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本文对PVA膜宏观专利数据以及专利技术进行了详细分析。PVA膜专利研究和保护的内容主要涉及原材料、配方、生产工艺、应用领域、装备等多个方面。PVA膜专利技术主要涉及偏光膜、包装膜以及农膜三个方面,其中,偏光膜专利数量最多。PVA偏光膜专利技术主要分为纯PVA膜专利技术、PVA改性技术以及染料/碘系偏光膜技术。在产品研制过程中,重点从原材料的组合应用、生产工艺两个方面着手进行优化。 相似文献
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本文对PVA膜宏观专利数据以及专利技术进行了详细分析。PVA膜专利研究和保护的内容主要涉及原材料、配方、生产工艺、应用领域、装备等多个方面。PVA膜专利技术主要涉及偏光膜、包装膜以及农膜三个方面,其中,偏光膜专利数量最多。PVA偏光膜专利技术主要分为纯PVA膜专利技术、PVA改性技术以及染料/碘系偏光膜技术。在产品研制过程中,重点从原材料的组合应用、生产工艺两个方面着手进行优化。 相似文献
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介绍了传统型烟用包装膜的重点研究领域,主要包括高挺性、高透明性和高耐磨性。并综述了烟用包装膜的最新研究进展,重点介绍防伪型和环保型烟用包装膜的研究情况。最后介绍了功能型烟用包装膜,如光降解烟膜和生物降解烟膜的研究进展及应用前景。 相似文献
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用马来酸酐对玉米淀粉进行酯化处理制得醋酸酯淀粉,以溶液共混法分别制备了原淀粉(ST)/聚乙烯醇(PVA)、醋酸酯淀粉(SA)/聚乙烯醇共混膜,用FTIR表征了共混膜的结构;用DSC分析了共混膜的热性能;比较了共混膜的力学性能。结果表明,共混物的加入破坏了PVA的晶态结构,使共混膜的熔融温度向低温方向移动,热稳定性降低,但SA/PVA共混膜的热稳定大大高于ST/PVA共混膜,说明经酯化处理后淀粉的热稳定性增强。并且SA与PVA的相容性也较ST提高,使其共混膜的力学性能改善。表现为SA/PVA共混膜的力学性能明显高于同比例的ST/PVA共混膜。 相似文献
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PVA与壳聚糖共混膜的制备及性能研究 总被引:4,自引:0,他引:4
用溶液共混法制备PVA与壳聚糖共混膜,用红外光谱法对共混膜进行了表征,并对膜的吸水率、透光率和力学性能进行测试。结果表明,共混膜中PVA分子链与壳聚糖分子链有一定的相互作用,壳聚糖的引入有利于改善PVA的透光性和降低其吸水率。 相似文献
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The rational design of food packaging films with good antimicrobial activity, antioxidant activity, and monitorability is of great importance in intelligent packaging. In this study, an active composite film was prepared by adding curcumin to a dialdehyde cellulose (DAC)/polyvinyl alcohol (PVA) matrix. It was found that the Cur/DAC/PVA composite film exhibited optimal tensile strength at 30°C. The tensile strength of the composite film control PVA/DAC film was observed to increase by 176% due to the affection of hydrogen bonding. Under the influence of curcumin, the UV barrier property and antioxidant activity of the composite film were significantly increased, and the ABTS+• was removed by 0.5Cur/DAC/PVA up to 88% at low curcumin content. The water solubility and water vapor permeability were both reduced to some degree. It was also observed that composite film displayed an inhibitory effect on the growth of Staphylococcus aureus bacteria. Meanwhile, the Ritger and Peppas release model was used to study the release control capability of curcumin. Furthermore, the Cur/DAC/PVA composite film demonstrated excellent color response to pH, which it they could be used for intelligent packaging with real-time visual monitoring. 相似文献
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Patrícia Pinheiro dos Santos Acosta Juliana Machado Latorres Vilásia Guimarães Martins 《应用聚合物科学杂志》2023,140(3):e53342
The aim of this study was to prepare active, biodegradable methylcellulose films and evaluate their properties after incorporating cinnamon (Cinnamomum cassia) and litsea cubeba (Litsea cubeba) essential oils. The properties of the methylcellulose films were modified with the addition of essential oils. The surfaces were smooth and homogeneous in all samples. The film with cinnamon oil showed higher antibacterial activity against Staphylococcus aureus and Escherichia coli and the film with litsea cubeba showed higher antioxidant activity against ABTS radical. The biodegradation time of the films in black sand and beach soil was 20 days. The films produced that presented the highest potential to become active packaging were the film with litsea cubabe oil as antioxidant packaging and the film with cinnamon oil as antibacterial packaging. 相似文献
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Membrane separation is an important processing technology used for separating food ingredients and fractionating value‐added components from food processing byproducts. Long‐term performance of polymeric membranes in food protein processing is impeded by the formation of fouled layers on the membrane surface as a result of protein adsorption onto the membrane surface. Surface modification of synthetic membranes, i.e., changing surface characteristics to reduce protein adsorption permanently, is one of the innovative ways of reducing the fouling of membrane surfaces. In this study, surface modification of flat‐sheet ultrafiltration membrane, polyethersulfone (PES), was investigated in improving the hydrophilicity of PES surfaces, thereby reducing adsorption of the protein caused by hydrophobic–hydrophobic interaction between the protein and the membrane. Hydrophilic polymer grafting through thin‐film composite using interfacial polymerization was employed to improve the hydrophilicity of the commercial PES membranes. Poly(vinyl alcohol), poly(ethylene glycol), and chitosan were chosen as hydrophilic polymers to graft on PES membrane because of their excellent hydrophilic property. Modified PES membranes were characterized by contact angle, FTIR, XPS, and AFM. Contact angles of modified PES membranes were reduced by 25 to 40% of that of the virgin PES membrane. XPS spectrum supported that the PES membranes were successfully modified by interfacial polymerization. Tapping‐mode AFM was used to examine the changes in surface topography of modified PES membranes. The PES membranes modified by interfacial polymerization showed lower roughness (from 1.2 to 2.0 nm) than that of virgin PES membrane (2.1 nm). The results of these instrumental analyses indicated that the PES membranes were successfully enhanced hydrophilically through interfacial polymerization. The protein adsorption on the modified membranes was reduced by 30 to 35% as a result of surface modification of the PES membranes using interfacial polymerization technique. Published 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2009 相似文献
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Sona Chavoshizadeh Sajad Pirsa Forough Mohtarami 《European Journal of Lipid Science and Technology》2020,122(3)
In this study, a smart biodegradable film based on wheat gluten modified with chlorophyll (WG/Ch) is presented. The effect of chlorophyll on the antioxidant activity and mechanical properties of WG/Ch film is studied. Scanning electron microscopy and Fourier‐transform infrared spectroscopy (FT‐IR) analyses are used to study the structure and chemical composition of gluten‐based films. The WG/Ch film is used in the packaging of sesame oil. The effect of WG/Ch film on increasing the shelf life and detecting expiration time of oil is studied. FT‐IR results show that weak interactions are created between gluten and chlorophyll. The antioxidant activity of the WG film is 60% and it increases to 85% by the addition of chlorophyll. The results show that with the increasing storage time of oil samples, oxidative indices are increased, but the WG/Ch film decreases the sesame oil oxidation significantly (almost in the all oxidative indices 50% decrease is observed). Practical Applications: The WG/Ch film is used in the packaging of sesame oil. The effect of WG/Ch film on the increasing of shelf life and detecting expiration time of oil is studied. By increasing storage time and oxidant, acidity, acid number, PA, and oil color change are increased, but the WG/Ch active film decreases the sesame oil oxidation significantly. Also, by examining the color properties of the active film, it is observed that with increasing storage time and oxidant percent, the color of the film is changed (from green to yellow), which can be used to estimate the oil expiration time. It should be mentioned that the film's color changes are visible to the naked eye. 相似文献
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Hiroyuki Moroi 《Polymer International》1988,20(4):335-343
The following aspects of the manufacture, properties and applications of biaxially oriented poly(vinyl alcohol) (PV-OH) films are discussed: selection of starting PV-OH; method of production by successive biaxial orientation: technical aspects of production; characteristics and applications of the film. Biaxially oriented PV-OH films have good antistatic properties, good thermal resistance, oil and solvent resistance, and excellent gas barrier properties, and are used in food packaging applications. The following aspects of the manufacture, properties and applications of poly(vinyl alcohol) film produced by a blown film technique are discussed: selection of starting PV-OH; process for the production of hot-water-soluble (HWS) film; technical aspects of film production; characteristics and applications of the film. Blown films, which are hot-water-soluble, are produced in tubular form, for conversion into disposable laundry bags. 相似文献
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聚乙烯醇(PVA)因其良好的化学稳定性、耐酸碱、耐有机溶剂性以及优异的成膜性和生物安全性,成为应用最广泛的亲水性膜材料之一。但亲水性PVA膜力学性能弱和耐水性能差等缺点严重限制其实际应用。近些年,人们通过共混、纳米复合、热处理、化学交联以及协同改性等方法对PVA膜进行了大量的改性研究工作并取得了众多成果。本文总结了不同PVA膜改性方法的特点及存在的问题,重点阐述了性能优异的填料在纳米复合改进PVA膜力学性能上的研究现状,简述了共混、热处理、化学交联对改性PVA膜的作用,强调了协同改性对提高PVA膜综合性能的重要意义,为设计和制备高性能的PVA膜提供一定的参考。指出改性后的PVA膜在水处理和食品包装领域具有良好的应用前景。 相似文献
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The properties of polyamide (PA) thin film composite (TFC) membranes are affected by many variables, especially the additives in the process of interfacial polymerization that play an important role in the properties of membranes. In this study, a new type graphite carbon was added into organic phase containing trimesoyl chloride for interfacial polymerization with aqueous phase containing m-phenylenediamine to prepare modified polyamide thin film nanocomposite (TFN) membranes for reverse osmosis (RO) adhibition. Polysulfone ultrafiltration membranes were used as the carrier of the interfacial polymerization. The concentration of graphite carbon was selected from 0.002 to 0.01 wt%. The polyamide nanocomposite membrane prepared with the concentration of 0.004 wt% graphite carbon showed the best RO desalination performance, which the water flux of this TFN membrane is over 2.3 times as much as pristine TFC membrane, and the salt rejection is over 99%. This article provides a well-performing polyamide thin film nanocomposite membrane modified by a new-type carbon nanoparticles consequently. 相似文献
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通过酰胺化反应将4-羧基苯硼酸(PBA)接枝到聚乙烯胺(PVAm)高分子链上,制得改性聚乙烯胺(PVAm-g-PBA),利用FTIR和1HNMR对其结构进行了表征。采用硅晶片和聚苯乙烯微球(PS)作为模拟物,将PVAm-g-PBA和聚乙烯醇(PVA)组装到其表面并研究了自组装过程中基材表面电荷的变化规律及自组装膜层厚度的变化。将PVAm-g-PBA与PVA通过pH可控的层层自组装方法处理再生纤维素膜表面。结果表明:PVAm-g-PBA的等电点为pH=7.9;在p H=9.5、与PVA组装上30层高分子膜时,再生纤维素膜的抗张强度与断裂伸长率分别提高了53%和76%。处理后的再生纤维素膜的机械性能得到了明显改善。 相似文献
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研究了醋酸乙烯/乙烯/丙烯酸酯多元共聚乳液的合成.在高压反应釜中采用间歇聚合工艺进行乳液聚合,使用聚乙烯醇作为主要保护胶体,采用非离子和阴离子复合乳化剂以及氧化-还原引发体系,通过引入丙烯酸酯类软单体,实现醋酸乙烯/乙烯/丙烯酸酯多元共聚,生产出低温柔性好、对非极性材料(例如BOPP)具有优异粘接性能的新型多元改性共聚VAE乳液.用于防水涂料和包装行业,效果优良. 相似文献