Recycling alkaline fuel cell waste heat for cooling production via temperature-matching elastocaloric cooler

To recycle byproduct waste heat, a new hybrid system model that integrates alkaline fuel cell (AFC) with temperature-matching elastocaloric cooler (ECC) is proposed. Considering diverse irreversible effects in thermodynamic and electrochemical processes, the mathematical model of hybrid system is formulated, and the performance metrics of the hybrid system are obtained. The optimally operating current density range of AFC enabling ECC to work is determined. Numerical calculation shows that the equivalent peak output power density and its according efficiency can be 51.64% and 20.88% higher than that of the single AFC, respectively. ECC is demonstrated to be an effective and competitive technology for AFC waste heat harvesting. In addition, considerable sensitivity analyses are performed to check the dependence of the proposed system performance on some key variables, including operating pressure, operating temperature, thermodynamic loss composite parameter, elastocaloric material types and elastocaloric properties, cross-sectional area ratio and length ratio for ECC. The results derived may offer some insights into the design or operation of practical AFC-ECC hybrid systems.     

Coupled thermal model of photovoltaic-thermoelectric hybrid panel for sample cities in Europe

In general, modeling of photovoltaic-thermoelectric (PV/TEG) hybrid panels have been mostly simplified and disconnected from the actual ambient conditions and thermal losses from the panel. In this study, a thermally coupled model of PV/TEG panel is established to precisely predict performance of the hybrid system under different weather conditions. The model takes into account solar irradiation, wind speed and ambient temperature as well as convective and radiated heat losses from the front and rear surfaces of the panel. The model is developed for three sample cities in Europe with different weather conditions. The results show that radiated heat loss from the front surface and the convective heat loss due to the wind speed are the most critical parameters on performance of the hybrid panel performance. The results also indicate that, with existing thermoelectric materials, the power generation by the TEG is insignificant compared to electrical output by the PV panel, and the TEG plays only a small role on power generation in the hybrid PV/TEG panel. However, contribution of the TEG in the power generation can be improved via higher ZT thermoelectric materials and geometry optimization of the TEG.     

Energetic and exergetic analyses of a combined system consisting of a high-temperature polymer electrolyte membrane fuel cell and a thermoelectric generator with Thomson effect

A combined system model consisting of a high-temperature polymer electrolyte membrane fuel cell (HT-PEMFC), a regenerator and a thermoelectric generator (TEG) is proposed, where the TEG is applied to harness the generated waste heat in the HT-PEMFC for extra electricity production. The TEG considers not only the Seebeck effect and Peltier effect but also the Thomson effect. The mathematical expressions of power output, energy efficiency, exergy destruction rate and exergy efficiency for the proposed system are derived. The energetic and exergetic performance characteristics for the whole system are revealed. The optimum operating ranges for some key performance parameters of the combined system are determined using the maximum power density as the objective function. The combined system maximum power density and its corresponding energy efficiency and exergy efficiency allow 19.1%, 12.4% and 12.6% higher than that of a stand-alone HT-PEMFC, while the exergy destruction rate density is only increased by 8.6%. The system performances are compared between the TEG with and without the Thomson effect. Moreover, the impacts of comprehensive parameters on the system performance characteristics are discussed. The obtained results are helpful in developing and designing such an actual combined system for efficient and clean power production.     

A hybrid TEG/wind system using concentrated solar energy and chimney effect

This paper investigates a novel hybrid system combining thermal electrical generators (TEGs) and a wind turbine. The mathematical model of the system is derived and solved to investigate the performance of the proposed system. In the proposed system, solar energy is converted to heat by an absorber plate. Some portion of this heat is converted to electricity using TEG, while another portion of the heat is used to heat up air flowing in an inclined duct placed underneath the absorber plate. Heating the air inside the system enhances the current speed because of the effect of buoyancy. A wind turbine is placed inside the duct parallel to air flow before it exits to the atmosphere. The wind current is accelerated before passing through the turbine by using venture effect. The TEGs are exposed to the concentrated solar radiation. This can be obtained using a compound parabolic concentrator. The proposed configuration has multiadvantages: (1) the wind is used to drive a wind turbine; (2) air cools the rear surfaces of TEGs to increase the temperature difference between the opposite surfaces, thus generates more electrical power; and (3) it uses buoyancy effect to increase the wind stream speed, thus enhancing the power generated from turbine. It is found that the solar concentration ratio is the most important factor contributing to enhancing the TEG efficiency. The buoyancy effect leads to turbine power boost at high wind speeds more than at low wind speeds.     

Design optimization under uncertainty of hybrid fuel cell energy systems for power generation and cooling purposes

Reliance on point estimates when developing hybrid energy systems can over/underestimate system performance. Analyzing the sensitivity and uncertainty of large-scale hybrid systems can be a challenging task due to the large number of design parameters to be explored. In this work, a comprehensive and efficient sensitivity/uncertainty methodology is applied on two fuel cell hybrid systems to help analysts to investigate hybrid systems more efficiently. This methodology also includes a step-by-step approach to perform design optimization under uncertainty of energy systems. The two hybrid systems are: molten carbonate fuel cell with thermoelectric generator (MCFC-TEG) and phosphoric acid fuel cell with refrigerator (PAFC-REF). Various sensitivity and uncertainty methods are utilized to analyze the design parameters and their effect on the performance of these two systems. These methods perform local and regression-based sensitivity analysis, Monte Carlo uncertainty propagation, parameter screening, and variance decomposition. Detailed approach is adopted to identify and rank the influential design parameters for each system. Results demonstrate that the optimum power output of the MCFC-TEG has 10% uncertainty, driven mainly by the operating temperature, cahtode activation energy, TEG figure of merit, and TEG thermal conductivity. However, PAFC-REF is more reliable with larger power output and 1.4% uncertainty, driven by the charge transfer coefficient, heat transfer in the refrigeration cycle, cold reservoir temperature, and operating temperature. Based on this identification, design optimization under uncertainty is performed using these sensitive parameters to improve the system performance through increasing the power output and reducing its uncertainty.     

Thermoelectric conversion of waste heat from IC engine‐driven vehicles: A review of its application,issues, and solutions

Thermoelectric generator (TEG) is a promising thermoelectric (TE) conversion technology to effectively recover and convert waste heat from vehicle exhaust into useful energy, ie, electricity. Exhaust TEG (ETEG) is a system that is incorporated into the exhaust manifold of a vehicle. Exhaust TEG comprises of a heat exchanger, TEG modules, heat sink, and power conditioning unit. The present work reviews different vehicular ETEGs based on engine type, engine‐rated power, type and number of TEG module, efficiency of ETEG and TEG, exhaust and coolant temperature, and power output of ETEG . In addition to these, the technical issues faced in these ETEGs are addressed under 2 categories, viz., primary (TEG with low ZT TE material and inefficient heat exchanger and heat sink) and secondary issues (low operating temperature TEG modules and installation position of ETEG). In addition to it, effects of vibration and thermal cycling of exhaust system on TEG modules that may arise in ETEG are also discussed. A review of preventive solutions to the issues is also presented. Finally, the economic aspects of an ETEG are also discussed. The review highlights the need of commercialization of TE materials with ZT > 2, high‐temperature operating range, and segmented TEG modules in large volumes so that their practice can be extended in vehicular applications. Heat exchanger modeling using computational fluid dynamics and interfacing with heat transfer theory is essential to maintain temperature uniformity across the TEG modules. Installation of ETEG in the exhaust pipe should be such that it does not affect the performance of the engine. It is also realized that sturdy TEG modules should be developed for long‐term operation to prevent degradation due to mechanical vibration and thermal cycling of the vehicle. Further, ETEG is economically beneficial in vehicles such as trucks owing to availability of high thermal energy in their exhaust stream.     

A thermoelectric generator and water-cooling assisted high conversion efficiency polycrystalline silicon photovoltaic system

Solar energy has been increasing its share in the global energy structure. However, the thermal radiation brought by sunlight will attenuate the efficiency of solar cells. To reduce the temperature of the photovoltaic (PV) cell and improve the utilization efficiency of solar energy, a hybrid system composed of the PV cell, a thermoelectric generator (TEG), and a water-cooled plate (WCP) was manufactured. The WCP cannot only cool the PV cell, but also effectively generate additional electric energy with the TEG using the waste heat of the PV cell. The changes in the efficiency and power density of the hybrid system were obtained by real time monitoring. The thermal and electrical tests were performed at different irradiations and the same experiment temperature of 22°C. At a light intensity of 1000 W/m², the steady-state temperature of the PV cell decreases from 86.8°C to 54.1°C, and the overall efficiency increases from 15.6% to 21.1%. At a light intensity of 800 W/m², the steady-state temperature of the PV cell decreases from 70°C to 45.8°C, and the overall efficiency increases from 9.28% to 12.59%. At a light intensity of 400 W/m², the steady-state temperature of the PV cell decreases from 38.5°C to 31.5°C, and the overall efficiency is approximately 3.8%, basically remain unchanged.     

Integrating high-temperature proton exchange membrane fuel cell with duplex thermoelectric cooler for electricity and cooling cogeneration

To harvest the waste heat from exothermic reaction processes, a novel hybrid system model mainly incorporating a high-temperature proton exchange membrane fuel cell (HT-PEMFC) and a duplex thermoelectric cooler is conceptualized to theoretically predict the potential performance limit. The duplex thermoelectric cooler is composed of a thermoelectric generator (TEG) and a thermoelectric cooler (TEC), where the TEG harvests the waste heat to generate electricity and the TEC utilizes the generated electricity for cooling production. A mathematical model is established to estimate the proposed system performance from both exergetic and energetic perspectives considering various irreversible effects, from which effectiveness and practicality of the proposed system can be examined. The hybrid system maximal output power density allows 14.1% greater than that of the basic HT-PEMFC, whereas the according destruction rate density of exergy is decreased by 7.7%. The feasibility and effectiveness of the proposed system configuration are verified. Moreover, substantial parametric analyses indicate that the proposed system performance can be improved by elevating the HT-PEMFC operating temperature, inlet relative humidity and doping level while worsened by enhancing the leak current density, electrolyte thickness and Thomson coefficient. The results acquired may be helpful in designing and optimizing such an actual hybrid system.     

MCFC-并联TTEG混合系统的性能优化

为有效回收熔融碳酸盐燃料电池产生的余热,提出一种由熔融碳酸盐燃料电池(MCFC)、两级并联温差发电器(TTEG)和回热器组合而成的混合系统模型.考虑MCFC电化学反应中的过电势损失和混合系统中的不可逆损失,通过数值分析得出混合系统的输出功率和效率的数学表达式,获得混合系统的一般性能特征,讨论MCFC电流密度与温差发电器...     

Exergy flow and energy utilization of direct methanol fuel cells based on a mathematic model

An exergetic analysis model for direct methanol fuel cell (DMFC) is established in the present paper. Expressions of electrical, thermal and total exergetic efficiencies have been deduced with consideration of methanol crossover and over potential in operation. Furthermore, energy utilization of a DMFC system is quantitatively calculated and changes of electrical efficiency and thermal efficiency at various current density, methanol concentration, operating temperature, and cathode pressure have been investigated. Some suggestions of optimal operating conditions of direct methanol fuel cell based on our findings are put forward. Results show that the thermal energy generated in a DMFC takes up a significant amount of exergy in total energy and should be sufficiently used to obtain high total efficiency in a DMFC, high methanol crossover rate is the predominant cause of energy loss when the fuel cell operates at low current density, and total exergetic efficiency of a DMFC reaches its peak value at relatively high current density.     

Experiments and simulations on low-temperature waste heat harvesting system by thermoelectric power generators

In this case study, a system to recover waste heat comprised 24 thermoelectric generators (TEG) to convert heat from the exhaust pipe of an automobile to electrical energy has been constructed. Simulations and experiments for the thermoelectric module in this system are undertaken to assess the feasibility of these applications. A slopping block is designed on the basis of simulation results to uniform the interior thermal field that improves the performance of TEG modules. Besides simulations, the system is designed and assembled. Measurements followed the connection of the system to the middle of an exhaust pipe. Open circuit voltage and maximum power output of the system are characterized as a function of temperature difference. Through these simulations and experiments, the power generated with a commercial TEG module is presented. Overview this case study and our previous work, the results establish the fundamental development of low-temperature waste heat thermoelectric generator system that enhances the TEG efficiency for vehicles.     

The performance analysis and multi-objective optimization of a typical alkaline fuel cell

Based on the model of a typical alkaline fuel cell (AFC) with circulating potassium hydroxide (KOH) solution as electrolyte and oxygen as oxidant and the experimental data available in the current literature, thermodynamic-electrochemical analyses on the performance of the AFC are carried out, in which multi-irreversibilities such as charger-transfer, concentration and ohmic overpotentials are taken into account. Expressions for the power output and efficiency of the AFC are derived, from which the general performance characteristics of the AFC are discussed in detail. It is found that the power output and efficiency of the AFC first increase and then decrease as the electrolyte concentration is increased, and consequently, there exist the optimal electrolyte concentrations for different temperatures. It is also found that the power output is not a monotonic function of the electric current density while the efficiency is a monotonically decreasing function of the electric current density. According to the performance characteristic curves of the AFC, the optimal operation regions of some main parameters are determined. Moreover, a new multi-objective function is used to further optimize the characteristics of the AFC. Some significant results for the optimal design and operation of practical AFCs are obtained.     

Energy efficiency analysis and impact evaluation of the application of thermoelectric power cycle to today’s CHP systems

High efficiency thermoelectric generators (TEG) can recover waste heat from both industrial and private sectors. Thus, the development and deployment of TEG may represent one of the main drives for technological change and fuel substitution. This paper will present an analysis of system efficiency related to the integration of TEG into thermal energy systems, especially Combined Heat and Power production (CHP). Representative implementations of installing TEG in CHP plants to utilize waste heat, wherein electricity can be generated in situ as a by-product, will be described to show advantageous configurations for combustion systems. The feasible deployment of TEG in various CHP plants will be examined in terms of heat source temperature range, influences on CHP power specification and thermal environment, as well as potential benefits. The overall conversion efficiency improvements and economic benefits, together with the environmental impact of this deployment, will then be estimated. By using the Danish thermal energy system as a paradigm, this paper will consider the TEG application to district heating systems and power plants through the EnergyPLAN model, which has been created to design suitable energy strategies for the integration of electricity production into the overall energy system.     

Parameter optimization study on SOFC‐MGT hybrid power system

This paper mainly studied the solid oxide fuel cell (SOFC)–micro gas turbine (MGT) hybrid power system. The key parameters that greatly influence the overall system performance have been studied and optimized. The thermodynamic potential of improving the hybrid system performance by integrating SOFC with the advanced thermal cycle system is analyzed. The optimization rules of main parameters of SOFC‐MGT hybrid power system with the turbine inlet temperature (TIT) of MGT as a constraint condition are revealed. The research results show that TIT is a key parameter that limits the electrical efficiency of hybrid power system. With the increase of the cell number, both the power generation efficiency of the hybrid cycle power system and TIT increase. Regarding the hybrid system with the fixed cell number, in order to get a higher electrical efficiency, the operating temperature of SOFC should be enhanced as far as possible. However, the higher operating temperature will result in the higher TIT. Increasing of fuel utilization factor is an effective measure to improve the performance of hybrid system. At the same time, TIT increases slightly. Both the electrical efficiency of hybrid power system and TIT reduce with the increase of the ratio of steam to carbon. The achievements obtained from this paper will provide valuable information for further study on SOFC‐MGT hybrid power system with high efficiency. Copyright © 2010 John Wiley & Sons, Ltd.     

Development of solid oxide fuel cell and battery hybrid power generation system

Solid oxide fuel cell hybrid generation system is the best scheme for the load tracking of off-grid monitoring stations. But there are still potential problems that need to be addressed: preventing fuel starvation and ensuring thermal safety while meeting load tracking in hybrid power generation system. In order to solve these problems, a feasible hybrid power generation system structure scheme is proposed which combined SOFC subsystem and Li-ion battery subsystem. Then a model of the hybrid power generation system is built based on the proposed system structure. On this basis, an adaptive controller, include the adaptive energy management algorithm and current feedforward gas supply strategy, is applied to manage the power-sharing in this hybrid system as well as keep the system operating within the safety constraints. The constraints, including maintaining the bus voltage at the desired level, keeping SOFC operating temperature in safety, and mitigating fuel starvation are explicitly considered. The stability of the proposed energy management algorithm is analyzed. Finally, the developed control algorithm is applied to the hybrid power generation system model, the operation result proves the feasibility of the designed controller strategy for hybrid generation system and effectively prevent fuel starvation and ensure thermal safety.     

Thermodynamic analysis of a parabolic trough solar power plant integrated with a biomass-based hydrogen production system

In the current study, a solar energy power plant integrated with a biomass-based hydrogen production system is investigated. The proposed plant is designed to supply the required energy for the hydrogen production process along with the electrical energy generation. Thermochemical processes are used to obtain high-purity hydrogen from biomass-based syngas. For this purpose, the simulation of the plant is performed using Aspen HYSYS software. Thermodynamic performance evaluation of the hybrid system is conducted with exergy analysis. Based on the obtained results, the exergy efficiencies of the hydrogen production process and power generation systems are 55.8% and 39.6%, respectively. The net power output of the system is obtained to be 38.89 MWe. Furthermore, the amount of produced hydrogen in the integrated system is 7912.5 tons/year with a flow rate of 10.8 tons/h synthesis gas for 7500 h/year operation. Results show that designing and operating a hybrid high-performance energy system using two different renewable sources is an encouraging approach to reduce the environmental impact of energy conversion processes and the effective use of energy resources.     

A 500 W low-temperature thermoelectric generator: Design and experimental study

Most of the current thermal power-generation technologies must first convert thermal energy to mechanical work before producing electricity. In this study, a direct heat to electricity (DHE) technology using the thermoelectric effect, without the need to change through mechanical energy, was applied to harvest low-enthalpy thermal work. Such a power generation system has been designed and built using thermoelectric generator (TEG) modules. Experiments have been conducted to measure the output power at different conditions: different inlet temperature and temperature differences between hot and cold sides. TEG modules manufactured with different materials have also been tested. The power generator assembled with 96 TEG modules had an installed power of 500 W at a temperature difference of around 200 °C. An output power of over 160 W has been generated with a temperature difference of 80 °C. The power generated by the thermoelectric system is almost directly proportional to the temperature difference between the hot and the cold sides. The cost of the DHE power generator is lower than that of photovoltaics (PV) in terms of equivalent energy generated.     

A computational simulation of an alkaline fuel cell

An advanced one-dimensional, isothermal mathematical model for a single cell of an alkaline fuel cell (AFC) is presented. Advances in an expression for the volume average velocity and in correlations and parameters are achieved. The parameters and operating conditions of the model are based on the Obiter Fuel Cell, which is employed as a power source for NASA space shuttles. A stimulated result is obtained that shows a close agreement with some of the experimental data. Profiles of variables, local overpotential and local current density are also obtained as a function of cell voltage. An investigation of the influence of initial electrolyte concentration shows that the performance of the AFC is maximized at a concentration of 3.5 M. Finally, it is found that increasing the operating pressure steadily enhances cell performance.     

Analytical model of parallel thermoelectric generator

The paper studied the performances of parallel thermoelectric generator (TEG) by theoretical analysis and experimental test. An analytical model of parallel TEG was developed by theoretical analysis and calculation, based on thermodynamics theory, semiconductor thermoelectric theory and law of conservation of energy. Approximate expressions of output power and current of parallel TEG were deduced by the analytical model. An experimental system was built to verify the model. The results indicate that only when all of the thermoelectric modules (TE modules) in the parallel TEG have the same inherent parameters and working conditions, the parallel properties of the TEG are the same as that of common DC power. The existence of contact resistance is just like the increase of the TE module’s internal resistance, which leads to the deceases of output power. The thermal contact resistance reduces the output power by reducing the temperature difference between the two sides of the thermocouples. The results derived from the model are basically consistent with the experimental results, the model is suitable for the performance researching and designing of parallel TEG.     

Electrical and electrical–thermal power plants with molten carbonate fuel cell/gas turbine‐integrated systems

In this article the calculation tool further developed and implemented in Matlab language by the authors was used to determine some optimal operating conditions in electrical and thermal or electrical terms for two different types of hybrid systems: molten carbonate fuel cells (MCFC)/gas turbine with their heat recovery system and the hybrid systems operating in these optimal conditions were analyzed. In the heat recovery system, in both cases, a part of the thermal energy of these gases is used to produce the steam necessary for the MCFC system. The remaining thermal energy is used, in one case, for the production of steam at various levels of pressure and temperature, which feeds a steam bottom plant to produce additional electric energy; in the other case, the same thermal energy is used to produce steam for cogenerative use. The heat recovery system was suitably designed according to the circumstances and the performances and the specific CO₂ emissions of the hybrid systems were evaluated. Copyright © 2010 John Wiley & Sons, Ltd.