JHG—120醇醚磺基琥珀酸单酯二钠盐研制成功

吉林化学工业公司研究院开发成功的 JHG—120 醇醚磺基琥珀酸单酯二钠盐技术成果,目前正式通过专家技术鉴定。醇醚磺基琥珀酸单酯二钠盐,是阴离子表面活性剂磺基琥珀酸系列中的一种,它兼有阴离子和非离子表面活性剂的特点,并且是温和型表面活性剂中价格最低的一种,广泛地应用于温和型洗涤剂,浴液,洗     

磺基琥珀酸单酯二钠盐的异构体分析

用核磁共振谱测定了两种磺基琥珀酸单酯二钠盐钠磺基的位置，确定磺基以α位为主。     

JHZ-120醇醚磺基琥珀酸单酯二钠盐通过鉴定

吉林化学工业公司研究院开发的JHZ-120醇醚磺基琥珀酸单酯二钠盐,于1993年7月6日通过了技术鉴定。醇醚磺基琥珀酸尊酯二钠盐是阴离子表面活性剂磺基琥珀酸盐类系列中的一种,它兼有阴离子和非离子表面活性剂的特点,并且是温和性表面活性剂中价格最低的一种,可广泛地用于温和型洗涤剂、浴液、洗手剂、香波、餐洗、和化妆品等日用化学品中,还可以用于涂料、皮革、造纸、纺     

磺基琥珀酸单酯盐的研究及应用

本文重点介绍新型阴离子表面活性剂磺基琥珀酸单酯二钠盐的特性、制备工艺以及在民用和工业上特别是在石油钻井、洗井作业上的应用,显示了磺基琥珀酸单酯盐在表面活性剂领域内的竞争力。     

混合废纸洗涤法脱墨剂的研制

本文简要介绍了十八烷基硫酸酯钠盐,十二烷基醇加EO／PO成嵌段物,烷基聚氧乙烯醚磺基琥珀酸单酯二钠盐以及少量无机盐复配的新型脱墨剂,刺激性低,易生物降解。以洗涤法进行混合废纸脱墨,得白度（83．2％ISO）、尘埃度（156．1mm^2／m^2）的再生浆。     

十一烯酸单乙醇酰胺磺基琥珀酸酯二钠的合成与应用

本文着重叙述了十一烯酸单乙醇酰胺磺基琥珀酸酯二钠盐的主要性能、合成方法及在化妆品、洗涤剂中的应用。     

十一烯酸乙醇酰胺磺化琥珀酸酯二钠盐

十一烯酸单乙醇酰胺磺化琥珀酸酯二钠盐（Disodium undecenyl monoethanol amide sulfosuccinate)，又名磺基琥珀酸单十一烯酰胺基乙脂二钠，俗名为去头屑剂NS。     

月桂醇聚氧乙烯醚(7)辛基磺基琥珀酸混合双酯钠的合成与性能

采用控制酯化率和非外加相转移催化剂在敞开体系中进行反应的方法合成月桂醇聚氧乙烯醚(7)辛基磺基琥珀酸混合双酯钠.得到最佳工艺条件:n(月桂醇聚氧乙烯醚(7)):n(顺酐)为1.00:1.10,于130℃下单酯化反应2.5 h,得到产率为99.1%的单酯化产物.n(二乙基己醇):n(顺酐)为4.0:1.0,于190℃下双酯化反应5.0 h.得到产率为94.3%的双酯化产物.n(亚硫酸氢钠):n(顺酐)为1.10:1.00,加热介质温度为200℃下磺化反应5 h.并测定了产物的表面活性和应用性能.与磺基琥珀酸二辛酯钠盐(快T)和月桂醇聚氧乙烯醚(7)磺基琥珀酸单酯二钠盐进行性能对比.结果表明:耐硬水能力、分散力、钙皂分散性能和去油污性能较磺基琥珀酸二辛酯钠盐均得到了改善,并与月桂醇聚氧乙烯醚(7)磺基琥珀酸单酯二钠盐相比,渗透性能得到较大的提高.     

磺基琥珀酸酯铵的合成及其抗静电性能评价

以马来酸酐、脂肪醇和亚硫酸氢钠为原料经过酯化、磺化反应合成磺基琥珀酸酯钠,然后分别与四丁基氯化铵(TBAC)、十六烷基三甲基氯化铵(CTAC)和十四烷基二甲基苄基氯化铵反应,合成了12个不同结构的磺基琥珀酸酯铵(ASS)油溶性离子液体,研究了磺基琥珀酸酯铵中阴、阳离子的烃基结构对磺基琥珀酸酯铵抗静电性能的影响。结果表明,阳离子的烃基结构对磺基琥珀酸酯铵抗静电性能的影响较大,阳离子为四丁基铵和十六烷基三甲基铵的磺基琥珀酸酯铵,在0号商品柴油中加剂量为50 mg/L时,柴油电导率增加值(Δκ)可达到100 pS/m,符合行业标准要求。     

磺基硅聚氧乙烯醚琥珀酸单酯二钠盐

南京工业大学的许澎等人以有机硅聚醚、马来酸酐、亚硫酸氢钠为原料,合成了磺基硅聚氧乙烯醚琥珀酸单酯二钠盐。产物具有较好的表面活性,临界表面张力为26.4 mN/m。     

Preparation and Physiochemical Properties of Disodium Lauryl Glucoside Sulfosuccinate

A new synthetic route to a mild surfactant disodium lauryl glucoside sulfosuccinate (AG‐SS) containing two hydrophilic groups is described and its measured physicochemical properties reported. AG‐SS was synthesized from lauryl glucoside reacted with maleic acid anhydride, and then sulfonated with sodium sulfite. The structure and composition of the product were defined by Fourier transform infrared spectroscopy and liquid chromatography–mass spectrometry. The surface activity measurement showed that the critical micelle concentration (CMC) and that the surface tension at CMC (γ_CMC) of AG‐SS were 2.59 × 10^?4 mol/L and 35.21 mN/m at 25 °C, respectively. AG‐SS exhibited excellent water solubility eliminating the disadvantage of lauryl glucoside; its foaming ability was also remarkable.     

Synthesis of Alkyl Monoglucoside Citric Monoester and Properties of Its Sodium Salt

A series of disodium alkyl monoglucoside citric monoesters (AG‐EC) were synthesized with an indirect method using glucosides, lauryl/decyl/octyl alcohol and citric acid. The structure and composition of the synthesized surfactants were defined by Fourier transform infrared spectroscopy (FTIR) and liquid chromatography–mass spectrometry (LC/MS). The surface properties, foaming ability and wetting ability were investigated. AG‐EC surfactants exhibited excellent water solubility which eliminated the defect of long‐chain alkyl glucoside. All three surfactants showed high surface activities. AG12‐EC and AG10‐EC showed remarkable foaming abilities in distilled water and hard water. Aqueous solutions of AG‐EC surfactants spread slowly on a parafilm surface.     

新型混合反胶团萃取溶菌酶的平衡行为

研究了由阴离子表面活性剂二-(2-乙基己基)琥珀酸酯磺酸钠(AOT)和非离子表面活性剂聚氧乙烯基(聚合度为4)壬基酚醚(OPE4)组成的一种新型混合反胶团体系及其萃取溶菌酶的平衡行为. 结果表明,该反胶团体系具有较大的含水量,且其含水量在较大的表面活性剂配比(0~0.8)范围内维持恒定,是由静电作用和胶束形态改变共同作用的结果. 无机盐种类和离子强度对上述混合反胶团的含水量有着显著的影响,继而影响到溶菌酶的萃取率. 它可归结为盐离子对扩散双电层和水化膜斥力的因素所致. 降低pH和提高总表面活性剂浓度均有利于溶菌酶的萃取.     

On the role of hydrophilicity and hydrophobicity in aqueous heterophase polymerization

This paper reports on experimental results of aqueous heterophase polymerizations with monomers of quite different solubility in water ranging from the water-soluble 2-hydroxyethyl methacrylate to lauryl methacrylate with solubility in water of only about 10⁻⁴ mM. A calorimetric study revealed the strong influence of both the hydrophilicity of the monomer and the stirrer speed on the rate of polymerization in the absence of surfactants. In order to obtain maximum latex yield and high efficiency (which is a measure considering colloidal properties, polymerization recipe, and polymerization parameters) the initiator-surfactant combination must be properly chosen in dependence on the hydrophilicity of the monomer. Results are presented for sodium alkyl sulfates or disodium-N-stearoyl-l-glutamate as surfactant and potassium peroxodisulfate, or poly(ethylene glycol)-azo- compounds, or 2,2′-azobis(N-2′-methylpropanoyl-2-amino-alkyl-1)-sulfonates as initiators.     

系列烷基糖苷硫酸酯盐的性能研究

对实验室自制的系列烷基糖苷硫酸酯盐（APGS）表面活性剂的表面性能和应用性能进行了测定，并对其构效关系进行了研究。结果表明，系列烷基糖苷硫酸酯盐是烷基糖苷的衍生物，是一类性能优良的阴离子表面活性剂，具有优异的泡沫、润湿能力，良好的乳化、分散能力，还具有良好的抗硬水能力，具有广泛的开发应用前景。     

Synthesis of Ethoxylated Alkyl Sulfosuccinate Surfactants and the Investigation of Mixed Solutions

A series of ethoxylated sodium monoalkyl sulfosuccinate (ESMASS) ester surfactants were prepared by reacting polyethylene glycol (molecular weight 600) with sodium monoalkyl sulfosuccinate (SMASS). The esters were prepared by reacting octyl, lauryl, or cetyl alcohol with sodium sulfosuccinate (SSS) to prepare E(14)SMOSS, E(14)SMLSS, and E(14)SMCSS. The chemical structures of the prepared surfactants were confirmed by Fourier transform infrared (FTIR) and ¹H-NMR spectroscopy. The surface tension of the synthesized surfactants was measured at 25 °C individually or mixing at different molar fractions with sodium dioctyl sulfosuccinate. The surface active properties were calculated and the micellization process of the mixture was investigated. The molar ratio of anionic (SDOSS) and anionic–nonionic surfactant moieties [E(14)SMOSS, E(14)SMLSS, and E(14)SMCSS] in the mixed aggregates were deduced using the regular solution approximation equations. Depending on the critical micelle concentration values measured for each surfactant individually, and as well as the mixed systems, the minimum surface tension was exhibited at a ratio of 0.6 SDOSS:0.4 E(14)SMCSS. The micellar composition of the mixed aggregates were explained and discussed based on the effect of their chemical structures. The activity coefficient (f ₁, f ₂), interaction parameter (β), and ideality of anionic–nonionic mixed aggregates were evaluated.

Solubilization of phosphatidylcholine unilamellar liposomes caused by alkyl glucosides

Solubilizing alterations caused by a series of alkyl glucosides (alkyl chain lengths ranging from C₈ to C₁₂) in phosphatidylcholine (PC) unilamellar liposomes were investigated. Surfactant-to-phospholipid molar ratios (Re) and bilayer/aqueous phase partition coefficients (K) were determined by monitoring changes in static light scattering (SLS) of the system during solubilization. At the two interaction levels investigated (surfactant concentrations producing SLS values of 100 and 0% for each surfactant/PC system studied) the free surfactant concentration for each surfactant was always comparable to its critical micelle concentration (CMC). This indicates that liposome solubilization was mainly ruled by mixed micelle formation. A rise in CMC (or decrease in the surfactant alkyl chain length) resulted in an increase in the ability of these surfactants to saturate or solubilize PC liposomes and, inversely, in an abrupt decrease in their affinity with these bilayer structures. The overall balance of these opposite tendencies shows that the octyl glucoside had the highest ability to saturate and solubilize liposomes (lowest Re values), whereas the dodecyl glucoside exhibited the highest degree of partitioning into liposomes or affinity with bilayer structures (highest K values). From a practical viewpoint, the use of nonyl glucoside reduced approximately 2.5 times the concentration needed to saturate and solubilize 1.0 mM PC liposomes with respect to that needed using the conventional octyl glucoside.     

清洗剂用烷基糖苷及其衍生物的研究进展

清洗剂在生产生活中具有重要作用,烷基糖苷(APG)作为新型绿色表面活性剂,具有表面活性高、去污力强、生态毒性低及可生物降解等优点,是用于清洗剂的理想表面活性剂.但长烷基链APG水溶性和抗硬水能力差,限制了其应用范围.APG糖环上的羟基可与多种基团连接生成性能更加优异的衍生物,这些衍生物在克服糖苷缺点的同时又具有各自不同...     

表面活性剂与钕离子对金属表面化学镀镍磷的影响

采用紫外-可见分光光度计,研究了固定工艺条件下十二烷基二甲基甜菜碱(BS-12)与琥珀酸二(2-乙基己基)酯磺酸钠(SDOS)两种表面活性剂及钕离子对金属表面化学镀镍磷的影响,得到较佳的工艺条件:SDOS与BS-12摩尔比为1:1,Ni~(2+)与H_2PO_2-摩尔比为0.3,pH=8,70℃施镀并添加适量的硫酸钕.探讨了表面活性剂的作用机制.结果表明,在固定的基础镀液中加入SDOS与BS-12混合表面活性剂,镀液会产生明显的温度效应和很强的协同效应,其镀速的增加比相应的单一表面活性剂所产生的增幅要大;加入稀土金属钕离子后,镀速下降,但镀层质量得到改善.     

页岩抑制剂阳离子烷基糖苷的合成——醚化反应条件探究

为解决烷基糖苷钻井液在现场应用过程中出现的井壁失稳情况,中国石化集团中原油田开展了新型页岩抑制剂阳离子烷基糖苷的研制。对阳离子烷基糖苷合成过程中醚化反应条件进行了考察。考察了环氧氯丙烷与烷基糖苷物质的量比、醚化反应时间、醚化反应温度、烷基糖苷加料方式等对合成产品性能的影响,得出醚化反应最优化反应条件为：环氧氯丙烷与烷基糖苷物质的量比为1：1．5、醚化反应时间2．Oh、醚化反应温度86℃、烷基糖苷0．5h内分2次加入。本研究为得到抑制性能优良的钻井液用阳离子烷基糖苷打下了良好的基础。