In-Plane Fourfold Symmetry of the Upper Critical Field Observed in La(Sr)214 Single Crystals

In order to establish the existence of in-plane anisotropy of the upper critical field H _c2 (), the out-of-plane resistivity _c measurements were performed on La(Sr)214 single crystals with rectangular and cylindrical shape under rotating magnetic field applied within the ab-plane. Although observed _c shows non-sinusoidal twofold symmetry, clear fourfold symmetry was obtained after subtracting twofold sinusoidal component in _c which is due to the unavoidable misalignment of the magnetic field with respect to ab-plane. H _c2 () is estimated from the extracted fourfold component of _c with the flux flow theory. Angular dependence of H _c2 () was well fitted by cos(4). Since the fourfold component of H _c2 () was largest at = n/2, which corresponds to the a-axis direction, the present results strongly suggest the type symmetry in La(Sr)214. In addition, the difference in fourfold component of H _c2 at = n/2 and n/2+/4 was found to increase with decreasing temperature.     

Comparative study of solubilities of hydrogen,nitrogen and carbon in α-iron

Solubility data of hydrogen, nitrogen and carbon in -iron are analysed on the basis of statistical thermodynamics. Present analysis appears to yield realistic values for the enthalpy term of the solutions of these interstitial elements into -Fe, while the entropy terms remain ambiguous. During the course of this analysis a parameter _x, which refers to the solubility limit of the specific interstitial element X (X=hydrogen, nitrogen or carbon), is also estimated; _H< _N< _C. This order of _X values appears to be in accord with the observation that, under normal conditions, the solubility of carbon is the highest and that of hydrogen the lowest in -Fe, while the atomic size increases with the order hydrogen相似文献   

Grain growth in the two-phase Al-Cu alloys

Grain and phase growth in the two-phase Al-Cu alloys containing 6, 11, 1 7, 24 and 33 wt % Cu were investigated by annealing at 535 °C for 0.5–100 h. The grain and phase sizes of the phase are seen to be larger than that of the phase. The size of phase decreases whereas the size of phase increases with increasing copper content in the alloy. As such, the phase- and grain-size distributions are broader than the phase- and grain-size distributions, but the size range depends on annealing time and alloy composition. The grain sizes of the ,d , and ,d , phases can be related to the volume fraction of the phase,f , according to the equationd = 0.497d /f .     

A comparative assessment of creep property predictions for a 1CrMoV rotor steel using the CRISPEN, CDM, Omega and Theta projection techniques

This paper assesses the relative accuracy of a number of techniques that are capable of predicting a wide range of creep properties. The techniques studied in this paper include the 4-, 6-, CRISPEN, Omega and CDM methodologies. The parameters of these models were estimated from short-term creep property data on 1CrMoV steel and these estimated models were then used to predict the known longer-term creep properties of this steel. It was found that the CDM approach yielded predicted times to failure that were wholly inadequate. The 6- approach was best for predicting long term times to failure. The best minimum creep rate predictions came from using either the 4-, or the CRISPEN or the Omega technique. Finally, times to small strains were best predicted using the 6- and CRISPEN techniques.     

Analysis of the effect of the decomposition of char-forming heat-insulating materials on the free discharge of a gas mixture

The article presents results of a numerical solution of a nonsteady problem on the free discharge of a mixture of gases from a hemispherical volume with allowance for thermal decomposition of heat-insulating materials.Notation V volume - S area - t - P p - T - u v - Q q, dimensional and dimensionless time, pressure, temperature, TIM decomposition rate, and heat flux - adiabatic exponent - R gas constant - density - H specific enthalpy - c specific heat - thermal conductivity - , , _s dimensionless complexes - coefficient expressing the radiative properties of the gas medium and the heat-transfer surface - Stefan-Boltzmann constant Indices 0 initial state and scale factors - s surface - coke - M TIM material - P pyrolysis front - A ablation front - v volatile degradation products - adiabatic conditions - c completion of discharge Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 54, No. 5, pp. 787–793, May, 1988.     

The interdependence between the incidence angles associated with quasi-stable intersections during ion erosion

A general discussion, which is valid for any angular dependence of sputtering yieldS=S(), concerning the interdependence between the incidence angles _e and ₀, associated with quasi-stable intersections during ion erosion, is given. The object was firstly to establish the location of _e roots as a function of ₀ and secondly to identify the stationary points and general trend for the complex dependence _e= _e( ₀). The results obtained are applied to a quasi-stability analysis of some specific surface features during ion erosion. Various possible types of quasi-stable intersections (surface-surface, plane-surface, plane-plane) are reviewed from the point of view of their evolution caused by ion bombardment.     

Preparation of epitaxially grown LaSrCoO3 thin films on SrTiO3(100) substrates by the dipping-pyrolysis process

LaSrCoO₃ thin films were spin-coated onto SrTiO₃(100) substrates by the dipping-pyrolysis process. X-ray diffraction -2 scans and X-ray diffraction scans were used to determine the crystallinity and in-plane alignment behavior of the films. The X-ray diffraction pattern shows the film obtained by annealing at 800°C was highly oriented. The X-ray diffraction pole-figure analysis and reciprocal-space mapping (-2 scans) of the resulting film showed that the film comprising the pseudocubic phase had an epitaxial relationship with the SrTiO₃ substrate.     

Heat conduction in a multilayer composite wedge

A new method for analytically solving a problem of steady-state heat conduction for multilayer composite wedge-shaped bodies is suggested based on a generalization of the integral Mellin transform.Notation T temperature - _rr, thermal conductivity coefficients - thickness of composite material layers (1) - N₁(), N ₂ ⁽¹⁾ (), N ₂ ⁽²⁾ () auxiliary local functions from the rapid variable =r/ - m(r, p) auxiliary function entering the core of the generalized integral Mellin transform - ₀ half of the wedge aperture angle Moscow Institute of Chemical Engineering. Translated from Inzhenerno-Fizicheskii Zhurnal, Vol. 64, No. 4, pp. 487–491, April, 1993.     

Analytical and graphical evaluation of local quasi-stable angular points during ion bombardment at oblique incidence

An implied analytical condition, connecting the incidence angles _o and _e between the two intersecting microfacet normals and the ion beam direction, has been inferred for the existence of local quasi-stable intersections (angular points) during ion erosion. This condition, which can also be deduced on the basis of the erosion slowness curve, leads to a higher degree algebraic equation with a parameter, applicable for any dependence S=S (), expressed as an algebraic polynomial expression in cos . A new graphical method for evaluation of orientations _e compatible with a given orientation _o, based on a known polar diagram cursor-type, has also been proposed.     

A model with length scales for composites with periodic structure. Steady state heat conduction problem

A new high-order model for analysing distribution of temperature in periodic composites is proposed. The original scalar elliptic problem with Y-periodic coefficients (Y is a cube) is replaced with a vectorial elliptic problem of constant coefficients. The unknown fields are: the averaged distribution of temperature and the vector field which stands for perturbation of the temperature within the cells of periodicity. The recovery of temperature in the original composite is given by the approximation: 0(x)=0(x) +h ^a (x/) _a (x) analogous with the first terms of the two-scale asymptotic expansion known from the homogenization theory. The functions h are defined as approximations of the solutions to the basic cell problems. In contrast to the two-scale expansion the expression for satisfies the boundary condition.     

Simulating Crack Trajectories from a radially loaded hole

A procedure for determining the trajectory of growth of a crack in the neighbourhood of a stress-raising feature is described, The method relies on first determining the underlying stress field, and then formulating an integral equation along the (generally) curvilinear contour of the crack, which ensures that its surfaces remain traction free. The crack tip stress intensities are calculated, from which an increment of growth is found using the ^max criterion. The technique is then applied to the determination of the growth trajectory for a crack growing from a circular hole loaded by pressing a pin against its boundary.     

Interaction among a row of ellipsoidal inclusions

In this paper the interaction among a row of N ellipsoidal inclusions of revolution is considered. Inclusions in a body under both (A) asymmetric uniaxial tension in the x-direction and (B) axisymmetric uniaxial tension in the z-direction are treated in terms of singular integral equations resulting from the body force method. These problems are formulated as a system of singular integral equations with Cauchy-type or logarithmic-type singularities, where unknowns are densities of body forces distributed in the r,,z directions. In order to satisfy the boundary conditions along the ellipsoidal boundaries, the unknown functions are approximated by a linear combination of fundamental density functions and polynomials. The present method is found to yield rapidly converging numerical results for interface stresses. When the elastic ratio E ₁E _I/E _M>1, the primary feature of the interaction is a large compressive or tensile stress _n on the interface =0. When E ₁E _I/E _M<1, a large tensile stress or _t on the interface =1/2 is of interest. If the spacing b/d and the elastic ratio E _I/E _M are fixed, the interaction effects are dominant when the shape ratio a/b is large. For any fixed shape and spacing of inclusions, the maximum stress is shown to be linear with the reciprocal of the squared number of inclusions.     

Electrical conductivity,thermoelectric power and dielectric constant of NiWO4

The a.c. electrical conductivity ( _ac), thermoelectric power () and dielectric constant () of antiferromagnetic NiWO₄ are presented. _ac and have been measured in the temperature range 300 to 1000 K and in the temperature range 600 to 1000 K. Conductivity data are interpreted in the light of band theory of solids. The compound obeys the exponential law of conductivity = ₀ exp (–W/kT). Activation energy has been estimated as 0.75eV. The conductivity result is summarized in the following equation =2.86 exp (–0.75 eV/kT)^–1 cm^–1 in the intrinsic region. The material is p-type below 660 K and above 950 K, and is n-type between 660 and 950 K.     

Vibrations of axially compressed laminated orthotropic cylindrical shells,including transverse shear deformation

Summary The free vibrations, buckling and the effect of initial prestress upon the frequency spectrum of orthotropic composite cylindrical shells are examined in the context of a theory that includes transverse shear deformation. Results obtained are compared with the predictions of refined Love-type theory and simplified Donnell-type theory that do not consider shear deformation.The calculated examples indicate that transverse shear deformation can be significant not only for short composite shells but even for longer shells possessing low shear moduli.

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Schwingungen axial gedrückter, laminierter, orthotroper zylindrischer Schalen einschließlich Querschubverformung

Zusammenfassung Es werden die freien Schwingungen, das Beulen und der Einfluß einer Anfangsvorspannung auf das Frequenzspektrum orthotroper, kompositer, zylindrischer Schalen im Rahmen einer Theorie, die die Querschubverformung mitberücksichtigt, untersucht. Die erhaltenen Resultate werden mit den Vorhersagen der verbesserten Loveschen Theorie und der vereinfachten Donnellschen Theorie, welche keine Querschubverformung in Betrach ziehen, verglichen.Die durchgerechneten Beispiele zeigen, daß die Querschubverformung nicht nur für kurze, komposite Schalen sondern sogar für längere Schalen mit niederem Schubmodul Bedeutung gewinnen kann.

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Nomenclature a radius of reference surface of cylindrical shell - A _i amplitudes of displacements - A _ij elastic area - B _ij elastic statical moment - D _ij elastic moment of inertia - E _ij elastic stiffness modulus - h shell thickness - k ₄₄,k ₅₅ shear correction factors - l length of cylindrical shell - L _ij functional operator - m number of half-waves in axial direction - M ,M ,M axial, circumferential and twisting moments, respectively - n number of circumferential waves - N ⁰ axial compression force - N ,N ,N axial, circumferential and shear forces, respectively - Q ,Q transverse shear forces - R ₀,R ₁,R ₂ inertia terms - t time - T matrix defined in Eq. (25) - u, v, w displacements in axial, circumferential and radial directions, respectively - U _i time-independent displacement or rotation - nondimensional axial wave parameter - , , axial, circumferential and shear strains, respectively - radial coordinate, taken positive inward - polar angle - , , curvature changes - circular frequency - nondimensional axial coordinate - density - , , , , stress components - , rotations of normal to undeformed midsurface With 6 Figures     

Microstructure of a rapidly solidified 65Al-20Cu-15Fe (at. %) alloy

The microstructure of rapidly solidified 65Al-20Cu-15Fe (at. %) powders was investigated by analytical transmission electron microscopy. It was found that segregation in the powder particle occurred during solidification. The major phase present in the powder particles was the icosahedral quasicrystalline l-phase, which was determined to have space group . Two other crystalline phases, -AlCu₃ and -Al₁₃Fe₄, coexisted with the l-phase. The l-phase was revealed by convergent beam electron diffraction to have three-dimensional quasiperiodicity ( = 1.618) which is different from quasicrystals in the other systems. The compositions of the three phases have been analysed by energy dispersive X-ray analysis. The l-phase in this system could be approximately described as Al₅CuFe. The composition of the -Al₁₃Fe₄ was very close to the equilibrium condition while -AlCu₃ was far from stoichiometry. An orientation relationship between -AlCu₃ and -Al₁₃Fe₄ was found as follows: [110][010] [111][001]     

Spin diffusion coefficient of the A and B phases of liquid3He

The spin diffusion coefficient tensors are calculated in the A and B phases of liquid ³ He in the _{L D} <1 regime by using the Kubo formula approach. The spin wave dispersions are also obtained in the presence of diffusive flow of the normal component. The results agree with Combescot's results qualitatively in the _{L D} <1 regime.     

On the parametric instability of laminated plates modeled within a high-order shear-deformation theory

Summary The parametric instability of cross-ply laminated plates, subjected to periodic in-plane loadsP(t)=P _s+P _d cos t, is investigated. Within the high-order shear deformation lamination theory the motion is governed by three coupled partial differential equations, which are nonsymmetric in their nature. Using the method of multiple-scale, analytical expressions for the instability regions are obtained at= _j ± _i , where _i are the natural frequencies of the system. It is shown that beside the principal instability region at=2 ₁, other instability regions can exist for the first mode, and their significance is examined by various parameters such as the length-to-thickness ratio and the modulus ratio.     

Predicting times to low strain for a 1CrMoV rotor steel using a 6-θ projection technique

The projection method of creep analysis is known to produce the poorest predictions of creep properties at low strains. This paper applies a recently suggested modification of the concept to 1CrMoV rotor steel where long term data exists to enable an assessment of this modification to be made. The modification takes the form of two additional terms that allow the initial stages of any creep curve to be modelled more accurately. The paper shows that the resulting 6- approach produces predictions of long-term failure times and minimum creep rates that are as good as those obtained using the traditional 4- approach. Unlike the 4- approach, the 6- approach is also shown to be capable of accurately predicting times to very low strains (0.05% and 0.1%) at stress levels as low as 77 MPa (well below the lowest stress of 230 MPa used in the theta analysis). For times to 1.0% strain or more the 4- and 6- techniques give similar short and long-term predictions.     

Precipitation hardening in an Al-Cu-Si-Mg alloy at 130 to 220° C

The variation of the hardness of a complex Al alloy, of the L70 type, (Al 4% Cu 0.8% Si 0.8% Mg 0.7% Mn 0.5% Fe) with ageing time at 130, 160 and 190° C was measured and correlated with transmission electron microscope observations of preciptate morphology. It was established that the peak hardness, after both 160 and 190° C ageing, was associated with coherent precipitate particles with a diameter of 700 Å and the subsequent limited overageing at these temperatures was controlled by the slow growth of particles. Measurements of particle coarsening at 220° C suggested that the process occurred by Ostwald ripening. In contrast, ageing at 130° C gave a series of hardness—time plateaus, which were ascribed to the sequential precipitation of zones,' and precipitates.     

Microstructural evolution in rapidly solidified Al-Cu-Si ternary alloys

Several Al-Cu-Si alloys were melt spun to produce stable, fine scale microstructures suitable for superplastic deformation and consolidation. Scanning electron microscopy of the ribbon cross-sections reveal two distinct alternating microstructural morphologies, suggesting transitions in solidification behavior. One structure consists of intimately interlocked -Al and (Al₂Cu) phases with dispersed spheroids of (Si). The other structure consists of equiaxed or cellular-dendritic -Al with interdendritic and (Si). The latter was found in the middle portion of the ribbon cross-section when cast at a low speed, and throughout the ribbon cross-section when cast at high speed. The dendritic structure appears to result from independent nucleation events in the undercooled liquid ahead of the solid-liquid interface. The solidification mechanism for the interlocked structure appears to involve multiple nucleation of the phase followed by its cooperative growth with the -Al phase. This cooperative growth is unlike that which forms a lamellar structure, as it results in a branched, randomly oriented network. We postulate that the (Si) phase is the first phase to form from the undercooled liquid, and it is uniformly dispersed throughout the undercooled melt. The (Si) spheroids provide nucleation sites for the phase because of its observed association with the phase. The -Al grain size varies from 1 m near the wheel side surface of the ribbon to 8 m with sub-grains near the free surface. The size of the and (Si) phases is on the order of a m and less. The microstructural size scale appears to be small enough for this material to exhibit superplastic behavior when deformed.