cylinder diesel engine using hydrogen as inducted fuel and diesel as injected fuel with exhaust gas recirculation

Fast depletion of fossil fuels is demanding an urgent need to carry out research work to find out the viable alternative fuels for meeting sustainable energy demand with minimum environmental impact. In the future, our energy systems will need to be renewable and sustainable, efficient and cost-effective, convenient and safe. The technology for producing hydrogen from a variety of resources, including renewable, is evolving and that will make hydrogen energy system as cost-effective. Hydrogen safety concerns are not the cause for fear but they simply are different than those we are accustomed to with gasoline, diesel and other fossil fuels. For the time being full substitution of diesel with hydrogen is not convenient but use of hydrogen in a diesel engine in dual fuel mode is possible. So Hydrogen has been proposed as the perfect fuel for this future energy system. The experiment is conducted using diesel–hydrogen blend. A timed manifold induction system which is electronically controlled has been developed to deliver hydrogen on to the intake manifold. The solenoid valve is activated by the new technique of taking signal from the rocker arm of the engine instead of cam actuation mechanism. In the present investigation hydrogen-enriched air has been used in a diesel engine with hydrogen flow rate at 0.15 kg/h. As diesel is substituted and hydrogen is inducted, the NO_x emission is increased. In order to reduce NO_x emission an EGR system has been developed. In the EGR system a lightweight EGR cooler has been used instead of bulky heat exchanger. In this experiment performance parameters such as brake thermal efficiency, volumetric efficiency, BSEC are determined and emissions such as oxides of nitrogen, carbon dioxide, carbon monoxide, hydrocarbon, smoke and exhaust gas temperature are measured. Dual fuel operation with hydrogen induction coupled with exhaust gas recirculation results in lowered emission level and improved performance level compared to the case of neat diesel operation.     

Experimental investigation of the effects of simultaneous hydrogen and nitrogen addition on the emissions and combustion of a diesel engine

Overcoming diesel engine emissions trade-off effects, especially NO_x and Bosch smoke number (BSN), requires investigation of novel systems which can potentially serve the automobile industry towards further emissions reduction. Enrichment of the intake charge with H₂ + N₂ containing gas mixture, obtained from diesel fuel reforming system, can lead to new generation low polluting diesel engines.     

Performance and combustion characteristics of a direct injection SI hydrogen engine

Hydrogen with low spark-energy requirement, wide flammability range and high burning velocity is an important candidate for being used as fuel in spark-ignition engines. It also offers CO₂ and HC free combustion and lean operation resulting in lower _NOx${\mathrm{NO}}_x$ emissions. However, well examined external mixing of hydrogen with intake air causes backfire and knock especially at higher engine loads. In addition, low heating value per unit of volume of hydrogen limits the maximum output power. In this study, attention was paid to full usage of hydrogen advantage employing internal mixing method. Hydrogen was directly injected into cylinder of a single-cylinder test engine using a high-pressure gas injector and effects of injection timing and spark timing on engine performance and _NOx${\mathrm{NO}}_x$ emission were investigated under wide engine loads. The results indicate that direct injection of hydrogen prevents backfire, and that high thermal efficiency and output power can be achieved by hydrogen injection during late compression stroke. Moreover, by further optimization of the injection timing for each engine load, _NOx${\mathrm{NO}}_x$ emission can be reduced under the high engine output conditions.     

Hydrogen effects on the diesel engine performance and emissions

In this research, effects of hydrogen addition on a diesel engine were investigated in terms of engine performance and emissions for four cylinders, water cooled diesel engine. Hydrogen was added through the intake port of the diesel engine. Hydrogen effects on the diesel engine were investigated with different amount (0.20, 0.40, 0.60 and 0.80 lpm) at different engine load (20%, 40%, 60%, 80% and 100% load) and the constant speed, 1800 rpm. When hydrogen amount is increased for all engine loads, it is observed an increase in brake specific fuel consumption and brake thermal efficiency due to mixture formation and higher flame speed of hydrogen gas according to the results. For the 0.80 lpm hydrogen addition, exhaust temperature and NOx increased at higher loads. CO, UHC and SOOT emissions significantly decreased for hydrogen gas as additional fuel at all loads. In this study, higher decrease on SOOT emissions (up to 0.80lpm) was obtained. In addition, for 0.80 lpm hydrogen addition, the dramatic increase in NOx emissions was observed.     

Homogeneous Charge Compression Ignition (HCCI) combustion: Implementation and effects on pollutants in direct injection diesel engines

Homogeneous Charge Compression Ignition (HCCI) combustion is a combustion concept which offers simultaneous reductions in both NO_x and soot emissions from internal combustion engines. In light of increasingly stringent diesel emissions limits, research efforts have been invested into HCCI combustion as an alternative to conventional diesel combustion. This paper reviews the implementation of HCCI combustion in direct injection diesel engines using early, multiple and late injection strategies. Governing factors in HCCI operations such as injector characteristics, injection pressure, piston bowl geometry, compression ratio, intake charge temperature, exhaust gas recirculation (EGR) and supercharging or turbocharging are discussed in this review. The effects of design and operating parameters on HCCI diesel emissions, particularly NO_x and soot, are also investigated. For each of these parameters, the theories are discussed in conjunction with comparative evaluation of studies reported in the specialised literature.     

The effects of injection timing on NOx emissions of a low heat rejection indirect diesel injection engine

Higher NO_x is one of the major problems to be overcomed in a low heat rejection (LHR) diesel engine as insulation leads to an increase in combustion temperature about 200–250 °C compared to an identical standard (STD) diesel engine. High combustion temperatures alter optimum injection timing of a LHR engine. With the proper adjustment of the injection timing, it is possible to partially offset the adverse effect of insulation on heat release rate and hence to obtain improved performance and lower NO_x. However, the injection timing and brake specific fuel consumption (BSFC) trade-off must be considered together in performance and NO_x emission point of view. In this study, optimum injection timing was found with 4 crank angle (34° CA) retarded before top dead centre (BTDC) in LHR diesel engine in comparison to that of STD diesel engine (38° CA BTDC). When the LHR engine was operated with the injection timing of the 38 crank angle, which is the optimum value of the STD engine, it was shown that NO_x emission increased about 15%. However, when the injection timing was retarded to 34° CA in the LHR case, it was observed a decrease on the NO_x emissions with about 40% and the brake specific fuel consumption (BSFC) with about 6% compared to that of the STD case. Thus, by retarding the injection timing, an additional 1.5% saving in fuel consumption was obtained.     

Investigation of the effects of hydrogen on cylinder pressure in a split-injection diesel engine at heavy EGR

The distinctive properties of hydrogen have initiated considerable applied research related to the internal combustion engine. Recently, it has been reported that NO_x emissions were reduced by using hydrogen in a diesel engine at low temperature and heavy EGR conditions. As the continuing study, cylinder pressure was also investigated to determine the combustion characteristics and their relationship to NO_x emissions. The test engine was operated at constant speed and fixed diesel fuel injection rate (1500 rpm, 2.5 kg/h). Diesel fuel was injected in a split pattern into a 2-L diesel engine. The cylinder pressure was measured for different hydrogen flow rates and EGR ratios. The intake manifold temperature was controlled to be the same to avoid the gas intake temperature variations under the widely differing levels (2%-31%) of EGR. The measured cylinder pressure was analyzed for characteristic combustion values, such as mass burn fraction and combustion duration.The rising crank angle of the heat release rate was unaffected by the presence of hydrogen. However, supplying hydrogen extended the main combustion duration. This longer main combustion duration was particularly noticeable at the heavy EGR condition. It correlated well with the reduced NO_x emissions.     

Experimental investigation of the effects of separate hydrogen and nitrogen addition on the emissions and combustion of a diesel engine

An experimental investigation of the effects of separate hydrogen and nitrogen addition on the emissions and combustion of a diesel engine was performed and the results are presented in the current paper.     

The effect of HRG gas addition on diesel engine combustion characteristics and exhaust emissions

Extensive studies have been dedicated in the last decade to the possibility to use hydrogen in the dual-fuel mode to improve combustion characteristics and emissions of a diesel engine. The results of these studies, using pure hydrogen or hydrogen containing gas produced through water electrolysis, are notably different.The present investigation was conducted on a tractor diesel engine running with small amounts of the gas—provided by a water electrolyzer—aspirated in the air stream inducted in the cylinder. The engine was operated at light and medium loads and various speeds.It was found that the addition of HRG gas has a slight negative impact, up to 2%, on the engine brake thermal efficiency. Smoke is significantly reduced, up to 30%, with HRG enrichment, while NO_x concentrations vary in both senses, up to 14%, depending on the engine operation mode. A relative small amount of HRG gas can be used with favorable effects on emissions and with a small penalty in thermal efficiency.     

Combustion,performance and emissions of ULSD,PME and B50 fueled multi-cylinder diesel engine with naturally aspirated hydrogen

An experimental study was conducted on a diesel engine fueled with ultra-low sulfur diesel (ULSD), palm methyl ester (PME), a blended fuel containing 50% by volume each of the ULSD and PME, and naturally aspirated hydrogen, at an engine speed of 1800 rev min⁻¹ under five loads. Hydrogen was added to provide 10% and 20% of the total fuel energy. The following results are obtained with hydrogen addition. There is little change in peak in-cylinder pressure and peak heat release rate. The influence on fuel consumption and brake thermal efficiency is engine load and fuel dependent; being negative for the three liquid fuels at low engine loads but positive for ULSD and B50 and negligible for PME at medium-to-high loads. CO and CO₂ emissions decrease. HC decreases at medium-to-high loads, but increases at low loads. NO_x emission increases for PME only but NO₂ increases for the three liquid fuels. Smoke opacity, particle mass and number concentrations are all reduced for the three liquid fuels.     

Experimental investigation of combustion characteristics and NOx emission of a turbocharged hydrogen internal combustion engine

In order to alleviate the contradictions of increasingly prominent environmental pollution, greenhouse gas emissions and oil resource security issues, the search for renewable and clean alternative energy sources is getting more and more attention. Hydrogen energy is known as a future energy source because of its safety, reliability, wide range of resources and non-polluting products. Hydrogen internal combustion engine combines the technical advantages of traditional internal combustion engines and has comprehensive comparative advantages in terms of manufacturing cost, fuel adaptability and reliability. It is one of the practical ways to realize hydrogen energy utilization. In this paper, the combustion characteristics and NOx emission of a turbocharged hydrogen engine were investigated using the test data. The results showed the combustion duration (the crank angle of 10%–90% fuel burned) at 1500 rpm and 2000 rpm was equal and the combustion duration is much bigger than the other loads when the BMEP is 0.27 MPa. The reason is the effect of the turbocharger on the gas exchange process, which will influence the combustion process. The cylinder pressure and pressure rise rate were also investigated and the peak pressure rise rate was lower than 0.25 MPa/°CA at all working conditions. Moreover, the NOx emission changed from 300 ppm to 1200 ppm with engine speed increasing and the maximum value can reach to 7000 ppm when the equivalence ratio is 0.88 at 2500 rpm, maximum brake torque. The NOx emission shows different changing tendencies with different working conditions. Finally, these conclusions can be used to develop controlling strategies to solve the contradictions among power, brake thermal efficiency and NOx emission for the turbocharged hydrogen internal combustion engines.     

Theoretical investigation of the combustion performance of ammonia/hydrogen mixtures on a marine diesel engine

Ammonia is a good hydrogen carrier and can be well combined with hydrogen for combustion. The combustion performance of the mixtures of ammonia and hydrogen in a medium-speed marine diesel engine was investigated theoretically. The HCCI combustion mode was selected for reducing thermal-NO_x production. The start fire characteristic of the NH₃–H₂ mixtures was studied under different equivalence ratio, hydrogen-doped ratio, and intake air temperature and pressure. Then, the combustion performance of the NH₃–H₂ mixtures (doping 30% hydrogen) was analyzed at a typical operation condition of engine. The addition hydrogen improved the laminar flame velocity of ammonia, and affected the NO_x emission. For the medium-speed marine engine fueled with NH₃–H₂, reducing combustion temperature, introducing EGR and combining with post-treatment technology would be a feasible scheme to reduce NO_x emission.     

H2 effects on diesel combustion and emissions with an LPL-EGR system

In this study, we examined H₂ effects on the combustion and emissions of a diesel engine with low-pressure loop (LPL) exhaust gas recirculation (EGR). We converted a 2.2-L four-cylinder direct-injection diesel engine satisfying Euro5 for H₂ supply. An LPL-EGR system replaced the high-pressure loop (HPL) EGR system. For all tests, the brake mean effective pressure (BMEP) was kept at 4 bar and the EGR ratio was varied from 9 to 42%. The H₂ energy percentage was varied from 0 to 7.4% independently to evaluate the H₂ effects and EGR effects separately. The heat release rate was calculated from the measured cylinder pressure. We found that substitution of H₂ for diesel fuel made the premixed burn fraction larger, and reduced the nitrous oxide (NOx) and particulate matter (PM) emissions simultaneously. For example, the NOx emissions were reduced by 36% for an EGR of 42% and an H₂ percentage of 7.4%. PM emissions were reduced by 18% for an EGR of 35% and an H₂ percentage of 7.4% compared with diesel fuel only cases.     

Influence of hydrogen co-combustion with diesel fuel on performance,smoke and combustion phases in the compression ignition engine

The main objective of this study was to examine impact of hydrogen addition to the compression ignition engine fueled with either rapeseed methyl ester (RME) or 7% RME blended diesel fuel (RME7) on combustion phases and ignition delay as well as smoke and exhaust toxic emissions. Literature review shows in general, hydrogen in those cases is used in small amounts below lower flammability limits. Novelty of this work is in applying hydrogen at amounts up to 44% by energy as secondary fuel to the compression ignition engine. Results from experiments show that increase of hydrogen into the engine makes ignition delay shortened that also affects main combustion phase. In all tests the trends of exhaust HC and CO toxic emissions vs. hydrogen addition were negative. The trend of smokiness decreased steadily with increase of hydrogen. Amounts of hydrogen addition by energy share were limited to nearly 35% due to combustion knock occurring at nominal load.     

Experimental investigation on biogas enrichment with hydrogen for improving the combustion in diesel engine operating under dual fuel mode

Biogas valorization as fuel for internal combustion engines is one of the alternative fuels, which could be an interesting way to cope the fossil fuel depletion and the current environmental degradation. In this circumstance, an experimental investigation is achieved on a single cylinder DI diesel engine running under dual fuel mode with a focus on the improvement of biogas/diesel fuel combustion by hydrogen enrichment. In the present investigation, the mixture of biogas, containing 70% CH₄ and 30% CO₂, is blended with the desired amount of H₂ (up to 10, 15 and 20% by volume) by using MTI 200 analytical instrument gas chromatograph, which flow thereafter towards the engine intake manifold and mix with the intake air. Depending on engine load conditions, the volumetric composition of the inducted gaseous fraction is 20–50% biogas, 2–10% H₂ and 45–78% air. Near the end of the compression stroke, a small amount of diesel pilot fuel is injected to initiate the combustion of the gas–air mixture. Firstly, the engine was tested on conventional diesel mode (baseline case) and then under dual fuel mode using the biogas. Consequently, hydrogen has partially enriched the biogas. Combustion characteristics, performance parameters and pollutant emissions were investigated in-depth and compared. The results have shown that biogas enriched with 20% H₂ leads to 20% decrease of methane content in the overall exhaust emissions, associated with an improvement in engine performance. The emission levels of unburned hydrocarbon (UHC) and carbon monoxide (CO) are decreased up to 25% and 30% respectively. When the equivalence ratio is increased, a supplement decrease in UHC and CO emissions is achieved up to 28% and 30% respectively when loading the engine at 60%.     

Direct injection of hydrogen main fuel and diesel pilot fuel in a retrofitted single-cylinder compression ignition engine

Up to 90% hydrogen energy fraction was achieved in a hydrogen diesel dual-fuel direct injection (H2DDI) light-duty single-cylinder compression ignition engine. An automotive-size inline single-cylinder diesel engine was modified to install an additional hydrogen direct injector. The engine was operated at a constant speed of 2000 revolutions per minute and fixed combustion phasing of ?10 crank angle degrees before top dead centre (°CA bTDC) while evaluating the power output, efficiency, combustion and engine-out emissions. A parametric study was conducted at an intermediate load with 20–90% hydrogen energy fraction and 180-0 °CA bTDC injection timing. High indicated mean effective pressure (IMEP) of up to 943 kPa and 57.2% indicated efficiency was achieved at 90% hydrogen energy fraction, at the expense of NO_x emissions. The hydrogen injection timing directly controls the mixture condition and combustion mode. Early hydrogen injection timings exhibited premixed combustion behaviour while late injection timings produced mixing-controlled combustion, with an intermediate point reached at 40 °CA bTDC hydrogen injection timing. At 90% hydrogen energy fraction, the earlier injection timing leads to higher IMEP/efficiency but the NO_x increase is inevitable due to enhanced premixed combustion. To keep the NO_x increase minimal and achieve the same combustion phasing of a diesel baseline, the 40 °CA bTDC hydrogen injection timing shows the best performance at which 85.9% CO₂ reduction and 13.3% IMEP/efficiency increase are achieved.     

Effect of hydrogen addition on RCCI combustion of a heavy duty diesel engine fueled with landfill gas and diesel oil

The aim of this study is to investigate the effects of hydrogen addition on RCCI combustion of an engine running on landfill gas and diesel oil. A single cylinder heavy– duty diesel engine is set in operation at 9.4 bar IMEP. A certain amount of diesel fuel per cycle is fed into the engine and hydrogen is added to landfill gas while keeping fixed fuel energy content. The developed simulation results confirm that hydrogen addition which is the most environmental friendly fuel causes the fuel consumption per any cycle to reduce. Also, the peak pressure is increased while the engine load is reduced up to 4%. Landfill gas which is enriched with hydrogen improves the rate of methane dissociation and reduces the combustion duration at the same time the engine operation would not be exposed to diesel knock. Moreover, hydrogen addition to landfill gas would reduce engine emissions considerably.     

Effect of natural gas enrichment with hydrogen on combustion characteristics of a dual fuel diesel engine

Environmental benefits are one of the main motivations encouraging the use of natural gas as fuel for internal combustion engines. In addition to the better impact on pollution, natural gas is available in many areas. In this context, the present work investigates the effect of hydrogen addition to natural gas in dual fuel mode, on combustion characteristics improvement, in relation with engine performance. Various hydrogen fractions (10, 20 and 30 by v%) are examined. Results showed that natural gas enrichment with hydrogen leads in general to an improved gaseous fuel combustion, which corresponds to an enhanced heat release rate during gaseous fuel premixed phase, resulting in an increase in the in-cylinder peak pressure, especially at high engine load (4.1 bar at 70% load). The highest cumulative and rate of heat release correspond to 10% Hydrogen addition. The combustion duration of gaseous fuel combustion phase is reduced for all hydrogen blends. Moreover, this technique resulted in better combustion stability. For all hydrogen test blends, COV_IMEP does not exceed 10%. However, no major effect on combustion noise was noticed and the ignition delay was not affected significantly. Regarding performance, an important improvement in energy conversion was obtained with almost all hydrogen blends as a result of improved gaseous fuel combustion. A maximum thermal efficiency of 32.5%, almost similar to the one under diesel operation, and a minimum fuel consumption of 236 g/kWh, are achieved with 10% hydrogen enrichment at 70% engine load.