Tribological Behavior of NiAl–1.5 wt% Graphene Composite Under Different Velocities

The progress in aerospace field requires a new NiAl matrix composite that can stand against wear and decrease the energy dissipation through decreasing friction. In this study, the tribological behavior of NiAl–1.5 wt% graphene composite is investigated at room temperature under a constant load of 12 N and different sliding velocities. The results show that the friction coefficient and wear rate increase with increasing sliding velocity from 0.2 to 0.4 m/s due to the adhesion between the sliding bodies and tearing of the graphene layer. The friction coefficient and wear rate tend to decrease at a sliding velocity of 0.6 m/s as a result of severe plastic deformation and grain refinement of the worn surface. However, at 0.8 m/s the friction coefficient reaches a minimum value and the wear rate increases and changes the wear mechanism to fatigue wear. It can be concluded that various wear mechanisms lead to different tribological performance of NiAl–1.5 wt% graphene composite.     

The Influence of the Matrix Microstructure on Abrasive Wear Resistance of Heat-Treated Fe–32Cr–4.5C wt% Hardfacing Alloy

The abrasion wear resistance of Fe–32Cr–4.5C wt% hardfacing alloy was investigated as a function of matrix microstructure. In this study, the alloy was deposited on ASTM A36 carbon steel plates by the shielded metal arc welding (SMAW) process and the as-welded matrix microstructure was changed into ferrite, martensite, and tempered martensite by heat treatment processes. The Pin-on-disk test results show that under low (5 N) and high (20 N) load conditions, the wear resistance behavior of the as-welded matrix sample is 20 and 15% higher, respectively, than the martensitic matrix sample, although the bulk hardness of the as-welded matrix is 5% lower. The ferritic matrix sample has the poorest wear resistance behavior which is less than half of that of the as-welded matrix one. Micro-ploughing, micro-cutting, and micro-cracking are recognized as the micro-mechanisms in the material removal in which the proportion of micro-ploughing mechanism increased by increasing matrix toughness.     

Tribological Behavior of 1.41 wt% C Ultrahigh-carbon Steel With Quenching and Low-temperature Tempering Treatment

The tribological behavior of 1.41 wt% C ultrahigh-carbon steel (UHCS-1.41C) was investigated in comparison with a GCr15 bearing steel with a pin-on-disk and a two-disk tribometer at varying applied loads in ambient conditions. The wear surfaces of the specimens were examined with an optical microscope, EDX, and SEM. The retained austenite was measured by XRD. The results show that the friction coefficient of UHCS-1.41C is higher than that of GCr15 at a low load (6 N); however, it becomes lower than that of GCr15 at higher loads (10 N, 20 N). The wear rate of UHCS-1.41C is always lower than that of GCr15 according to the results of the two-disk test. UHCS-1.41C exhibits a stronger work hardening ability, which results in a higher resistance to wear than that of GCr15 during the two-disk test.     

Effect of counterface balls on the friction layer of Ni3Al matrix composites with 1.5 wt% graphene nanoplatelets

Research on the friction layer is needed to minimize friction- and wear-related mechanical failures in moving mechanical assemblies. Dry sliding tribological tests of Ni₃Al matrix composites (NMCs) with 1.5 wt% graphene nanoplatelets (GNPs) sliding against different counterface balls are undertaken at the condition of 10 N–0.234 m s^?1 in this study. When sliding against GCr15 steel, a uniform and thick friction layer is formed, resulting in a lower friction coefficient (0.29–0.31) and wear rate (2.0–3.1 × 10^?5 mm³ N^?1 m^?1). While sliding against Al₂O₃ and Si₃N₄, the formation and stability of the friction layers are restricted in the severe wear regime, and the NMCs exhibit higher friction coefficients and wear rates. Therefore, various counterface balls have a great effect on the stability and thickness of the friction layer, thus affecting the tribology performance of NMCs. The result also shows that GNPs exhibit enrichment and self-organized microstructures in the friction layer. In addition, the friction layer is also found to be divided into two layers, protecting the subsurface from further damage and reducing shear.     

Optimum selection of abrasive flow machining conditions during fine finishing of Al/15 wt% SiC-MMC using Taguchi method

Abrasive flow machining (AFM) is gaining widespread application finishing process on difficult to reach surfaces in aviation, automobile, and tooling industry. Al/SiC_p-MMC is a promising material in these industries. Here, AFM has been used to finish conventionally machined cylindrical surface of Al/15 wt% SiC_p-MMC workpiece. This paper presents the utilization of robust design-based Taguchi method for optimization of AFM parameters. The influences of AFM process parameters on surface finish and material removal have been analyzed. Taguchi experimental design concept, L₁₈ (6¹?×?3⁷) mixed orthogonal array is used to determine the S/N ratio and optimize the AFM process parameters. Analysis of variance and F test values also indicates the significant AFM parameters affecting the finishing performance. The mathematical models for R _a, R _t, ΔR _a, and ΔR _t and material removal are established to investigate the influence of AFM parameters. Conformation test results verify the effectiveness of these models and optimal parametric combination within the considered range. Scanning electron micrographs testifies the effectiveness of AFM process in fine finishing of Al/15 wt% SiC_p-MMC.     

Mechanical and tribological properties of Cr–Nb double-glow plasma coatings deposited on Ti–Al alloy

Double-glow plasma (DGP) coatings are recommended for metallic components to mitigate the damage induced by complex working conditions in previous studies. In this paper, Nb-rich (Cr–Nb₄) and Cr-rich (Cr₄–Nb) -alloyed layers were formed onto the Ti–Al substrate via a DGP process to enhance its wear resistance. Scratch and Nano-indentation tests were used to evaluate the mechanical properties of the coatings. The tribological behaviour of the coatings were investigated using a pin-on-disc tribometer by rubbing against the GCr15 ball. Results from surface analysis techniques showed that the coatings mainly comprised Cr, Nb and Cr₂–Nb phases, and were well bonded to the substrate. The hardness of the Cr–Nb₄ coating was 11.61GPa and the Cr₄–Nb coating was 9.66 GPa which all higher than that of the uncoated Ti–Al which was 5.65 GPa. However, the critical load of the Cr₄–Nb coating ~21.64 was higher than that of the Cr–Nb₄ coating ~17.6. And the specific wear rate of Cr–Nb₄ coating, Cr₄–Nb coating and uncoated Ti–Al were 3.54 × 10^?4, 0.01 × 10^?4 and 1.53 × 10^?4mm³ N^?1 m^?1_, respectively. The low-wear mechanism of the coatings is discussed in detail in this paper.     

Transmission Electron Microscopy Analysis of Mo–W–S–Se Film Sliding Contact Obtained by Using Focused Ion Beam Microscope and In Situ Microtribometer

To better understand the fundamentals of solid lubrication, microstructural analyses on the wear scar surface and contact interface of Mo–W–S–Se composite films produced by pulsed laser deposition were completed. Focused ion beam (FIB), transmission electron microscopy (TEM), and X-ray energy dispersive spectroscopy were employed to study the cross-sectional microstructure and chemistry of wear scars. In particular, a novel microtribometer was built for in situ tribological measurements within a FIB microscope. The sliding tip was welded in contact to the wear scar surface on the film under load by re-deposition of sputtering materials from the FIB cut of the tip. Using this technique, cross-sectional TEM specimens were prepared precisely at the contact point without tip/film separation. Here, the in situ FIB microtribometer is critically important for retaining the microstructure of lubricant films as formed at the sliding contact interface between the tip and film without separation. It provides the unique ability to stop sliding, section the contact, and reveal microstructural changes to that contact without disrupting the sliding interface. The cross-sectional TEM measurements were performed on the sliding contact interface for both the regions in contact and just past contact, and both the reorientation and recrystallization of lubricant films were revealed.     

Comparative study of the tribological behavior of self-lubricating W–S–C and Mo–Se–C sputtered coatings

Transition metal dichalcogenides (TMD) have been one of the best alternatives as low friction coatings for tribological applications, particularly in dry and vacuum environments. However, besides their deficient behavior in humid containing atmospheres, their extensive application has also been restricted due to their low load-bearing capacity. In order to overcome these problems, recently the alloying with C has been tried with the expectation of simultaneously improving the coatings hardness and reaching sliding contacting phases more convenient for achieving low friction in humid environments.The practical application of this concept was extensively studied with the W–S–C system, with the C addition being achieved either by reactive or co-sputtering processes. The best tribological results were obtained by co-sputtering from a C target embedded with an increasing number of WS₂ pellets. Excellent results were reached from the more than one order of magnitude increase in the coatings hardness up to friction coefficients which are close to those of the references of self-lubricating coatings: TMD for dry or vacuum atmospheres or C-based coatings for terrestrial sliding conditions.Following the good results achieved with W–S–C system, other TMDs systems have been envisaged to be studied. The main focus was placed on the Mo–Se–C system.In this paper, the general comparison between W–S–C and Mo–Se–C coatings is presented. The main effort is pointed on the tribological behavior of both systems when tested by pin-on-disk against steel counterpart balls under different testing conditions: applied normal loads, temperatures and relative humidity of the atmospheres. Both coatings were deposited by co-sputtering from a C target with a varying number of TMD pellets which could lead to C contents in the films in the range from 30  up to 70 at.%. A Ti interlayer was interposed between the films and the substrates for improving the adhesion.Typically, W–S–C films are harder than Mo–Se–C films. From the tribological point of view, W–S–C films are more thermally stable than Mo–Se–C films although the friction coefficients of these last ones are lower when tested in humid containing atmospheres.     

Relations of counterface materials with stability of tribo-oxide layer and wear behavior of Ti–6.5Al–3.5Mo–1.5Zr–0.3Si alloy

Dry sliding wear tests of Ti–6.5Al–3.5Mo–1.5Zr–0.3Si alloy (TC11 alloy) sliding against AISI 52100 and AISI M2 steels were performed under the load of 50–250 N at 25–600 °C. For two kinds of counterface materials, the titanium alloy presented totally different wear behaviours as the function of temperature. The appreciable variations of the titanium alloy sliding against different counterface materials were attributed the fact that a hard counterface caused unstable existence of tribo-layers by its microcutting action, thus resulting in the increase of wear rate. It is suggested that the hard counterface must be avoided as the counterface for the titanium alloy/steel sliding system.     

Cavitation erosion of Fe–Mn–Si–Cr shape memory alloys

Cavitation erosion tests of three Fe–Mn–Si–Cr shape memory alloys were carried out at speed 34 and 45 m/s using a rotating disc rig, and their cavitation damage has been investigated by comparison with a referring 13Cr–5Ni–Mo stainless steel used for hydraulic turbine vanes. The research results proved that the cavitation erosion of the Fe–Mn–Si–Cr shape memory alloys is a failure of low cycle fatigue and fracture propagates along grain boundaries. After 48 h cavitation erosion the cumulative mass losses of the studied alloys at speed 45 m/s are more than theirs at speed 34 m/s; however, the effect of velocity on cavitation damage of the Fe–Mn–Si–Cr alloys is much lower than that of 13Cr–5Ni–Mo stainless steel. The cumulative mass loss of the 13Cr–5Ni–Mo stainless steel are 26.3 mg at speed 45 m/s and 3.2 mg at speed 34 m/s, and the mass losses of the Fe–Mn–Si–Cr alloys are within the range of 3.6–7.3 mg at speed 45 m/s and 2.0–4.1 mg at speed 34 m/s. The surface elasticity of the Fe–Mn–Si–Cr shape memory alloys is better than that of the 13Cr–5Ni–Mo stainless steel, and the effect of surface elasticity on cavitation damage increases with velocity. The excellent surface elasticity of the cavitation-induced hexagonal closed-packed (h.c.p.) martensite plays a key role in contribution of phase transformation to the cavitation erosion resistance of the Fe–Mn–Si–Cr shape memory alloys. The cavitation damage of the studied alloys at speed 45 m/s mainly depends on their surface elasticity, and the variation of 48 h cumulative mass loss (Δm) as a function of the elastic depth (h_e) can be expressed as Δm=2.695+[1371.94/(4(h_e−46.83)²+12.751)] with a correlation factor of 0.99345.     

EDM of hybrid Al–SiCp–B4Cp and Al–SiCp–Glassp MMCs

Hybrid metal matrix composites are a class of material system, with two or more discrete particulate reinforcement. Notwithstanding their superior properties, their widespread application is constrained by the difficulty in machining them. Non-conventional processes such as electrical discharge machining can be applied to machine such composites. This work reports on the application of EDM to machine cast aluminum–silicon carbide–boron carbide and cast aluminum–silicon carbide–glass hybrid metal matrix composites and how the metal removal rate and surface finish vary in response to the various EDM parameters     

Evaluation of performance of nanofluid using multiwalled carbon nanotubes for machining of Ti–6AL–4V

Machining of titanium alloys generate very high temperature in the cutting zone. This results in rapid tool wear and poor surface properties. Therefore, improvement in cutting performance in machining of titanium alloys is very much dependent on effectiveness of the cooling strategies applied. In the present work, performance of nanofluid using multiwalled carbon nanotubes (MWCNTs) dispersed in distilled water and sodium dodecyl sulfate (SDS) as surfactant is evaluated for turning operation on Ti–6Al–4V workpieces. Turning operations were carried out under three different conditions – dry, with conventional cutting fluid and with nanofluid. Nanofluid application was limited to 1 L/h and it was applied at the tool tip through gravity feed. Various machining responses like cutting force, surface finish and tool wear were analyzed while turning at optimum cutting parameters as 150 m/min, 0.1 mm/rev and 1 mm depth of cut. Later on, machining performance of nanofluid is confirmed at low cutting speed of 90 m/min. Nanofluid outperformed conventional cutting fluid with 34% reduction in tool wear, average 28% drop in cutting forces and 7% decrease in surface roughness at cutting speed of 150 m/min.     

Analysis of Fretting Fatigue of Cavitation Shotless Peened Ti–6Al–4V

Fretting fatigue behavior of cavitation shotless peened titanium alloy, Ti–6Al–4V coupons was investigated using finite element method and a critical plane-based multi-axial fatigue parameter. Cavitation shotless peening (CSP)-induced compressive residual stress, which was larger at the contact surface than its counterpart from the shot peening (SP). However, compressive residual stress decreased more sharply with distance from the contact surface in CSP than in SP. Analysis using a critical plane-based multi-axial fatigue parameter demonstrated that the crack initiation would occur inside the cavitation shotless peened specimen which matched with the experimental observations. On the other hand, crack initiation would occur on the contact surface in the shot peened specimen which again was in agreement with experiments. The analysis also showed that the crack propagation part of the total fretting fatigue life was longer in the shot peened specimen than in the cavitation shotless peened specimen while the crack initiation part was almost equal from both peening methods. Therefore, CSP could not improve the fretting fatigue life/strength as much as the SP did but it improved relative to the un-peened specimen.     

Stress–Strain State of Welds

Russian Engineering Research - A method is proposed for analysis of the stress–strain state of welds in large rolling-stock components, using SolidWorks/Simulation software.     

Influence of Parameters of Reactive Magnetron Sputtering on Tribomechanical Properties of Protective Nanostructured Ti–Al–N Coatings

The influence of substrate temperature and bias voltage on the structure and tribomechanical properties of the Ti–Al–N coatings obtained by reactive magnetron sputtering technique has been investigated. The structure and elemental and phase compositions have been studied by scanning electron microscopy, Rutherford backscattering, and X-Ray diffraction. The results of friction and wear experiments indicated that the lowest coefficient of friction (three times lower than 12Cr18Ni10Ti) corresponded to a coating deposited at a bias voltage of–200 V and a substrate temperature of 340°С, while the most wear-resistant coating (under a load of 700 mN and the testing time of 1080 s) was Ti–Al–N sputtered at a bias voltage of–200 V and a substrate temperature of 440°С.     

Influence of plasma nitriding on fretting wear behaviour of Ti–6Al–4V

Plasma nitriding was performed on Ti–6Al–4V samples at 520 °C in two environments (pure nitrogen and a mixture of nitrogen and hydrogen in the ratio of 3:1) for two different time periods (4 and 18 h). Fretting wear tests were conducted on unnitrided and nitrided samples for 50,000 cycles using alumina ball counterbody. Plasma nitriding reduced the tangential force coefficient of Ti–6Al–4V. The samples nitrided for 4 h exhibited higher hardness and lower tangential force coefficient compared to the specimens nitrided for 18 h. The samples nitrided in nitrogen–hydrogen mixture environment exhibited higher hardness and lower tangential force coefficient compared to the specimens nitrided in pure nitrogen. The samples plasma nitrided in nitrogen–hydrogen mixture for 4 h exhibited the highest hardness and the lowest tangential force coefficient. The wear volume and specific wear rate of the plasma nitrided samples were lower than those of the unnitrided samples. A consistent trend was not observed regarding which nitriding condition would result in lower wear volume and specific wear rate at different loads.     

Determination of a Mobile-Ion Concentration in the Dielectric Films of Metal–Insulator–Semiconductor Structures

An experimental technique for determining the surface concentration N _Sof mobile ions in dielectric films of metal–insulator–semiconductor (MIS) structures is described. The technique is based on synchronous recording of the dynamic volt–ampere and low-frequency capacity–voltage characteristics of a sample under investigation. These experimental dependences are shown to ensure accurate extraction of the ion current peaks whose areas are proportional to N _S. These characteristics also allow the relaxation of the surface semiconductor potential to be found, which is needed for reconstructing the dependence of the convection ion current on the voltage drop across the insulation gap of the MIS capacitor. A comparative analysis with other known methods for determining N _Sis carried out. The proposed technique helps find a mobile-ion concentration from a 5 × 10⁹to 10¹³-cm^–2range, including the case when ion current peaks do not appear on the current–voltage characteristics.     

Effect of Micro-scale Y Addition on the Fracture Properties of Al–Cu–Mn Alloy

Rare earth (RE) elements have positive effects on Al alloy, while most research is focused on microstructure and mechanical properties. As important application indices, toughness and plasticity are properties that are sensitive to alloy fracture characteristics, and few research studies have characterized the fracture properties of Al–Cu–Mn alloy on RE elements. The effect of different contents of Y on the fracture properties of Al–Cu–Mn alloy is investigated. T6 heat treatment (solid solution and artificial aging treatment), optical microscope (OM), scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS) methods are applied to the alloy. Results showed that when Y element is present at 0.1%, the section of the as-cast alloy has smaller sized dimples and the fracture mode presents ductile features. Slight changes in hardness are also observed and maintained at about 60 HV. With increasing content of the RE element Y from 0.1 to 0.5%, the θ phase and Cu atoms in the matrix were reduced and most stopped at Grain boundaries (GBs). Micro-segregation and an enriched zone of Y near the GBs gradually increased. At the same time, the inter-metallic compound AlCuY is aggregated at grain junctions causing deterioration of the micro-structure and fracture properties of the alloy. After T6 treatment, the flatness of the fracture surface was lower than that of all the as-cast alloy showing lots of dimples and teared edges with a significant increase in hardness. When Y content was 0.1%, the strength and hardness of the alloy increased due to refinement of the grain strengthening effect. The content of Y elements segregated in the inter-dendritic zone and GBs is reduced. Plasticity and deformation compatibility also improved, making cracks difficult to form and merge with each other along adjacent grain junctions and providing an increased potential for ductile fracture. This paper proposes the addition of RE Y as an effective and prospective strategy to improve the fracture properties of the Al–Cu–Mn alloy and provide a meaningful reference in terms of improving overall performance.     

Investigation of Electrical Characteristics of Thin Silicone–Carbon Coatings

The complex resistance of silicone–carbon films of thickness more than 3 m is measured on the basis of an analysis of the electrotechnical substitution circuit containing a capacitor and a resistor. It was found that the parameters of the equivalent circuit determined experimentally make it possible to estimate whether the film thickness is greater than 3 m or not, i.e., to measure the film thickness more than 3 m. In this case, at frequencies higher that 100 kHz only the capacitive component of the impedance can be measured, whereas the active component associated most likely with the presence of silicon carbide in the film material was detected at lower frequencies. It is shown that for carrying out similar experiments with thinner coatings it is necessary to use a probe covered by a dielectric material with the higher dielectric constant.     

Selective laser melting W–10 wt.% Cu composite powders

Tungsten–Copper (W–Cu) alloys are promising materials for electrical and thermal applications. However, its forming method still remains limited in conventional powder metallurgy technique which is not suitable for manufacturing parts with intricate shapes. In this work, selective laser melting technology was introduced for fabricating W–10 wt.% Cu alloys parts. The morphological feature of a single molten track was analyzed. The results show that liquid phase sintering with complete melting of the binder (Cu), but nonmelting of the structural metal (W), acts as the main mechanism in this process. The melting conditions of single layers in different processing parameters were investigated. The results show that a moderate melting zone can be acquired from an established process map. Moreover, investigations on multilayers forming show that the final density increases with the decrease of scan speed until it reaches a plateau due to the insufficient rearrangement in liquid phase sintering and the balling effect.