Effect of ignition timing and compression ratio on the performance of a hydrogen–ethanol fuelled engine

This paper presents the results obtained of a compression ignition engine (modified to run on spark ignition mode) fuelled with hydrogen–ethanol dual fuel combination with different percentage substitutions of hydrogen (0–80% by volume with an increment of 20%) under variable compression ratio conditions (i.e. 7:1, 9:1 and 11:1) by varying the spark ignition timing at a constant speed of 1500 rpm. The various engine performance parameters studied were brake specific fuel consumption, brake mean effective pressure and brake thermal efficiency. It was found from the present study that for specific ignition timing the brake mean effective pressure and the brake thermal efficiency increases with the increase of hydrogen fraction in ethanol and all hydrogen substitutions showed the maximum increase in brake thermal efficiency and reduction in brake specific fuel consumption value at around 25^° CA advanced ignition timing. The best operating conditions were obtained at a compression ratio of 11:1 and the optimum fuel combination was found to be 60–80% hydrogen substitution to ethanol.     

Investigations on the influence of ethanol and water injection techniques on engine's behavior of a hydrogen - biofuel based dual fuel engine

This work explores the influence of hydrogen and ethanol on improving engine's behavior of Maduca longifolia oil (MO) based dual fuel diesel engine. A mono cylinder diesel engine was tested in dual fuel mode of operation at the rated power output of 3.7 kW under variable hydrogen energy shares from 0 to the maximum allowable limit (until severe knocking i.e. upto 20%). The knock limit was further extended by injecting water and ethanol at the intake manifold and the engine's performance, emission and combustion characteristics were analyzed. In addition ethanol was also injected and introduced along with the intake air for comparison with hydrogen dual fuel mode. Dual fuel operation increased the BTE from 25.2% with neat MO to a maximum of 28.5% and 30% respectively with hydrogen and ethanol for the energy share of 15% and 38% where as the BTE was 30.8% with ND. The smoke opacity was reduced from 78% with neat MO to 58% for the hydrogen energy share of 15% which is the MEP (maximum efficiency point) whereas the smoke emission was noted as 51% with ND operation. However, hydrogen induction increased the NO (nitric oxide) emission. Injection of water and ethanol at the inlet was observed to extend the knocking limit with improved BTE. The BTE reached a maximum of 30.1% with 5% water and 30.8% with 10% ethanol injection. The MEPs were arrived as 31% and 30% hydrogen energy shares respectively with 5% water and 10% ethanol injection. It was concluded that hydrogen induction can be very effective in improving the diesel engine's performance when using MO as base fuel when operating on dual fuel mode. The performance could be improved by extending the knock limit by injecting ethanol and water along with hydrogen.     

CFD analysis of hydrogen injection pressure and valve profile law effects on backfire and pre-ignition phenomena in hydrogen-diesel dual fuel engine

This paper focuses on optimizing the hydrogen TMI (timed manifold injection) system through valve lift law and hydrogen injection parameters (pressure, injection inclination and timing) in order to prevent backfire phenomena and improve the volumetric efficiency and mixture formation quality of a dual fuel diesel engine operating at high load and high hydrogen energy share. This was achieved through a numerical simulation using CFD code ANSYS Fluent, developed for a single cylinder hydrogen-diesel dual fuel engine, at constant engine speed of 1500 rpm, 90% of load and 42.5% hydrogen energy share. The developed tool was validated using experimental data. As a results, the operating conditions of maximum valve lift = 10.60 mm and inlet valve closing = 30 °CA ABDC (MVL10 IVC30) prevent the engine from backfire and pre-ignition, and ensure a high volumetric efficiency. Moreover, a hydrogen start of injection of 60 °CA ATDC (HSOI60) is appropriate to provide a pre-cooling effect and thus, reduce the pre-ignition sources and helps to quench any hot residual combustion products. While, the hydrogen injection pressure of 2.7 bar and an inclination of 60°, stimulate a better quality of hydrogen-air mixture. Afterwards, a comparison between combustion characteristics of the optimized hydrogen-diesel dual fuel mode and the baseline (diesel mode) was conducted. The result was, under dual fuel mode there is an increase in combustion characteristics and NOx emissions as well as a decrease in CO2 emissions. For further improvement of dual fuel mode, retarding diesel start of injection (DSOI) strategy was used.     

Experimental study on improving the efficiency of hydrogen production by partial oxidation of ethanol

Bioethanol as the renewable biomass fuel gradually becomes a promising feedstock for hydrogen production. To improve the efficiency of hydrogen production, a typical double-layer porous media burner was established for the partial oxidation reaction of ethanol (POE). The effects of porous media structure, initial ethanol and air conditions on the temperature distribution and gas production were investigated based on the start-up characteristics of the burner. The results indicate that the lowest start-up time (2400 s) and best hydrogen production (9.80%) were obtained by filling the downstream section with 8 mm Al₂O₃ pellets and introducing ethanol at the upstream inlet, compared with that of 6 and 10 mm pellets. The productions of methane and hydrogen were improved to some extent by adding the water with 10% fraction. And the highest concentration of hydrogen was achieved at the air velocity of 8 cm/s. When the O₂/C ratios were 0.2 and 0.25, the maximum hydrogen yield (23.28%) and ethanol conversion (77.42%) were obtained respectively.     

Conversion of a gasoline engine-generator set to a bi-fuel (hydrogen/gasoline) electronic fuel-injected power unit

The modifications performed to convert a gasoline carbureted engine-generator set to a bi-fuel (hydrogen/gasoline) electronic fuel-injected power unit are described. Main changes affected the gasoline and gas injectors, the injector seats on the existing inlet manifold, camshaft and crankshaft wheels with their corresponding Hall sensors, throttle position and oil temperature sensors as well as the electronic management unit. When working on gasoline, the engine-generator set was able to provide up to 8 kW of continuous electric power (10 kW peak power), whereas working on hydrogen it provided up to 5 kW of electric power at an engine speed of 3000 rpm. The air-to-fuel equivalence ratio (λ) was adjusted to stoichiometric (λ = 1) for gasoline. In contrast, when using hydrogen the engine worked ultra-lean (λ = 3) in the absence of connected electric load and richer as the load increased. Comparisons of the fuel consumptions and pollutant emissions running on gasoline and hydrogen were performed at the same engine speed and electric loads between 1 and 5 kW. The specific fuel consumption was much lower with the engine running on hydrogen than on gasoline. At 5 kW of load up to 26% of thermal efficiency was reached with hydrogen whereas only 20% was achieved with the engine running on gasoline. Regarding the NO_x emissions, they were low, of the order of 30 ppm for loads below 4 kW for the engine-generator set working on hydrogen. The bi-fuel engine is very reliable and the required modifications can be performed without excessive difficulties thus allowing taking advantage of the well-established existing fabrication processes of internal combustion engines looking to speed up the implementation of the energetic uses of hydrogen.     

Comparative study of fuel gas production for SOFC from steam and supercritical-water reforming of bioethanol

Theoretical study of fuel gas (H₂ + CO) production for SOFC from bioethanol was carried out to compare performances between two reforming technologies, including steam reforming (SR) and supercritical-water reforming (SCWR). It demonstrates that the fuel gas productions are comparable among the two reforming systems; however, SCWR requires the operation at much higher temperature and pressure than SR. The maximum hydrogen yield can be obtained at 850 K, atmospheric pressure, ethanol to water molar feed ratio of 1:20 for SR system and at 1300 K, 22.1 MPa, and ethanol to water feed ratio of 1:20 for SCWR. The use of a distillation column to purify the bioethanol feed was proven to improve the fuel conversion efficiency of both systems. The analysis reveals that SCWR is a promising system for fuel production for SOFC when a gas turbine is incorporated to the system for energy recovery. Further, it is not necessary to distil bioethanol to obtain too high ethanol recovery (i.e. >90%) as higher energy consumption at the distillation column could lead to lower overall thermal efficiency.     

Performance of an anode-supported solid oxide fuel cell with direct-internal reforming of ethanol

A theoretical study of a solid oxide fuel cell (SOFC) fed by ethanol is presented in this study. The previous studies mostly investigated the performance of ethanol-fuelled fuel cells based on a thermodynamic analysis and neglected the presence of actual losses encountered in a real SOFC operation. Therefore, the real performance of an anode-supported SOFC with direct-internal reforming operation is investigated here using a one-dimensional isothermal model coupled with a detailed electrochemical model for computing ohmic, activation, and concentration overpotentials. Effects of design and operating parameters, i.e., anode thickness, temperature, pressure, and degree of ethanol pre-reforming, on fuel cell performance are analyzed. The simulation results show that when SOFC is operated at the standard conditions (V = 0.65 V, T = 1023 K, and P = 1 atm), the average power density of 0.51 W cm⁻² is obtained and the activation overpotentials represent a major loss in the fuel cell, followed by the ohmic and concentration losses. An increase in the thickness of anode decreases fuel cell efficiency due to increased anode concentration overpotential. The performance of the anode-supported SOFC fuelled by ethanol can be improved by either increasing temperature, pressure, degree of pre-reforming of ethanol, and steam to ethanol molar ratio or decreasing the anode thickness and fuel flow rate at inlet. It is suggested that the anode thickness and operating conditions should be carefully determined to optimize fuel cell efficiency and fuel utilization.     

Comparison between direct small molecular weight alcohols fuel cells’ and hydrogen fuel cell’s parameters at low and high temperature. Thermodynamic study

In this paper, direct alcohol fuel cells’ thermodynamics parameters were calculated by means of analytical formulas using thermodynamic data. The effect of temperature on reversible efficiency, electromotive force and specific energy for fuel cells supplied with alcohols having from one to five carbons was studied in the range between 298.15 and 1300 K.All parameters were also compared with those of hydrogen fuel cell. It was found that reversible efficiency, electromotive force and specific energy are a function of the amount of carbon atoms in the fuel and a function of temperature. In addition, alcohol’s structure influences fuel cells’ parameters too.We have found that there is a competition between hydrogen, ethanol and methanol at standard conditions, while methanol, ethanol, propanol isomers, 2-methylpropan-1-ol and butan-2-ol, as classified, appear more indicated than hydrogen at more elevated temperature.Therefore, the approach presented here can be considered as sufficient enough for a primary choice of an alcohol that could be used in fuel cells in the future.     

Stoichiometric H2ICEs with water injection

For the most part, gasoline engines operate close to stoichiometry because of the high power density and the easy after treatment through the very well established three-way catalytic converter technology. The lean burn gasoline engine suffers major disadvantages for the after treatment still requiring aggressive research and development to meet future emission standards more than for the lower power density compensated by the better fuel conversion efficiency running lean. Hydrogen engines are usually run ultra-lean to avoid abnormal combustion phenomena and possibly to avoid the emission of nitrogen oxides without the difficult non-stoichiometric after treatment. While the ultra-lean combustion of hydrogen may reduce the formation of NOx within the cylinder but makes the power density very low, the only lean combustion of hydrogen requires after treatment for NOx reduction. The suppression of abnormal combustion in hydrogen engines has been a challenge for the three regimes of abnormal combustion, knock (auto ignition of the end gas region), pre-ignition (uncontrolled ignition induced by a hot spot prior of the spark ignition) and backfire (premature ignition during the intake stroke, which could be seen as an early form of pre-ignition). Direct injection and jet ignition coupled to port water injection are used here to avoid the occurrence of all these abnormal combustion phenomena as well as to control the temperature of gases to turbine in a turbocharged stoichiometric hydrogen engine.     

Analysis of CRDI diesel engine characteristics operated on dual fuel mode fueled with biodiesel-hydrogen enriched producer gas under the single and multi-injection scheme

The present work aims to investigate the consequences of pilot fuel (PF) multiple injections and hydrogen manifold injection (HMI) on the combustion and tailpipe gas characteristics of a common rail direct injection (CRDI) compression ignition (CI) engine operated on dual fuel (DF) mode. The CI engine can perform on a wide variety of fuels and under high pilot fuel (PF) pressure. Pilot fuel injection (PFI) is achieved at TDC, 5, 10, and 15ºCA before the top dead center (bTDC), and divided injection consists of injecting fuel in three different magnitudes on a time basis and PF is injected into the engine cylinder at a pressure of 600 bar. In this work, the hydrogen flow rate (HFR) was fixed at 8 lpm constant and producer gas was inducted without any restriction. The investigational engine setup has the ability to deliver a PF and hydrogen (H₂) precisely in all operating circumstances using a separate electronic control unit (ECU). Results showed that diesel-hydrogen enriched producer gas (HPG) operation at maximum operating conditions provided amplified thermal efficiency by 4.01% with reduced emissions, except NOx levels, compared to biodiesel-HPG operation. Further, DiSOME with the multi-injection strategy of 60 + 20+20 and 50 + 25+25, lowered thermal efficiency by 4.8% and 9.12%, respectively compared to identical fuel combinations under a single injection scheme. However, reductions in NOx levels, cylinder pressure, and HRR were observed with a multi-injection scheme. It is concluded that multi-injection results in lower BTE, changes carbon-based emissions marginally, and decreases cylinder pressure and heat release rate than the traditional fuel injection method.     

Performance evaluation of a fuel processing system based on membrane reactors technology integrated with a PEMFC stack

The development of fuel cells is promised to enable the distributed generation of electricity in the near future. However, the infrastructure for production and distribution of hydrogen, the fuel of choice for fuel cells, is currently lacking. Efficient production of hydrogen from fuels that have existing infrastructure (e.g., natural gas, gasoline or LPG) would remove a major drawback to use fuel cells for distributed power generation.The aim of this paper is to define the better operating conditions of an innovative hydrogen generation system (the fuel processing system, FP) based on LPG steam reforming, equipped with a membrane shift reactor, and integrated with a PEMFC (Proton Exchange Membrane Fuel Cell) stack of 5 kWel.With respect to the conventional hydrogen generation systems, the use of membrane reactors (MRs) technology allows to increase the hydrogen generation and to simplify the FP-PEMFC plant, because the CO removal system, needed to reduce the CO content at levels required by the PEMFC, is avoided.Therefore, in order to identify the optimal operating conditions of the FP-PEMFC system, a sensitivity analysis on the fuel processing system has been carried out by varying the main operating parameters of both the reforming reactor and the membrane water gas shift reactor. The sensitivity analysis has been performed by means of a thermochemical model properly developed.Results show that the thermal efficiency of the fuel processing system is maximize (82.4%, referred to the HHV of fuels) at a reforming temperature of 800 °C, a reforming pressure of 8 bar, and an S/C molar ratio equal to 6. In the nominal operating condition of the PEMFC stack, the FP-PEMFC system efficiency is 36.1% (39.0% respect to the LHV).     

Modelling of an HTPEM-based micro-combined heat and power fuel cell system with methanol

A fuel cell-based combined heat and power system using a high temperature proton exchange membrane fuel cell has been modelled. The fuel cell is fed with the outlet hydrogen stream from a methanol steam reforming reactor. In order to provide the necessary heat to this reactor, it was considered the use of a catalytic combustor fed with methanol. The modelling aims to fit the hydrogen production to the demand of the fuel cell to provide 1 kW_e, maintaining a CO concentration always lower than 30,000 ppm. A system with 65 cells (45.16 cm² cell area) stack operating at 150 °C and hydrogen utilization factor = 0.9 (with O₂/methanol ratio = 2 at combustor; H₂O/methanol ratio = 2 and temperature = 300 °C at reformer) needed a total methanol flow of 23.8 mol h⁻¹ (0.96 L h⁻¹) to reach 1 kW_e, with a system power efficiency (LHV basis) ca. 24% and a CHP efficiency over 87%. The ability to recycle the non-converted hydrogen from the fuel cell anode to the combustor and to use the heat produced at the fuel cell for obtaining hot water increased the global energy efficiency.     

A parametric comparison of three fuel recirculation system in the closed loop fuel supply system of PEM fuel cell

Anodic fuel recirculation system has a significant role on the parasitic power of proton exchange membrane fuel cell (PEMFC). In this paper, different fuel supply systems for a PEMFC including a mechanical compressor, an ejector and an electrochemical pump are evaluated. Furthermore, the performances of ejector and electrochemical pump are studied at different operating conditions including operating temperature of 333 K–353 K, operating pressure of 2 bar–4 bar, relative humidity of 20%–100%, stack cells number from 150 to 400 and PEMFC active area of 0.03 m²–0.1 m². The results reveal that higher temperature of PEMFC leads to lower power consumption of the electrochemical pump, because activation over-potential of electrochemical pump decreases at higher temperatures. Moreover, higher operating temperature and pressure of PEMFC leads to higher stoichiometric ratio and hydrogen recirculation ratio because the motive flow energy in ejector enhances. In addition, the recirculation ratio and hydrogen stoichiometric ratio increase, almost linearly, with increase of anodic relative humidity. Utilization of mechanical compressor leads to lower system efficiency than other fuel recirculating devices due to more power consumption. Utilization of electrochemical pump in anodic recirculation system is a promising alternative to ejector due to lower noise level, better controllability and wide range of operating conditions.     

Effects of PEMFC operating parameters on the performance of an integrated ethanol processor

In this paper the performance of a complete fuel cell system processing ethanol fuel has been analyzed as a function of the main fuel cell operating parameters. The fuel processor is based on the steam reforming process, followed by high- and low-temperature shift reactors, and carbon monoxide preferential oxidation reactor, which are coupled to a polymeric fuel cell (PEMFC). The goal was to analyze and improve the fuel cell system performance by simulation techniques. PEMFC operation has been analyzed using an available parametric model, which was implemented within HYSYS environment software. Pinch Analysis concepts were used to investigate the process energy integration and determine the maximum efficiency minimizing ethanol consumption. The system performance was analyzed for the SR-12 Modular PEM Generator, the Ballard Mark V fuel cell and the BCS 500 W stack. The net system efficiency is dependent on the required power demand. Efficiency values higher than 50% at low loads and less than 30% at high power demands are computed. In addition, the effect of fuel cell temperature, pressure and hydrogen utilization was analyzed. The trade-off between the reformer yield and the fuel cell performance defines the optimal operation pressure. The cell temperature determines operating zones where the water, involved in the reforming reactions, can be produced or demanded.     

Fuel effects on start-up energy and efficiency for automotive PEM fuel cell systems

This paper investigates the effects of various fuels on hydrogen production for automotive PEM fuel cell systems. Gasoline, methanol, ethanol, dimethyl ether and methane are compared for their effects on fuel processor size, start-up energy and overall efficiencies for 50 kW_e fuel processors. The start-up energy is the energy required to raise the temperature of the fuel processor from ambient temperature (20 °C) to that of the steady-state operating temperatures. The fuel processor modeled consisted of an equilibrium-ATR (autothermal), high-temperature water gas shift (HTS), low-temperature water gas shift (LTS) and preferential oxidation (PrOx) reactors. The individual reactor volumes with methane, dimethyl ether, methanol and ethanol were scaled relative to a gasoline-fueled fuel processor meeting the 2010 DOE technical targets. The modeled fuel processor volumes were, 25.9 L for methane, 30.8 L for dimethyl ether, 42.5 L for gasoline, 43.7 L for ethanol and 45.8 L for methane. The calculated fuel processor start-up energies for the modeled fuels were, 2712 kJ for methanol, 3423 kJ for dimethyl ether, 6632 kJ for ethanol, 7068 kJ for gasoline and 7592 kJ for methane. The modeled overall efficiencies, correcting for the fuel processor start-up energy using a drive cycle of 33 miles driven per day, were, 38.5% for dimethyl ether, 38.3% for methanol, 37% for gasoline, 34.5% for ethanol and 33.2% for methane assuming a steady-state efficiency of 44% for each fuel.     

Effect of hydrogen addition on combustion and emissions performance of a spark-ignited ethanol engine at idle and stoichiometric conditions

Regarding the limited fossil fuel reserves, the renewable ethanol has been considered as one of the substitutional fuels for spark ignition (SI) engines. But due to its high latent heat, ethanol is usually hard to be well evaporated to form the homogeneous fuel–air mixture at low temperatures, e.g., at idle condition. Compared with ethanol, hydrogen possesses many unique combustion and physicochemical properties that help improve combustion process. In this paper, the performance of a hydrogen-enriched SI ethanol engine under idle and stoichiometric conditions was investigated. The experiment was performed on a modified 1.6 L SI engine equipped with a hydrogen port-injection system. The ethanol was injected into the intake ports using the original engine gasoline injection system. A self-developed hybrid electronic control unit (HECU) was adopted to govern the opening and closing of hydrogen and ethanol injectors. The spark timing and idle bypass valve opening were governed by the engine original electronic control unit (OECU), so that the engine could operate under its original target idle speed for each testing point. The engine was first fueled with the pure ethanol and then hydrogen volume fraction in the total intake gas was gradually increased through increasing hydrogen injection duration. For a specified hydrogen addition level, ethanol flow rate was reduced to keep the hydrogen–ethanol–air mixture at stoichiometric condition. The test results showed that hydrogen addition was effective on reducing cyclic variations and improving indicated thermal efficiency of an ethanol engine at idle. The fuel energy flow rate was reduced by 20% when hydrogen volume fraction in the intake rose from 0% to 6.38%. Both flame development and propagation periods were shortened with the increase of hydrogen blending ratio. The heat transfer to the coolant was decreased and the degree of constant volume combustion was enhanced after hydrogen addition. HC and CO emissions were first reduced and then increased with the increase of hydrogen blending fraction. The acetaldehyde emission from the hydrogen-enriched ethanol engine is lower than that from the pure ethanol engine. However, the addition of hydrogen tended to increase NO_x emissions from the ethanol engine at idle and stoichiometric conditions.     

Fuel cells for carbon capture and power generation: Simulation studies

The decarbonization of hydrocarbons is explored in this work as a method to produce hydrogen and mitigate carbon dioxide (CO₂) emissions. An integrated process for power generation and carbon capture based on a hydrocarbon fueled-decarbonization unit was proposed and simulated. Ethane and propane were used as fuels and subjected to the thermal decomposition (decarbonization) process. The system is also composed of a carbon fuel cell (CFC) and hydrogen fuel cell (HFC) for the production of power and a pure CO₂ stream that is ready for sequestration. The HFC is a high-temperature proton exchange membrane fuel cell operating at 200 °C. Simulations were performed using ASPEN HYSYS V.10 for the entire process including the CFC and HFC being operated at various operating temperatures (200–800 °C). The power output from the CFC and the HFC as well as the overall process efficiency were calculated. The model incorporates an energy recovery system by adopting a counter-current shell and tube heat exchangers and a turbine. The water produced from the fuel cell system can be utilized in the plant to recover the heat from the furnace. The results showed a 100% carbon capture with a nominal plant capacity of 108 MWe produced when propane fuel was fed to the decarbonizer. The CFC theoretical efficiency is 100% and the practical efficiency was taken as 70% when all internal polarizations were considered. The results showed that, in the case of propane, the CFC power output was 89 MWe when the CFC operated at 650 °C, and the HFC power output was around 45 MWe at 200 °C with an overall actual plant efficiency of 35% and 100% carbon capture. Sensitivity analysis recommends a hydrocarbon fuel cost of 0.011 $/kW as the most feasible option. The results reported here on the decarbonization of hydrocarbon fuels are promising toward the direct production of hydrogen with full carbon dioxide sequestration at a potentially lower cost especially in rural areas. The overall actual efficiencies are very competitive to those of conventional power plants operated without carbon capture.     

Analysis of performance parameters of an ethanol fueled spark ignition engine operating with hydrogen enrichment

Concerns with the environment and energy security have increased interest in phasing out fossil fuels in the automotive industry, as it transitions from conventional internal combustion engines (ICE) to electric and fuel cell powertrains. During this transition, ethanol is of particular interest as a renewable fuel option in ICE, despite drawbacks compared to gasoline. Adding hydrogen to ethanol could remedy the disadvantages associated with ethanol, while maintaining the benefits of using renewable fuels. There is a gap in the literature of both experimental and numerical studies considering hydrogen addition in turbocharged ethanol engines. Therefore, this paper presents an experimental and numerical study of a turbocharged ethanol engine operating with hydrogen enrichment at stoichiometric conditions under boosted conditions. It was concluded that hydrogen addition allowed spark ignition engines to achieve lower brake specific energy consumption, better performance, and lower emissions. Thus, after proper calibration, a simulation model was created and shown to be a suitable tool to predict engine performance of a spark ignition engine operating with hydrogen enrichment and reduce the overall number of experimental tests needed to tune engines operating with this fuel blend. Finally, some operating strategies are recommended based on these findings.     

Design of a methanol reformer for on-board production of hydrogen as fuel for a 3 kW High-Temperature Proton Exchange Membrane Fuel Cell power system

The method of Computational Fluid Dynamics is used to predict the process parameters and select the optimum operating regime of a methanol reformer for on-board production of hydrogen as fuel for a 3 kW High-Temperature Proton Exchange Membrane Fuel Cell power system. The analysis uses a three reactions kinetics model for methanol steam reforming, water gas shift and methanol decomposition reactions on Cu/ZnO/Al₂O₃ catalyst. Numerical simulations are performed at single channel level for a range of reformer operating temperatures and values of the molar flow rate of methanol per weight of catalyst at the reformer inlet. Two operating regimes of the fuel processor are selected which offer high methanol conversion rate and high hydrogen production while simultaneously result in a small reformer size and a reformate gas composition that can be tolerated by phosphoric acid-doped high temperature membrane electrode assemblies for proton exchange membrane fuel cells. Based on the results of the numerical simulations, the reactor is sized, and its design is optimized.     

Intra-fuel cell stack measurements of transient concentration distributions

Intra-fuel-cell measurements are required to understand detailed fuel-cell chemistry and physics, validate models, optimize system design and control, and realize enhanced efficiency regimes; in comparison, conventional integrated fuel-cell supply and effluent measurements are fundamentally limited in value. Intra-reactor measurements are needed for all fuel cell types. This paper demonstrates the ability of a capillary-inlet mass spectrometer to resolve transient species distributions within operating polymer-electrolyte-membrane (PEM) fuel cells and at temperatures typical of solid-oxide fuel cells (SOFC). This is the first such demonstration of a diagnostic that is sufficiently minimally invasive as to allow measurements throughout an operating fuel cell stack. Measurements of transient water, hydrogen, oxygen and diluent concentration dynamics associated with fuel-cell load switching suggest oxygen-limited chemistry. Intra-PEM fuel cell measurements of oxygen distribution at various fuel-cell loads are used to demonstrate concentration gradients, non-uniformities, and anomalous fuel cell operation.