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芳叔胺促进剂对不饱和聚酯树脂固化的研究 总被引:1,自引:0,他引:1
研究了过氧化二苯甲酰(BPO)分别与芳叔胺N,N-二甲基苯胺(DMA)、N,N-二甲基对甲苯胺(DMPT)和N-甲基-N-2-羟乙基对甲苯胺(MHPT)组成的体系引发不饱和聚酯树脂进行固化,在测定的温度范围内(0-40℃),芳叔胺的活性顺序为:MHPT>DMPT>DMA。用膨胀计法测定了芳叔胺引发不饱和聚酯树脂在甲苯中的引发速率。同时采用自恰场(SCF)密度泛函法(B3LYP)对三种芳叔胺进行了量化计算和结构分析,发现MHPT促进效果最佳的原因是羟基同氮原子形成分子内氢键,使氮原子上的孤对电子同苯环共轭程度不如DMA和DMPT,从而减少了氮原子电子密度的降低,有利于亲核取代反应。 相似文献
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一、前言不饱和聚酯树脂I号引发剂即过氧化环己酮的邻苯二甲酸二丁酯糊,是国内通用的不饱和聚酯树脂引发剂。其生产工艺一般分为直接法和间接法两种。间接法是在稀硝酸介质中,低温条件下用双氧水氧化环己酮,直接法是以邻苯二甲酸二丁酯(以下简称二 相似文献
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综述了2005~2006年国外不饱和聚酯树脂的市场动态、工业发展趋势及技术进展。市场动态包括:原油价格及其对UPR的影响;UPR与不同成型方法的FRP的消费概况;面对全球经济发展战略,UPR树脂工业的兼并重组和发展;2005年中国UPR进出口量;2005年日本不饱和聚酯树脂的消费量;不饱和聚酯复合材料及其应用和销售;汽车用复合材料的不饱和聚酯树脂配方。技术进展包括:固化程度监测仪器;不饱和聚酯树脂的新型改性剂—环氧改性酚醛清漆;低轮廓添加剂;双重引发和促进体系。对生物复合材料工业进展进行了重点介绍。 相似文献
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采用过氧化甲乙酮(MEKP)/异辛酸钴氧化还原体系20℃下引发固化不饱和聚酯树脂(UPR),研究MEKP和异辛酸钴用量对UPR凝胶时间和放热峰温度的影响,结果表明,MEKP适用量为树脂质量的2.0%~3.0%,异辛酸钴适用量为树脂质量的0.02%~0.04%。 相似文献
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N-甲基-N-2-羟乙基对甲苯胺和过氧化物引发体系 总被引:1,自引:0,他引:1
研究了N,N 二甲基苯胺(DMA)和N 甲基 N 2 羟乙基对甲苯胺(MHPT)与过氧化物组成的引发体系对不饱和聚酯树脂(UPR)固化的影响。结果表明:在促进剂浓度相同时,MHPT的凝胶时间为DMA的1/4~1/7,固化时间为DMA的缩短50%~25%,放热峰温度和巴氏硬度比DMA的高;固化温度与凝胶时间曲线表明MH PT比DMA的反应活性更高。温度比较低时(5℃),2,4 二氯代过氧化二苯甲酰(DCBPO)和过氧化二苯甲酰(BPO)/DMA体系不能使树脂快速固化,而DCBPO和BPO/MHPT体系能使树脂快速固化。使用DSC对固化的树脂样品进行非等温扫描,结里显示玻璃化转变温度和固化程度比DMA的高。 相似文献
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不饱和聚酯树脂室温固化引发剂体系 总被引:2,自引:0,他引:2
<正>不饱和聚酯树脂的固化是遵循游离基(共)聚合反应原理.游离基(共)聚合反应,除用加热、光照(紫外光)或高能射线(X、γ射线等)辐照引发外,绝大多数都是在引发剂的存在下实现的.引发剂的作用在于受热后分解产生游离基,游离基与不饱和聚酯及不饱和单体(交联剂)作用以引发(共)聚合反应.目前,不饱和聚酯树脂固化用的引发剂主要是有机过氧化物.这些有机过氧化物的分解活化能一般在25—40千卡/摩尔之间,临界温度在60℃以上,对于固化温度要求在 相似文献
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Steady-state and transient studies of the partial oxidation of butadiene to maleic anhydride were performed over a Te-promoted vanadia molybdate catalyst previously used by Fiolitakis et al. (1983) for a study of maleic anhydride production from benzene. Inhibition of the partial oxidation by butadiene was observed. Pathways for CO2 and maleic anhydride formation are different. False-start behaviour for some products was observed and attributed to conflicting contributions of adsorption and catalyst reduction or oxidation. The reaction mechanism for butadiene differs from that reported from benzene oxidation by Fiolitakis et al. (1983). 相似文献
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H2O2、金属离子等对Cr(Ⅵ)离子光催化还原及对敌敌畏农药光催化氧化的影响 总被引:5,自引:0,他引:5
以Cr(Ⅵ)离子、敌敌畏农药作为污染物的代表,研究了H2O2、金属离子等对Cr(Ⅵ)离子光催化还原及对敌敌畏农药光催化氧化的影响。结果表明,加入少量的H2O2对Cr(Ⅵ)离子的光催化还原起阻碍作用,对敌敌畏农药的光催化氧化起促进作用;加入少量的Cu^2 对Cr(Ⅵ)离子光催化还原及对敌敌畏农药的光催化氧化均起促进作用;加入Zn^2 ,Na^ 对Cr(Ⅵ)离子及敌敌畏农药的光催化降解均无明显的影响;加入甲醇、甲苯对Cr(Ⅵ)离子的光催化还原起促进作用,对敌敌畏农药的光催化氧化起阻碍作用。探讨了H2O2、金属离子等对Cr(Ⅵ)离子光催化还原及对敌敌畏农药光催化氧化影响的机理。 相似文献
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Total Oxidation of Hydrocarbons on Perovskite Oxides 总被引:7,自引:0,他引:7
T. Seiyama 《Catalysis Reviews》1992,34(4):281-300
Perovskite-type oxides containing transition metals are attracting great attention as catalysts for complete oxidation of hydrocarbons as well as electrochemical reduction of oxygen (1). A s far as I know, the use of perovskite-type oxides as catalysts was first reported by Meadowcroft in 1970 (2) for the electrochemical reduction of oxygen. Soon after that, Voorhoeve et al. (3) reported the high catalytic activity of perovskite oxides for heterogeneous oxidation. These studies triggered many studies thereafter which are related to exhaust control catalysts and electrode catalysts. 相似文献
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T. Seiyama 《Catalysis Reviews》2013,55(4):281-300
Perovskite-type oxides containing transition metals are attracting great attention as catalysts for complete oxidation of hydrocarbons as well as electrochemical reduction of oxygen (1). A s far as I know, the use of perovskite-type oxides as catalysts was first reported by Meadowcroft in 1970 (2) for the electrochemical reduction of oxygen. Soon after that, Voorhoeve et al. (3) reported the high catalytic activity of perovskite oxides for heterogeneous oxidation. These studies triggered many studies thereafter which are related to exhaust control catalysts and electrode catalysts. 相似文献
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Chemical looping combustion (CLC) is potentially the technology best suited for capturing CO2 at low cost and efficiently providing a low energy option for the separation of CO2 from flue gases. The process consists in the cyclic reduction and oxidation of metal oxide particles, which act as oxygen carriers. The particles are exchanged between two reactors, usually a circulating fluidised bed and a bubbling bed reactor, where the oxidation and reduction reactions occur, respectively. Noorman et al. (2007) explored a dynamically operated packed bed for CLC technology. Successive work undertaken by the same group (Noorman et al., 2009) has shown the feasibility of the concept, and expressions for the mass and heat front velocities were determined. In this work, the oxidation of the packed bed reactor is analysed as a problem presenting discontinuities which are sustained by transport processes and are indistinguishable from phase interfaces. Travelling mass and heat fronts arise as a consequence of the reaction kinetics; a specific problem is analysed, where the oxidation is modelled similarly to an adsorption problem and the mass front velocity is calculated for some limiting transport conditions. It is shown that the mass front velocity arises naturally when the Kotchine's procedure (Astarita and Ocone, 2002) is applied to the system. An interesting feature of the analysis presented here is that some general results can be obtained without making any specific assumption about the kinetics. The results obtained are indeed amenable to be extended to other processes where the reacting material is a bed of solid particles. The treatment presented can be implemented when small perturbations occur in the bed, thus giving useful information on predicting whether the unwanted changes in the process conditions are sustained or die out. 相似文献
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本文综合介绍Al4SiC4的最新研究进展。三元碳化物Al4SiC4属于六方晶体结构,空间群为P63mc,它具有优异的的高温抗氧化性能;优良的热稳定性和良好的室温及高温力学性能等。 相似文献
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环己烷催化氧化催化剂的研究进展 总被引:1,自引:0,他引:1
综述了国内外环己烷选择性氧化催化剂的研究进展,对目前环己烷氧化所用催化剂体系进行了总结及比较分析,重点介绍了分子筛催化剂体系中TS-1、MCM、SBA-15等分子筛催化体系. 相似文献
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壳聚糖的改性及其应用进展 总被引:1,自引:0,他引:1
介绍了壳聚糖的结构;重点论述了壳聚糖的一些主要的改性方法,包括醚化、氧化、酰化、交联、烷基化、接枝共聚、季铵化及和其他材料复合等方法;并综述了壳聚糖及其衍生物在水处理、医药、食品加工及其他领域的应用现状。 相似文献
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A study of the electrochemistry of trace metals in heavy metal fluoride melts at 550 °C has been conducted at a stationary electrode with a view to establishing electroanalytical methods for these melts. Reproducible differential pulse voltammetry traces were obtained, the trace metal oxidation peaks behaving as predicted by the theory of Osteryoung et al. The peak current for Fe2+ reduction in a fluoride melt was found to be linear in pulse amplitude up to 70 mV and linear in (pulse duration)–1/2. The peak potential was also found to be a linear function of pulse amplitude. Scan rates around 3 mV s–1 and sampling times around 8 ms were found to produce the optimum analytical response. 相似文献