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1.
The main challenge on the fueling of pure hydrogen in the automotive vehicles is the limitation in the hydrogen separation from the product of steam reforming and gasification plants and the storage issues. On the other hand, hydrogen fueling in automotive engines has resulted in uncontrolled combustion. These are some of the factors which motivated for the fueling of raw syngas instead of further chemical or physical processes. However, fueling of syngas alone in the combustion chamber has resulted in decreased power output and increased in brake specific fuel consumption. Methane augmented hydrogen rich syngas was investigated experimentally to observe the behavior of the combustion with the variation of the fuel-air mixture and engine speed of a direct-injection spark-ignition (DI SI) engine. The molar ratio of the high hydrogen syngas is 50% H2 and 50% CO composition. The amount of methane used for augmentation was 20% (V/V). The compression ratio of 14:1 gas engine operating at full throttle position (the throttle is fully opened) with the start of the injection selected to simulate the partial DI (180° before top dead center (BTDC)). The relative air-fuel ratio (λ) was set at lean mixture condition and the engine speed ranging from 1500 to 2400 revolutions per minute (rpm) with an interval of 300 rpm. The result indicated that coefficient of variation of the indicate mean effective pressure (COV of IMEP) was observed to increase with an increase with λ in all speeds. The durations of the flame development and rapid burning stages of the combustion has increased with an increase in λ. Besides, all the combustion durations are shown to be more sensitive to λ at the lowest speed as compared to the two engine speeds.  相似文献   

2.
The product of gasification of solid biomass, also called syngas is believed to be good fuel for internal combustion engines in the move from the carbon based fuel to zero emission fuels. The only problem is its lower calorific value which is placed at one third of that of compressed natural gas (CNG). There are latest efforts to enhance the hydrogen rich syngas by augmenting it with methane so that the calorific value can be improved. This paper presents experimental results of the effect of the start of fuel injection timing (SOI) on the combustion characteristics, performance and emissions of a direct-injection spark-ignition engine fueled with a 20% methane augmented hydrogen rich syngas of molar ratio of 50% H2 and 50% CO composition. The engine was operated at fully open throttle and the start of fuel injection (SOI) was varied at 90, 120 and 180° before top dead center (BTDC). The experiment was conducted at lean mixture conditions in the low and medium engine speed ranges (1500–2400 RPM). The spark advance was set to the minimum advance for a maximum brake torque in all the test parameters. The methane augmented hydrogen rich syngas was observed to perform well over wide range of operation with SOI = 180°CA BTDC. However, SOI = 120°CA BTDC performed well at lower speeds recording improved performance and emissions. Limitation of operable load was observed for both SOI = 120°CA BTDC and 90°CA BTDC due to an insufficient time for complete injection of fuel at lower relative air–fuel ratio (λ) with higher speeds.  相似文献   

3.
The proven feasibility of ammonia combustion in compression-ignition engines has led to it being considered as a carbon-free replacement for diesel fuel. Due to its high auto-ignition temperature, however, a more realistic strategy would be to aim for a step-change reduction in carbon emissions by co-fuelling a diesel engine with ammonia. In assessing this strategy, ammonia gas was introduced into the air-intake manifold of a compression-ignition engine, while diesel fuel was injected directly into the cylinder to ignite the mixture. By substituting only 3% of the air intake by ammonia, the diesel consumption and the CO2 emissions decreased by 15%. The combustion and emission characteristics were then compared when the same percentage of air intake (by mass) was substituted by either dissociated ammonia (a mixture of H2, N2 with small percentages of NH3) or pure hydrogen, to mimic the other possible forms in which the co-fuel can be delivered to the engine. The addition of pure hydrogen resulted in the best engine performance, both in terms of combustion efficiency and regulated emission quality. The thermal combustion efficiency declined by only ∼0.5% when the H2 was replaced by undissociated ammonia at low load, but N2O now appeared in the emissions. Co-fuelling the engine with dissociated ammonia may provide the ideal compromise in terms of thermal combustion efficiency and emission quality, while also providing a waste-heat recovery mechanism.  相似文献   

4.
The present study is an attempt to investigate a syngas-diesel dual fueled diesel engine operation under varying load conditions from the second law point of view. The fuel type in dual fuel operation is achieved by varying the volumetric fractions of hydrogen (H2) and carbon monoxide (CO) content in syngas. It is revealed that increasing the hydrogen quantity of syngas increases the cumulative work availability and reduces the destroyed availability. This enhancement is due to a better combustion process and increased work output when a high amount of H2 quantity is employed. At lower loads, the in-cylinder combustion temperatures are reduced in case of the dual fuel combustion. Hence, the destruction availability is increased due to poor combustion and reduced heat transfer availability losses. When the engine is operated beyond 40% load, the destroyed availability reduced due to higher combustion temperature and pressure. The increase in the both exhaust gas and cooling water availabilities are reflected in an increase in second law efficiency with increasing load. The dual fuel cumulative work availability is increased at higher loads and thus, the exergy efficiency is increased.  相似文献   

5.
The effect of the addition of hydrogen (H2) on the combustion process and nitric oxide (NO) formation in a H2-diesel dual fuel engine was numerically investigated. The model developed using AVL FIRE as a platform was validated against the cylinder pressure and heat release rate measured with the addition of up to 6% (vol.) H2 into the intake mixture of a heavy-duty diesel engine with exhaust gas recirculation (EGR). The validated model was applied to further explore the effect of the addition of 6%–18% (vol.) H2 on the combustion process and formation of NO in H2-diesel dual fuel engines. When the engine was at N = 1200 rpm and 70% load, the simulation results showed that the addition of H2 prolonged ignition delay, enhanced premixed combustion, and promoted diffusion combustion of the diesel fuel. The maximum peak cylinder pressure was observed with addition of 12% (vol.) H2. In comparison, the maximum peak heat release rate was observed with the addition of 16% (vol.) H2. The addition of H2 was a crucial factor dominating the increased NO emissions. Meanwhile, the addition of H2 reduced soot emissions substantially, which may be due to the reduced diesel fuel burned each cycle. Furthermore, proper combination of adding H2 with EGR can improve combustion performance and reduce NO emissions.  相似文献   

6.
The objective of this study was to investigate the performance and emissions of a pilot-ignited, supercharged, dual-fuel engine powered by different types of syngas at various equivalence ratios. It was found that if certain operating conditions were maintained, conventional engine combustion could be transformed into combustion with two-stage heat release. This mode of combustion has been investigated in previous studies with natural gas, and has been given the name PREmixed Mixture Ignition in the End-gas Region (PREMIER) combustion. PREMIER combustion begins as premixed flame propagation, and then, because of mixture autoignition in the end-gas region, ahead of the propagating flame front, a transition occurs, with a rapid increase in the heat release rate. It was determined that the mass of fuel burned during the second stage affected the rate of maximum pressure rise. As the fuel mass fraction burned during the second stage increased, the rate of maximum pressure rise also increased, with a gradual decrease in the delay between the first increase in the heat release rate following pilot fuel injection and the point when the transition to the second stage occurred. The H2 and CO2 content of syngas affected the engine performance and emissions. Increased H2 content led to higher combustion temperatures and efficiency, lower CO and HC emissions, but higher NOx emissions. Increased CO2 content influenced performance and emissions only when it reached a certain level. In the most recent studies, the mean combustion temperature, indicated thermal efficiency, and NOx emissions decreased only when the CO2 content of the syngas increased to 34%. PREMIER combustion did not have a major effect on engine cycle-to-cycle variation. The coefficient of variation of the indicated mean effective pressure (COVIMEP) was less than 4% for all types of fuel at various equivalence ratios, indicating that the combustion was within the stability range for engine operation.  相似文献   

7.
The combustion, performance, and emissions of syngas (H2/CO) in a four-stroke, direct-injection, spark-ignition engine were experimentally investigated. The engine was operated at various speeds, ranging from 1500 to 2400 rev/min, with the throttle being held in the wide-open position. The start of fuel injection was fixed at 180° before the top dead center, and the ignition advance was set at the maximal brake torque. The air/fuel ratio was varied from the technically possible lowest excess air ratio (λ) to lean operation limits. The results indicated that a wider air/fuel operating ratio is possible with syngas with a very low coefficient of variation. The syngas produced a higher in-cylinder peak pressure and heat-release rate peak and faster combustion than for CNG. However, CNG produced a higher brake thermal efficiency (BTE) and lower brake specific fuel consumption (BSFC). The BTE and BSFC of the syngas were on par to those of CNG at higher speeds. For the syngas, the total hydrocarbon emission was negligible at all load conditions, and the carbon monoxide emission was negligible at higher loads and increased under lower load conditions. However, the emission of nitrogen oxides was higher at higher loads with syngas.  相似文献   

8.
The dilution effects of CO2 and H2O on partially premixed swirling syngas flames are investigated with the large eddy simulation (LES) method. The linear-eddy model (LEM) is employed to directly resolve the unclosed molecular diffusion, scalar mixing and chemical reaction processes occurring at subgrid scale level using their specific length and time scales instead of modelling, which makes the LES-LEM approach quite attractive for hydrogen fuel combustion as the obviously different diffusion and reaction characteristics of H2 and H compared to other species in the syngas mixture. Firstly, adding CO2 into the fuel stream can significantly decrease the flame temperature during the partially premixed combustion. The concentration of H and OH radicals decreases upon CO2 dilution and thus the chemical reaction processes are modified. Compared with CO2, H2O is less effective in changing the temperature field because of the chemical effects of H2O. The simultaneous addition of H2O and CO2 as dilution gases with volume ratio 1:1 into the fuel stream is also conducted to identify the effects of H2O and CO2 on partially premixed combustion dynamics by comparing with single H2O and CO2 cases. The obtained results are expected to provide helpful information for the design and operation of gas turbine combustion systems with syngas fuels.  相似文献   

9.
This paper investigated the effect of hydrogen (H2) addition on the combustion process of a heavy-duty diesel engine. The addition of a small amount of H2 was shown to have a mild effect on the cylinder pressure and combustion process. When operated at high load, the addition of a relatively large amount of H2 substantially increased the peak cylinder pressure and the peak heat release rate. Compared to the two-stage combustion process of diesel engines, a featured three-stage combustion process of the H2–diesel dual fuel engine was observed. The extremely high peak heat release rate represented a combination of diesel diffusion combustion and the premixed combustion of H2 consumed by multiple turbulent flames, which substantially enhanced the combustion process of H2–diesel dual fuel engine. However, the addition of a relatively large amount of H2 at low load did not change the two-stage heat release process pattern. The premixed combustion was dramatically inhibited while the diffusion combustion was slightly enhanced and elongated. The substantially reduced peak cylinder pressure at low load was due to the deteriorated premixed combustion.  相似文献   

10.
Biogas valorization as fuel for internal combustion engines is one of the alternative fuels, which could be an interesting way to cope the fossil fuel depletion and the current environmental degradation. In this circumstance, an experimental investigation is achieved on a single cylinder DI diesel engine running under dual fuel mode with a focus on the improvement of biogas/diesel fuel combustion by hydrogen enrichment. In the present investigation, the mixture of biogas, containing 70% CH4 and 30% CO2, is blended with the desired amount of H2 (up to 10, 15 and 20% by volume) by using MTI 200 analytical instrument gas chromatograph, which flow thereafter towards the engine intake manifold and mix with the intake air. Depending on engine load conditions, the volumetric composition of the inducted gaseous fraction is 20–50% biogas, 2–10% H2 and 45–78% air. Near the end of the compression stroke, a small amount of diesel pilot fuel is injected to initiate the combustion of the gas–air mixture. Firstly, the engine was tested on conventional diesel mode (baseline case) and then under dual fuel mode using the biogas. Consequently, hydrogen has partially enriched the biogas. Combustion characteristics, performance parameters and pollutant emissions were investigated in-depth and compared. The results have shown that biogas enriched with 20% H2 leads to 20% decrease of methane content in the overall exhaust emissions, associated with an improvement in engine performance. The emission levels of unburned hydrocarbon (UHC) and carbon monoxide (CO) are decreased up to 25% and 30% respectively. When the equivalence ratio is increased, a supplement decrease in UHC and CO emissions is achieved up to 28% and 30% respectively when loading the engine at 60%.  相似文献   

11.
Hydrogen (H2) is a carbon-free fuel with many excellent combustion characteristics, but abnormal combustion is one of the main obstacles to the promotion and application of hydrogen-fueled engines. This experimental study aims to investigate the suppression of the heat release rate (HRR) of a hydrogen-fueled engine through the addition of ammonia (NH3). The engine was run at 1300 rpm, with manifold absolute pressure (MAP) of 61 kPa and NH3 addition ratio of 0% and 2.2%, under lean-burn conditions. The results showed that the addition of small amounts of ammonia reduced the combustion rate of the fuel mixture, prolonged the flame development period (CA0-10) and propagation durations (CA10-90) of the engine, and reduced the peak in-cylinder pressure and peak HRR under lean-burn conditions. The addition of ammonia increased the peak indicated mean effective pressure (IMEP) and the peak indicated thermal efficiency (ITE) of the engine. The addition of ammonia resulted in increased nitrogen oxides (NOx) emissions.  相似文献   

12.
Ammonia is a good hydrogen carrier and can be well combined with hydrogen for combustion. The combustion performance of the mixtures of ammonia and hydrogen in a medium-speed marine diesel engine was investigated theoretically. The HCCI combustion mode was selected for reducing thermal-NOx production. The start fire characteristic of the NH3–H2 mixtures was studied under different equivalence ratio, hydrogen-doped ratio, and intake air temperature and pressure. Then, the combustion performance of the NH3–H2 mixtures (doping 30% hydrogen) was analyzed at a typical operation condition of engine. The addition hydrogen improved the laminar flame velocity of ammonia, and affected the NOx emission. For the medium-speed marine engine fueled with NH3–H2, reducing combustion temperature, introducing EGR and combining with post-treatment technology would be a feasible scheme to reduce NOx emission.  相似文献   

13.
Varying proportions of hydrogen and carbon monoxide (synthesis gas) have been investigated as a spark ignition (SI) engine fuel in this paper. It is important to understand how various synthesis gas compositions effect important SI combustion fundamentals, such as knock and burn duration, because in synthesis gas production applications, the compositions can vary significantly depending on the feedstock and production method.A single cylinder cooperative fuels research (CFR) engine was used to investigate the knock and combustion characteristics of three blends of synthesis gas (H2/CO ratio); 1) 100/0, 2) 75/25, and 3) 50/50, by volume. These blends were tested at three compression ratios (6:1, 8:1, and 10:1), and three equivalence ratios (0.6, 0.7, and 0.8).It was revealed that the knock limited compression ratio (KLCR) of a H2/CO mixture increases with increasing CO fraction, for a given spark timing. For a given equivalence ratio and spark timing, a 50%/50% H2/CO mixture produced a KLCR of 8:1 compared to a 100% H2 condition, which produced a KLCR of 6:1. The burn duration and ignition lag is also increased with increasing CO fraction. The results from this work are important for those considering using synthesis gas as a fuel in SI engines. It reveals that although CO is a slow burning fuel, higher CO fractions in synthesis gas can be beneficial, because of its increased resistance to knock, which gives it the potential of producing higher indicated efficiencies through the utilization of an engine with a higher compression ratio.  相似文献   

14.
This paper investigates the emissions of the unburned gaseous fuels of a heavy-duty diesel engine converted to operate under natural gas (NG)-diesel and hydrogen (H2)-diesel dual fuel combustion mode. The detailed effects of the addition of H2, NG, engine load, and engine speed on the exhaust emissions of the unburned H2, methane (CH4), and carbon monoxide (CO) were experimentally investigated. The combustion efficiencies of CH4 and H2 supplemented were also examined and compared.  相似文献   

15.
It is necessary to develop an H2 engine with a higher performance than the conventional gasoline or diesel engines for its practical use. The methods of supplying and storing H2 are very crucial issues. The H2 engine tends to produce low power output because the heat of combustion per unit volume of H2-air mixture is low and abnormal combustion such as back fire or preignition must be avoided during operation. At the Musashi Institute of Technology, a higher power two-stroke H2 diesel turbo engine has been developed. This engine was made capable of high power output by the following method. The liquid H2 stored in the LH2-tank was pressurized by a well-designed pump and was directly injected into the combustion chamber. The H2 was ignited on the hot surface and with the aid of a turbocharger, the engine was able to produce high power output.  相似文献   

16.
A previously developed and validated zero-dimensional, multi-zone, thermodynamic combustion model for the prediction of spark ignition (SI) engine performance and nitric oxide (NO) emissions has been extended to include second-law analysis. The main characteristic of the model is the division of the burned gas into several distinct zones, in order to account for the temperature and chemical species stratification developed in the burned gas during combustion. Within the framework of the multi-zone model, the various availability components constituting the total availability of each of the multiple zones of the simulation are identified and calculated separately. The model is applied to a multi-cylinder, four-stroke, turbocharged and aftercooled, natural gas (NG) SI gas engine running on synthesis gas (syngas) fuel. The major part of the unburned mixture availability consists of the chemical contribution, ranging from 98% at the inlet valve closing (IVC) event to 83% at the ignition timing of the total availability for the 100% load case, which is due to the presence of the combustible fuel. On the contrary, the multiple burned zones possess mainly thermomechanical availability. Specifically, again for the 100% load case, the total availability of the first burned zone at the exhaust valve opening (EVO) event consists of thermomechanical availability approximately by 90%, with similar percentages for all other burned zones. Two definitions of the combustion exergetic efficiency are used to explore the degree of reversibility of the combustion process in each of the multiple burned zones. It is revealed that the crucial factor determining the thermodynamic perfection of combustion in each burned zone is the level of the temperatures at which combustion occurs in the zone, with minor influence of the whole temperature history of the zone during the complete combustion phase. The availability analysis is extended to various engine loads. The engine in question is supplied with increasingly leaner mixtures as loads rise in order to keep the emitted nitrogen oxides (NOx) low. Therefore, in-cylinder combustion temperatures are reduced, resulting in increased destruction of availability due to combustion and reduced availability losses due to heat transfer with the cylinder walls, when expressed as percentages of the fuel chemical availability. Specifically, when engine load increases from 40% to 100% of full load, with the relative air–fuel ratio also increasing from 1.56 to 1.83, the destroyed availability due to combustion rises from 14.19% to 15.02% of the fuel chemical availability, while the respective percentage of the cumulative availability loss due to heat transfer decreases from 13.37% to 9.05%.  相似文献   

17.
In this paper the combustion and ignition process in the hydrogen-fueled peripheral-ported rotary engine with single and dual laser ignition systems was studied numerically. The computational method was established for the process simulation including interaction between turbulence and chemical reactions. The detailed chemical kinetic model of hydrogen combustion was used. It was shown that the ignition and combustion process in the H2-fueled rotary engine is highly transient with specific distortion and stretching of the combustion front in the combustion chamber due to complex motion of the rotor relative to the engine housing. The single and dual laser ignition systems were simulated to compare the ignition efficiency and the rate of hydrogen burning out. The evaluation of pressure in the combustion chamber was performed and compared with the experimental data obtained for the rotary engine fueled by natural gas. It was shown that the H2-fueled rotary engine with the dual laser ignition system has potential application in alternative automotive industry due to high efficiency and near-zero carbon-based emission.  相似文献   

18.
Concerns as to the adverse effects of diesel engine exhaust on urban air quality have resulted in increasingly stringent emissions legislation, with the prospect of many major global cities potentially banning diesel vehicles. Emissions of nitrogen oxides (NOx) and particulate matter (PM) are linked to increases in premature mortality, and the simultaneous control of both pollutants through modified combustion strategies presents a significant challenge. In this work, the effects of displacing diesel fuel with hydrogen on exhaust emissions were investigated in both a single cylinder research engine and in a demonstration vehicle. In the initial stage, tests were undertaken on a supercharged, direct injection, single cylinder diesel research engine at different engine loads, intake air pressures and EGR levels. Hydrogen was aspirated with the intake air, and EGR was simulated by supplying the intake pipe with compressed nitrogen gas. The results showed a reduction in CO2 and particulate emissions with increasing H2 addition, and an increase in NOx emissions at H2 levels greater than 10% of the total input energy to the engine. The next stage involved tests on a chassis dynamometer with a small van equipped with the multi-cylinder version of the single cylinder research engine. The van was fitted with a programmable H2 augmentation system, with H2 addition levels specified by accelerator pedal position. During full drive cycle tests conducted with and without H2 augmentation up to 10%, an average rate of 1 kW of H2 was supplied to the engine. With H2 augmentation, over the total drive-cycle, reductions in CO, NOx and particle number were observed, but a higher total PM mass was recorded.  相似文献   

19.
The main objective of the present investigation is to conduct the performance, combustion and emission analysis of CI engine operated using hydrogen enriched syngas (pyrolytic gas) and biodiesel (pyrolytic oil) as dual fuel mode condition. Both the pyrolytic oil and syngas is obtained from single feedstock delonix regia fruit pod through pyrolysis process and then pyrolytic oil is converted into biodiesel through esterification. Initially biomass is subjected to thermal degradation at various pyrolysis temperature ranges like 350–600 °C. During the pyrolysis process syngas, pyrolytic oil and char are produced. The syngas is directly used in the CI engine and pyrolytic oil is converted into biodiesel and then used in the CI engine. The pyrolytic oil and syngas is subjected to FTIR and GC/TCD analysis respectively. The syngas analysis confirms the presence of various gases like H2, CH4, CO2, CO and C2H4 in different proportions. The various proportions of the syngas is mainly depending upon the reactor temperature and moisture content in the biomass. The syngas composition varies with increase in the temperature and at 400 °C, higher amount of hydrogen is present and its composition are H2 28.2%, CO is 21.9%, CH4 is 39.1% and other gases in smaller amounts. The biodiesel of B20 and syngas of 8lpm produced from the same feedstock are considered as test sample fuels in the CI engine under dual fuel mode operation to study the performance and emission characteristics. The study reveals that BTE has slight increase than diesel of 1.5% at maximum load. On the another hand emission like CO, HC and smoke are reduced by 15%,25% and 32% respectively at full load condition, whereas NOx emission is increased at all loads in the range of 10–15%. Therefore B20+syngas of 8lpm can be used as an alternative fuel in CI engine without any modification and major products from pyrolysis process with waste biomass is fully used as fuel in the CI engine.  相似文献   

20.
In the current work, Chemkin Pro's HCCI numerical model is used in order to explore the feasibility of using hydrogen in a dual fuel concept where hydrogen peroxide acts as ignition promoter. The analysis focuses on the engine performance characteristics, the combustion phasing and NOx emissions. It is shown that the use of hydrogen/hydrogen peroxide at extremely fuel lean conditions (φeff = 0.1 ? 0.4) results in significantly better performance characteristics (up to 60% increase of IMEP and 80% decrease of NOx) compared to the case of a preheated hydrogen/air mixture that aims to simulate the use of a glow plug. It is also shown that the addition of H2O2 up to 10% (per fuel volume) increases significantly the IMEP, power, torque, thermal efficiency (reaching values more than 60%) while also decreasing remarkably NOx emissions which will not require any exhaust after-treatment, for all engine speeds. The results presented herein are novel and promising, yet further research is required to demonstrate the feasibility of the proposed technology.  相似文献   

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