An effective Seebeck coefficient obtained by experimental results of a thermoelectric generator module

This article proposes a concept of “effective Seebeck coefficient”, which discusses the inconsistency between the theoretical Seebeck coefficient and the measured one. The inconsistency can be explained via contact effect and thermal resistor network. Two different clamping forces are applied to the TEG module to observe the contact effect. Throughout the experiments, the electric resistance seems insensitive to the clamping force; somehow the thermal contact effect dominates the TEG module performance. In addition, a thermal resistor network, which is used to calculate the exact temperature difference traverse the TE ingot, has been constructed. After applying a suitable clamping pressure and modifying the actual ΔT with thermal resistor network, the “effective Seebeck coefficient” has been proposed. Notably, this proposed value is very helpful for better understanding characteristics of the behavior of the TEG module operating in the actual conditions we provided, and it can be used to predict the performance of the TEG module under any other condition.     

Experimental and analytical study on thermoelectric self cooling of devices

This paper presents and studies the novel concept of thermoelectric self cooling, which can be introduced as the cooling and temperature control of a device using thermoelectric technology without electricity consumption.For this study, it is designed a device endowed with an internal heat source. Subsequently, a commonly used cooling system is attached to the device and the thermal performance is statistically assessed. Afterwards, it is developed and studied a thermoelectric self cooling system appropriate for the device.Experimental and analytical results show that the thermal resistance between the heat source and the environment reduced by 25-30% when the thermoelectric self cooling system is installed, and indicates the promising applicability of this technology to devices that generate large amounts of heat, such as electrical power converters, transformers and control systems. Likewise, it was statistically proved that the thermoelectric self cooling system leads to significant reductions in the temperature difference between the heat source and the environment, and, what is more, this reduction increases as the heat flow generated by the heat source increases, which makes evident the fact that thermoelectric self cooling systems work as temperature controllers.     

A novel maximum power point tracker for thermoelectric generation system

In this paper, a novel hybrid maximum power point tracking (MPPT) method is proposed and investigated. The proposed MPPT technique combines the simplicity of perturb and observe (P&O) method and the fast tracking ability of open circuit voltage (OCV) method. The advantages of the proposed MPPT approach include fast tracking speed, no additional circuit required and no temporary power loss. To validate the feasibility of the proposed MPPT technique, an 1.2 kW thermoelectric generation system for industrial waste heat recovery is also constructed, experimental results show that comparing with conventional P&O technique, the proposed method can improve the tracking speed for 42.9% and 86.2% when temperature differences are ΔT = 60 °C and ΔT = 180 °C, respectively. Moreover, the energy loss can be improved by 24.0% and 87.0% when temperature differences are ΔT = 60 °C and ΔT = 180 °C, respectively.     

Energy efficiency analysis and impact evaluation of the application of thermoelectric power cycle to today’s CHP systems

High efficiency thermoelectric generators (TEG) can recover waste heat from both industrial and private sectors. Thus, the development and deployment of TEG may represent one of the main drives for technological change and fuel substitution. This paper will present an analysis of system efficiency related to the integration of TEG into thermal energy systems, especially Combined Heat and Power production (CHP). Representative implementations of installing TEG in CHP plants to utilize waste heat, wherein electricity can be generated in situ as a by-product, will be described to show advantageous configurations for combustion systems. The feasible deployment of TEG in various CHP plants will be examined in terms of heat source temperature range, influences on CHP power specification and thermal environment, as well as potential benefits. The overall conversion efficiency improvements and economic benefits, together with the environmental impact of this deployment, will then be estimated. By using the Danish thermal energy system as a paradigm, this paper will consider the TEG application to district heating systems and power plants through the EnergyPLAN model, which has been created to design suitable energy strategies for the integration of electricity production into the overall energy system.     

A numerical study on the performance of miniature thermoelectric cooler affected by Thomson effect

Miniature thermoelectric cooler (TEC) has been considered as a promising device to achieve effective cooling in microprocessors and other small-scale equipments. To understand the performances of miniature thermoelectric coolers, three different thermoelectric cooling modules are analyzed through a three-dimensional numerical simulation. Particular attention is paid to the influence of scaling effect and Thomson effect on the cooling performance. Two different temperature differences of 0 and 10 K between the top and the bottom copper interconnectors are taken into account. In addition, three different modules of TEC, consisting of 8, 20 and 40 pairs of TEC, are investigated where a single TEC length decreases from 500 to 100 μm with the condition of fixed ratio of cross-sectional area to length. It is observed that when the number of pairs of TEC in a module is increased from 8 to 40, the cooling power of the module grows drastically, revealing that the miniature TEC is a desirable route to achieve thermoelectric cooling with high performance. The obtained results also suggest that the cooling power of a thermoelectric cooling module with Thomson effect can be improved by a factor of 5-7%, and the higher the number of pairs of TEC, the better the improvement of the Thomson effect on the cooling power.     

Design of innovative power conditioning system for the grid integration of thermoelectric generators

Recently, thermoelectric generators (TEGs) have emerged as a potential alternative for clean energy generation, due mainly to the technology innovation and the marked cost reduction of modules, as well as their distinctive advantages. In a TEG system, the electronic power conditioning system (PCS) plays a vital role in ensuring the effective power grid integration, since it is subject to requirements related not only to the variable thermal source itself but also to its effects on the grid operation. This paper proposes an enhanced structure of PCS for the grid integration of TEG arrays to maximize the energy capture from a variable heat source. The innovative topology employed consists of a Z-source inverter that allows the flexible, efficient and reliable generation of high quality electric power from the TEG array. A full detailed model is described and its control scheme is designed. The dynamic performance of the proposed systems is fully validated by computer simulation and experimental studies.     

Neural network model of 100 W portable PEM fuel cell and experimental verification

The inherent properties of artificial neural networks (ANNs) such as low sensitivity to noise and incomplete information make the ANN a promising candidate to model the fuel cell system. In this paper, an ANN-based model of 100 W portable direct hydrogen fed proton exchange membrane fuel cell (PEMFC) is presented. The model is built based on experimentally collected data from a portable 100 W direct hydrogen fed PEMFC in the authors’ laboratory. A multilayer feedforward ANN with back-propagation training algorithm is used to model the portable PEMFC. The ANN consists of fully connected four layers network with two hidden layers. The PEMFC ANN model is trained using extracted data from experimentally measured and calculated parameters. To validate the model, the outputs of the PEMFC ANN are compared against experimental data and results from a dynamic model of portable direct hydrogen fed PEMFC. In addition, three statistical indices to measure variations, unbiasedness (precision), and accuracy in voltage, power, and hydrogen flow are used to evaluate the PEMFC ANN model performance. The indices indicate that the maximum variations, unbiasedness, and accuracy of the voltage, power, and hydrogen flow are 1.45%, 2.04%, and 1.90%, respectively, which shows a close agreement between the outputs of the PEMFC ANN and the experimental results.     

A novel thermoelectric refrigeration system employing heat pipes and a phase change material: an experimental investigation

This paper presents results of tests carried out to investigate the potential application of heat pipes and phase change materials for thermoelectric refrigeration. The work involved the design and construction of a thermoelectric refrigeration prototype. The performance of the thermoelectric refrigeration system was investigated for two different configurations. The first configuration employed a conventional heat sink system (bonded fin heat sink) on the cold side of the thermoelectric cells. The other configuration used an encapsulated phase change material in place of the conventional heat sink unit. Both configurations used heat pipe embedded fins as the heat sink on the hot side. Replacement of the conventional heat sink system with an encapsulated phase change material was found to improve the performance of the thermoelectric refrigeration system. In addition, it provided a storage capability that would be particularly useful for handling peak loads and overcoming losses during door openings and power-off periods. Results showed that the heat sink units employing heat pipe embedded fins were well suited to this application. Results also showed the importance of using a heat pipe system between the cold junction of the thermoelectric cells and the cold heat sink in order to prevent reverse heat flow in the event of power failure.     

Development of a 30 W class direct formic acid fuel cell stack with high stability and durability

A medium-scale DFAFC stack was designed and fabricated in this work. The power output of this stack was high to 32 W, which can satisfy the power requirement of most portable electrical devices. The ultrasonically mixed Pt/C + Pd/C catalyst was optimized as the anode catalyst for the stack fabrication by using a single cell. The feeding formic acid concentration and oxygen flow rate respectively in anode and cathode side were also experimentally optimized before the stack fabrication. Under the optimal operation conditions, the life time test was carried out for the DFAFC stack using the optimal anode catalyst. The stack can stably operate for about 50 h with 1.5 L fuel supplied, and its high durability was confirmed by the 240 h continuous life time test.     

The impact of increased interconnection on electricity systems with large penetrations of wind generation: A case study of Ireland and Great Britain

Increased interconnection has been highlighted as potentially facilitating the integration of wind generation in power systems by increasing the flexibility to balance the variable wind output. This paper utilizes a stochastic unit commitment model to simulate the impacts of increased interconnection for the island of Ireland with large penetrations of wind generation. The results suggest that increased interconnection should reduce average prices in Ireland, and the variability of those prices. The simulations also suggest that while increased interconnection may reduce carbon dioxide emissions in Ireland, Great Britain would experience an increase in emissions, resulting in total emissions remaining almost unchanged. The studies suggest that increased interconnection would not reduce excess wind generation. This is because under unit commitment techniques which incorporate wind power forecasts in the scheduling decisions, wind curtailment is minimal even with low levels of interconnection. As would be expected an increase in interconnection should improve system adequacy considerably with a significant reduction in the number of hours when the load and reserve constraints are not met.     

Design, integration and demonstration of a 50 W JP8/kerosene fueled portable SOFC power generator

A man-portable solid oxide fuel cell (SOFC) system integrated with desulfurized JP8 partial oxidation (POX) reformer was demonstrated to supply a continuous power output of 50 W. This paper discusses some of the design paths chosen and challenges faced during the thermal integration of the stack and reformer in aiding the system startup and shutdown along with balance of plant and power management solutions. The package design, system capabilities, and test results of the prototype unit are presented.     

A miniaturized power generation system cascade utilizing thermal energy of a micro-combustor: Design and modelling

Currently, combustion-based micro power devices encounter the problem of low conversion efficiency. A miniaturized power generation system cascade utilizing thermal energy of a micro-combustor is proposed, because thermophotovoltaic (TPV) cells and thermoelectric (TE) modules work at different temperature levels. The system consists of a planar micro-combustor with a bended extension at the exit, two GaSb TPV modules to convert high temperature thermal radiation and two Bi–Te based TE modules attached to the bended extension to harness medium temperature thermal energy. The mathematical modelling approach to quantify the power output and conversion efficiency is systematically presented. The modelling results show that the integration of the TE modules could significantly improve the system efficiency. When burning the H₂/air mixture, the overall system efficiency could reach 2.5% under the flow condition of U₀ = 3 m/s and Φ = 1.0. Finally, measures for better thermal management to further enhance the conversion efficiency are discussed.     

CO tolerance and durability study of PtMe(Me = Ir or Pd) electrocatalysts for H2-PEMFC application

In the present work, carbon supported PtMe (Me = Ir or Pd) electrocatalysts, with different atomic ratios (Pt/Me (20 wt%) = 3:1, 1:1, 1:3), are thoroughly investigated towards CO tolerance and durability, as anode and cathode for H₂-PEMFCs (hydrogen fed proton exchange membrane fuel cells) application. The electrocatalysts are prepared via a pulse-microwave assisted polyol synthesis method and their durability and electrocatalytic activity in presence and absence of CO are evaluated using the techniques of electrochemical impedance spectroscopy (EIS), cyclic voltammetry (CV), linear sweep voltammetry (LSV), chronoamperometry (CA) and rotating disk electrode (RDE). For the investigation of CO tolerance a protocol is set that could be used by other research groups, since various procedures are reported in literature. It is found that Pd/C shows higher CO tolerance than Pt/C, while the PtPd₃/C exhibits the highest CO tolerance ability, even after being exposed for 9 h at 400 ppm CO. Despite the fact that Pt₃Ir/C shows higher CO tolerance ability than Pt/C, it cannot resist at such high CO concentrations for more than 6 h. Finally, it is found that PtIr/C and PtPd/C exhibit very good durability even after 5000 accelerated durability test (ADT) cycles, while Pt₃Pd/C and PtPd/C present the highest mass activities (339.4 and 410 mA/mg_Pt respectively at 0.9 V), which are 4 and 5 times higher than the one observed over commercial Pt/C (82.75 mA/mg_Pt).     

Fuel cells and energy networks of electricity,heat, and hydrogen: A demonstration in hydrogen-fueled apartments

A demonstration was performed to evaluate our proposal of a residential energy system based on fuel cells and energy networks of electricity, hot water, and hydrogen. The demonstration was conducted from April 2007 to March 2009 in a small apartment building constructed for experimental purposes in Osaka City. Three small proton exchange membrane fuel cells were installed, and the electricity and hot water from the fuel cells were shared among 6 units via an internal electricity grid and hot water pipe. A hydrogen production facility, a small storage device, and a hydrogen pipe were installed to supply hydrogen to the fuel cells. Six families went about their normal daily lives using this system. The energy flow from hydrogen production to consumption was demonstrated. The results of fuel cell operation, energy supply, and energy demand, as well as an analysis of primary energy saving and CO₂ emission mitigation are presented.     

Multi‐fault detection and diagnosis of HVAC systems: an experimental study

The objective of this study is to detect faults due to multiple element failures in HVAC systems occurring concurrently. To classify and detect single as well as multiple faults, measurements were made of supply air temperature, OA‐damper position, supply fan pressure, indoor temperature and airflow rate in a variable air volume heating ventilating and air conditioning test facility. Experimental results show that three types of patterns emerge in the analysis of multi‐fault problems. To solve the multi‐fault problem, a new strategy based on pattern classification and the use of residual ratios is presented. It is shown that the residual ratio can be used to diagnose and accurately identify and detect multiple‐faults occurring in HVAC systems. Copyright © 2005 John Wiley & Sons, Ltd.     

A maximum power tracking algorithm based on Impp = f(Pmax) function for matching passive and active loads to a photovoltaic generator

In this paper, a method that forces a photovoltaic generator (PVG) to operate at its maximum power point under variable load and insolation conditions is developed. The method is based on closed loop current control, in which the reference current is determined from the fitted function of I_mpp versus P_max, points of a particular PVG. A simplified computer model of the PVG is given and computer simulations for demonstrating the effectiveness of the proposed algorithm are presented. The method has also been applied using a PC with IO interface card in the laboratory. From the results of the simulations and experimental studies, it is concluded that the proposed approach can be used as a robust and fast acting maximum power point tracker.     

Photovoltaics in buildings: A case study for rural England and Malaysia

This paper presents results obtained from a practical study of photovoltaics in buildings, in rural England and a computer model simulation study in Malaysia. It is a particular application of Building integrated PhotoVoltaics (BiPV) where the PV modules are fitted as partial roofing material. Data from a monitored BiPV-UK installation were analysed and compared with PVSYST 2.0 predictions. This computer model was then used to simulate BiPV applications for the standard school building in Malaysia, enhanced with a thermal computer model SUNREL 1.0β. Whilst cost-effectiveness has been a major issue in its proliferated use, the technology has been without doubt established. Based on the simulated system performances, it can be seen that the application of BiPV technology in Malaysia seems to offer a much better potential as has been expected.     

The country-dependent shaping of ‘hydrogen niche’ formation: A comparative case study of the UK and South Korea from the innovation system perspective

This paper reports an international comparison of hydrogen niche formation in the UK and South Korea with special regard to policy development. Hydrogen energy development has provided us with a good example of ongoing phenomena during the early stage of socio-technical transition, in other words, the socio-technical niche. The purpose of the case studies was to see the country dependence in shaping the early stage (the period between the year 2002 and 2005) of hydrogen niche formation from the national innovation system perspective. The findings show certain differences in the background of hydrogen energy policies and the manners of policy development. There also are differences in the R&D activities, including not only the way in which they are performed, but also the strategic focussing of R&D, which have been influenced by R&D systems and the industrial structures of the national innovation systems. Vision-articulating processes and the roles and tendency towards intervention of governments are diverse. The research result will contribute to better understanding of the geography of socio-technical transition with empirical evidence. From that, one will be hinted that the hydrogen future may be diverse in different locations.     

A study of thin‐flame quasisteady sphericosymmetric combustion of multicomponent fuel droplets. Part I: modelling for droplet surface regression and non‐unity gas‐phase Lewis number

A model for sphericosymmetric thin‐flame combustion of multicomponent fuel droplets has been developed in the first part of this two‐part work. The model incorporates effects of droplet surface regression and gas‐phase Lewis number. It is observed that both these effects affect the results substantially. The study also reveals the transient nature of the combustion process. Copyright © 1999 John Wiley and Sons, Ltd.